JP2002330820A - Skin cleaning-wiping tissue paper - Google Patents
Skin cleaning-wiping tissue paperInfo
- Publication number
- JP2002330820A JP2002330820A JP2001140933A JP2001140933A JP2002330820A JP 2002330820 A JP2002330820 A JP 2002330820A JP 2001140933 A JP2001140933 A JP 2001140933A JP 2001140933 A JP2001140933 A JP 2001140933A JP 2002330820 A JP2002330820 A JP 2002330820A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- pulp
- weight
- talc
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Sanitary Thin Papers (AREA)
- Paper (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本願発明は、皮脂吸収作用を
もつ皮膚清拭用化粧用紙に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic paper for wiping skin having a sebum absorbing effect.
【０００２】[0002]
【従来の技術】人体の顔面皮膚に分泌される皮脂を吸収
して顔面を清拭する化粧用紙として脂取り紙が知られて
いる。この脂取り紙は、皮脂吸収性は勿論のこと、それ
以外にも、顔面皮膚への肌ざわり感触とか柔軟性といっ
た感覚上の要素も重要である。2. Description of the Related Art A grease-absorbing paper is known as a decorative paper for cleaning the face by absorbing sebum secreted into the facial skin of a human body. This fat-absorbing paper is not only important for sebum absorption, but also for sensory factors such as skin feel to the face skin and flexibility.
【０００３】ところで、皮脂吸収作用をもつ皮膚清拭用
化粧用紙（いわゆる「脂取り紙」）に柔軟性を付与する
ために色々な柔軟剤を使用することが考えられるが、従
来から一般的な柔軟剤の添加は、紙の繊維間結合を弱
め、脂取り紙の基本的機能である皮脂吸収作用を低下さ
せるという問題がある。[0003] By the way, various softeners may be used to impart softness to cosmetic paper for wiping the skin having a sebum-absorbing action (so-called "fatting paper"). There is a problem that the addition of the softener weakens the inter-fiber bond of the paper and reduces the sebum-absorbing action, which is a basic function of the greased paper.
【０００４】保湿効果により紙を柔軟化させる天然素材
に由来するコラーゲンなどの成分・繊維は非常に高価で
あり、また、硬化しやすく、その保湿能力が低下するた
め、効果を持続することが難しい。[0004] Components and fibers such as collagen derived from a natural material that softens paper due to its moisturizing effect are very expensive, are easily cured, and have a reduced moisturizing ability, so that it is difficult to maintain the effect. .
【０００５】また、天然に置き換え素材としての合成の
柔軟剤（たとえば、東邦化学 ソフノン）があるが、合
成柔軟剤は有臭性があり、化粧用紙には不適合である。[0005] In addition, there is a synthetic softener (eg, Toho Kagaku Sofnon) as a replacement material in nature, but the synthetic softener has an odorous property and is incompatible with decorative paper.
【０００６】一方、紙に柔軟性を付与するための物理的
方法として、いわゆる金箔打ち加工法があるが、この方
法は、生産性が悪くコスト高になり、消費者に安価な製
品を提供できない、という難点がある。On the other hand, as a physical method for imparting flexibility to paper, there is a so-called gold leaf stamping method. However, this method results in poor productivity and high cost, and cannot provide consumers with inexpensive products. There is a disadvantage.
【０００７】[0007]
【発明が解決しようとする課題】本願発明は、すぐれた
皮脂吸収性とともに、高度な柔軟性をそなえた皮膚清拭
用化粧用紙を低コストに提供しようとなされたものであ
る。SUMMARY OF THE INVENTION An object of the present invention is to provide a cosmetic paper for wiping the skin which has excellent sebum absorbency and high flexibility at a low cost.
【０００８】[0008]
【課題を解決するための手段】本願発明の皮膚清拭用化
粧用紙は、紙の主成分となる繊維原料のほかに、皮脂吸
収作用をもつ吸油性填料と、紙に柔軟性を付与する柔軟
剤とを基本構成要素としてなる。Means for Solving the Problems The decorative paper for skin wiping according to the present invention has an oil-absorbing filler having a sebum-absorbing action, in addition to a fiber raw material which is a main component of the paper, and a softness which imparts flexibility to the paper. And an agent as a basic component.
【０００９】本願発明の化粧用紙の原料となる繊維とし
ては、木材パルプ繊維、マニラ麻、亜麻、***、黄麻、
楮、三椏、雁皮等の靱皮繊維、コットン、藁、竹、ケナ
フ等の非木材パルプ繊維、アクリルやレーヨン等の化学
繊維、シルク等の動物繊維が挙げられる。特にマニラ
麻、亜麻、***、黄麻、楮、三椏、雁皮等の靱皮繊維を
原料とする化粧用紙は強度が高く、吸脂能力に優れてい
る。これらの繊維は、それぞれ単独で用いられてもよ
く、また２種以上を混合して用いてもよい。一般公知の
抄紙方法で抄紙された化粧用紙の坪量（ＪＩＳＰ−８１
２４による。以下、同じ）が８〜３０ｇ／ｍ2であれ
ば、化粧用紙として好適に使用できる。上記化粧用紙の
坪量が８ｇ／ｍ2未満であると強度が低く使用時に撚れ
や破損を生じやすくなり、坪量が３０ｇ／ｍ2を超える
とコストが嵩むだけでなく、また、しなやかさがなくな
り、使用感が悪化する。The fibers used as raw materials for the decorative paper of the present invention include wood pulp fibers, manila hemp, flax, hemp, jute,
Examples include bast fibers such as mulberry, mitsumata, and goose, non-wood pulp fibers such as cotton, straw, bamboo, and kenaf; chemical fibers such as acrylic and rayon; and animal fibers such as silk. In particular, decorative paper made from bast fibers such as manila hemp, flax, hemp, jute, jute, mulberry, mitsumata, and goose is a material with high strength and excellent oil absorbing ability. These fibers may be used alone or in combination of two or more. Basis weight (JISP-81) of decorative paper made by a generally known paper making method
24. The same applies hereinafter) if it is 8 to 30 g / m 2, which can be suitably used as decorative paper. If the basis weight of the decorative paper is less than 8 g / m 2 , the strength is low, and twisting or breakage tends to occur during use. If the basis weight exceeds 30 g / m 2 , not only the cost increases but also the flexibility is increased. Disappears and the usability deteriorates.
【００１０】脂取り紙用として好適な填料としては、従
来公知の吸油性無機填料が使用可能であるが、たとえば
スチレンビーズのような有機填料も使うことができる。As fillers suitable for fat-removing paper, conventionally known oil-absorbing inorganic fillers can be used, but organic fillers such as styrene beads can also be used.
