JPH03112922A - Foamable bathing agent for inhibiting floating of fumaric acid - Google Patents
Foamable bathing agent for inhibiting floating of fumaric acidInfo
- Publication number
- JPH03112922A JPH03112922A JP24947589A JP24947589A JPH03112922A JP H03112922 A JPH03112922 A JP H03112922A JP 24947589 A JP24947589 A JP 24947589A JP 24947589 A JP24947589 A JP 24947589A JP H03112922 A JPH03112922 A JP H03112922A
- Authority
- JP
- Japan
- Prior art keywords
- fumaric acid
- water
- bath
- bathing agent
- floating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 title claims abstract description 62
- 239000001530 fumaric acid Substances 0.000 title claims abstract description 31
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 title abstract description 9
- 238000003287 bathing Methods 0.000 title abstract description 7
- 230000002401 inhibitory effect Effects 0.000 title 1
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 8
- -1 polyoxyethylene Polymers 0.000 claims abstract description 7
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 5
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 5
- 229930006000 Sucrose Natural products 0.000 claims abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 4
- 239000000194 fatty acid Substances 0.000 claims abstract description 4
- 229930195729 fatty acid Natural products 0.000 claims abstract description 4
- 239000005720 sucrose Substances 0.000 claims abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract 2
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract 2
- 239000000654 additive Substances 0.000 claims description 32
- 230000000996 additive effect Effects 0.000 claims description 18
- 238000005187 foaming Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract description 4
- 239000001569 carbon dioxide Substances 0.000 abstract description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 230000017531 blood circulation Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000004060 metabolic process Effects 0.000 abstract description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract description 2
- 230000000638 stimulation Effects 0.000 abstract description 2
- 238000004090 dissolution Methods 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 235000002906 tartaric acid Nutrition 0.000 description 3
- 239000011975 tartaric acid Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 206010016352 Feeling of relaxation Diseases 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013040 bath agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、浴湯に投入して炭酸ガスを発生せしめ、この
発生ガスに−よって皮膚に程よい刺激を与えて血行をよ
くし、疲労回復および新陳代謝を早める目的で使用され
る発泡性入浴剤に関し、さらに詳しくはフマル酸と炭酸
塩を配合した入浴剤において、入浴剤が浴場中に溶ける
ときに生じるフマル酸の浮きを抑止した入浴剤に関する
。[Detailed Description of the Invention] [Industrial Application Field] The present invention generates carbon dioxide gas by adding it to bath water, and the generated gas gives moderate stimulation to the skin to improve blood circulation and relieve fatigue. and effervescent bath additives used for the purpose of accelerating metabolism, and more specifically, regarding bath additives containing fumaric acid and carbonate that suppress the floating of fumaric acid that occurs when the bath additive dissolves in the bath. .
［従来の技術］
一般に、この種の入浴剤は、炭酸塩と有機酸の組合せを
含有したものであって、前述のように浴湯中に炭酸ガス
の気泡を発生せしめ、リラックス感や爽快感を高め、入
浴を楽しくする効果を有する。[Prior Art] Generally, this type of bath additive contains a combination of carbonate and organic acid, and as mentioned above, generates carbon dioxide gas bubbles in the bath water, giving a relaxing and refreshing feeling. It has the effect of increasing your bathing experience and making bathing more enjoyable.
この種の入浴剤中に配合する有機酸としては、クエン酸
、酒石酸、コハク酸が一般的に使用されている。ところ
で、フマル酸はクエン酸、酒石酸、コハク酸より安価な
ため有利であるが、水に難溶性であるためこれをそのま
ま入浴剤用の酸剤として使用するには問題があった。Citric acid, tartaric acid, and succinic acid are commonly used as organic acids to be incorporated into this type of bath additive. Incidentally, although fumaric acid is advantageous because it is cheaper than citric acid, tartaric acid, and succinic acid, it is poorly soluble in water, so there is a problem in using it as it is as an acid agent for bath additives.
従来、この問題を解決すべく、上記入浴剤にショ糖脂肪
酸エステルのような非イオン系界面活性剤を添加すると
いう報告がある（特公昭６４−７９６５号公報参照）。Conventionally, in order to solve this problem, there has been a report that a nonionic surfactant such as sucrose fatty acid ester is added to the bath additive (see Japanese Patent Publication No. 7965/1983).
しかし、この配合では、フマル酸の浮きは抑えられが、
界面活性剤に起因する気泡が生じていつまでも消えずに
残り、完全な問題解決はなされていない。However, with this formulation, the floating of fumaric acid was suppressed, but
Bubbles caused by the surfactant are generated and remain forever, and the problem has not been completely resolved.
