JP2005104973A - 化粧料用組成物 - Google Patents
化粧料用組成物 Download PDFInfo
- Publication number
- JP2005104973A JP2005104973A JP2004259518A JP2004259518A JP2005104973A JP 2005104973 A JP2005104973 A JP 2005104973A JP 2004259518 A JP2004259518 A JP 2004259518A JP 2004259518 A JP2004259518 A JP 2004259518A JP 2005104973 A JP2005104973 A JP 2005104973A
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- Prior art keywords
- cosmetic
- group
- acid
- mass
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 104
- 239000000203 mixture Substances 0.000 title claims abstract description 64
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- 229920001296 polysiloxane Polymers 0.000 claims abstract description 68
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 125000000129 anionic group Chemical group 0.000 claims abstract description 14
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 3
- 239000000843 powder Substances 0.000 claims description 43
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 229920000642 polymer Polymers 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
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- 150000002009 diols Chemical class 0.000 description 6
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 6
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- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
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- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A—HUMAN NECESSITIES
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- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
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Landscapes
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- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
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- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
(Xは、芳香族、脂肪族、及び脂環式型の炭化水素基からなる群より選ばれる2価の炭化水素基)
を介して互いに結合されているポリシロキサン共重合体を含む化粧料用組成物である。
上記本発明の好ましい態様は下記のとおりである。
前記アルキル基が、炭素数16〜38のアルキル基である上記化粧料用組成物。
前記ポリシロキサン繰り返し単位(D)が、分子量500〜20,000の、2個の水酸基を有するポリシロキサンから誘導されたものである上記化粧料用組成物。
繰り返し単位(A)が、下記式(2)で表される基を含むことを特徴とする上記化粧料用組成物。
(Zは完全にまたは部分的にカチオン性の基で中和されていてもよいアニオン性の基であり、R1はメチル基もしくはエチル基である)