【００１１】化粧用紙用、特に脂取り紙用として好適な
吸油性無機填料としては、クレー、タルク、炭酸カルシ
ウム、ホワイトカーボン、酸化チタン、ヒドロキシアパ
タイト等があるが、その中で最も好適な無機填料として
は本願出願人の先願にかかる特願２０００−２３４９０
８号で開示されている「ヒドロキシアパタイト」含有の
無機填料がある。ヒドロキシアパタイト［Ｃａ10（ＰＯ
4）6（ＯＨ）2］は、人の骨や歯の成分であり、リン酸
カリシウムの一種で、工業的には陽イオン、陰イオン、
たんぱく質、アミノ酸などに対して優れた吸着性を有す
る材料として、また、生体への影響が小さいことから、
人工歯根など生体適合材として注目されている。ヒドロ
キシアパタイトは、皮脂の中でも、特に酸化された皮脂
（過酸化脂質）を効率よく吸着する性質を有するため、
これを吸油性填料中に含有させることにより、酸化皮脂
を効率よく吸収する化粧用紙が得られる。ヒドロキシア
パタイトの含有量は、化粧用紙の主成分である繊維原料
に対して１〜１００重量％とするのがよい。１％未満だ
と十分な過酸化脂質吸着効果が得られず、１００％以上
だと化粧用紙としての十分な紙の強度が得られない。[0011] Oil-absorbing inorganic fillers suitable for decorative paper, especially for fat-removing paper, include clay, talc, calcium carbonate, white carbon, titanium oxide, hydroxyapatite and the like. Japanese Patent Application No. 2000-23490 related to the prior application of the present applicant.
No. 8 discloses an inorganic filler containing “hydroxyapatite”. Hydroxyapatite [Ca 10 (PO
4 ) 6 (OH) 2 ] is a component of human bones and teeth, and is a kind of potassium phosphate, and is industrially a cation, anion,
As a material with excellent adsorptivity to proteins and amino acids, and because it has a small effect on living organisms,
Attention has been paid to biocompatible materials such as artificial roots. Hydroxyapatite has the property of efficiently adsorbing oxidized sebum (lipid peroxide), especially among sebum,
By incorporating this in an oil-absorbing filler, a decorative paper that efficiently absorbs oxidized sebum can be obtained. The content of hydroxyapatite is preferably 1 to 100% by weight with respect to the fiber raw material which is the main component of the decorative paper. If it is less than 1%, a sufficient lipid peroxide adsorbing effect cannot be obtained, and if it is 100% or more, sufficient paper strength as decorative paper cannot be obtained.
【００１２】上記填料中には、さらにタルクを含有させ
るのが好適である。タルクの含有量は、化粧用紙の主成
分である繊維原料に対して０．５〜９０重量％とするの
がよい。また、上記填料は平均粒子径を０．５〜８μｍ
とするのがよい（就中、０．５〜２μｍの範囲が、化粧
用紙の平滑度を向上させる上で特に好適である）。更に
好適には、２種類以上の填料を組み合わせるのが好適で
あり、特にヒドロキシアパタイトとタルクの組み合わせ
は、柔軟性、吸脂性に好適な相乗効果をかもしだす。It is preferable that the filler further contains talc. The content of talc is preferably 0.5 to 90% by weight with respect to the fiber material which is the main component of the decorative paper. The filler has an average particle size of 0.5 to 8 μm.
(Particularly, the range of 0.5 to 2 μm is particularly preferable for improving the smoothness of the decorative paper). More preferably, two or more fillers are combined, and in particular, the combination of hydroxyapatite and talc produces a synergistic effect suitable for flexibility and oil absorbency.
【００１３】平均粒子径が０．５μｍ未満の填料は、紙
中への歩留まりが悪く、コスト的に不利であり、脂質の
除去性に劣る。平均粒子径が８μｍを超えると肌触りが
極端に悪化し、粉落ちなどの問題が生じる。上記のよう
に、填料中にタルクを０．５〜９０重量％含有させる
と、紙の平滑度が向上し、化粧用紙の肌触りがよくな
る。さらに加えて、吸脂時に紙の透明度を向上させる機
能がより優れたものとなる。また、本願発明の化粧用紙
には、保湿剤およびおしろい粉の少なくとも一方を含有
させることもできる。保湿剤やおしろい粉を含有させる
ことにより、皮膚の保護性や化粧の効果により優れた化
粧用紙となる。A filler having an average particle size of less than 0.5 μm has a low yield in paper, is disadvantageous in cost, and is inferior in lipid removal. If the average particle size exceeds 8 μm, the touch becomes extremely poor, and problems such as powder dropping occur. As described above, when talc is contained in the filler in an amount of 0.5 to 90% by weight, the smoothness of the paper is improved, and the feel of the decorative paper is improved. In addition, the function of improving the transparency of paper at the time of oil absorption becomes more excellent. Further, the decorative paper of the present invention may contain at least one of a humectant and a white powder. By containing a moisturizing agent and a white powder, it becomes a cosmetic paper which is more excellent in the protective properties of the skin and the effect of the makeup.
【００１４】本願発明の化粧用紙では、上記例示のよう
な填料のほかに、さらに化粧用紙に柔軟性を与付するた
めに多価アルコール系の柔軟剤を添加する。In the decorative paper of the present invention, a polyhydric alcohol-based softener is further added to the decorative paper in addition to the filler described above in order to impart flexibility to the decorative paper.
【００１５】本願発明にかかる化粧用紙は、上記例示の
填料や柔軟剤等が、どのような形態で含まれていてもよ
い。内添されていてもよいし、抄紙後の原紙に填料を塗
工するようにしてもよい。The decorative paper according to the present invention may contain the filler, the softener and the like exemplified above in any form. It may be internally added, or a filler may be applied to the base paper after paper making.
【００１６】なお、本願発明の化粧用紙は、既知の化粧
用紙の抄紙方法に基づいて、抄紙することが可能であ
る。たとえば、填料や柔軟剤等を添加した繊維パルプス
ラリーを既知の抄紙機によって抄紙して製造することが
可能である。The decorative paper of the present invention can be made based on a known decorative paper making method. For example, the fiber pulp slurry to which a filler, a softener and the like are added can be manufactured by making a paper using a known paper machine.
