JP2005525690A - Phase change memory with higher pore position - Google Patents
Phase change memory with higher pore position Download PDFInfo
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- H10N70/20—Multistable switching devices, e.g. memristors
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- H10N70/881—Switching materials
- H10N70/882—Compounds of sulfur, selenium or tellurium, e.g. chalcogenides
- H10N70/8828—Tellurides, e.g. GeSbTe
Abstract
ポアの位置を高くした相変化型メモリセル(10)は、相変化型メモリコンポーネントの製造プロセスを半導体基板(12)の他の部分と物理的に分離することにより相変化型メモリの製造を容易にする。本発明の実施の一態様として、半導体基板(12)内にあるコンタクト(16)は、絶縁体(20)により充填されたカップ状導体(18)と電気的に結合している。カップ状導体(18)は高い位置に設けられたポアまで電流を導くが、絶縁体(20)は熱的に電気的にポアを絶縁する役割を果たす。The phase change memory cell (10) with a higher pore position facilitates the manufacture of the phase change memory by physically separating the manufacturing process of the phase change memory component from the rest of the semiconductor substrate (12). To. As one embodiment of the present invention, the contact (16) in the semiconductor substrate (12) is electrically coupled to the cup-shaped conductor (18) filled with the insulator (20). The cup-shaped conductor (18) conducts current to a pore provided at a high position, while the insulator (20) plays a role of thermally and electrically insulating the pore.
Description
本発明は、一般的に、相変化材(phase-change materials)を使用するメモリに関する。 The present invention relates generally to memories that use phase-change materials.
相変化材は少なくとも2つの異なる状態を呈することがある。それらの状態はアモルファス(非結晶)状態と結晶状態と呼ばれることがある。これらの状態間の転移は温度変化に応じて選択的に引き起こされる場合がある。アモルファス状態は一般的に結晶状態よりも電気抵抗率が高いために、これらの状態は区別が可能である。アモルファス状態はより無秩序な原子構造を有し、結晶状態はより規則正しく配列した原子構造を有する。一般的に、どのような相変化材も利用することができる。場合によっては、薄膜カルコゲニド(chalcogenide)合金材料が特に適することがある。 The phase change material can exhibit at least two different states. These states are sometimes called an amorphous (non-crystalline) state and a crystalline state. The transition between these states may be selectively triggered in response to temperature changes. Since the amorphous state generally has a higher electrical resistivity than the crystalline state, these states can be distinguished. The amorphous state has a more disordered atomic structure, and the crystalline state has a more ordered atomic structure. In general, any phase change material can be utilized. In some cases, thin film chalcogenide alloy materials may be particularly suitable.
相変化は可逆的に引き起こされる場合がある。従って、メモリはアモルファス状態から結晶状態に変化し、またアモルファス状態に戻ることが可能であり、その逆の過程も起きる場合がある。要するに、各メモリセルは、高抵抗状態と低抵抗状態との間を可逆的に変化するプログラマブル抵抗器と考えることができる。 Phase changes may be caused reversibly. Accordingly, the memory can change from the amorphous state to the crystalline state and return to the amorphous state, and vice versa. In short, each memory cell can be thought of as a programmable resistor that reversibly changes between a high resistance state and a low resistance state.
状況によっては、メモリセルは多数の状態を有することがある。このとき、各状態は電気抵抗によって区別できるので、多数の電気抵抗によって決まる状態が実現可能であり、それにより複数ビットのデータを単一セルに記憶することが可能となる。 In some situations, a memory cell can have multiple states. At this time, since each state can be distinguished by electric resistance, a state determined by a large number of electric resistances can be realized, and thereby, a plurality of bits of data can be stored in a single cell.
様々な相変化合金が知られている。一般的に、カルコゲニド合金は、周期表VI族に属する1つ以上の元素を含みうる。特に適した一群の合金としてはGeSbTe合金がある。 Various phase change alloys are known. In general, chalcogenide alloys can include one or more elements belonging to Group VI of the periodic table. A particularly suitable group of alloys is GeSbTe alloys.
相変化材は、誘電材料を貫通する通路(passage)またはポア(pore:微細孔)の内側に形成される場合がある。相変化材は、通路のどちらか一方の端部においてコンタクト(contact)に結合されることがある。状態の転移は電流を流して相変化材を加熱することにより引き起こされることがある。 The phase change material may be formed inside a passage or pore through the dielectric material. The phase change material may be coupled to a contact at either end of the passage. The state transition may be caused by heating the phase change material by passing an electric current.