前記アニオン性基が、カルボキシル基である上記化粧料用組成物。
繰り返し単位(B)が、下記式(3)で表される基を含む上記化粧料用組成物。
(式(3)において、R2は炭素数8〜64の分岐していてよいアルキル基であり、Qは下記式(4)で表される基、(5)で表される基又はこれらの組合わせである。
繰り返し単位(A)、(B)、及び(D)が、合計重量に基き夫々0.1〜30質量%、1〜95質量%、及び1〜95質量%で含有されている上記化粧料用組成物。
繰り返し単位(A)、(B)、及び(D)に加え、下記基を含むところの繰り返し単位(C)が、それらの合計重量に基き0.1〜70質量%で含有されている上記化粧料用組成物。
(式(6)において、R3はO、N、及びS原子の少なくとも1種を含んでいてもよい炭素数1〜20の2価の炭化水素基である)
繰り返し単位(A)、(B)、(C)、及び(D)が、それらの合計重量に基き夫々1〜20質量%、5〜90質量%、1〜70質量%及び1〜80質量%で含有されている上記化粧料用組成物。
ポリシロキサン共重合体が、数平均分子量(ポリスチレン換算)2,000〜100,000を有する上記化粧料用組成物。
エマルジョンの形態である上記化粧料用組成物。
また、本発明は、上記化粧料用組成物(a)を総重量の2〜95質量%で含む化粧料にも関する。
好ましくは、該化粧料は、(b)油剤、(c)アルコール性水酸基(但し、炭素数11以上のアルコールを除く)を有する化合物、(d)水溶性高分子及び/又は水膨潤性高分子、(e)粉体及び/又は着色剤、(f)界面活性剤、(g)架橋型オルガノポリシロキサン、及び(h)25℃でガム状乃至非弾性固体状であり且つデカメチルシクロペンタシロキサンに可溶であるポリシロキサン樹脂の少なくとも1種をさらに含む、スキンケア化粧料、頭髪化粧料、制汗剤化粧料、メ−クアップ化粧料又は紫外線防御化粧料である。
(Xは、芳香族、脂肪族、及び脂環式型の炭化水素基からなる群より選ばれる2価の炭化水素基)
を介して互いに結合されているポリシロキサン共重合体を含む。Xとしては、ヘキサメチレン基、4,4’-ジフェニルメタン基、P-フェニレン基及び4,4’-メチレンビスシクロヘキシル基およびイソホロン基などが例示され、好ましくは、ヘキサメチレン基である。ジイソシアネート残基(1)は、Xを有するジイソシアネート化合物、例えばヘキサメチレンジイソシアネート、4,4’-ジフェニルメタンジイソシアネート、2,4‐トリレンジイソシアネート、2,6‐トリレンジイソシアネート、1-メチルシクロヘキシレン-2,4-ジイソシアネート、1-メチルシクロヘキシレン-2,6-ジイソシアネート、4,4’-ジシクロヘキシルメタンジイソシアネート、1,5-ナフチレンジイソシアネート、3,3’-ジメチル-4,4’-ビフェニレンジイソシアネート、キシリレンジイソシアネート、水添キシリレンジイソシアネート、イソホロンジイソシアネート、2,2,4-トリメチルヘキサメチレンジイソシアネート等とジオールとを反応させることによって形成することができる。
で表される基を含む。式(2)において、Zはカチオン性の基で中和されていてもよいアニオン性の基であり、R1はメチル基もしくはエチル基である。該アニオン性基としては、カルボキシル基、スルホン酸基、フェノール性基、及び、リン酸基等を挙げることができるが、好ましくはカルボキシル基である。中和は、カチオン性基を含む化合物、例えば無機もしくは有機塩基により行うことができ、その程度は、10〜100%当量、好ましくは30〜60%当量である。(A)単位は、ジメチロールプロパン酸又はジメチロールブタン酸から誘導することができる。
で表される基を含む。式(3)においてR2は炭素数8〜64の分岐していてもよいアルキル基である。R2の炭素数及び分岐の有無は、主として、化粧料を調製する際に使用する油剤により適宜変えることが好ましいが、典型的には炭素数16〜38の直鎖基である。 式(3)において、Qは下記式(4)で表される基、(5)で表される基又はこれらの組合わせである。
繰り返し単位(B)は、例えばダイセル化学工業製AOG−X68(構造式、CH2(OH)−CH(OH)−(CH2)nCH3、水酸基価は311KOHmg/g、平均分子量360、nの平均は約20)、同AOG−Y08(構造式、CH2(OH)−CH(OH)−(CH2)nCH3、水酸基価は204KOHmg/g、平均分子量550、nの平均は約34)から誘導することができる。
(式(7)において、R4は炭素数1〜7のアルキル基、p、q、s及びtは1〜5の整数、rは5〜60の整数である。)
(式(8)において、uは5〜60の整数、vは1〜5の整数、R4は式(8)において述べたのと同じであり、R5は水素原子または炭素数1〜7のアルキル基である。)