【００１７】一方、本願発明の化粧用紙は、次記の疑似
吸脂量測定方法による吸脂量が１ｇ／ｍ2以上であるこ
とが望ましい。吸脂量が１ｇ／ｍ2未満であると、吸収
する皮脂の量が少なすぎて化粧用紙として適さない。吸
脂量が１ｇ／ｍ2以上であれば、化粧用紙の皮脂吸収量
としては十分である。On the other hand, the decorative paper of the present invention desirably has an oil absorption of 1 g / m 2 or more according to the following pseudo oil absorption measurement method. If the amount of oil absorption is less than 1 g / m 2 , the amount of sebum absorbed is too small and is not suitable as a decorative paper. If the amount of oil absorption is 1 g / m 2 or more, the amount of sebum absorbed by the decorative paper is sufficient.
【００１８】上記疑似吸脂量測定法は、印刷適性試験機
の胴の表面に２１ｃｍ×２５ｃｍの試料片を粘着テープ
などで固定して有効面積１９ｃｍ×１８ｃｍとし、上記
印刷適性試験機の印刷ロールに油液（ヒマシ油８０重量
％＋ベンジルアルコール２０重量％）０．５ｍｌを膜厚
４．８μｍとなるように均一に塗布した上、上記胴と印
刷ロールとのニップ幅を５ｍｍとして転写回転速度３０
ｒｐｍで１回転させて、上記油液を上記試料に転写させ
る。その後に、転写後の有効面積分の試料片の重量から
転写前の有効面積分の紙の重量を差分した値（数１）に
基づいて、試料１ｍ2あたりの吸脂量とする。In the pseudo-absorbent amount measurement method, a 21 cm × 25 cm sample piece is fixed to the surface of a cylinder of a printability tester with an adhesive tape or the like to have an effective area of 19 cm × 18 cm. 0.5 ml of an oil solution (80% by weight of castor oil + 20% by weight of benzyl alcohol) was uniformly applied to the surface so as to have a film thickness of 4.8 μm, and the transfer rotation speed was set with the nip width between the cylinder and the printing roll being 5 mm. 30
The oil liquid is transferred to the sample by making one rotation at rpm. Then, based on the value (number 1) obtained by subtracting the weight of the paper of the effective area fraction before transfer from the weight of the effective area fraction sample piece after transfer, the oil absorption amount per sample 1 m 2.
【００１９】[0019]
【数１】 (Equation 1)
【００２０】また、脂取り紙に代表される、皮脂を吸収
させて除去することを目的とする化粧用紙は、使用者が
皮脂を拭き取れたことを視覚的に確認できるように、多
くの場合、皮脂を吸収すると、吸収部分の透明度が向上
する機能を有している。本願発明者らは、かかる機能の
良否をパンチ力という数値で表している。パンチ力は、
吸脂前と吸脂後の紙の色差より算出される値であり、パ
ンチ力の数値が高ければ高いほど、吸脂時に透明度が向
上することになり使用者の満足感が得られる化粧用紙で
ある。In addition, decorative paper, such as grease-absorbing paper, intended to absorb and remove sebum is often used to visually confirm that a user has wiped off sebum. When it absorbs sebum, it has the function of improving the transparency of the absorbed part. The present inventors express the quality of such a function by a numerical value called punch force. The punching power is
This is a value calculated from the color difference between the paper before and after oil absorption.The higher the punch force value, the higher the transparency when absorbing oil, and this is a decorative paper that gives the user satisfaction. is there.
【００２１】本願発明の化粧用紙は、上記パンチ力が
５．０以上であることが好ましい。パンチ力が５．０以
上あれば、吸脂時に透明性が発現して、吸脂高価を視覚
的に確認できる。ここで、パンチ力の測定方法は、次記
の通りである。まず、裏当てに白色板および黒色板を用
い、分光白色光度計「ＥＰＲ−８０ＷＸ」（東京電色株
式会社製）にて、転写前の紙試料の色彩度Ｌｗ、Ａｗ、
ＢｗおよびＬａ、Ａｂ、Ｂｂをそれぞれ測定し、両者の
色差ΔＥ1を（数２）に従って算出する。それととも
に、上記吸脂量の測定と同様に、上記印刷適性試験機の
胴の表面に２１ｃｍ×２５ｃｍの試料片を粘着テープな
どで固定して有効面積１９ｃｍ×１８ｃｍとし、上記印
刷適性試験機の印刷ロールに油液（ヒマシ油８０重量％
＋ベンジルアルコール２０重量％）０．５ｍｌを膜厚
４．８μｍとにるように均一に塗布し、上記胴と印刷ロ
ールとのニップ幅を５ｍｍとして転写回転速度３０ｒｐ
ｍで１回転させて、上記油液を上記試料に転写させる。
次いで、転写後の紙試料の色差ΔＥ2を転写前の紙試料
のΔＥ1と転写後の紙試料の色差ΔＥ2とから（数３）に
したがってパンチ力ΔＥを算出する。The decorative paper of the present invention preferably has the punch force of 5.0 or more. When the punching force is 5.0 or more, transparency is exhibited at the time of oil absorption, and the cost of oil absorption can be visually confirmed. Here, the method of measuring the punch force is as follows. First, using a white plate and a black plate as a backing, the color saturations Lw, Aw, and Aw of the paper sample before transfer were measured with a spectral white photometer “EPR-80WX” (manufactured by Tokyo Denshoku Co., Ltd.).
Bw and La, Ab, and Bb are measured, and the color difference ΔE 1 between them is calculated according to (Equation 2). At the same time, similarly to the measurement of the amount of oil absorption, a sample piece of 21 cm × 25 cm was fixed on the surface of the cylinder of the printability tester with an adhesive tape or the like to have an effective area of 19 cm × 18 cm. Oil liquid (castor oil 80% by weight)
+ Benzyl alcohol 20% by weight) 0.5 ml was uniformly applied so as to have a film thickness of 4.8 μm, the nip width between the cylinder and the printing roll was 5 mm, and the transfer rotation speed was 30 rpm.
The oil liquid is transferred to the sample by one rotation at m.
Then calculated punch Delta] E color difference Delta] E 2 of the paper sample after transfer from the color difference Delta] E 2 Metropolitan paper sample after transcription and Delta] E 1 of the paper samples prior to transfer in accordance with equation (3).
