JP2005281131A - 水素と電気エネルギーの同時生産のためのシステム及び方法 - Google Patents
水素と電気エネルギーの同時生産のためのシステム及び方法 Download PDFInfo
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Abstract
【解決手段】 水素と電気エネルギーの同時生産のためのシステムは、改質装置燃料と蒸気を受けて、水素リッチ改質油(44)を生成するように構成された改質装置(4)を含む。改質装置(4)と流体連通する分離ユニット(12)を更に含み、この分離ユニット(12)は、改質油(44)を受けて、該改質油(44)から水素を分離して排ガス(18)を生成するように構成される。また、燃焼用に燃料を受けて熱エネルギーと高温圧縮ガス(22)とを生成するように構成された燃焼器(6)を含み、この燃焼器(6)は、改質装置(4)と結合される。ガススタービンは、高温圧縮ガス(22)を膨張させて電気エネルギーと膨張ガス(30)とを生成し、燃焼器(6)からの熱エネルギーの少なくとも一部は、改質装置(4)内で改質油(44)を生成するのに使用される。
【選択図】 図1
Description
CH4 + H2O => CO + 3H2 (1)
CO + H2O => CO2 + H2 (2)
流入する燃料8の少なくとも一部は、改質装置4の改質プロセスによって転化されて水素を発生する。改質反応(1)は、ニッケルのような適切な蒸気改質触媒の存在下で起こる。改質反応(1)は、極めて吸熱性があり、約88,630BTU/moleの反応熱を有する。他の炭化水素燃料の改質反応は、同様に吸熱性である。改質油流44は、一酸化炭素(CO)、二酸化炭素(CO2)、水素(H2)、未使用燃料、及び水を含む。改質油流44は、分離ユニット12に供給され、該分離ユニットは、改質油流44から水素と一酸化炭素を分離して、二酸化炭素リッチ流14、水素リッチ流れ16、及び排ガス流18を生成する。1つの実施形態では、排ガス流18は燃料入口流8に再循環されて戻され、混合された流れは、蒸気と共に改質装置4に供給される。
6 燃焼器
8 改質装置燃料
10 燃料
12 分離ユニット
18 排ガス
22 高温圧縮ガス
26 ガスタービン
30 膨張ガス
32 熱回収蒸気発生器、HRSG
44 改質油
54 熱交換器
56 水ガスシフト反応器
60 水素及び二酸化炭素リッチ流
Claims (10)
- 水素と電気エネルギーの同時生産のためのシステムであって、
改質装置燃料(8)及び蒸気を受けて、水素リッチ改質油(44)を生成するように構成された改質装置(4)と、
前記改質装置(4)と流体連通し、前記改質油(44)を受けて該改質油(44)から水素を分離して排ガス(18)を生成するように構成された分離ユニット(12)と、
燃焼用に燃料(10)を受けて熱エネルギーと高温圧縮ガス(22)とを生成するように構成され、前記改質装置(4)と結合された燃焼器(6)と、
前記高温圧縮ガス(22)を膨張させて電気エネルギーと膨張ガス(30)とを生成するガススタービン(26)と、
を備え、
前記燃焼器(6)からの熱エネルギーの少なくとも一部が、前記改質装置(4)内で前記改質油(44)を生成するのに使用されることを特徴とするシステム。 - 前記排ガス(18)の少なくとも一部が、水素を分離した後に前記改質装置(4)に再循環されて戻される請求項1に記載のシステム。
- 前記改質油(44)が更に、一酸化炭素、二酸化炭素、及び前記改質装置燃料を含む請求項1に記載のシステム。
- 前記分離ユニット(12)が更に、一酸化炭素を二酸化炭素に転化して、水素と二酸化炭素リッチ流(60)とに転化する水ガスシフト反応器(56)を備える請求項3に記載のシステム。
- 蒸気を発生するための熱交換器(54)を更に備える請求項1に記載のシステム。
- 前記分離ユニット(12)から生成された前記水素が、前記燃焼器(6)用の燃料として使用される請求項1に記載のシステム。
- 蒸気を発生する熱回収蒸気発生器(HRSG)(32)と蒸気タービンとを更に備える請求項1に記載のシステム。
- 水素と電気エネルギーの同時生産のためのシステムであって、
改質装置燃料と蒸気を受けて、水素リッチ改質油(44)を生成するように構成された改質装置(4)と、
燃焼用に燃料(10)を受けて熱エネルギーと高温圧縮ガス(22)とを生成するように構成され、前記改質装置(4)と結合された燃焼器(6)と、
前記改質装置(4)と流体連通し、前記改質油(44)を受けて前記改質油(44)から水素を分離して排ガス(18)を生成するように構成された分離ユニット(12)と、
を備え、
前記燃焼器(6)からの前記熱エネルギーの少なくとも一部が、前記改質装置(4)内で前記改質油(44)を生成するのに使用され、
前記高温圧縮ガス(22)を膨張させて電気エネルギーと膨張ガス(30)とを生成するガススタービン(26)が更に設けられ、
前記燃焼器(6)からの熱エネルギーの少なくとも一部が、前記改質装置(4)内で前記改質油(44)を生成するのに使用され、前記分離ユニット(12)が前記改質油(44)から二酸化炭素を分離して、前記排ガス(18)の少なくとも一部を前記改質装置(4)に再循環させるように構成されたシステム。 - 水素及び電気エネルギーの同時生産のための方法であって、