式(6)において、R3はO、N、及びS原子の少なくとも1種を含んでいてもよい炭素数1〜20の2価の炭化水素基である。繰り返し単位(C)はジオール化合物、但し、繰り返し単位(B)を誘導するために使用するものを除く、から誘導することができる。該ジオール化合物としては公知のもの、例えばエチレングリコール、1,3−プロピレングリコール、1,2−プロピレングリコール、1,3−ブタンジオール、1,4−ブタンジオール、1,5−ペンタンジオール、1,6−ヘキサンジオール、3−メチル−1,5−ペンタンジオール、ネオペンチルグリコール、1,8−オクタンジオール、1,9−ノナンジオール、及びポリカーボネートジオール、例えばダイセル化学工業製、プラクセルCD220、を使用することができ、好ましくはポリカーボネートジオールが使用される。
ここでR6は、水素原子、水酸基又は炭素数2〜20の1価の非置換又はフッ素置換アルキル基、アリール基、アミノ置換アルキル基、アルコキシ基及び一般式(CH3)3SiO[(CH3)2SiO]lSi(CH3)2CH2CH2−で示される基から選択される基である。mは0〜1000の整数、nは0〜1000の整数、m+nが1〜2000の整数、x、yは0、1、2又は3、h及びjは0〜8の整数で3≦h+j≦8、kは1〜4の整数、lは0〜500の整数である。
以下に、本発明を実施例によって更に詳述するが、本発明はこれによって限定されるものではない。尚、特に断らない限り、以下に記載する「%」は「質量%」を意味する。
(水酸基価59KOHmg/g)を160g、テトラヒドロフランを196g加え、均一に溶解させた。続いてヘキサメチレンジイソシアネートを65.5g加えて80℃で反応を行い、赤外吸収スペクトルで2,270cm-1の遊離イソシアネート基がないことを確認した後、50℃に冷却し、不揮発成分量に対し40%となるイオン交換水と、中和剤:NaOHを3.9g(COOHの50%当量)加え、系内を均一に乳化させた。
最後に、系内のテトラヒドロフランを真空蒸留により除いてエマルジョン状の組成物を得た。該エマルジョンを乾燥させて得られた共重合体の酸価は、0.66KOHmg/g、その数平均分子量は、12,100であった。
最後に、系内のテトラヒドロフランを真空蒸留により除いてエマルジョン状の組成物を得た。該エマルジョンを乾燥させて得られた共重合体の酸価は、0.90KOHmg/gであった。その数平均分子量は、10,100であった。
(水酸基価35KOHmg/g)を120g、テトラヒドロフランを191g加え、均一に溶解させ、溶液濃度を調節した。続いてヘキサメチレンジイソシアネートを61.5g加えて80℃で反応を行い、赤外吸収スペクトルで2,270cm-1の遊離イソシアネート基がないことを確認した後、50℃に冷却し、固形分に対し40%となるイオン交換水と、中和剤:トリエチルアミンを6.5g(COOHの35%当量)加え、系内を均一に乳化させた。最後に、系内のテトラヒドロフランを真空蒸留により除いてエマルジョン状の組成物を得た。該エマルジョンを乾燥させて得られた共重合体の酸価は、0.64KOHmg/gであった。その数平均分子量は、13,200であった。
・AOG−X68:1,2−ヒドロキシアルカン(ダイセル化学工業製)
CH2(OH)−CH(OH)−(CH2)nCH3(nの平均は約20、平均分子量360)
・AOG−Y08:1,2−ヒドロキシアルカン(ダイセル化学工業製)
CH2(OH)−CH(OH)−(CH2)nCH3(nの平均は約34、平均分子量550)
・プラクセルCD220:ポリカーボネートジオール(ダイセル化学工業社製)
HO(C6H12OC(=O)O)nC6H12OH(nの平均は約13、平均分子量2,000)
(処方)
質量(%)
1. ステアリン酸 1.0
2. ベヘニルアルコール 0.4
3. モノステアリン酸グリセリル 0.3
4. 流動パラフィン 10.0
5. トリオクタノイン 5.0
6. ステアリル変性アクリレートシリコーン(注1) 3.0
7. セスキオレイン酸ソルビタン 0.5
8. ポリソルベート80 1.0
9. アクリル酸/アルキルコポリマー(30%aq) 2.0
10.1,3−ブチレングリコール 3.0
11.トリエタノールアミン 1.0
12.実施例1の組成物 8.0
13.顔料 10.0
14.精製水 62.0
(注1)信越化学工業(株)製:KP−561P(商品名)
(製造方法)
A)成分1〜8を加熱溶解する。
B)成分9〜12及び14の一部を混合し、加熱する。
C)成分13を14の残部に混合し分散する。
D)上記B)にA)を加え乳化する。
E)C)をD)に加え、混合する
以上のようにして得られた本発明品のO/Wリキッドファンデーションは、べたつきがなく、のび広がりも軽く、しかも、密着感に優れ、おさまりも良く、化粧持ちに優れたファンデーションである事が判った。
(処方)
質量(%)
1. デキストリン脂肪酸エステル 9.0
2. トリオクタノイン 18.0
3. フェニルポリシロキサン(注1) 4.0
4. 有機変性ベントナイト 1.0
5. ポリエーテル変性シリコーン(注2) 1.5
6. デカメチルペンタシロキサン 40.5
7. 1,3−ブチレングリコール 3.0
8. 実施例4の組成物 6.0
9. 顔料 8.0
10.精製水 9.0
(注1)信越化学工業(株)製:KF−54(商品名)
(注2)信越化学工業(株)製:KF−6028(商品名)
(製造方法)
A)成分1〜6、10を加熱攪拌する。
B)成分7〜9を混合し、加熱する。