【００２２】[0022]
【数２】ΔＥｎ＝{(Ｌｗ−Ｌｂ)2＋(Ａｗ−Ａｂ)2＋(Ｂ
ｗ−Ｂｂ)2}/2 ただし、Ｌｗ：白色使用時の明度、Ｌｂ：黒色使用時の
明度 Ａｗ：白色使用時の青〜黄色味、Ａｂ：黒色使用時の青
〜黄色味 Ｂｗ：白色使用時の赤〜緑色味、Ｂｂ：黒色使用時の赤
〜緑色味## EQU2 ## ΔEn = {(Lw−Lb) 2 + (Aw−Ab) 2 + (B
w-Bb) 2 } / 2 , where Lw: lightness when using white, Lb: lightness when using black Aw: blue to yellow when using white, Ab: blue to yellow when using black Bw: when using white Red to green color when using, Bb: Red to green color when using black
【００２３】[0023]
【数３】ΔＥ＝ΔＥ1＋ΔＥ2 ΔＥ：パンチ力 一方、好適には、本願発明の化粧用紙に含有される上記
例示の無機填料は、上記のように、タルク０．５〜９０
重量％とヒドロキシアパタイトとを含有するのが好まし
い。上記タルクは、平均粒子径が０．５〜８μｍのタル
クであり、好適には、平均粒子径０．５〜２μｍの微粉
タルクである。タルクの平均粒子径は、既知のマイクロ
トラック法によって測定すればよい。また、整粒された
市販のタルク（日本タルク株式会社製、ＳＧ−２００
０）等を用いることもできる。タルクを含有させること
により、紙の平滑度が向上し、肌触りが良くなり、使用
感に優れた化粧用紙となる。ΔE = ΔE 1 + ΔE 2 ΔE: punch force On the other hand, preferably, the above-mentioned inorganic filler contained in the decorative paper of the present invention is talc 0.5 to 90 as described above.
It is preferred that it contains weight% and hydroxyapatite. The talc is talc having an average particle diameter of 0.5 to 8 μm, and is preferably fine talc having an average particle diameter of 0.5 to 2 μm. The average particle diameter of talc may be measured by a known microtrack method. A commercially available talc (SG-200 manufactured by Nippon Talc Co., Ltd.)
0) can also be used. By containing talc, the smoothness of the paper is improved, the feel is improved, and a decorative paper excellent in usability is obtained.
【００２４】かかる化粧用紙は、非常に肌触り感に優
れ、かつ酸化皮脂の吸脂性にも優れ、さらに、一般的な
化粧用紙、特に脂取り紙の機能である、皮脂を吸収した
際に、その吸収部分の透明度が向上するという機能がよ
り優れたものとなる。よって、使用者は、吸脂効果を視
覚的に確認でき、満足感が得られるようになる。Such a decorative paper is very excellent in feel to the touch and also excellent in the oil absorbing property of oxidized sebum. The function of improving the transparency of the absorbing portion becomes more excellent. Therefore, the user can visually confirm the fat-absorbing effect, and can obtain satisfaction.
【００２５】また、本願発明の化粧用紙は、保湿剤やお
しろい粉などを含有させることも可能である。上記保湿
剤としては、ホホバ油、グリセロール、１，３−ブチレ
ングリコール、ヒアルロン酸、コラーゲン等の保湿機能
をもった物質が挙げられる。Further, the decorative paper of the present invention can contain a humectant, a white powder and the like. Examples of the humectant include substances having a moisturizing function, such as jojoba oil, glycerol, 1,3-butylene glycol, hyaluronic acid, and collagen.
【００２６】本願発明の化粧用紙は、着色剤を用いて着
色することも可能である。化粧用紙を着色すると、吸脂
部分と非吸脂部分とのコントラストがはっきりして、よ
り吸脂効果を視覚によって確認がしやすくなる。着色剤
としては、塩基性染料、酸性染料、直接染料といった公
知の染料および顔料を用いることが可能である。顔料
は、色の滲みが少なく、耐色性に優れている。染料は化
粧紙が肌に直接触れるものであることから、食用染料が
好ましい。The decorative paper of the present invention can be colored using a coloring agent. When the decorative paper is colored, the contrast between the oil-absorbing portion and the non-oil-absorbing portion becomes clear, and it becomes easier to visually confirm the oil-absorbing effect. As the coloring agent, known dyes and pigments such as basic dyes, acid dyes and direct dyes can be used. The pigment has less color bleeding and is excellent in color fastness. The dye is preferably an edible dye because the decorative paper directly touches the skin.
【００２７】化粧用紙の柔軟性に関する要素として、本
願発明者は、紙の坪量及び密度、柔軟剤の種類と添加量
が特に重要であると考えるとともに、これらの３要素
と、化粧用紙の軟らかさ、パンチ力、皮脂吸収作用及び
ふきとり適性との関係をみるために、１２例の試料を作
り、それぞれについて種々のテストを行って、表１のよ
うな結果を得た。As factors relating to the flexibility of the decorative paper, the present inventor considers that the basis weight and density of the paper, the type and the amount of the softener are particularly important, and considers these three factors and the softness of the decorative paper. Twelve samples were prepared and subjected to various tests to determine the relationship between punching force, sebum absorption and wipeability, and the results shown in Table 1 were obtained.
【００２８】なお、本願発明の化粧用紙では柔軟剤とし
て日新化学研究所 ネオソフターを使用する。In the decorative paper of the present invention, Nissin Chemical Laboratory Neosofter is used as a softening agent.
【００２９】＜評価基準＞本願発明者が、化粧用紙の軟
らかさ：紙パルプ技術協会が発行するＪＡＰＡＮＴＡＰ
ＰＩ規格 Ｔ４９８による「ハンドルオメータ法」に基
づき測定した。パンチ力、吸脂量の測定：前段に記載し
たとおりである。<Evaluation Criteria> Softness of decorative paper was determined by the inventor of the present invention: JAPANTAP issued by Japan Pulp and Paper Technology Association.
It was measured based on the "handle ometer method" according to PI standard T498. Measurement of punch force and oil absorption: As described in the previous paragraph.
【００３０】過酸化脂質の吸着率：次記のとおり測定し
た。まず、図１のように組立てた装置のカラム１に試料
１ｇを入れ、ｎ−ヘキサン４ｇで希釈したオリーブ油
（和光純薬製）２ｇをカラム１の上部から流す。このと
き、カラム１内をオリーブ油が流れるように吸引しなが
ら行う。次いで、カラム上部よりｎ−ヘキサン１００ｍ
ｌを流して流出液を採取する。次いで、その流出液をウ
ォーターバスで蒸発させ、残量約１０ｍｌになったとこ
ろで、ウォータバスより取り出し、該混合液に氷酢酸１
０ｍｌおよびヨウ化カリウム２ｇを添加して撹拌する。
次いで、この混合液中の遊離したヨウ素を、ビュレット
を用いて０．０１ｍｏｌ／ｌチオ硫酸ナトリウムにて滴
定する。終点はデンプン指示薬を入れ求める。滴定結果
より過酸化物価を求め、求められた過酸化物価より過酸
化脂質の吸着量を算出する。Adsorption rate of lipid peroxide: Measured as described below. First, 1 g of a sample is put into the column 1 of the apparatus assembled as shown in FIG. 1, and 2 g of olive oil (manufactured by Wako Pure Chemical Industries, Ltd.) diluted with 4 g of n-hexane flows from the top of the column 1. At this time, the operation is performed while suction is applied so that olive oil flows in the column 1. Then, n-hexane 100 m from the top of the column
Flow 1 and collect the effluent. Next, the effluent was evaporated in a water bath. When the remaining amount became about 10 ml, the effluent was taken out of the water bath, and glacial acetic acid 1 was added to the mixed solution.