改質装置燃料と蒸気との混合体を改質装置(4)内で改質して水素リッチ改質油(44)を生成する段階と、
前記改質油(44)から水素を分離して排ガス(18)を生成する段階と、
前記改質装置(4)と結合された燃焼器(6)内で燃料を燃焼させて熱エネルギーと高温圧縮ガス(22)とを生成する段階と、
前記高温圧縮ガス(22)を膨張中のガススタービン(26)内で膨張させて電気エネルギーと膨張ガス(30)とを生成する段階と、
を含み、
前記燃焼器(6)からの前記熱エネルギーの少なくとも一部が、前記改質装置(4)内で前記改質油(44)を生成するのに使用されるようにする方法。 - 燃焼器改質装置システムであって、
燃料及び酸化剤を受けて燃焼させ、高温圧縮ガス(22)及び熱エネルギーを生成するように構成された燃焼器(6)と、
前記燃焼器(6)に密接して接触し、改質装置燃料及び蒸気を受けて水素リッチ改質油(44)を生成するように構成された改質装置(4)と、
を備え、
前記改質装置(4)が前記燃焼器(6)と結合され、前記燃焼器(6)からの前記熱エネルギーの少なくとも一部が、前記改質装置(4)内で前記改質油(44)を生成するのに使用されることを特徴とする燃焼器改質装置システム。
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Cited By (7)
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JP2007302553A (ja) * | 2006-05-09 | 2007-11-22 | Ifp | オンサイト水素燃焼による熱供給で炭化水素の留分を水蒸気改質することにより水素富有ガスと電力とを併産する方法 |
JP2008180213A (ja) * | 2006-12-18 | 2008-08-07 | General Electric Co <Ge> | NOx排出物を低減させるための改良システム及び方法 |
JP2008179496A (ja) * | 2007-01-23 | 2008-08-07 | Toho Gas Co Ltd | 水素製造装置およびその方法 |
JP2009508790A (ja) * | 2005-09-19 | 2009-03-05 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | 少なくとも1つのガスタービンにより製造される酸素含有ガスを用いて合成ガスを製造するための方法 |
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KR20190080354A (ko) * | 2017-12-28 | 2019-07-08 | 대우조선해양 주식회사 | 부유식 발전 플랜트 및 부유식 발전 플랜트의 운용 방법 |
JP2020501076A (ja) * | 2016-11-09 | 2020-01-16 | 8 リバーズ キャピタル,エルエルシー | 水素の一貫生産を伴う電力生産のためのシステム及び方法 |
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JP2011207755A (ja) * | 2010-03-30 | 2011-10-20 | General Electric Co <Ge> | 流体被冷却改質器および改質器を冷却するための方法 |
JP2020501076A (ja) * | 2016-11-09 | 2020-01-16 | 8 リバーズ キャピタル,エルエルシー | 水素の一貫生産を伴う電力生産のためのシステム及び方法 |
JP7113394B2 (ja) | 2016-11-09 | 2022-08-05 | 8 リバーズ キャピタル,エルエルシー | 水素の一貫生産を伴う電力生産のためのシステム及び方法 |
KR20190080354A (ko) * | 2017-12-28 | 2019-07-08 | 대우조선해양 주식회사 | 부유식 발전 플랜트 및 부유식 발전 플랜트의 운용 방법 |
KR102473954B1 (ko) * | 2017-12-28 | 2022-12-05 | 대우조선해양 주식회사 | 부유식 발전 플랜트 및 부유식 발전 플랜트의 운용 방법 |
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EP1582502A1 (en) | 2005-10-05 |
CN1676460A (zh) | 2005-10-05 |
EP1582502B1 (en) | 2018-05-16 |
CN1676460B (zh) | 2011-06-08 |
US7752848B2 (en) | 2010-07-13 |
US20050210881A1 (en) | 2005-09-29 |
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