JP2005298454A - Powdery bath preparation composition - Google Patents
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- JP2005298454A JP2005298454A JP2004121159A JP2004121159A JP2005298454A JP 2005298454 A JP2005298454 A JP 2005298454A JP 2004121159 A JP2004121159 A JP 2004121159A JP 2004121159 A JP2004121159 A JP 2004121159A JP 2005298454 A JP2005298454 A JP 2005298454A
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本発明は、入浴剤組成物、さらに詳しくは容易かつ迅速に浴湯に十分な炭酸ガスを溶解させることができる粉末状入浴剤組成物に関する。 The present invention relates to a bath composition, and more particularly to a powder bath composition that can easily and quickly dissolve sufficient carbon dioxide gas in bath water.
入浴剤は、浴湯に香り、色調を与えたり、皮膚に適度な刺激を与えることにより、血液の循環を活発にし、疲労回復、新陳代謝を増進させるものである。一方浴湯に溶解した炭酸ガスは、皮膚に浸透し、末梢血管を広げて血行を促進する効果、保温効果、爽快感付与効果等を有する。このため、炭酸塩と有機酸とを配合し、浴湯に溶解することにより炭酸ガスが発生する錠剤タイプやブリケットタイプの入浴剤が市販されている。 Bathing agents give aroma and color to bath water, or give moderate stimulation to the skin, thereby activating blood circulation and improving fatigue recovery and metabolism. On the other hand, carbon dioxide dissolved in bath water has an effect of penetrating into the skin and promoting blood circulation by expanding peripheral blood vessels, a heat retaining effect, a refreshing feeling imparting effect and the like. For this reason, tablet-type and briquette-type bathing agents in which carbon dioxide gas is generated by blending carbonate and organic acid and dissolving in bath water are commercially available.
しかしながら、上記剤型の入浴剤は、賦形剤、結合剤等を用いて所定の形状にする必要があり、工程が煩雑な上、炭酸ガスの溶解に時間がかかるという問題があった。また粉末状の入浴剤として種々の検討がされているが（特許文献１〜２参照）、浴湯に添加すると直ちに炭酸塩と有機酸とが反応し、大部分の炭酸ガスが浴湯の表面付近で瞬時に発生するため、浴湯に十分な炭酸ガスを溶解させることが困難であったり、未反応のまま炭酸塩が沈降して浴槽底部に残留する等の問題を有し、満足できるものはなかった。
したがって本発明は、炭酸塩と有機酸との配合により、血行促進効果等を発揮するのに十分な量の炭酸ガスを短時間に溶解させることができる粉末状入浴剤組成物を提供することを目的とする。 Therefore, the present invention provides a powder bath composition capable of dissolving a sufficient amount of carbon dioxide gas in a short time to exhibit a blood circulation promoting effect and the like by blending a carbonate and an organic acid. Objective.
かかる実状に鑑み、本発明者は上記目的を達成すべく鋭意研究した結果、炭酸塩及び有機酸以外の水溶性物質と、特定粒径の炭酸塩及び特定粒径の有機酸を含有する粉末状入浴剤組成物が、血行促進効果等を発揮するに十分な量の炭酸ガスを短時間に浴湯に溶解させることができることを見出し、本発明を完成させた。 In view of this situation, the present inventor has intensively studied to achieve the above object, and as a result, a powdery substance containing a water-soluble substance other than carbonate and organic acid, carbonate having a specific particle size and organic acid having a specific particle size. The present inventors have found that a bathing agent composition can dissolve a sufficient amount of carbon dioxide gas in bath water in a short time to exert a blood circulation promoting effect and the like, thereby completing the present invention.
すなわち本発明の請求項１は、（Ａ）粒径２００〜１０００μｍの粒子が６０％以上である炭酸塩、（Ｂ）粒径５００〜１２００μｍの粒子が６０％以上である有機酸、並びに（Ｃ）炭酸塩及び有機酸を除く水溶性粉状物質を含有することを特徴とする粉末状入浴剤組成物である。 That is, claim 1 of the present invention includes (A) a carbonate having a particle diameter of 200 to 1000 μm of 60% or more, (B) an organic acid having a particle diameter of 500 to 1200 μm of 60% or more, and (C ) A powdery bath agent composition comprising a water-soluble powdery substance excluding carbonate and organic acid.