Add 0 ml and 2 g of potassium iodide and stir.
Next, the released iodine in the mixture is titrated with 0.01 mol / l sodium thiosulfate using a burette. The end point asks for a starch indicator. The peroxide value is determined from the titration result, and the amount of lipid peroxide adsorbed is calculated from the determined peroxide value.
【００３１】[0031]
【表１】 [Table 1]
【００３２】表１に記載されている各試料について、柔
軟性、パンチ力、吸脂量及びふきとり適性について測定
したところ、試料ＮＯ．１〜１２の各試料のうち、試料
ＮＯ．１〜６の各試料は、柔らかさ、パンチ力、吸脂
量、ふきとり適性とも目標とする数値又は結果が得られ
た。For each sample described in Table 1, the flexibility, punch force, amount of oil absorption, and suitability for wiping were measured. Among the samples Nos. 1 to 12, Sample Nos. For each of the samples 1 to 6, the desired numerical values or results were obtained for the softness, the punching force, the amount of oil absorption, and the suitability for wiping.
【００３３】これに対して、表１に記載されている試料
ＮＯ．１〜１２の各試料のうち、試料ＮＯ．７〜１２の
各試料は次のような理由で化粧用紙として不適格であっ
た。On the other hand, the sample Nos. Among the samples Nos. 1 to 12, Sample Nos. Each of Samples 7 to 12 was unsuitable as decorative paper for the following reasons.
【００３４】すなわち、試料ＮＯ．７の試料は、坪量を
小さくしてみたものであるが（５ｇ／ｍ2）、使用時に
撚れや破れが生じ、又吸脂量も１ｇ／ｍ2に満たず、化
粧用紙としては不適格であった。That is, the sample NO. The sample No. 7 has a reduced basis weight (5 g / m 2 ), but twists and tears occur during use, and the amount of grease absorption is less than 1 g / m 2, which is unsuitable as decorative paper. Eligible.
【００３５】試料ＮＯ．８の試料は、試料ＮＯ．７の試
料とは逆に坪量を大きくしてみたものであるが（３３ｇ
／ｍ2）、必要な柔軟性が得られなかった。Sample No. Sample No. 8 is Sample No. In contrast to the sample No. 7, the basis weight was increased (33 g).
/ M 2 ), the required flexibility could not be obtained.
【００３６】次に、試料ＮＯ．９の試料は、柔軟剤の添
加量を少なくしてみたものであるが、（０．０５重量
％）、必要な柔軟性に欠けるものであった。Next, the sample NO. In the sample No. 9, the amount of the softening agent added was reduced, but the sample lacked the necessary flexibility (0.05% by weight).
【００３７】試料ＮＯ．１０の試料は、密度を大きくし
てみたものであるが（０．８５ｇ／ｃｍ3）、必要な吸
脂量が得られなかった。Sample No. For sample No. 10, the density was increased (0.85 g / cm 3 ), but the required amount of oil absorption was not obtained.
【００３８】試料ＮＯ．１１の試料は、多量の柔軟剤を
添加してみたものであるが（１２０重量％）、柔軟性は
十分であったが、その逆作用として必要な吸脂量（１．
０ｇ／ｍ2）とパンチ力が得られなかった。Sample No. The sample No. 11 was obtained by adding a large amount of softener (120% by weight), but the softness was sufficient, but the required amount of oil absorption (1.
0 g / m 2 ), and a punch force could not be obtained.
【００３９】次に、試料ＮＯ．１２の試料は、密度を小
さくしてみたものであるが（０．３０ｇ／ｃｍ3）、必
要な吸脂量（１ｇ／ｍ2）及びパンチ力が得られなかっ
た。又、ふきとり適性の点でも良好な結果が得られなか
った。Next, the sample NO. Twelve samples were obtained by reducing the density (0.30 g / cm 3 ), but the required amount of oil absorption (1 g / m 2 ) and the punching power could not be obtained. Also, good results could not be obtained in terms of suitability for wiping.
【００４０】以上の考察にもとずいて、本願発明者は、
皮膚清拭用の化粧用紙として好適な数値として坪量の範
囲を８〜３０ｇ／ｍ2とし、密度を０．４０〜０．７５
ｇ／ｃｍ3とし、柔軟剤の添加量を繊維原料に対して
０．１〜１００重量％としたものである。Based on the above considerations, the present inventor
The preferred range for the cosmetic paper for wiping the skin is that the basis weight range is 8 to 30 g / m 2 and the density is 0.40 to 0.75.
g / cm 3, and the amount of the softener added is 0.1 to 100% by weight based on the fiber raw material.
【００４１】[0041]
【実施例】＜実施例１＞針葉樹パルプと広葉樹パルプと
の混合パルプ（針葉樹パルプ／広葉樹パルプ：８０／２
０）を原料とし叩解度５００ｍｌに調整し、平均粒子径
１μｍのタルク２５重量パーセントおよび平均粒子径３
μｍのヒドロキシアパタイト５重量パーセントを添加し
たパルプスラリーを、既知の抄紙機にて抄紙して坪量１
５ｇ／ｍ 2の化粧用紙を得た。EXAMPLES Example 1 Softwood Pulp and Hardwood Pulp
Mixed pulp (softwood pulp / hardwood pulp: 80/2)
0) as raw material, adjusted to 500ml of beating degree, average particle size
1 μm talc 25 weight percent and average particle size 3
add 5 weight percent of hydroxyapatite
The pulp slurry is made into a paper by a known paper machine to obtain a basis weight of 1.
5g / m TwoI got cosmetic paper.
