JP4693715B2 - 二酸化炭素隔離を伴う発電用システムおよび方法 - Google Patents
二酸化炭素隔離を伴う発電用システムおよび方法 Download PDFInfo
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- JP4693715B2 JP4693715B2 JP2006187421A JP2006187421A JP4693715B2 JP 4693715 B2 JP4693715 B2 JP 4693715B2 JP 2006187421 A JP2006187421 A JP 2006187421A JP 2006187421 A JP2006187421 A JP 2006187421A JP 4693715 B2 JP4693715 B2 JP 4693715B2
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C9/00—Controlling gas-turbine plants; Controlling fuel supply in air- breathing jet-propulsion plants
- F02C9/26—Control of fuel supply
- F02C9/40—Control of fuel supply specially adapted to the use of a special fuel or a plurality of fuels
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
- F02C3/22—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/34—Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C7/00—Features, components parts, details or accessories, not provided for in, or of interest apart form groups F02C1/00 - F02C6/00; Air intakes for jet-propulsion plants
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C9/00—Controlling gas-turbine plants; Controlling fuel supply in air- breathing jet-propulsion plants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
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- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Carbon And Carbon Compounds (AREA)
- Treating Waste Gases (AREA)
Description
CO+H2O ⇒ CO2+H2 (2)
入ってくる燃料106の少なくとも一部分が、改質区域104内での改質プロセスによって変換されて、水素を発生する。改質反応(1)は通常、ニッケルなど適切な蒸気改質触媒の存在下で行われる。改質反応(1)は、一般には高い吸熱性のものであり、約88630BTU/モルの反応熱を有する。他の炭化水素燃料の改質反応も同様に吸熱性である。一酸化炭素と水とがさらに反応して、改質区域104内で二酸化炭素を生成する場合がある。これは、水性ガスシフト反応として知られている発熱反応(2)によって実現される場合がある。改質物の流れ110は、一般には少なくとも一酸化炭素(CO)、二酸化炭素(CO2)、水素(H2)、未利用燃料、および水を含む。水素発生システム102は、熱交換器112および水素分離器120を含むことができる。改質物の流れ110は、熱交換器112を使用して約200℃〜約400℃の範囲内の温度まで冷却することができ、冷却された改質物の流れ118を発生する。他の例示的な温度範囲は、約225℃〜約375℃、および約250℃〜約350℃を含む。冷却された改質物の流れ118は、分離ユニット120内に導入することができ、この分離ユニット120が、冷却された改質物の流れ118から水素を分離して、水素リッチな蒸気124とオフガス流122とを生成する。
12 第1のタービンシステム
14 第1の燃料
16 第2のタービンシステム
18 第2の燃料
20 圧縮酸化剤
22 第1の燃焼室
24 第1の圧縮機
26 圧縮酸化剤の第1の部分
28 第1のタービン
30 第1の排出
32 第1の排気
34 第2の燃焼室
36 圧縮酸化剤の第2の部分
38 第2のタービン
40 第2の排出
42 第2の排気
44 第2の圧縮機
46 再循環流
48 スプリット流
50 CO2分離ユニット
52 回転子
54 発電機
56 第1のHRSG
58 回転子
60 発電機
62 第2のHRSG
64 水
66 蒸気の第1の部分
68 冷却された第1の排気
70 水
72 蒸気の第2の部分
74 蒸気タービン
76 発電機
78 冷却された第2の排気
80 水分分離器
82 水分分離器からの放出流
84 第2の圧縮機44からの圧縮流
86 CO2リッチな流れ
88 CO2希薄な流れ
100 発電システム
102 水素発生システム
104 改質区域
106 燃料
108 バーナー
110 改質物
112 熱交換器
114 水
116 蒸気
118 冷却された改質物
120 水素分離器
122 オフガス
124 水素リッチな流れ
126 補給燃料および空気
128 バーナーからの排気ガス
130 熱交換器
132 冷却されたスプリット流
134 CO2分離器
136 CO2リッチな流れ
138 CO2希薄な流れ
140 加熱されたCO2希薄な流れ
150 発電のための方法
152 第1のステップ
154 第2のステップ
156 第3のステップ
158 第4のステップ
160 第5のステップ
Claims (10)
- 第1のガスタービンシステム(12)と第2のガスタービンシステム(16)とを有する発電システムであって、