また本発明の請求項２は、炭酸塩が炭酸ナトリウム及び／又は炭酸水素ナトリウムであることを特徴とする請求項１記載の粉末状入浴剤組成物である。 The second aspect of the present invention is the powder bath composition according to the first aspect, wherein the carbonate is sodium carbonate and / or sodium hydrogen carbonate.
また本発明の請求項３は、有機酸が無水クエン酸及び／又はリンゴ酸であることを特徴とする請求項１又は２記載の粉末状入浴剤組成物である。 The third aspect of the present invention is the powder bath composition according to the first or second aspect, wherein the organic acid is anhydrous citric acid and / or malic acid.
また本発明の請求項４は、水溶性粉状物質が無機塩であることを特徴とする請求項１〜３のいずれか１項に記載の粉末状入浴剤組成物である。 Moreover, Claim 4 of this invention is a powdery bath agent composition of any one of Claims 1-3 whose water-soluble powdery substance is an inorganic salt.
また本発明の請求項５は、無機塩が硫酸ナトリウム及び／又は塩化ナトリウムであることを特徴とする請求項４記載の粉末状入浴剤組成物である。 The fifth aspect of the present invention is the powder bath composition according to the fourth aspect, wherein the inorganic salt is sodium sulfate and / or sodium chloride.
本発明の粉末状入浴剤組成物は、血行促進効果等を発揮するに十分な量の炭酸ガスを短時間に溶解させることができる。 The powder bath composition of the present invention can dissolve a sufficient amount of carbon dioxide gas in a short time to exhibit a blood circulation promoting effect and the like.
本発明において粉末状とは、粒径１〜３０００μｍ程度のものであり、一般的に粉状、粒状、顆粒状とよばれるものを含む。また本発明において、例えば粒径２００〜１０００μｍの粒子が６０％以上である炭酸塩とは、粒径が２００〜１０００μｍの範囲内にある炭酸塩粒子の重量が、全炭酸塩粒子重量の６０％以上であることをいう。また、該粒径はふるい分け法により測定できる。 In the present invention, the powdery form has a particle size of about 1 to 3000 μm, and generally includes powdery, granular, and granular forms. In the present invention, for example, the carbonate having a particle size of 200 to 1000 μm is 60% or more means that the weight of the carbonate particle having a particle size in the range of 200 to 1000 μm is 60% of the total carbonate particle weight. That's it. The particle size can be measured by a sieving method.
本発明に用いられる炭酸塩は、粒径２００〜１０００μｍの粒子が６０％以上である必要がある。当該範囲の粒径を持つ炭酸塩であれば、粒径が大きい粒子が多いため浴湯に添加したとき溶解に時間を要し、粒子が浴槽の下方まで沈降しながら共存する有機酸と徐々に反応するので、浴湯中に炭酸ガスが十分に溶解する。一方、粒径１０００μｍよりも大きいの粒子が多いと、炭酸塩の溶解時間が長くなりすぎて底部に沈降、残留して短時間で浴湯中に炭酸ガスを十分に溶解させることができなくなる。 The carbonate used in the present invention needs to have 60% or more of particles having a particle size of 200 to 1000 μm. In the case of a carbonate having a particle size in this range, since many particles have a large particle size, it takes time to dissolve when added to bath water, and the particles gradually settle with the organic acid that coexists while sinking to the bottom of the bath. Since it reacts, carbon dioxide is sufficiently dissolved in the bath water. On the other hand, if there are many particles having a particle size larger than 1000 μm, the dissolution time of the carbonate becomes too long and settles and remains at the bottom, so that the carbon dioxide gas cannot be sufficiently dissolved in the bath water in a short time.
上記粒径分布を有する炭酸塩は、常法により製造することができる。 The carbonate having the above particle size distribution can be produced by a conventional method.
本発明に用いられる炭酸塩としては例えば、炭酸水素ナトリウム、炭酸ナトリウム、セスキ炭酸ナトリウム、炭酸カリウム、炭酸水素カリウム、炭酸アンモニウム、炭酸マグネシウム等が挙げられ、これらを１種又は２種以上用いることができる。このうち炭酸ナトリウム、炭酸水素ナトリウムが好ましい。 Examples of the carbonate used in the present invention include sodium bicarbonate, sodium carbonate, sodium sesquicarbonate, potassium carbonate, potassium bicarbonate, ammonium carbonate, magnesium carbonate, etc., and these may be used alone or in combination. it can. Of these, sodium carbonate and sodium hydrogen carbonate are preferred.