C)A)にB)を加え乳化する。
以上のようにして得られた本発明品のW/O口紅は、のび広がりも軽く、しかも、密着感に優れ、化粧持ちに優れた口紅である事が判った。
(処方)
質量(%)
1. ステアリン酸 1.0
2. セチルアルコール 0.5
3. ステアリン酸モノグリセライド 0.5
4. ミツロウ 7.0
5. カルナバワックス 2.0
6. トリオクタノイン 3.0
7. セスキオレイン酸ソルビタン 0.7
8. ポリソルベート80 1.5
9. 1,3−ブチレングリコール 5.0
10.アクリル酸/アルキルコポリマー(30%aq) 2.5
11.実施例1の組成物 25.0
12.トリエタノールアミン 0.7
13.顔料 10.0
14.精製水 40.6
(製造方法)
A)成分1〜8を加熱攪拌する。
B)成分13をA)に加え混合分散する。
C)成分9〜12,14を混合し加熱する。
D)C)をB)に加え乳化する。
以上のようにして得られた本発明品のO/Wマスカラは、カール性に優れ、化粧持ちの良いマスカラである事が判った。
(処方)
質量(%)
1. ステアリン酸 1.0
1. 実施例3の組成物 50.0
2. アクリル酸/アルキルコポリマー(30%aq) 2.5
3. トリエタノールアミン 0.7
4. ポリオキシエチレンアルキルリン酸エステル 0.2
5. 顔料 15.0
6. 1,3−ブチレングリコール 6.0
7. 精製水 24.6
(製造方法)
A)成分1〜3、7の一部を混合する。
B)成分4〜6、7の残部を加え混合分散する。
C)B)をA)に加え混合する。
以上のようにして得られたアイライナーは密着性に優れ、化粧持ちの良いアイライナーである事が判った。
(処方)
質量(%)
1. 実施例1の組成物 8.0
2. カルボキシビニルポリマー(1%aq) 20.0
3. トリエタノールアミン 0.2
4. 1,3−ブチレングリコール 6.0
5. 精製水 65.8
(製造方法)
A)成分1〜5を混合する。
以上のようにして得られたヘアーセットローションはセット性に優れ、セット効果の持続性に優れたセットローションである事が判った。
(処方)
質量(%)
1. 実施例2の組成物 80.0
2. エタノール 10.0
3. 染料 3.0
4. 精製水 7.0
(製造方法)
A)成分1〜4を混合する。
以上のようにして得られた水系ネイルエナメルは安全性も高く、良好な艶、化粧持ちの持続性に優れたネイルエナメルである事が判った。
ジメチロールブタン酸を28.9g及びポリシロキサンを370.8g、夫々用い、及び、AOGを用いなかったことを除き、実施例1と同様にしてポリシロキサン共重合体組成物を得た。該組成物を、実施例5の実施例1の組成物に代えて用いたことを除き、実施例5と同様にO/Wリキッドファンデーションを調製した。得られたファンデーションは、実施例5のものと比べて、のび広がりが悪く、使用感が劣り、また、化粧持ちが悪かった。
Claims (25)
- 前記アルキル基が、炭素数16〜38のアルキル基であることを特徴とする請求項1記載の化粧料用組成物。
- 前記ポリシロキサン繰り返し単位(D)が、分子量500〜20,000の、2個の水酸基を有するポリシロキサンから誘導されたものであることを特徴とする請求項1または2記載の化粧料用組成物。
- 前記アニオン性基が、カルボキシル基であることを特徴とする請求項4記載の化粧料用組成物。
- 繰り返し単位(A)、(B)、及び(D)が、合計重量に基き夫々0.1〜30質量%、1〜95質量%、及び1〜95質量%で含有されていることを特徴とする請求項1〜6のいずれか1項記載の化粧料用組成物。
- 繰り返し単位(A)、(B)、(C)、及び(D)が、(A)〜(D)の合計重量に基き夫々1〜20質量%、5〜90質量%、1〜70質量%及び1〜80質量%で含有されていることを特徴とする請求項8記載の化粧料用組成物。
- ポリシロキサン共重合体が、数平均分子量(ポリスチレン換算)2,000〜100,000を有することを特徴とする請求項1〜9のいずれか1項記載の化粧料用組成物。
- エマルジョンの形態であることを特徴とする請求項1〜10のいずれか1項記載の化粧料用組成物。
- 請求項1〜11のいずれか1項記載の組成物(a)を総重量の2〜95質量%で含む化粧料。
- (b)油剤をさらに含む請求項12記載の化粧料。
- (b)油剤が、25℃で液状の油剤の少なくとも1種を含む、請求項13記載の化粧料。
- (b)油剤が、25℃で揮発性のシリコーン油を含む、請求項13又は14記載の化粧料。
- (b)油剤が、融点が50℃以上の固形油剤を含む、請求項13〜15のいずれか1項記載の化粧料。
- (c)アルコール性水酸基(但し、炭素数11以上のアルコールを除く)を有する化合物をさらに含有する請求項12〜16のいずれか1項記載の化粧料。
- (c)アルコール性水酸基を有する化合物が、炭素数2〜10の、水溶性の一価又は多価アルコールである、請求項17記載の化粧料。
- (d)水溶性高分子及び/又は水膨潤性高分子をさらに含有する請求項12〜18のいずれか1項記載の化粧料。