前記第1のガスタービンシステム(12)が、
炭素ベース燃料を実質的に含まない主として水素からなる第1の燃料流(14)を燃焼するように構成された第1の燃焼室(22)と、
圧縮酸化剤の第1の部分(26)を前記第1の燃焼室(22)に供給するように構成された第1の圧縮機(24)と、
前記第1の燃焼室(22)からの第1の排出(30)を受け取り、第1の排気(32)および電気エネルギーを発生するように構成された第1のタービン(28)と、を備え、
前記第2のガスタービンシステム(16)が、
第2の燃料流(18)を燃焼して第2の排出(40)を発生するように構成された第2の燃焼室(34)であって、前記第1のガスタービンシステム(12)の前記第1の圧縮機(24)が圧縮酸化剤の第2の部分(36)を前記第2の燃焼室に供給するように構成されている第2の燃焼室(34)と、
前記第2の燃焼室(34)からの前記第2の排出を受け取って、第2の排気(42)および電気エネルギーを発生するように構成された第2のタービン(38)と、
二酸化炭素を含む前記第2の排出(42)を受け取り、再循環流(46)を前記第2の燃焼室(34)に排出し、かつスプリット流(48)を、二酸化炭素を回収するように適合された分離器システム(50)に排出するように構成された第2の圧縮機(44)と、を備える、発電システム。 - 前記分離器システム(50)が、スプリット流から熱を回収するように構成された熱交換器(130)と、二酸化炭素リッチな流れおよび二酸化炭素希薄な流れを発生するように構成された二酸化炭素分離器(134)とを備える請求項1記載のシステム。
- 前記熱交換器(130)が、前記二酸化炭素分離器(134)からの前記二酸化炭素希薄な流れとの交換時に、前記スプリット流(48)から熱を回収するように構成された相互交換器を備える請求項2記載のシステム。
- 前記二酸化炭素分離器(134)がメンブレンユニットを備える請求項2又は3に記載のシステム。
- 前記第1の排気(32)から熱を回収して、蒸気の第1の部分(66)を発生するように構成された第1の熱回収蒸気発生器(56)と、前記第2の排気(42)から熱を回収して、蒸気の第2の部分(72)を発生するように構成された第2の熱回収蒸気発生器(62)とを更に備える請求項1乃至4のいずれか1項に記載のシステム。
- 水素発生システム(102)を更に備える請求項1乃至5のいずれか1項に記載のシステム。
- 前記水素発生システム(102)が、化石ベース燃料を改質して、水素を含む改質物(110)を発生するように構成された改質区域(104)を備える請求項6記載のシステム。
- 前記水素発生システム(102)が、さらに熱交換器(112)と水素分離器(120)とを備える請求項7記載のシステム。
- 前記水素分離器(120)が圧力スイング吸着を採用する請求項8記載のシステム。
- 炭素ベース燃料を実質的に含まない水素リッチな流れを燃焼し、二酸化炭素を実質的に含まない排気を排出するように構成された第1のタービンシステム(12)と、
炭素ベース燃料を燃焼し、二酸化炭素リッチな圧縮流を、二酸化炭素を回収するように適合された二酸化炭素分離器(134)に排出するように構成された第2のタービンシステム(16)とを備える発電システムであって、前記第1のタービンシステム(12)内の圧縮機が前記第2のタービンシステム(16)に空気を供給するように構成され、
実質的な量の二酸化炭素を大気へ排出しない発電システム。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US11/178,165 | 2005-07-08 | ||
US11/178,165 US7266940B2 (en) | 2005-07-08 | 2005-07-08 | Systems and methods for power generation with carbon dioxide isolation |
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JP2007016787A JP2007016787A (ja) | 2007-01-25 |
JP4693715B2 true JP4693715B2 (ja) | 2011-06-01 |
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JP2006187421A Expired - Fee Related JP4693715B2 (ja) | 2005-07-08 | 2006-07-07 | 二酸化炭素隔離を伴う発電用システムおよび方法 |
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US (1) | US7266940B2 (ja) |
EP (1) | EP1741899A3 (ja) |
JP (1) | JP4693715B2 (ja) |
KR (1) | KR101280164B1 (ja) |
CN (1) | CN100549389C (ja) |
CA (1) | CA2551219C (ja) |
MX (1) | MXPA06007819A (ja) |
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CA2551219A1 (en) | 2007-01-08 |
CN1959085A (zh) | 2007-05-09 |
MXPA06007819A (es) | 2007-01-10 |
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KR20070006616A (ko) | 2007-01-11 |
US20070006592A1 (en) | 2007-01-11 |
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CA2551219C (en) | 2014-08-05 |
EP1741899A2 (en) | 2007-01-10 |
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US7266940B2 (en) | 2007-09-11 |
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