アクセスデバイスが、半導体集積回路基板内にその上に積層する相変化材を活性化するために設けられることがある。他の相変化型メモリコンポーネントも半導体基板内に一体化されることがある。集積回路配置構造(integrated topography)上にパターン形成することにより下地の集積回路配置構造に悪影響が及ぼされる場合がある。このため、以前に製作された集積回路配置構造に一切妨害を与えることのない仕方により、集積回路の他の部分の上に相変化型メモリを形成することが望ましいであろう。 An access device may be provided to activate the phase change material that is stacked on the semiconductor integrated circuit substrate. Other phase change memory components may also be integrated into the semiconductor substrate. Forming a pattern on an integrated circuit arrangement structure (integrated topography) may adversely affect the underlying integrated circuit arrangement structure. For this reason, it would be desirable to form phase change memory on other portions of the integrated circuit in a manner that does not interfere with any previously fabricated integrated circuit arrangement.
相変化型メモリの別の問題として、各メモリセルからの熱損失が大きくなるほどデバイスをプログラミングするために印加されなければならない電流が大きくなるということがある。このため、加熱された相変化材からの熱損失量を減らすことが望ましいであろう。同様に、相変化材全体にわたって熱を均一に分布させることが望ましい。しかしながら、現在提案されている多くの技術によれば、デバイスの電気抵抗はプログラミング後に局所的に変動するという結果がもたらされることがある。またこのような電気抵抗の局所的変動の結果、相変化型プログラミング中に局所的な領域に応力が発生することもある。 Another problem with phase change memory is that the greater the heat loss from each memory cell, the greater the current that must be applied to program the device. For this reason, it would be desirable to reduce the amount of heat loss from the heated phase change material. Similarly, it is desirable to distribute heat uniformly throughout the phase change material. However, many currently proposed techniques can result in the electrical resistance of the device fluctuating locally after programming. Also, as a result of such local variations in electrical resistance, stress may occur in local regions during phase change programming.
セルサイズを可能な限り小さくして製造コストを減らすことが望ましいであろう。また、製造工程数を最大限減らして製造コストを減らすことも望ましい。 It would be desirable to reduce the manufacturing cost by making the cell size as small as possible. It is also desirable to reduce the manufacturing cost by reducing the number of manufacturing steps as much as possible.
以上のことから、相変化型メモリとその製造技術を改良することが必要とされている。 In view of the above, it is necessary to improve the phase change memory and its manufacturing technology.
図1に、本発明の実施の一態様として、高い位置に設けられたポア(elevated pore)を含みうる相変化型メモリ10を示す。基板12は、ベースコンタクト(base contact)16を通る電流を制御するアクセストランジスタ(図示せず)を含む集積回路を含みうる。浅いトレンチ型絶縁構造14は、基板12内に形成された構造の他の部分からメモリセル10を絶縁する。本発明の実施の一態様によれば、基板12上にはライナー導体(liner conductor)18が配設される。本発明の実施の一態様によれば、このライナー導体18は、管状でカップ状の形をしており、充填用絶縁体20で満たされる中空になった中央領域が設けられることがある。ライナー導体18は、ベースコンタクト16から、高い位置に設けられたポアに上向きに電流を流す。
FIG. 1 shows a phase-
高い位置に設けられたポアは、同じく管状でカップ状の抵抗または下部電極22を含みうる。下部電極22内側内部には、対向する1対のスペーサ24と相変化層28とによって画定されるポアが存在する。本発明の実施の一態様において、相変化層28が管状でカップ状であってもよく、上部電極30が詰められていてもよい。本発明の実施の一態様として、上部電極30と相変化材28とがパターン形成されていてもよい。
The elevated pore may include a tubular or cup-shaped resistor or
以下、図2(図2A〜図2I)を参照して、図1に示された構造を形成するためのプロセスについて説明する。図2Aにおいて、最初に、エッチストップ層(etch stop layer)26と誘電層32とを貫いてポア(微細孔)34が形成される。エッチストップ層26は、それを取り巻く様々な層と比較してよりエッチングされにくい性質を持つ素材でありうる。本発明の実施の一態様として、このエッチストップ層26は、窒化珪素(silicon nitride)またはSi3N4でありうる。
Hereinafter, a process for forming the structure shown in FIG. 1 will be described with reference to FIG. 2 (FIGS. 2A to 2I). In FIG. 2A, first, pores (fine holes) 34 are formed through the