- (e)粉体及び/又は着色剤をさらに含有する請求項12〜19のいずれか1項記載の化粧料。
- (f)界面活性剤をさらに含有する請求項12〜20のいずれか1項記載の化粧料。
- (g)架橋型オルガノポリシロキサンをさらに含有する請求項12〜21のいずれか1項記載の化粧料。
- (g)架橋型オルガノポリシロキサンが、自重以上の重量の、粘度0.65mm2/秒(25℃)〜10.0mm2/秒(25℃)のシリコーンで膨潤された形態である、請求項22記載の化粧料。
- (h)25℃でガム状乃至非弾性固体状であり且つデカメチルシクロペンタシロキサンに可溶であるポリシロキサン樹脂をさらに含む、請求項12〜23のいずれか1項記載の化粧料。
- 化粧料が、スキンケア化粧料、頭髪化粧料、制汗剤化粧料、メ−クアップ化粧料又は紫外線防御化粧料である、請求項12〜24のいずれか1項記載の化粧料。
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JP2004259518A JP4491305B2 (ja) | 2003-09-10 | 2004-09-07 | 化粧料用組成物 |
US10/936,483 US7790191B2 (en) | 2003-09-10 | 2004-09-09 | Cosmetic composition |
DE602004010472T DE602004010472T2 (de) | 2003-09-10 | 2004-09-10 | Kosmetische Zubereitung enthaltend einen Polysiloxan Copolymer |
EP04077508A EP1514533B1 (en) | 2003-09-10 | 2004-09-10 | Cosmetic composition comprising a polysiloxane copolymer |
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JP2004259518A JP4491305B2 (ja) | 2003-09-10 | 2004-09-07 | 化粧料用組成物 |
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JP2005104973A true JP2005104973A (ja) | 2005-04-21 |
JP4491305B2 JP4491305B2 (ja) | 2010-06-30 |
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US (1) | US7790191B2 (ja) |
EP (1) | EP1514533B1 (ja) |
JP (1) | JP4491305B2 (ja) |
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Cited By (3)
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JP2007161716A (ja) * | 2005-12-16 | 2007-06-28 | L'oreal Sa | 少なくとも3つの水素結合の形成が可能な(チオ)ウレタン/(チオ)尿素コポリマーを含む化粧品組成物および美容処理方法 |
JP2007161715A (ja) * | 2005-12-16 | 2007-06-28 | L'oreal Sa | 少なくとも1つのイオン性基を含むコポリマーを含む化粧用または医薬用組成物および化粧用トリートメント方法 |
JP2012012351A (ja) * | 2010-07-02 | 2012-01-19 | Nikko Chemical Co Ltd | 油中水型乳化剤組成物及び該組成物を用いた油中水型乳化組成物並びに化粧料 |
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ES2380626T3 (es) * | 2004-10-22 | 2012-05-16 | L'oreal | Composiciones cosmética que contiene un polímero de poliorganosiloxano |
US8591923B2 (en) * | 2005-12-16 | 2013-11-26 | L'oreal | Cosmetic compositon comprising a (thio)urethane/(thio)urea copolymer capable of forming at least 3 hydrogen bonds, and a method of cosmetic treatment |
US20100008880A1 (en) * | 2006-05-03 | 2010-01-14 | John Castro | Clear Cosmetic Compositions And Methods Of Using |
