JP2006176781A - ポリマー添加剤およびこれらの添加剤を含む接着剤組成物 - Google Patents
ポリマー添加剤およびこれらの添加剤を含む接着剤組成物 Download PDFInfo
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- JP2006176781A JP2006176781A JP2005369673A JP2005369673A JP2006176781A JP 2006176781 A JP2006176781 A JP 2006176781A JP 2005369673 A JP2005369673 A JP 2005369673A JP 2005369673 A JP2005369673 A JP 2005369673A JP 2006176781 A JP2006176781 A JP 2006176781A
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- polymer
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- aqueous
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- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
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- XZHNPVKXBNDGJD-UHFFFAOYSA-N tetradecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C=C XZHNPVKXBNDGJD-UHFFFAOYSA-N 0.000 description 1
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- 229960002447 thiram Drugs 0.000 description 1
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- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
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- 239000000080 wetting agent Substances 0.000 description 1
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- 239000002023 wood Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- BIDDLDNGQCUOJQ-SDNWHVSQSA-N α-phenylcinnamic acid Chemical compound C=1C=CC=CC=1/C(C(=O)O)=C\C1=CC=CC=C1 BIDDLDNGQCUOJQ-SDNWHVSQSA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
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- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
【解決手段】新規なポリマー添加剤が開示され、この添加剤は、水性アクリルエマルションポリマー(共重合単位として、0.25重量%から99.75重量%までのモノエチレン性不飽和非イオン性C1−C10(メタ)アクリルモノマー、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および0.25重量%から10重量%までのモノエチレン性不飽和酸モノマーを含む)を含み、前記水性エマルションポリマーは−100℃〜100℃までのTg、1,000から40,000までの重量平均分子量を有する。他のポリマー添加剤に比べ、粘着性、接着力、可塑性および剥離強度、ならびに水白化抵抗性の改善されたバランスを有する。
【選択図】なし
Description
比較用のポリマー添加剤を米国特許第4,912,169号(実施例I−XXI)および第6,300,407号(実施例4−8)に記載されている通りに調製した。更に、低MwのpBAおよび低MwのpEHAを比較用の可塑剤として使用した。他の比較例は、商業的に入手可能な従来の粘着付与剤および可塑剤を含んだ。商業的な粘着付与性樹脂であるTackolyn(商標)を組成物に加えた点を除き、接着剤組成物を調製した。Harwick(Akron、Ohio)から入手可能な天然樹脂コールタール誘導可塑剤である20PHRのNatrorez(商標)25を組成物に加えた点を除き、エラストマー組成物を調製した。硬化されたエラストマー材料を用いて、DMTAによるTg、ショアA硬度、100%伸張、伸張@破断%、引張強さ、およびダイCティア(Die C Tear)を測定した。
先行する実施例で調製されたポリマー添加剤を、アクリル酸ブチルをベースとしたエマルション接着剤において、接着力特性について試験した。これらの乳化重合されたポリマー添加剤を28%の水酸化アンモニウム水溶液で処理し、pHを9にした。次いで、上述の各エマルションを様々なレベルでアクリルエマルション接着剤と混合し、水酸化アンモニウム溶液を加えることによりpHを9に調節した。次いで、これらの接着剤−添加剤の混合物を、アセトンで拭いたポリエチレンテレフタレートシートにコーティングし、105℃で5分間乾燥させた(または、指示されている場合には、二軸方向に延伸された未処理のポリプロピレンにコーティングし、70℃で15分間乾燥させた)。乾燥させた接着剤フィルムの厚みは0.001インチであった。次いで、これらのコーティングされたシートを未処理のポリプロピレンカバーシートにラミネート化した。このラミネートを幅1インチのストリップ状に切断し、試験する前に、少なくとも24時間、温度25℃および相対湿度50%でコンディショニングした。
E=完全な透明性を伴う優れたフィルム品質
VG=非常に僅かな曇りしかない非常に良好なフィルム品質
G=僅かな曇りを伴う良好なフィルム品質
F=中等度の曇りを伴う適正なフィルム品質
P=ひどい曇りを伴う劣質なフィルム品質
Claims (6)
- ポリマー添加剤であって、当該添加剤が水性アクリルエマルションポリマーを含み、該水性アクリルエマルションポリマーは、更に、共重合単位として、乾燥ポリマー重量に基づき、0.25重量%から99.75重量%までのモノエチレン性不飽和非イオン性C1−C10(メタ)アクリルモノマー、乾燥ポリマー重量に基づき、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および、乾燥ポリマー重量に基づき、0.25重量%から10重量%までのモノエチレン性不飽和酸モノマーを含んでおり;当該水性エマルションポリマーが、−100℃から100℃までのTgを有し、且つ、1,000から40,000の間の重量平均分子量を有する、ポリマー添加剤。
- 接着剤組成物であって、当該組成物が:
(a)水性アクリルエマルションポリマーから調製された1以上のポリマー添加剤を、乾燥重量ベースで0.5%から約55%と、
ここで該水性アクリルエマルションポリマーは、更に、共重合単位として、乾燥ポリマー重量に基づき、0.25重量%から99.75重量%までのモノエチレン性不飽和非イオン性C1−C10(メタ)アクリルモノマー、乾燥ポリマー重量に基づき、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および、乾燥ポリマー重量に基づき、0.25重量%から10重量%までのモノエチレン性不飽和酸モノマーを含んでおり;当該水性エマルションポリマーは、−100℃から100℃までのTgを有し、且つ、1,000から40,000の間の重量平均分子量を有している;並びに、
スチレン、ブタジエン、アクリロニトリル、エチレン、酢酸ビニル、アクリル酸、アクリル酸のエステル、メタクリル酸およびメタクリル酸のエステルからなる群から選択される1以上のモノマーから調製された1以上の接着剤ポリマーまたはコポリマーと
を含む、接着剤組成物。 - (a)スチレン、ブタジエン、アクリロニトリル、エチレン、酢酸ビニル、アクリル酸、アクリル酸のエステル、メタクリル酸およびメタクリル酸のエステルからなる群から選択される1以上のモノマーから調製された1以上の接着剤ポリマーまたはコポリマーと、(b)乾燥重量ベースで0.5%から約55%までの1以上のポリマー添加剤との混合物を含む接着剤組成物であって、
ここで、ポリマー添加剤が水性アクリルエマルションポリマーを含み、該水性アクリルエマルションポリマーが、更に、共重合単位として、乾燥ポリマー重量に基づき、0.25重量%から99.75重量%までのモノエチレン性不飽和非イオン性(メタ)アクリルモノマー、乾燥ポリマー重量に基づき、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および、乾燥ポリマー重量に基づき、0.25重量%から10重量%までのモノエチレン性不飽和酸モノマーを含んでおり;ポリマー添加剤が、−100℃から100℃までのTgを有し、且つ、1,000から40,000の間の重量平均分子量を有する、接着剤組成物。 - 多機能性ポリマー添加剤であって、当該添加剤が水性アクリルエマルションポリマーを含み、該水性アクリルエマルションポリマーが、更に、共重合単位として、乾燥ポリマー重量に基づき、0.25重量%から99.75重量%までのモノエチレン性不飽和非イオン性(メタ)アクリルモノマー、乾燥ポリマー重量に基づき、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および、乾燥ポリマー重量に基づき、0.25重量%から10重量%までのモノエチレン性不飽和酸モノマーを含んでおり;前記水性エマルションポリマーが、−100℃から100℃までのTgを有し、且つ、1,000から40,000の間の重量平均分子量を有しており;ここで、当該ポリマー添加剤が水性エマルションポリマーを安定化させ、粘着性を付与し、可塑化することにより、該水性エマルションポリマーを改質する、多機能性ポリマー添加剤。
- 添加剤であって、当該添加剤が水性アクリルエマルションポリマーを含み、該水性アクリルエマルションポリマーは、更に、共重合単位として、乾燥ポリマー重量に基づき、0.25重量%から99.75重量%までの1以上のモノエチレン性不飽和非イオン性C10−C50(メタ)アクリルモノマー、乾燥ポリマー重量に基づき、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および、乾燥ポリマー重量に基づき、0.25重量%から10重量%までの1以上のモノエチレン性不飽和酸モノマーを含んでおり;当該ポリマー添加剤が、−100℃から100℃までのTgを有し、且つ、500から50,000の間の重量平均分子量を有する、添加剤。
- エラストマーであって、当該エラストマーが:
(a)水性アクリルエマルションポリマーから調製された1以上のポリマー添加剤を、乾燥重量ベースで0.5%から約55%と、
ここで当該水性アクリルエマルションポリマーは、更に、共重合単位として、乾燥ポリマー重量に基づき、0.25重量%から99.75重量%までのモノエチレン性不飽和非イオン性C10−C50(メタ)アクリルモノマー、乾燥ポリマー重量に基づき、0.40重量%から99.75重量%までの1以上のエチレン性不飽和界面活性剤モノマー、および、乾燥ポリマー重量に基づき、0.25重量%から10重量%までのモノエチレン性不飽和酸モノマーを含んでおり;当該水性エマルションポリマーが、−100℃から100℃までのTgを有し、且つ、1,000から40,000の間の重量平均分子量を有している;並びに、
スチレン、ブタジエン、アクリロニトリル、エチレン、酢酸ビニル、アクリル酸、アクリル酸のエステル、メタクリル酸およびメタクリル酸のエステルからなる群から選択される1以上のモノマーから調製された1以上の接着剤ポリマーまたはコポリマーと
を含む、エラストマー。
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JP2009191106A (ja) * | 2008-02-12 | 2009-08-27 | Lintec Corp | 粘着剤組成物及び粘着シート |
KR20130108108A (ko) * | 2012-03-23 | 2013-10-02 | 디아이씨 가부시끼가이샤 | 점착 부여제, 수성 점착제 및 점착 시트 |
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JP2009191106A (ja) * | 2008-02-12 | 2009-08-27 | Lintec Corp | 粘着剤組成物及び粘着シート |
KR20130108108A (ko) * | 2012-03-23 | 2013-10-02 | 디아이씨 가부시끼가이샤 | 점착 부여제, 수성 점착제 및 점착 시트 |
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JP2014062211A (ja) * | 2012-09-24 | 2014-04-10 | Dic Corp | 水性粘着剤及び粘着シート |
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EP1674481A1 (en) | 2006-06-28 |
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