次に図2Bに示されているように、本発明の実施の一態様として、ライナー導体18がポア34の内側に積層されていてもよい。ライナー導体18は、チタン、窒化チタン、タングステン、またはこれらの材料の組み合わせであってもよい。ライナー導体18は、円筒形ポア34の内側を覆い、充填材20が詰められていてもよい。有利には、ライナー導体18は、ポア34の側壁を不断に密着して覆う。充填材20は、熱的に及び電気的に絶縁性を有する。本発明の実施の一態様においては、この充填材20は二酸化珪素でありうる。
Next, as shown in FIG. 2B, as one embodiment of the present invention, the
次に図2Cの段階において、図2Bに示された構造が平坦化処理されていてもよい。本発明の実施の一態様において、平坦面Sを作り出すためにCMP(Chemical Mechanical Planarization:化学機械平坦化)工程が利用されることがある。平坦化処理の停止点をうまくコントロールするためにエッチストップ層26を使用してもよい。
Next, in the stage of FIG. 2C, the structure shown in FIG. 2B may be planarized. In one embodiment of the present invention, a CMP (Chemical Mechanical Planarization) process may be used to create the flat surface S. An
図2Dに示されているように、充填材20はコントロールされた距離までエッチングされる。このようにして、開口部36がコントロールされた深さまで形成される。本発明の実施の一態様において、充填材20のエッチングとしてドライ絶縁体エッチング(dry insulator etch)を実施してもよい。その後、ライナー導体18のエッチングを行ってもよい。実施の一態様として、このライナー導体18が、最小限のオーバーエッチングにより等方性エッチングされていてもよい。実施の一態様として、ライナー導体18は、充填材20のエッチング後にウェットエッチング(wet etch)を使用してエッチングされることがある。
As shown in FIG. 2D, the
次に、図2Eに示されるように、本発明の実施の一態様として、抵抗または下部電極22が積層されていてもよい。エッチストップ層26の上面にある開口部36は、下部電極22で覆われていてもよい。そして、この下部電極22は絶縁体40で覆われていてもよい。下部電極22によってライナー導体18との電気的接続が提供されるため、基板12内にあるベースコンタクト16までの電気的接続が提供される。
Next, as shown in FIG. 2E, as an embodiment of the present invention, a resistor or
その後、図2Eに示された構造に対してCMP等の平坦化プロセスが実行されて、図2Fに示された平坦化された構造が作り出される。そして、ライナー導体18に対して溝切エッチング(recess etch)が施されて、Eで示された陥凹領域(recessed region)が形成される。実施の一態様として、この溝切エッチングは、短いウェットエッチング(short wet etch)であってもよい。
Thereafter, a planarization process, such as CMP, is performed on the structure shown in FIG. 2E to create the planarized structure shown in FIG. 2F. The
この後、ドライまたはウェット絶縁体エッチング等のエッチングプロセスを使用して絶縁体40を取り除くことができ、その結果、図2Gに示されるように、Fで示されたポアが作り出されて下部電極22が露出する。その後、図2Hに示されるように、側壁スペーサ24が形成されてもよい。例えば、絶縁材を積層し、積層した絶縁材を異方性エッチングすることにより、側壁スペーサ24を従来通りに形成してもよい。実施の一態様において、この側壁スペーサ24は、窒化珪素または二酸化珪素でありうる。
After this, the
次に、図2Iに示されるように、図2Hの構造は、相変化層28と上部電極層30とによって被覆されていてもよい。実施の一態様において、相変化層28は、カップ状であり、その側面をスペーサ24によって画定され、その底面を下部電極22によって画定されるポア内を下向きに延びる。実施の一態様において、相変化材は、Ge2Sb2Te5でありうる。
Next, as shown in FIG. 2I, the structure of FIG. 2H may be covered by the
上部電極28は、複数の層から成るサンドウィッチ構造の場合がある。実施の一態様として、このサンドウィッチ構造は、底の方から順に、チタンと、窒化チタンと、アルミニウムとを含む。
The
このようにして、基板12内のベースコンタクト16からライナー導体18を通って下部電極22に至り、そして相変化層28に至る電気的接続が構築される。最後に、実施の態様によっては、相変化層28と上部電極30とは、パターン形成されて、図1に示された構造が実現されることがある。
In this way, an electrical connection is established from the
実施の態様によっては、基板12よりも上にポアを持ち上げることによって相変化型メモリセルを標準的なCMOS(complementary metal oxide semiconductor)工程に取り込むことが容易になる。特に、ポアを持ち上げることによって、基板12内の集積回路配置構造にパターン形成することを避けることができる。その結果、フォトリソグラフィ工程を平坦化された表面上で行うことができる。
In some embodiments, the phase change memory cell can be easily incorporated into a standard complementary metal oxide semiconductor (CMOS) process by raising the pore above the
実施の態様によっては、熱効率の良いデバイス構造は、デバイスのプログラミングに必要な電力を減らすことによって改良されたデバイス性能を実現する。相変化層28により代表されるプログラマブル媒体の容積は、その周囲をほぼ断熱する。
In some embodiments, the thermally efficient device structure achieves improved device performance by reducing the power required to program the device. The volume of the programmable medium represented by the
下部電極22は、より低い電流で相変化を引き起こすための熱を与える。下部電極22は比較的に薄く作られていてもよく、そのようにすることにより実施の態様によっては電極22を通じての熱損失が小さくなる。さらに実施の態様によっては、プログラミング中の熱分布はより均一になり、プログラミング後のデバイス電気抵抗の局所変動がより小さく抑えられる。またこの構造によれば、実施の態様によっては相変化を生じさせる際に局所領域における応力の発生がより抑えられるという結果ももたらされる。
The
同様に、実施の態様によっては、セルサイズを小さくすることができ、それにより製造コストが減少する。また、本構造を形成するのにマスキング工程を2工程だけ追加することが必要とされるだけでよく、それによってもコストが減少し、工程サイクル時間が短縮される。 Similarly, in some embodiments, the cell size can be reduced, thereby reducing manufacturing costs. Also, only two masking steps need be added to form this structure, which also reduces cost and process cycle time.
本発明は、限定された数の実施態様についてのみ説明がなされたが、当業者であればそれらの実施態様の多数の変更及び変形を考えることができるであろう。本願の特許請求の範囲は、全てのそのような変更及び変形を本発明の技術的思想の範囲内に入るものとしてカバーすることを意図している。 Although the present invention has only been described with respect to a limited number of embodiments, those skilled in the art will be able to contemplate many variations and modifications of those embodiments. The claims of this application are intended to cover all such changes and modifications as fall within the scope of the inventive concept.
Claims (30)
該半導体構造基板を層により被覆するステップと、
該層を貫通して前記ベースコンタクトに至る電気的接続を形成するステップと、
該層を覆うように、前記ベースコンタクトと電気的に結合する相変化層を形成するステップと
を含んでなる方法。 Forming a base contact in a semiconductor structure substrate;
Coating the semiconductor structure substrate with a layer;
Forming an electrical connection through the layer to the base contact;
Forming a phase change layer electrically coupled to the base contact so as to cover the layer.
該半導体構造基板上に形成されたベースコンタクトと、
該半導体構造基板を上から覆う絶縁層と、
該絶縁層を貫通して形成されており、電気的接続部を含む通路と、
該電気的接続部と電気的に結合した相変化層と
を含んでなるメモリ。 A semiconductor structure substrate;
A base contact formed on the semiconductor structure substrate;
An insulating layer covering the semiconductor structure substrate from above;
A passage formed through the insulating layer and including an electrical connection;
A memory comprising a phase change layer electrically coupled to the electrical connection.
該半導体構造基板の上に間隔を置いて配置された相変化層と、
該相変化層を前記半導体構造基板に電気的に結合させる管状コネクタと
を含んでなるメモリ。 A semiconductor structure substrate;
A phase change layer disposed on the semiconductor structure substrate at an interval;
And a tubular connector for electrically coupling the phase change layer to the semiconductor structure substrate.
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US09/944,478 US6764894B2 (en) | 2001-08-31 | 2001-08-31 | Elevated pore phase-change memory |
PCT/US2002/026375 WO2003021693A2 (en) | 2001-08-31 | 2002-08-20 | Elevated pore phase-change memory |
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JP2005525690A true JP2005525690A (en) | 2005-08-25 |
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JP2003525922A Expired - Fee Related JP4150667B2 (en) | 2001-08-31 | 2002-08-20 | Phase change memory with higher pore position |
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JP (1) | JP4150667B2 (en) |
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WO (1) | WO2003021693A2 (en) |
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JP4150667B2 (en) | 2008-09-17 |
KR100534530B1 (en) | 2005-12-07 |
TW579593B (en) | 2004-03-11 |
KR20040032955A (en) | 2004-04-17 |
US6764894B2 (en) | 2004-07-20 |
WO2003021693A2 (en) | 2003-03-13 |
US20040202033A1 (en) | 2004-10-14 |
US7326952B2 (en) | 2008-02-05 |
WO2003021693A3 (en) | 2003-11-13 |
US20030116794A1 (en) | 2003-06-26 |
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