本発明に用いられる有機酸は、粒径５００〜１２００μｍの粒子が６０％以上である必要がある。粒径５００μｍ未満の微小な粒子が多いと有機酸は浴湯表面で瞬時に溶解して希薄になり、共存して沈降する炭酸塩と効率よく反応できず、結果として短時間に浴湯中に炭酸ガスを十分に溶解させることができない。一方、粒径１２００μｍよりも大きい粗い粒子が多いと、投入すると直ちに浴槽底部に沈降してしまい緩やかに沈降する炭酸塩と効率よく反応できず、やはり短時間に浴湯中に炭酸ガスを十分に溶解させることができない。 The organic acid used in the present invention needs to have 60% or more of particles having a particle size of 500 to 1200 μm. When there are many fine particles with a particle size of less than 500 μm, the organic acid dissolves instantly and dilutes on the surface of the bath water and cannot react efficiently with the carbonate that coexists and settles, resulting in a short time in the bath water. Carbon dioxide cannot be dissolved sufficiently. On the other hand, if there are many coarse particles having a particle size larger than 1200 μm, they immediately settle on the bottom of the bathtub when they are added and cannot react efficiently with the carbonate that slowly settles down. It cannot be dissolved.
本発明に用いられる有機酸としては例えば、クエン酸、酒石酸、リンゴ酸、マロン酸、ピリドンカルボン酸、コハク酸、フマル酸、アジピン酸、グルタル酸等が挙げられ、これらの有機酸を１種又は２種以上用いることができる。このうちクエン酸、リンゴ酸が好ましく、特にクエン酸が好ましい。 Examples of the organic acid used in the present invention include citric acid, tartaric acid, malic acid, malonic acid, pyridone carboxylic acid, succinic acid, fumaric acid, adipic acid, glutaric acid, and the like. Two or more kinds can be used. Of these, citric acid and malic acid are preferable, and citric acid is particularly preferable.
本発明に用いられる炭酸塩及び有機酸を除く水溶性粉状物質は、炭酸塩と有機酸が浴湯中で反応して発泡する際に、反応を物理的に妨害することにより液面で瞬時に起る反応を遅延させるとともに、反応により発生した気泡を自己の沈降により底方向に巻き込むことにより気泡の浴湯中での滞留時間を延長することによって、浴湯中炭酸ガス濃度を上げる働きがある。 The water-soluble powdery substance excluding the carbonate and organic acid used in the present invention is instantly in the liquid surface by physically interfering with the reaction when the carbonate and the organic acid react and foam in the bath water. In addition to delaying the reaction that takes place in the bath water and extending the residence time of the bubbles in the bath water by entraining the bubbles generated by the reaction toward the bottom by self-settling, the function of raising the carbon dioxide concentration in the bath water is there.
本発明に用いられる炭酸塩及び有機酸を除く水溶性粉状物質としては例えば、硫酸ナトリウム、硫酸マグネシウム、塩化カリウム、塩化ナトリウム等の水溶性の無機塩、あるい
はグルコース、フルクトース、キシロース、ガラクトース等の単糖類、シュークロース、ラクトース、トレハロース等の二糖類、プルラン、デキストリン、デンプン、グァーガム、キサンタンガム等の水溶性の多糖類、及びポリエチレングリコール、カゼイン、コラーゲン、ポリビニルピロリドン、ポリビニルアルコール、カルボキシメチルセルロース等の水溶性の高分子化合物等が挙げられ、これらの水溶性粉状物質を１種又は２種以上用いることができる。このうち浴湯中での溶解性及び製剤の安定性から水溶性の無機塩が好ましく、その中でも硫酸ナトリウム、塩化ナトリウムが特に好ましい。
Examples of the water-soluble powdery substance excluding carbonate and organic acid used in the present invention include water-soluble inorganic salts such as sodium sulfate, magnesium sulfate, potassium chloride and sodium chloride, or glucose, fructose, xylose and galactose. Monosaccharides, disaccharides such as sucrose, lactose, trehalose, water-soluble polysaccharides such as pullulan, dextrin, starch, guar gum, xanthan gum, and water-soluble such as polyethylene glycol, casein, collagen, polyvinyl pyrrolidone, polyvinyl alcohol, carboxymethyl cellulose High molecular weight compounds, and the like, and one or more of these water-soluble powders can be used. Among these, a water-soluble inorganic salt is preferable from the viewpoint of solubility in bath water and stability of the preparation, and sodium sulfate and sodium chloride are particularly preferable.
本発明の粉末状入浴剤組成物における（Ａ）粒径２００〜１０００μｍの粒子が６０％以上である炭酸塩、（Ｂ）粒径５００〜１２００μｍの粒子が６０％以上である有機酸、並びに（Ｃ）炭酸塩及び有機酸を除く水溶性粉状物質の好適な配合量は次の通りである。（Ａ）成分は、粉末状入浴剤組成物の総量を基準として、２０〜７０質量％が好ましく、特に好ましくは３５〜５０質量％であり、（Ｂ）成分は、粉末状入浴剤組成物の総量を基準として、１０〜６０質量％が好ましく、特に好ましくは３０〜４０質量％であり、（Ｃ）成分は、１０〜５０質量％が好ましく、特に好ましくは２０〜４０質量％である。 In the powdered bath composition of the present invention, (A) a carbonate having a particle size of 200 to 1000 μm is 60% or more, (B) an organic acid having a particle size of 500 to 1200 μm is 60% or more, and ( C) The suitable compounding quantity of the water-soluble powdery substance excluding carbonate and organic acid is as follows. The component (A) is preferably 20 to 70% by mass, particularly preferably 35 to 50% by mass, based on the total amount of the powder bath composition, and the component (B) is a powder bath composition. 10-60 mass% is preferable on the basis of the total amount, particularly preferably 30-40 mass%, and the component (C) is preferably 10-50 mass%, particularly preferably 20-40 mass%.
尚、本発明の粉末状入浴剤組成物の０．０１質量％水溶液のｐＨ（２５℃）は、５．０〜７．０、特に５．５〜６．５の範囲内であることが好ましい。ｐＨが５．０〜７．０であれば、発生した炭酸ガスが浴湯中でＣＯ２として存在し、血行促進等の効果が十分に発揮される。 In addition, it is preferable that the pH (25 degreeC) of 0.01 mass% aqueous solution of the powdery bath agent composition of this invention exists in the range of 5.0-7.0, especially 5.5-6.5. . When the pH is 5.0 to 7.0, the generated carbon dioxide gas is present as CO 2 in the bath water, and effects such as blood circulation promotion are sufficiently exhibited.
本発明においては、本発明の効果を阻害しない範囲で、通常入浴剤に用いられているホホバ油等の油性成分、グリセリン脂肪酸エステル等の界面活性剤、ビタミンＡ等のビタミン類、ペプシン等の蛋白分解酵素、着色料、香料（カプセル化してもよい）等を添加することができる。 In the present invention, oily components such as jojoba oil, which are usually used for bathing agents, surfactants such as glycerin fatty acid esters, vitamins such as vitamin A, and proteins such as pepsin, as long as the effects of the present invention are not impaired. Degrading enzymes, coloring agents, fragrances (may be encapsulated) and the like can be added.
本発明の粉末状入浴剤組成物は、炭酸塩、有機酸、水溶性粉状物質、及び必要に応じて他の添加物を混合し、適宜撹拌することによって得ることができる。 The powdered bath composition of the present invention can be obtained by mixing carbonate, an organic acid, a water-soluble powdery substance, and other additives as required, and appropriately stirring.
次に実施例により本発明をさらに詳細に説明するが、本発明は以下の実施例に限定されるものではない。 EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited to a following example.
実施例１〜５、比較例１〜４
下記表１に示す組成で、粉末状入浴剤組成物を常法にしたがって製造した。
Examples 1-5, Comparative Examples 1-4
With the composition shown in Table 1 below, a powder bath composition was produced according to a conventional method.
試験法
上記で得られた粉末状入浴剤組成物４０ｇを、４０℃、１５０Ｌの浴湯に添加し、１分間放置した後、浴湯中の炭酸ガス濃度を炭酸ガス電極を用いて測定した。結果を表１に併せて示す。
Test Method After adding 40 g of the powdered bath composition obtained above to 40 ° C. and 150 L of bath water and allowing it to stand for 1 minute, the concentration of carbon dioxide in the bath was measured using a carbon dioxide electrode. The results are also shown in Table 1.
表１より、実施例１〜５の場合は比較例１〜４と比べて溶存炭酸ガス濃度が約１．４〜８．５倍であることが確認された。 From Table 1, in the case of Examples 1-5, compared with Comparative Examples 1-4, it was confirmed that the dissolved carbon dioxide gas concentration is about 1.4 to 8.5 times.
次に下記の組成の粉末状入浴剤組成物を常法にしたがって製造した。上記試験法により溶存炭酸ガス濃度を測定したところ、いずれも２００〜２３０ｐｐｍの範囲のものであった。 Next, a powder bath composition having the following composition was produced according to a conventional method. When the dissolved carbon dioxide concentration was measured by the above test method, all were in the range of 200 to 230 ppm.
実施例６
組成 （質量％）
無水硫酸ナトリウム 残 量
炭酸水素ナトリウム ２０．０
（粒径２００〜１０００μｍの粒子が６５％）
炭酸ナトリウム １５．０
（粒径２００〜１０００μｍの粒子が６５％）
無水クエン酸 ３５．０
（粒径５００〜１２００μｍの粒子が６５％）
トウキ末 １．０
チンピ末 １．０
センキュウ末 １．０
法定色素 微 量
香料 １．０
モノオレイン酸ＰＯＥ（２０）ソルビタン ０．１
無水ケイ酸 １．０
−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 １００．０
Example 6
Composition (mass%)
Anhydrous sodium sulfate Residual amount Sodium bicarbonate 20.0
(65% of particles with a particle size of 200-1000 μm)
Sodium carbonate 15.0
(65% of particles with a particle size of 200-1000 μm)
Anhydrous citric acid 35.0
(65% of particles with a particle size of 500-1200 μm)
End of Toki 1.0
Chinpi powder 1.0
Senkyu powder 1.0
Legal dye Fine flavoring 1.0
Monooleic acid POE (20) sorbitan 0.1
Silicic anhydride 1.0
-------------------------
Total 100.0
実施例７
組成 （質量％）
無水硫酸ナトリウム 残 量
炭酸水素ナトリウム １５．０
（粒径２００〜１０００μｍの粒子が６５％）
炭酸ナトリウム ２０．０
（粒径２００〜１０００μｍの粒子が６５％）
無水クエン酸 ３６．０
（粒径５００〜１２００μｍの粒子が７９％）
トウキ末 ３．０
法定色素 微 量
香料 １．０
モノオレイン酸ＰＯＥ（２０）ソルビタン ０．１
表面処理酸化チタン ５．０
［Ｖ２５３３（レジノカラー工業社製）］
無水メタケイ酸ナトリウム １．０
無水ケイ酸 １．０
−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 １００．０
Example 7
Composition (mass%)
Anhydrous sodium sulfate Residual amount Sodium bicarbonate 15.0
(65% of particles with a particle size of 200-1000 μm)
Sodium carbonate 20.0
(65% of particles with a particle size of 200-1000 μm)
Citric anhydride 36.0
(79% of particles with a particle size of 500-1200 μm)
End of touki 3.0
Legal dye Fine flavoring 1.0
Monooleic acid POE (20) sorbitan 0.1
Surface-treated titanium oxide 5.0
[V2533 (manufactured by Resino Color Industries)]
Anhydrous sodium metasilicate 1.0
Silicic anhydride 1.0
-------------------------
Total 100.0
実施例８
組成 （質量％）
無水硫酸ナトリウム 残 量
炭酸水素ナトリウム ２０．０
（粒径２００〜１０００μｍの粒子が７１％）
炭酸ナトリウム １５．０
（粒径２００〜１０００μｍの粒子が７１％）
無水クエン酸 ３５．０
（粒径５００〜１２００μｍの粒子が６５％）
炭酸ガス封入固形粒状糖類＊１ ５．０
法定色素 微 量
香料 １．０
モノオレイン酸ＰＯＥ（２０）ソルビタン ０．１
無水ケイ酸 １．０
−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 １００．０
＊１：炭酸ガスを、デキストリン、白糖、乳糖を含む基材に封入し、固形粒状（０．０１〜５ｍｍ）に調製したもの。
Example 8
Composition (mass%)
Anhydrous sodium sulfate Residual amount Sodium bicarbonate 20.0
(71% of particles with a particle size of 200-1000 μm)
Sodium carbonate 15.0
(71% of particles with a particle size of 200-1000 μm)
Anhydrous citric acid 35.0
(65% of particles with a particle size of 500-1200 μm)
Carbon dioxide filled solid saccharides * 1 5.0
Legal dye Fine flavoring 1.0
Monooleic acid POE (20) sorbitan 0.1
Silicic anhydride 1.0
-------------------------
Total 100.0
* 1: Carbon dioxide gas sealed in a base material containing dextrin, sucrose, and lactose, and prepared into solid granules (0.01-5 mm).
実施例９
組成 （質量％）
塩化ナトリウム 残 量
炭酸水素ナトリウム ２０．０
（粒径２００〜１０００μｍの粒子が８３％）
炭酸ナトリウム １６．０
（粒径２００〜１０００μｍの粒子が６５％）
無水クエン酸 ３５．０
（粒径５００〜１２００μｍの粒子が７９％）
花弁凍結乾燥物 １．０
法定色素 微 量
香料 １．０
モノオレイン酸ＰＯＥ（２０）ソルビタン ０．１
合成ケイ酸アルミニウム １．０
−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 １００．０
Example 9
Composition (mass%)
Sodium chloride Residual amount Sodium bicarbonate 20.0
(83% of particles with a particle size of 200-1000 μm)
Sodium carbonate 16.0
(65% of particles with a particle size of 200-1000 μm)
Anhydrous citric acid 35.0
(79% of particles with a particle size of 500-1200 μm)
Petal freeze-dried product 1.0
Legal dye Fine flavoring 1.0
Monooleic acid POE (20) sorbitan 0.1
Synthetic aluminum silicate 1.0
-------------------------
Total 100.0
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004121159A JP2005298454A (en) | 2004-04-16 | 2004-04-16 | Powdery bath preparation composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004121159A JP2005298454A (en) | 2004-04-16 | 2004-04-16 | Powdery bath preparation composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2005298454A true JP2005298454A (en) | 2005-10-27 |
Family
ID=35330430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004121159A Pending JP2005298454A (en) | 2004-04-16 | 2004-04-16 | Powdery bath preparation composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2005298454A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009149532A (en) * | 2007-12-18 | 2009-07-09 | Kao Corp | Granular effervescent bath agent |
| JP2009155213A (en) * | 2007-12-25 | 2009-07-16 | Kao Corp | Granular bath agent composition |
| JP2011016749A (en) * | 2009-07-08 | 2011-01-27 | Kao Corp | Granular effervescent bath salt |
| JP2011016752A (en) * | 2009-07-08 | 2011-01-27 | Kao Corp | Granular effervescent bath salt |
| KR101284753B1 (en) * | 2011-09-19 | 2013-07-17 | 이진행 | Soap powder composition having effect of improving skin |
| JP2014210734A (en) * | 2013-04-19 | 2014-11-13 | クラシエホームプロダクツ株式会社 | Acidic bath composition |
| JP2017066102A (en) * | 2015-09-30 | 2017-04-06 | アース製薬株式会社 | Effervescent bath agent of compression-molding type |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06199652A (en) * | 1992-12-28 | 1994-07-19 | Kao Corp | Production of granular bathing agent |
| JPH1147220A (en) * | 1997-07-30 | 1999-02-23 | Kao Corp | Composition of granular bath medicine |
-
2004
- 2004-04-16 JP JP2004121159A patent/JP2005298454A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06199652A (en) * | 1992-12-28 | 1994-07-19 | Kao Corp | Production of granular bathing agent |
| JPH1147220A (en) * | 1997-07-30 | 1999-02-23 | Kao Corp | Composition of granular bath medicine |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009149532A (en) * | 2007-12-18 | 2009-07-09 | Kao Corp | Granular effervescent bath agent |
| JP2009155213A (en) * | 2007-12-25 | 2009-07-16 | Kao Corp | Granular bath agent composition |
| JP2011016749A (en) * | 2009-07-08 | 2011-01-27 | Kao Corp | Granular effervescent bath salt |
| JP2011016752A (en) * | 2009-07-08 | 2011-01-27 | Kao Corp | Granular effervescent bath salt |
| KR101284753B1 (en) * | 2011-09-19 | 2013-07-17 | 이진행 | Soap powder composition having effect of improving skin |
| JP2014210734A (en) * | 2013-04-19 | 2014-11-13 | クラシエホームプロダクツ株式会社 | Acidic bath composition |
| JP2017066102A (en) * | 2015-09-30 | 2017-04-06 | アース製薬株式会社 | Effervescent bath agent of compression-molding type |
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