US20070259012A1 (en) * | 2006-05-03 | 2007-11-08 | John Castro | Clear Cosmetic Compositions and Methods Of Use |
US8133477B2 (en) * | 2007-08-09 | 2012-03-13 | Hallstar Innovations Corp. | Dispersions of inorganic particulates containing alkoxycrylene |
WO2009150852A1 (ja) | 2008-06-12 | 2009-12-17 | 株式会社 資生堂 | 油中油型化粧料 |
US20100112022A1 (en) * | 2008-09-17 | 2010-05-06 | Jody Lynn Hoying | Antiperspirant Products and Methods of Merchandising the Same |
WO2011062449A2 (ko) * | 2009-11-20 | 2011-05-26 | (주)아모레퍼시픽 | 무기 분말을 함유하는 화장료 조성물 |
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WO2013137290A1 (ja) * | 2012-03-13 | 2013-09-19 | 住友精化株式会社 | 化粧料組成物 |
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US10765619B2 (en) * | 2018-06-04 | 2020-09-08 | Shin-Etsu Chemical Co., Ltd. | Silicone resin, making method, and cosmetics |
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- 2004-09-07 JP JP2004259518A patent/JP4491305B2/ja not_active Expired - Fee Related
- 2004-09-09 US US10/936,483 patent/US7790191B2/en active Active
- 2004-09-10 EP EP04077508A patent/EP1514533B1/en not_active Expired - Fee Related
- 2004-09-10 DE DE602004010472T patent/DE602004010472T2/de active Active
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JPH0789822A (ja) * | 1993-07-28 | 1995-04-04 | L'oreal Sa | 化粧料組成物 |
JPH0912425A (ja) * | 1995-06-27 | 1997-01-14 | L'oreal Sa | 化粧料又は皮膚科用組成物及びマルチブロック重縮合生成物 |
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Cited By (3)
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JP2007161716A (ja) * | 2005-12-16 | 2007-06-28 | L'oreal Sa | 少なくとも3つの水素結合の形成が可能な(チオ)ウレタン/(チオ)尿素コポリマーを含む化粧品組成物および美容処理方法 |
JP2007161715A (ja) * | 2005-12-16 | 2007-06-28 | L'oreal Sa | 少なくとも1つのイオン性基を含むコポリマーを含む化粧用または医薬用組成物および化粧用トリートメント方法 |
JP2012012351A (ja) * | 2010-07-02 | 2012-01-19 | Nikko Chemical Co Ltd | 油中水型乳化剤組成物及び該組成物を用いた油中水型乳化組成物並びに化粧料 |
Also Published As
Publication number | Publication date |
---|---|
EP1514533B1 (en) | 2007-12-05 |
JP4491305B2 (ja) | 2010-06-30 |
DE602004010472T2 (de) | 2008-11-13 |
US7790191B2 (en) | 2010-09-07 |
DE602004010472D1 (de) | 2008-01-17 |
US20050053571A1 (en) | 2005-03-10 |
EP1514533A1 (en) | 2005-03-16 |
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