【００４２】＜実施例２＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：５
０／５０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径３μｍのタルク１０重量パーセントおよび平均粒
子径３μｍのヒドロキシアパタイト１０重量パーセント
を添加したパルプスラリーを、既知の抄紙機にて抄紙し
て坪量１５ｇ／ｍ2の化粧用紙を得た。<Example 2> Mixed pulp of softwood pulp and Manila hemp pulp (softwood pulp / Manila hemp pulp: 5
0/50) as a raw material, adjusted to a beating degree of 500 ml, and pulp slurry to which 10% by weight of talc having an average particle diameter of 3 μm and 10% by weight of hydroxyapatite having an average particle diameter of 3 μm were added was formed into a paper by a known paper machine. A decorative paper having a basis weight of 15 g / m 2 was obtained.
【００４３】＜実施例３＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：７
５／２５）を原料とし叩解度５００ｍｌに調整し、平均
粒子径１μｍのタルク５０重量パーセントおよび平均粒
子径５μｍのヒドロキシアパタイト２０重量パーセント
を添加したパルプスラリーを、既知の抄紙機にて抄紙し
て坪量２０ｇ／ｍ2の化粧用紙を得た。Example 3 Mixed Pulp of Softwood Pulp and Manila Hemp Pulp (Softwood pulp / Manila hemp pulp: 7)
5/25) was used as a raw material, the beating degree was adjusted to 500 ml, and a pulp slurry to which 50% by weight of talc having an average particle diameter of 1 μm and 20% by weight of hydroxyapatite having an average particle diameter of 5 μm were added was made into a paper by a known paper machine. A decorative paper having a basis weight of 20 g / m 2 was obtained.
【００４４】＜実施例４＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：７
０／３０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径３μｍのタルク３０重量パーセントおよび平均粒
子径３μｍのヒドロキシアパタイト５０重量パーセント
を添加したパルプスラリーを、既知の抄紙機にて抄紙し
て坪量１５ｇ／ｍ2の化粧用紙を得た。Example 4 Mixed Pulp of Softwood Pulp and Manila Hemp Pulp (Softwood pulp / Manila hemp pulp: 7)
0/30) as a raw material, adjusted to a beating degree of 500 ml, and pulp slurry to which 30% by weight of talc having an average particle diameter of 3 μm and 50% by weight of hydroxyapatite having an average particle diameter of 3 μm were added was made into a paper by a known paper machine. A decorative paper having a basis weight of 15 g / m 2 was obtained.
【００４５】＜実施例５＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：３
０／７０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径１μｍのタルク１０重量パーセントおよび平均粒
子径３μｍのヒドロキシアパタイト５０重量パーセント
を添加したパルプスラリーを、既知の抄紙機にて抄紙し
て坪量３０ｇ／ｍ2の化粧用紙を得た。Example 5 Mixed Pulp of Softwood Pulp and Manila Hemp Pulp (Softwood pulp / Manila hemp pulp: 3)
0/70) as a raw material, the pulp slurry was adjusted to 500 ml, and 10% by weight of talc having an average particle diameter of 1 μm and 50% by weight of hydroxyapatite having an average particle diameter of 3 μm were added to a pulp slurry by a known paper machine. A decorative paper having a basis weight of 30 g / m 2 was obtained.
【００４６】＜実施例６＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：６
０／４０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径１μｍのタルク５重量パーセントおよび平均粒子
径５μｍのヒドロキシアパタイト５重量パーセントを添
加したパルプスラリーを、既知の抄紙機にて抄紙して坪
量８ｇ／ｍ 2の化粧用紙を得た。Example 6 Softwood Pulp and Manila Hemp Pulp
Pulp mixed with softwood (softwood pulp / Manila hemp pulp: 6
0/40) as the raw material and adjusted to a beating degree of 500 ml.
5% by weight of talc and average particle size of 1 μm
Add 5% by weight of hydroxyapatite with a diameter of 5μm
The added pulp slurry is made into paper using a known paper machine, and
8 g / m TwoI got cosmetic paper.
【００４７】上記実施例１〜６の各化粧用紙における密
度、柔軟剤添加量、軟らかさ、パンチ力、吸脂量、肌触
り、ふきとり適性等は、表２に示す通りであり、それぞ
れ本願発明の要件を充足し、総合判定においても良好と
認められた。The density, the amount of the softener added, the softness, the punching force, the amount of oil absorption, the feel, the suitability for wiping, etc., in each of the decorative papers of Examples 1 to 6 are as shown in Table 2, and each of the present invention is shown in FIG. The requirements were satisfied and the overall judgment was good.
【００４８】＜比較例１＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：４
０／６０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径１０μｍのタルク０．３重量パーセントおよび平
均粒子径５μｍのヒドロキシアパタイト５重量パーセン
トを添加したパルプスラリーを、既知の抄紙機にて抄紙
して坪量５ｇ／ｍ2の化粧用紙を得た。<Comparative Example 1> Mixed pulp of softwood pulp and manila hemp pulp (softwood pulp / manila hemp pulp: 4)
0/60) as a raw material and adjusted to a beating degree of 500 ml, and a pulp slurry to which 0.3% by weight of talc having an average particle diameter of 10 μm and 5% by weight of hydroxyapatite having an average particle diameter of 5 μm were added was subjected to papermaking using a known paper machine. Thus, a decorative paper having a basis weight of 5 g / m 2 was obtained.
【００４９】＜比較例２＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：５
０／５０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径５μｍのタルク１重量パーセントおよび平均粒子
径０．３μｍのヒドロキシアパタイト０．５重量パーセ
ントを添加したパルプスラリーを、既知の抄紙機にて抄
紙して坪量３３ｇ／ｍ2の化粧用紙を得た。Comparative Example 2 Mixed pulp of softwood pulp and manila hemp pulp (softwood pulp / manila hemp pulp: 5
0/50) as a raw material, the beating degree was adjusted to 500 ml, and a pulp slurry containing 1% by weight of talc having an average particle size of 5 μm and 0.5% by weight of hydroxyapatite having an average particle size of 0.3 μm was added to a known paper machine. To make a decorative paper having a basis weight of 33 g / m 2 .
【００５０】＜比較例３＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：９
０／１０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径０．３μｍのタルク５重量パーセントおよび平均
粒子径１０μｍのヒドロキシアパタイト３０重量パーセ
ントを添加したパルプスラリーを、既知の抄紙機にて抄
紙して坪量１５ｇ／ｍ2の化粧用紙を得た。Comparative Example 3 Mixed pulp of softwood pulp and manila hemp pulp (softwood pulp / manila hemp pulp: 9
0/10) as a raw material and adjusted to a beating degree of 500 ml, and a pulp slurry to which 5% by weight of talc having an average particle diameter of 0.3 μm and 30% by weight of hydroxyapatite having an average particle diameter of 10 μm were added was subjected to papermaking using a known paper machine. Thus, a decorative paper having a basis weight of 15 g / m 2 was obtained.