［発明の目的］
そこで、本発明者は、かかる欠点を克服せんと鋭意研究
を重ねた結果、特定の水溶性高分子化合物および界面活
性剤をそれぞれフマル酸に対して所要量含ませることに
よって、フマル酸の浮きを抑え、しかも気泡が残らなく
なることを見出し、本発明を完成するに至った。[Purpose of the Invention] Therefore, as a result of intensive research to overcome these drawbacks, the present inventor has found that by incorporating a specific water-soluble polymer compound and a surfactant in the required amounts relative to fumaric acid, They discovered that the floating of fumaric acid can be suppressed and no air bubbles remain, leading to the completion of the present invention.
［発明の構成］
すなわち、本発明による入浴剤は、フマル酸と炭酸塩を
含有する入浴剤において、ポリビニルピロリドン、ハイ
ドロキシプロピルセルロース、ポリビニルアルコールよ
り成る群から選ばれる１種または２種以上の水溶性高分
子化合物および界面活性剤が、それぞれフマル酸に対し
て１〜２０重量％および０．１重量％未満含まれている
ことを特徴とするフマル酸の浮き抑制発泡性入浴剤であ
る。[Structure of the Invention] That is, the bath additive according to the present invention is a bath additive containing fumaric acid and carbonate, which contains one or more water-soluble types selected from the group consisting of polyvinylpyrrolidone, hydroxypropyl cellulose, and polyvinyl alcohol. This fumaric acid foaming bath agent is characterized in that a polymer compound and a surfactant are contained in an amount of 1 to 20% by weight and less than 0.1% by weight based on fumaric acid, respectively.
本発明において、入浴剤の基本成分である炭酸塩の例と
しては、例えば炭酸水素ナトリウム、炭酸ナトリウム、
セスキ炭酸ナトリウムなどが挙げられ、これらは単独ま
たは２種以上の組合わせて使用できる。炭酸塩の含有量
は全組成物ｌｆｆ１に対して５〜８０重量％が好ましい
。また入浴剤の酸剤として使用するフマル酸の含有量は
、全組成物重量に対して２〜５０重量％が好ましい。In the present invention, examples of carbonates that are the basic components of bath additives include sodium hydrogen carbonate, sodium carbonate,
Examples include sodium sesquicarbonate, and these can be used alone or in combination of two or more. The carbonate content is preferably 5 to 80% by weight based on the total composition lff1. Further, the content of fumaric acid used as an acid agent in the bath additive is preferably 2 to 50% by weight based on the total weight of the composition.
本発明において、フマル酸の浮き抑止および気泡残留防
止のために添加する水溶性高分子化合物としては、ポリ
ビニルピロリドン、ハイドロキシプロピルセルロース、
ポリビニルアルコールが例示され、これら水溶性高分子
化合物が１種または２種以上の組み合わせで使用される
。In the present invention, water-soluble polymer compounds added to prevent fumaric acid from floating and from remaining bubbles include polyvinylpyrrolidone, hydroxypropyl cellulose,
Polyvinyl alcohol is exemplified, and these water-soluble polymer compounds may be used alone or in combination of two or more.
添加する水溶性高分子化合物の量は、本発明入浴剤の他
の含有成分の種類や浴湯中の入浴剤の濃度などによって
も異なるが、フマル酸に対して１〜２０重量％の範囲の
量が適当である。１％未満の量を用いても、ある程度の
効果はあるが、この水溶性高分子化合物を配合すること
による効果を十分に発揮させるには、これを１重量％以
上使用する方がよい。またこの水溶性高分子化合物を２
０ ｆｆｉ 量０６を越えた全使用しても特に差し支え
はないが、経済的な面を考慮すると２０重量％までが適
当である。The amount of the water-soluble polymer compound to be added varies depending on the types of other ingredients contained in the bath additive of the present invention and the concentration of the bath additive in the bath water, but it is in the range of 1 to 20% by weight based on fumaric acid. The amount is appropriate. Although there is some effect even if the amount is less than 1%, in order to fully exhibit the effect of blending this water-soluble polymer compound, it is better to use it in an amount of 1% by weight or more. In addition, this water-soluble polymer compound is
There is no particular problem even if the total amount exceeds 06, but from an economical point of view it is appropriate to use up to 20% by weight.
また界面活性剤としては例えばポリオキシアルキルエー
テルやショ糖脂肪酸エステルが好ましい。これらは単独
でまたは両者の組み合わせで使用される。添加する界面
活性剤の量は、本発明入浴剤の他の含有成分の種類や浴
湯中の入浴剤の濃度などによっても異なるが、フマル酸
に対して０，１重量％未満の範囲の量が適当である。界
面活性剤の量が０．１重量９６以上になると泡立ちが起
こるので、０．１重量％以上の量は好ましくない。Further, as the surfactant, for example, polyoxyalkyl ether and sucrose fatty acid ester are preferable. These may be used alone or in combination. The amount of surfactant to be added varies depending on the types of other ingredients contained in the bath additive of the present invention and the concentration of the bath additive in the bath water, but the amount is in the range of less than 0.1% by weight based on fumaric acid. is appropriate. If the amount of surfactant is 0.1% by weight or more, foaming will occur, so an amount of 0.1% by weight or more is not preferred.
また、本発明による入浴剤には、上記必須成分のほかに
、硫酸ナトリウム、硫酸マグネシウム、硫酸亜鉛などの
硫酸塩、あるいは塩化ナトリウムなどの塩酸塩を配合す
ることができる。In addition to the above-mentioned essential ingredients, the bath additive according to the present invention may contain sulfates such as sodium sulfate, magnesium sulfate, and zinc sulfate, or hydrochlorides such as sodium chloride.
さらに、本発明入浴剤には、一般にこの種入浴剤に配合
されている香料、色素、あるいはビタミン類、温泉の有
効成分、蛋白分解酵素、海草エキス、アルギン酸ナトリ
ウム、ラノリン、シリコン、生薬あるいはその抽出エキ
スなどを配合して、リラックス感や爽快感を高める効果
を一層向上することができる。Furthermore, the bath additives of the present invention include fragrances, pigments, or vitamins that are generally included in this type of bath additives, active ingredients from hot springs, proteolytic enzymes, seaweed extracts, sodium alginate, lanolin, silicone, herbal medicines or extracts thereof. By adding extracts and the like, the effect of increasing the feeling of relaxation and refreshment can be further improved.
本発明の入浴剤は、粉末、顆粒、結晶、錠剤などの形に
することができ、これらの製剤化のために、必要に応じ
て賦形剤、結合剤、崩壊剤、滑沢剤などを添加すること
もできる。The bath additives of the present invention can be in the form of powders, granules, crystals, tablets, etc., and excipients, binders, disintegrants, lubricants, etc. may be added as necessary to form these formulations. It can also be added.
［発明の効果］
上述のように、本発明の入浴剤は、フマル酸と炭酸塩を
含有する入浴剤において、ポリビニルピロリドン、ハイ
ドロキシプロピルセルロース、ポリビニルアルコールよ
り成る群から選ばれる１種または２ｗ１以上の水溶性高
分子化合物および界面活性剤が、それぞれフマル酸に対
して１〜２０重量％および０．１重量％未満含まれてい
るものであるので、フマル酸の浮きを効果的に抑えるこ
とができる上に、上記界面活性剤に起因する気泡を即座
に消去することができる。したがって、本発明によれば
、高価なりエン酸、酒石酸、コハク酸に代わり、安価な
フマル酸を使用することが可能となり、製造コストを大
幅に節減することができる。[Effects of the Invention] As described above, the bath additive of the present invention is a bath additive containing fumaric acid and a carbonate, and contains one or more than one selected from the group consisting of polyvinylpyrrolidone, hydroxypropylcellulose, and polyvinyl alcohol. Since the water-soluble polymer compound and the surfactant are contained in amounts of 1 to 20% by weight and less than 0.1% by weight, respectively, based on fumaric acid, floating of fumaric acid can be effectively suppressed. Moreover, air bubbles caused by the surfactant can be instantly eliminated. Therefore, according to the present invention, it is possible to use inexpensive fumaric acid in place of the expensive enoic acid, tartaric acid, and succinic acid, and it is possible to significantly reduce manufacturing costs.
Ｃ実 施 例コ
次に本発明の実施例およびこれと比較するための比較例
を幾つか挙げる。C Examples Next, some examples of the present invention and comparative examples for comparison therewith will be given.
実施例
表１に示す配合組成の入浴剤１〜７を調製した。これら
入浴剤をそれぞれ０．０１％水溶液になるように水中に
投入して、各入浴剤についてフマル酸の浮きおよび泡立
ちの残存具合を評価した。評価の結果は表１のとおりで
ある。同表中、各評価は次のとおりＯ印とＸ印で示した
。Example Bath additives 1 to 7 having the composition shown in Table 1 were prepared. Each of these bath additives was poured into water to form a 0.01% aqueous solution, and the residual degree of fumaric acid floating and foaming was evaluated for each bath additive. The results of the evaluation are shown in Table 1. In the same table, each evaluation is indicated by an O mark and an X mark as follows.
フマル酸の浮き Ｏ：無 ×：有気泡の残存
Ｏ：無 ×：有同表から明らかなように、実施
例の各入浴剤にはフマル酸の浮きおよび気泡の残存にま
ったく問題がない。Floating of fumaric acid O: None ×: Residual bubbles
O: None ×: Present As is clear from the table, each of the bath additives of Examples had no problems with fumaric acid floating and bubbles remaining.
比較例
表１に示す配合組成の入浴剤８〜１０を調製した。これ
ら入浴剤をそれぞれ０，０１％水溶液になるように水中
に投入して、各入浴剤についてフマル酸の浮きおよび泡
立ちの残存具合を、実施例の場合と同様に評価した。評
価の結果はやはり表１のとおりである。同表から明らか
なように、比較例の各入浴剤にはフマル酸の浮きおよび
気泡の残存に問題がある。Comparative Example Bath additives 8 to 10 having the formulation shown in Table 1 were prepared. Each of these bath additives was poured into water to form a 0.01% aqueous solution, and the remaining degree of fumaric acid floating and foaming was evaluated for each bath additive in the same manner as in the examples. The results of the evaluation are shown in Table 1. As is clear from the same table, each of the comparative bath additives has problems with fumaric acid floating and bubbles remaining.
（以下余白）(Margin below)
Claims (2)
リビニルピロリドン、ハイドロキシプロピルセルロース
、ポリビニルアルコールより成る群から選ばれる１種ま
たは２種以上の水溶性高分子化合物および界面活性剤が
、それぞれフマル酸に対して１〜２０重量％および０．
１重量％未満含まれていることを特徴とする、フマル酸
の浮き抑制発泡性入浴剤。(1) In bath additives containing fumaric acid and carbonate, one or more water-soluble polymer compounds and surfactants selected from the group consisting of polyvinylpyrrolidone, hydroxypropyl cellulose, and polyvinyl alcohol are each 1-20% by weight based on acid and 0.
A foaming bath additive that suppresses floating and contains fumaric acid in an amount of less than 1% by weight.
テルおよび／またはショ糖脂肪酸エステルである請求項
１記載の入浴剤。(2) The bath additive according to claim 1, wherein the surfactant is polyoxyethylene alkyl ether and/or sucrose fatty acid ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24947589A JPH03112922A (en) | 1989-09-25 | 1989-09-25 | Foamable bathing agent for inhibiting floating of fumaric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24947589A JPH03112922A (en) | 1989-09-25 | 1989-09-25 | Foamable bathing agent for inhibiting floating of fumaric acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03112922A true JPH03112922A (en) | 1991-05-14 |
Family
ID=17193517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24947589A Pending JPH03112922A (en) | 1989-09-25 | 1989-09-25 | Foamable bathing agent for inhibiting floating of fumaric acid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03112922A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007250642A (en) * | 2006-03-14 | 2007-09-27 | Toyo Denso Co Ltd | Compact and lightweight plug top direct-coupled ignition coil device |
| JP2009021295A (en) * | 2007-07-10 | 2009-01-29 | Shindengen Electric Mfg Co Ltd | Magnetic component |
| JP2012131739A (en) * | 2010-12-22 | 2012-07-12 | Kao Corp | Powder bubble bath composition |
| JP2012131740A (en) * | 2010-12-22 | 2012-07-12 | Kao Corp | Granular bath agent composition |
| JP2014043410A (en) * | 2012-08-27 | 2014-03-13 | Bathclin Corp | Briquette-type bathing agent |
-
1989
- 1989-09-25 JP JP24947589A patent/JPH03112922A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007250642A (en) * | 2006-03-14 | 2007-09-27 | Toyo Denso Co Ltd | Compact and lightweight plug top direct-coupled ignition coil device |
| JP2009021295A (en) * | 2007-07-10 | 2009-01-29 | Shindengen Electric Mfg Co Ltd | Magnetic component |
| JP2012131739A (en) * | 2010-12-22 | 2012-07-12 | Kao Corp | Powder bubble bath composition |
| JP2012131740A (en) * | 2010-12-22 | 2012-07-12 | Kao Corp | Granular bath agent composition |
| JP2014043410A (en) * | 2012-08-27 | 2014-03-13 | Bathclin Corp | Briquette-type bathing agent |
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