【００５１】＜比較例４＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：４
０／６０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径３μｍのタルク１５０重量パーセントおよび平均
粒子径３μｍのヒドロキシアパタイト３０重量パーセン
トを添加したパルプスラリーを、既知の抄紙機にて抄紙
して坪量２０ｇ／ｍ2の化粧用紙を得た。Comparative Example 4 Mixed pulp of softwood pulp and manila hemp pulp (softwood pulp / manila hemp pulp: 4)
0/60) as a raw material, adjusted to a beating degree of 500 ml, and pulp slurry to which 150% by weight of talc having an average particle diameter of 3 μm and 30% by weight of hydroxyapatite having an average particle diameter of 3 μm were added was made into a paper by a known paper machine. A decorative paper having a basis weight of 20 g / m 2 was obtained.
【００５２】＜比較例５＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：７
０／３０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径５μｍのタルク１０重量パーセントおよび平均粒
子径３μｍのヒドロキシアパタイト０．３重量パーセン
トを添加したパルプスラリーを、既知の抄紙機にて抄紙
して坪量１５ｇ／ｍ2の化粧用紙を得た。Comparative Example 5 Mixed pulp of softwood pulp and manila hemp pulp (softwood pulp / manila hemp pulp: 7)
0/30) as a raw material, adjusted to a beating degree of 500 ml, and added a pulp slurry containing 10% by weight of talc having an average particle diameter of 5 μm and 0.3% by weight of hydroxyapatite having an average particle diameter of 3 μm to a papermaking machine using a known paper machine. Thus, a decorative paper having a basis weight of 15 g / m 2 was obtained.
【００５３】＜比較例６＞針葉樹パルプとマニラ麻パル
プとの混合パルプ（針葉樹パルプ／マニラ麻パルプ：５
０／５０）を原料とし叩解度５００ｍｌに調整し、平均
粒子径３μｍのタルク１００重量パーセントおよび平均
粒子径３μｍのヒドロキシアパタイト１２０重量パーセ
ントを添加したパルプスラリーを、既知の抄紙機にて抄
紙して坪量１５ｇ／ｍ2の化粧用紙を得た。Comparative Example 6 Mixed pulp of softwood pulp and manila hemp pulp (softwood pulp / manila hemp pulp: 5)
0/50) as a raw material, adjusted to a beating degree of 500 ml, and made a pulp slurry to which 100% by weight of talc having an average particle diameter of 3 μm and 120% by weight of hydroxyapatite having an average particle diameter of 3 μm were added. A decorative paper having a basis weight of 15 g / m 2 was obtained.
【００５４】上記比較例１〜６の各化粧用紙における密
度、柔軟剤添加量、軟らかさ、パンチ力、吸脂量、肌触
り、ふきとり適性等は表２に示す通りであり、それらの
各比較例のものは、いずれかの項目で本願発明の要件を
充足せず、その結果、総合判定においても良好な評価を
得られなかった。The density, the amount of softener added, the softness, the punching force, the amount of oil absorption, the touch, the suitability for wiping, and the like of each of the decorative papers of Comparative Examples 1 to 6 are as shown in Table 2. Did not satisfy the requirements of the present invention in any of the items, and as a result, good evaluation was not obtained in the comprehensive judgment.
【００５５】[0055]
【発明の効果】以上の説明から明らかなように、本願発
明の皮膚清拭用化粧用紙は、必要な皮脂吸収作用のほ
か、十分な柔軟性をそなえており、使用感のすぐれたも
のであり、しかも安価に製造し得る効果がある。As is clear from the above description, the cosmetic paper for wiping skin according to the present invention has not only a necessary sebum absorbing effect but also a sufficient flexibility and is excellent in feeling of use. In addition, there is an effect that it can be manufactured at low cost.
【００５６】[0056]
【表２】 [Table 2]
【００５７】[0057]
【図１】過酸化脂質の吸着率の測定に用いた装置図であ
る。FIG. 1 is a diagram of an apparatus used for measuring the adsorption rate of lipid peroxide.
１・・・カラム。 1 ... column.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 黒木 繁徳 愛媛県伊予三島市紙屋町５番１号 大王製 紙株式会社内 Ｆターム(参考） 2D034 AB00 4L055 AA02 AA03 AA07 AG06 AG26 AG34 AH01 AH50 EA08 EA16 EA32 FA16 FA30 GA29 GA46 GA50 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Shigenori Kuroki 5-1 Kamiyacho, Iyo Mishima-shi, Ehime F-term in Daio Paper Co., Ltd. 2D034 AB00 4L055 AA02 AA03 AA07 AG06 AG26 AG34 AH01 AH50 EA08 EA16 EA32 FA16 FA30 GA29 GA46 GA50
Claims (4)
アルコール系からなる柔軟剤とを含み、ＪＩＳＰ−８１
２４による坪量が８〜３０ｇ／ｍ2であり、密度が０．
４０〜０．７５ｇ／ｃｍ3であり、上記柔軟剤の添加量
が上記繊維原料に対して０．１〜１００重量％であるこ
とを特徴とする皮膚清拭用化粧用紙。1. JISP-81 comprising a fiber raw material, an oil-absorbing filler, and a polyhydric alcohol-based softener.
24 has a basis weight of 8 to 30 g / m 2 and a density of 0.
A cosmetic paper for wiping skin, characterized in that the amount is 40 to 0.75 g / cm 3 and the amount of the softener is 0.1 to 100% by weight based on the fiber material.
００重量％のヒドロキシアパタイトを含むものであるこ
とを特徴とする請求項１記載の皮膚清拭用化粧用紙。2. The method according to claim 1, wherein the filler is 1 to 1 with respect to the fiber raw material.
The cosmetic paper for rinsing skin according to claim 1, wherein the cosmetic paper contains 00% by weight of hydroxyapatite.
〜９０重量％のタルクを含むものであることを特徴とす
る請求項１又は２記載の皮膚清拭用化粧用紙。3. The method according to claim 1, wherein the filler is 0.5 wt.
The cosmetic paper for rinsing skin according to claim 1 or 2, comprising talc in an amount of from 90 to 90% by weight.
ルクの平均粒子径が０．５〜８μｍであることを特徴と
する請求項２又は３記載の皮膚清拭用化粧用紙。4. The decorative paper for skin cleansing according to claim 2, wherein the average particle diameter of the hydroxyapatite and / or talc is 0.5 to 8 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001140933A JP4668456B2 (en) | 2001-05-11 | 2001-05-11 | Cosmetic paper for skin cleansing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001140933A JP4668456B2 (en) | 2001-05-11 | 2001-05-11 | Cosmetic paper for skin cleansing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002330820A true JP2002330820A (en) | 2002-11-19 |
| JP4668456B2 JP4668456B2 (en) | 2011-04-13 |
Family
ID=18987452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001140933A Expired - Lifetime JP4668456B2 (en) | 2001-05-11 | 2001-05-11 | Cosmetic paper for skin cleansing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4668456B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008080027A (en) * | 2006-09-28 | 2008-04-10 | Daio Paper Corp | Liquid chemical including tissue paper |
| JP2008088587A (en) * | 2006-09-29 | 2008-04-17 | Daio Paper Corp | Sanitary paper |
| JP2008188072A (en) * | 2007-01-31 | 2008-08-21 | Daio Paper Corp | Dry type skin cleaning sheet |
| JP2010180522A (en) * | 2009-01-07 | 2010-08-19 | Ishida Biyo Kenkyusho:Kk | Face-cleaning paper and method for producing the same |
| JP2012152349A (en) * | 2011-01-25 | 2012-08-16 | Yoshii Syouten Co Ltd | Absorbent paper and method of manufacturing the same |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6327411A (en) * | 1986-07-22 | 1988-02-05 | Shiseido Co Ltd | Dust preparation for skin external use |
| JPH0351396A (en) * | 1989-04-21 | 1991-03-05 | Asahi Optical Co Ltd | Functional paper |
| JPH05156596A (en) * | 1991-12-03 | 1993-06-22 | Kouno Seishi Kk | Fiber web having high water retention and production thereof |
| JPH09224868A (en) * | 1996-02-22 | 1997-09-02 | Daifuku Seishi Kk | Antimicrobial tissue and production thereof |
| JPH101900A (en) * | 1996-06-14 | 1998-01-06 | Daifuku Seishi Kk | Highly oil absorbing absorbent paper for makeup and its production |
| JPH11127955A (en) * | 1997-10-29 | 1999-05-18 | Oike Ind Co Ltd | Tissue |
| JPH11137336A (en) * | 1997-11-10 | 1999-05-25 | Daifuku Seishi Kk | Oil removing paper for cosmetics and its production |
| JP2000139755A (en) * | 1998-11-12 | 2000-05-23 | Miki Tokushu Seishi Kk | Sebum-wiping paper and its manufacture |
| JP2002045228A (en) * | 2000-08-02 | 2002-02-12 | Daio Paper Corp | Cosmetic paper |
-
2001
- 2001-05-11 JP JP2001140933A patent/JP4668456B2/en not_active Expired - Lifetime
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6327411A (en) * | 1986-07-22 | 1988-02-05 | Shiseido Co Ltd | Dust preparation for skin external use |
| JPH0351396A (en) * | 1989-04-21 | 1991-03-05 | Asahi Optical Co Ltd | Functional paper |
| JPH05156596A (en) * | 1991-12-03 | 1993-06-22 | Kouno Seishi Kk | Fiber web having high water retention and production thereof |
| JPH09224868A (en) * | 1996-02-22 | 1997-09-02 | Daifuku Seishi Kk | Antimicrobial tissue and production thereof |
| JPH101900A (en) * | 1996-06-14 | 1998-01-06 | Daifuku Seishi Kk | Highly oil absorbing absorbent paper for makeup and its production |
| JPH11127955A (en) * | 1997-10-29 | 1999-05-18 | Oike Ind Co Ltd | Tissue |
| JPH11137336A (en) * | 1997-11-10 | 1999-05-25 | Daifuku Seishi Kk | Oil removing paper for cosmetics and its production |
| JP2000139755A (en) * | 1998-11-12 | 2000-05-23 | Miki Tokushu Seishi Kk | Sebum-wiping paper and its manufacture |
| JP2002045228A (en) * | 2000-08-02 | 2002-02-12 | Daio Paper Corp | Cosmetic paper |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008080027A (en) * | 2006-09-28 | 2008-04-10 | Daio Paper Corp | Liquid chemical including tissue paper |
| JP2008088587A (en) * | 2006-09-29 | 2008-04-17 | Daio Paper Corp | Sanitary paper |
| JP2008188072A (en) * | 2007-01-31 | 2008-08-21 | Daio Paper Corp | Dry type skin cleaning sheet |
| JP2010180522A (en) * | 2009-01-07 | 2010-08-19 | Ishida Biyo Kenkyusho:Kk | Face-cleaning paper and method for producing the same |
| JP2012152349A (en) * | 2011-01-25 | 2012-08-16 | Yoshii Syouten Co Ltd | Absorbent paper and method of manufacturing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4668456B2 (en) | 2011-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3711477B2 (en) | Multifunctional decorative paper | |
| JP6034004B2 (en) | Toilet Paper | |
| JP2008518745A (en) | Tissue paper with silk fiber | |
| WO2007061023A1 (en) | Sanitary tissue paper and process for producing the same | |
| JPH06319664A (en) | Dressing absorbent paper | |
| JP2002330820A (en) | Skin cleaning-wiping tissue paper | |
| CN110512464A (en) | A kind of production method of antibacterial shield adornment paper | |
| JP4936583B2 (en) | Decorative paper | |
| JP3647909B2 (en) | Cosmetic degreasing paper | |
| JP2001211934A (en) | Cleansing paper for makeup | |
| JPS6411668B2 (en) | ||
| JP4919219B2 (en) | Cosmetic degrease paper | |
| JP2008188072A (en) | Dry type skin cleaning sheet | |
| JPH11279993A (en) | Absorbent paper for cosmetic | |
| JP4662369B2 (en) | Mud face pack manufacturing method | |
| JP4913414B2 (en) | Degreased paper | |
| JPH07189170A (en) | Softener for paper | |
| JP2006167030A (en) | Degreasing paper for makeup | |
| JP2003020593A (en) | Fiber web product | |
| EP3897526A1 (en) | Aqueous gels for dyeing or making up the eyebrows | |
| JP3323720B2 (en) | Textile web for tissue paper, toilet paper and paper towels | |
| JP6277842B2 (en) | Sanitary paper softener | |
| JP2001314229A (en) | Quality toilet paper for oil absorption | |
| JP2007061510A (en) | Sheet product and its manufacturing method | |
| JPH0229222A (en) | Facial tissue |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070118 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100209 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100412 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20101214 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110113 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140121 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4668456 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140121 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |