JP2002212055A - Liquid bathing agent composition - Google Patents
Liquid bathing agent compositionInfo
- Publication number
- JP2002212055A JP2002212055A JP2001007591A JP2001007591A JP2002212055A JP 2002212055 A JP2002212055 A JP 2002212055A JP 2001007591 A JP2001007591 A JP 2001007591A JP 2001007591 A JP2001007591 A JP 2001007591A JP 2002212055 A JP2002212055 A JP 2002212055A
- Authority
- JP
- Japan
- Prior art keywords
- titanium oxide
- acid
- examples
- liquid
- agent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、液体製剤中で酸化
チタンを長期にわたって分散安定化でき、浴湯に投入し
た後も安定に分散させることができる液体浴用剤組成物
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition for a liquid bath, which can stably disperse titanium oxide in a liquid preparation for a long period of time and can stably disperse it even after it has been put into a bath water.
【０００２】[0002]
【従来の技術】従来、温泉気分を楽しむ目的で酸化チタ
ンを浴湯に分散させた浴用剤が使用されているが、その
ほとんどは粉末又は固形状の浴用剤であり、液体のもの
はほとんどなかった。その理由は、液体製剤中で長期
間、安定に酸化チタンを分散させることが困難なためで
ある。酸化チタンを液体中に分散させる場合、酸化チタ
ン粒子のもつ分子間力や比重によって凝集・沈降してし
まうという問題点があった。2. Description of the Related Art Conventionally, bath agents in which titanium oxide is dispersed in bath water have been used for the purpose of enjoying the feeling of a hot spring, but most of them are powder or solid bath agents, and there are almost no liquid bath agents. Was. The reason is that it is difficult to stably disperse titanium oxide in a liquid preparation for a long period of time. When titanium oxide is dispersed in a liquid, there is a problem that the titanium oxide particles are aggregated and settled due to an intermolecular force and specific gravity of the particles.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、液体製剤中
で酸化チタンを長期にわたって分散安定化でき、浴湯に
投入した後も安定に分散させることができる液体浴用剤
組成物を提供することを目的とする。DISCLOSURE OF THE INVENTION The present invention provides a liquid bath agent composition which can stably disperse titanium oxide in a liquid preparation for a long period of time and can stably disperse it even after it has been put into bath water. With the goal.
【０００４】[0004]
【課題を解決するための手段】本発明者は、前記の目的
を達成すべく鋭意検討を行った結果、等電点がｐＨ７以
上の表面処理酸化チタンを用い、これに有機酸を配合さ
せて酸化チタン自体に電荷をもたせ自己分散させること
により、前記目的を達成できることを見出し、本発明を
完成するに至った。Means for Solving the Problems As a result of intensive studies to achieve the above object, the present inventor has used a surface-treated titanium oxide having an isoelectric point of pH 7 or more and mixed with an organic acid. The present inventors have found that the above object can be achieved by imparting electric charge to titanium oxide itself and dispersing the titanium oxide itself, thereby completing the present invention.
【０００５】即ち、本発明は以下の内容を包含する。 （１）（Ａ）等電点がｐＨ７以上の表面処理酸化チタン
と、（Ｂ）有機酸の少なくとも一種とを含有する液体浴
用剤組成物。 （２）更に、（Ｃ）水溶性高分子の少なくとも一種を含
有する前記（１）に記載の液体浴用剤組成物。That is, the present invention includes the following contents. (1) A liquid bath composition comprising (A) a surface-treated titanium oxide having an isoelectric point of pH 7 or more and (B) at least one organic acid. (2) The liquid bath agent composition according to the above (1), further comprising (C) at least one water-soluble polymer.
【０００６】[0006]
【発明の実施の形態】以下、本発明を詳細に説明する。
本発明においては、酸化チタンとして、等電点がｐＨ７
以上の表面処理酸化チタンを用いる。表面処理酸化チタ
ンの等電点がｐＨ７未満であると、溶解してアルカリ性
を呈する成分によって電荷が得られ、分散性は向上する
が、弱酸性である皮膚表面に対する影響を考えた場合、
好ましくない。本発明に用いる表面処理酸化チタンとし
ては、等電点がｐＨ７〜１１のものが特に好ましい。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
In the present invention, the titanium oxide has an isoelectric point of pH 7
The above surface-treated titanium oxide is used. If the isoelectric point of the surface-treated titanium oxide is less than pH 7, a charge is obtained by a component that dissolves and exhibits alkalinity, and the dispersibility is improved, but when considering the effect on the weakly acidic skin surface,
Not preferred. As the surface-treated titanium oxide used in the present invention, those having an isoelectric point of pH 7 to 11 are particularly preferable.
【０００７】金属酸化物は、それぞれ固有の等電点をも
っており、酸化チタンの等電点は、ｐＨ６付近である。
酸化チタン粒子表面を他の金属酸化物で被覆すると、粒
子の表面特性は当該金属酸化物の特性を示し、当該金属
酸化物と同じ等電点をもつようになる。それゆえ、酸化
チタン粒子表面をアルミナ（Ａｌ2Ｏ3）、酸化亜鉛等の
等電点がｐＨ７以上の金属酸化物で被覆することによ
り、等電点がｐＨ７以上の表面処理酸化チタンを得るこ
とができる。Each metal oxide has its own isoelectric point, and the isoelectric point of titanium oxide is around pH 6.
When the surface of the titanium oxide particles is coated with another metal oxide, the surface characteristics of the particles show the characteristics of the metal oxide and have the same isoelectric point as the metal oxide. Therefore, by coating the surface of the titanium oxide particles with a metal oxide having an isoelectric point of pH 7 or more, such as alumina (Al 2 O 3 ) or zinc oxide, it is possible to obtain a surface-treated titanium oxide having an isoelectric point of pH 7 or more. Can be.
【０００８】本発明の液体浴用剤組成物において、有機
酸は前記表面処理酸化チタンに電荷をもたせ自己分散さ
せるために用いられる。従って、浴用剤成分として許容
されるものであれば制限はなく、例えばグリコール酸、
乳酸、リンゴ酸、クエン酸、アスコルビン酸、安息香
酸、フマル酸、酒石酸、マロン酸、アジピン酸、ピロリ
ドンカルボン酸、サリチル酸、コハク酸が挙げられ、こ
れらは単独で、又は２種以上の組み合わせで用いられ
る。[0008] In the liquid bath composition of the present invention, an organic acid is used for imparting a charge to the surface-treated titanium oxide and for self-dispersion. Therefore, there is no limitation as long as it is acceptable as a bath agent component, for example, glycolic acid,
Lactic acid, malic acid, citric acid, ascorbic acid, benzoic acid, fumaric acid, tartaric acid, malonic acid, adipic acid, pyrrolidone carboxylic acid, salicylic acid, succinic acid, and these can be used alone or in combination of two or more. Can be
【０００９】本発明の液体浴用剤組成物における前記表
面処理酸化チタンの配合量は、通常１〜８０重量％、好
ましくは１〜５０重量％である。本発明の液体浴用剤組
成物における有機酸の配合量は、通常０．００１〜１０
重量％、好ましくは０．０１〜５重量％である。The amount of the surface-treated titanium oxide in the liquid bath composition of the present invention is usually 1 to 80% by weight, preferably 1 to 50% by weight. The compounding amount of the organic acid in the liquid bath composition of the present invention is usually 0.001 to 10
%, Preferably 0.01 to 5% by weight.
【００１０】前記表面処理酸化チタン（Ａ）と有機酸
（Ｂ）との配合割合［（Ａ）：（Ｂ）］は、通常１：１
０〜８００００：１、好ましくは１：５〜５０００：１
である。本発明の液体浴用剤組成物は、更に水溶性高分
子を配合することにより、製剤中及び浴湯中における前
記表面処理酸化チタンの分散安定性を更に高めることが
できる。The mixing ratio of the surface-treated titanium oxide (A) and the organic acid (B) [(A) :( B)] is usually 1: 1.
0-80000: 1, preferably 1: 5-5000: 1
It is. The liquid bath composition of the present invention can further enhance the dispersion stability of the surface-treated titanium oxide in the preparation and in the bath water by further blending a water-soluble polymer.
【００１１】前記水溶性高分子としては、例えば、デキ
ストリン、キサンタンガム等の微生物系多糖類、デンプ
ン、グアーガム、カラギーナン、寒天、マンナン等の植
物系多糖類、ゼラチン、カゼイン、アルブミン、コラー
ゲン等の動物系蛋白質などの天然高分子、また、半合成
高分子としては、メチルセルロース、エチルセルロー
ス、カルボキシメチルセルロースナトリウム、ヒドロキ
シエチルセルロース、カチオン化セルロース等のセルロ
ース系、可溶性デンプン、メチルデンプン等のデンプン
系、アルギン酸塩、アルギン酸プロピレングリコールエ
ステル等のアルギン酸系が挙げられる。水溶性合成高分
子の例としては、ポリエチレングリコール、ポリビニル
アルコール、カルボキシビニルポリマー、ポリアクリル
酸ナトリウム、ポリアクリル酸アンモニウム、ポリビニ
ルメチルエーテル等が挙げられる。これらの水溶性高分
子は、本発明の液体浴用剤組成物に、好ましくは０．０
１重量％以上、更に好ましくは０．１〜５０重量％含有
される。Examples of the water-soluble polymer include microbial polysaccharides such as dextrin and xanthan gum; plant polysaccharides such as starch, guar gum, carrageenan, agar, and mannan; and animal-based polysaccharides such as gelatin, casein, albumin, and collagen. Natural polymers such as proteins, and semi-synthetic polymers include celluloses such as methylcellulose, ethylcellulose, sodium carboxymethylcellulose, hydroxyethylcellulose, and cationized cellulose; starches such as soluble starch and methylstarch; alginates; propylene alginate Alginic acids such as glycol esters are exemplified. Examples of the water-soluble synthetic polymer include polyethylene glycol, polyvinyl alcohol, carboxyvinyl polymer, sodium polyacrylate, ammonium polyacrylate, polyvinyl methyl ether and the like. These water-soluble polymers are preferably added to the liquid bath agent composition of the present invention in an amount of 0.0
1% by weight or more, more preferably 0.1 to 50% by weight.
【００１２】本発明の液体浴用剤組成物には、前記成分
の他に、必要に応じて、無機顔料、多価アルコール、界
面活性剤、防腐剤、香料、無機塩類、油性成分、ビタミ
ン類、蛋白分解酵素、その他の成分を添加することがで
きる。無機顔料としては、例えば炭酸カルシウム、炭酸
マグネシウム、酸化亜鉛（亜鉛華）、タルク、ケイ酸カ
ルシウム、無水ケイ酸、カオリン、ベントナイト、雲母
チタン等が挙げられる。[0012] In addition to the above components, the liquid bath composition of the present invention may further comprise, if necessary, an inorganic pigment, a polyhydric alcohol, a surfactant, a preservative, a fragrance, an inorganic salt, an oil component, a vitamin, Proteolytic enzymes and other components can be added. Examples of the inorganic pigment include calcium carbonate, magnesium carbonate, zinc oxide (zinc white), talc, calcium silicate, silicic anhydride, kaolin, bentonite, and mica titanium.
【００１３】多価アルコールとしては、例えばエチレン
グリコール、プロピレングリコール、１，３−ブチレン
グリコール、３−メチル−１，３−ブタンジオール等の
２価アルコール；グリセリン等の３価アルコール；ソル
ビット、マンニット等の糖類が挙げられる。Examples of polyhydric alcohols include dihydric alcohols such as ethylene glycol, propylene glycol, 1,3-butylene glycol, and 3-methyl-1,3-butanediol; trihydric alcohols such as glycerin; And the like.
【００１４】界面活性剤としては、例えば、グリセリン
脂肪酸エステル、プロピレングリコール脂肪酸エステ
ル、ソルビタン脂肪酸エステル、ポリオキシエチレンソ
ルビタン脂肪酸エステル、テトラオレイン酸ポリオキシ
エチレンソルビット、ポリオキシエチレンアルキルエー
テル、ポリオキシエチレンポリオキシプロピレンアルキ
ルエーテル、ポリエチレングリコール脂肪酸エステル、
ポリオキシエチレン硬化ヒマシ油、ポリグリセリン脂肪
酸エステル等の非イオン界面活性剤；α−オレフィンス
ルホン酸ナトリウム、ラウリル硫酸ナトリウム、セチル
硫酸ナトリウム、ポリオキシエチレンラウリル硫酸ナト
リウム、スルホコハク酸ラウリル二ナトリウム等の陰イ
オン界面活性剤；カルボキシベタイン型、アミノカルボ
ン酸、スルホベタイン型等の両性界面活性剤；陽イオン
界面活性剤が挙げられるが、安全性の面から非イオン界
面活性剤が好ましい。Examples of the surfactant include glycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbite tetraoleate, polyoxyethylene alkyl ether, and polyoxyethylene polyoxy. Propylene alkyl ether, polyethylene glycol fatty acid ester,
Nonionic surfactants such as polyoxyethylene hydrogenated castor oil and polyglycerin fatty acid ester; anions such as sodium α-olefin sulfonate, sodium lauryl sulfate, sodium cetyl sulfate, sodium polyoxyethylene lauryl sulfate and disodium lauryl sulfosuccinate Surfactants; amphoteric surfactants such as carboxybetaine type, aminocarboxylic acid, and sulfobetaine type; and cationic surfactants. Nonionic surfactants are preferred from the viewpoint of safety.
【００１５】防腐剤としては、例えばパラオキシ安息香
酸エステル（例えば、メチルパラベン）、安息香酸、安
息香酸塩、フェノキシエタノールが挙げられる。香料と
しては、例えばラベンダー油、ジャスミン油、レモン油
等の天然香料、ゲラニオール、シトロネロール、フェネ
チルアルコール等の合成香料が挙げられる。Examples of preservatives include paraoxybenzoic acid esters (eg, methyl paraben), benzoic acid, benzoates, and phenoxyethanol. Examples of the flavor include natural flavors such as lavender oil, jasmine oil, and lemon oil, and synthetic flavors such as geraniol, citronellol, and phenethyl alcohol.
【００１６】無機塩類としては、例えば硫酸ナトリウ
ム、硫酸マグネシウム、塩化ナトリウム、塩化カリウ
ム、炭酸ナトリウム、炭酸水素ナトリウム、セスキ炭酸
ナトリウム、チオ硫酸ナトリウムが挙げられる。Examples of the inorganic salts include sodium sulfate, magnesium sulfate, sodium chloride, potassium chloride, sodium carbonate, sodium hydrogen carbonate, sodium sesquicarbonate, and sodium thiosulfate.
【００１７】油性成分としては、例えば、大豆油、ヌカ
油、ホホバ油、アボガド油、アーモンド油、オリーブ
油、カカオ脂、ゴマ油、パーシック油、ヒマシ油、ヤシ
油、ミンク油、牛脂、豚脂等の天然油脂、これらの天然
油脂を水素添加して得られる硬化油及びミリスチン酸グ
リセリド、２−エチルヘキサン酸グリセリド等の合成グ
リセリド、ジグリセリド等の油脂類；カルナウバロウ、
鯨ロウ、ミツロウ、ラノリン等のロウ類；流動パラフィ
ン、ワセリン、パラフィン、マイクロクリスタリンワッ
クス、セレシン、スクワラン、プリスタン等の炭化水素
類；ラウリン酸、ミリスチン酸、パルミチン酸、ステア
リン酸、ベヘニン酸、オレイン酸、リノール酸、リノレ
ン酸、ラノリン酸、イソステアリン酸等の高級脂肪酸
類；ラウリルアルコール、セチルアルコール、ステアリ
ルアルコール、オレイルアルコール、コレステロール、
２−ヘキシルデカノール等の高級アルコール類；オクタ
ン酸セチル、乳酸ミリスチル、乳酸セチル、ミリスチン
酸イソプロピル、パルミチン酸イソプロピル、アジピン
酸イソプロピル、ステアリン酸ブチル、オレイン酸デシ
ル、イソステアリン酸コレステロール等のエステル類；
精油類；シリコーン油類が挙げられる。Examples of the oily component include soybean oil, bran oil, jojoba oil, avocado oil, almond oil, olive oil, cacao butter, sesame oil, persic oil, castor oil, coconut oil, mink oil, beef tallow, lard, etc. Natural fats and oils such as hardened oils obtained by hydrogenating these natural fats and oils and synthetic glycerides such as myristic glyceride and 2-ethylhexanoic acid glyceride, and diglycerides; carnauba wax;
Waxes such as whale wax, beeswax, lanolin; liquid paraffin, vaseline, paraffin, microcrystalline wax, hydrocarbons such as ceresin, squalane, pristane; lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid , Higher fatty acids such as linoleic acid, linolenic acid, lanolinic acid and isostearic acid; lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, cholesterol,
Higher alcohols such as 2-hexyldecanol; esters such as cetyl octanoate, myristyl lactate, cetyl lactate, isopropyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, and cholesterol isostearate;
Essential oils; silicone oils.
【００１８】ビタミン類としては、例えばビタミンＡ、
ビタミンＢ、ビタミンＤ、ビタミンＥ、ビタミンＦ、ビ
タミンＫ、ビタミンＰ、ビタミンＵ、カルニチン、フェ
ルラ酸、γ−オリザノール、リポ酸、オロット酸及びそ
の誘導体等が挙げられる。蛋白分解酵素としては、例え
ばペプシン、トリプシン、キモトリプシン、カテプシ
ン、パパイン、ブロメライン、フィシン及び細菌酵母、
カビ由来のプロテアーゼ等が挙げられる。As vitamins, for example, vitamin A,
Examples include vitamin B, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, γ-oryzanol, lipoic acid, orotic acid, and derivatives thereof. Examples of proteolytic enzymes include, for example, pepsin, trypsin, chymotrypsin, cathepsin, papain, bromelain, ficin and bacterial yeast,
Mold-derived proteases and the like.
【００１９】その他の成分としては、イオウ、鉱砂、湯
の花、中性白土、卵黄末、イリ糠、雲母末、脱脂粉乳、
海藻エキス、色素、殺菌剤等が挙げられる。本発明の液
体浴用剤組成物は、前記表面処理酸化チタン、有機酸、
及び必要に応じて、水溶性高分子、その他の成分を、通
常、水と混合して液状とすることにより製造する。Other components include sulfur, mineral sand, hot water, neutral clay, egg yolk powder, rice bran, mica powder, skim milk powder,
Examples include seaweed extracts, pigments, and fungicides. The liquid bath composition of the present invention, the surface-treated titanium oxide, an organic acid,
And, if necessary, a water-soluble polymer and other components are usually mixed with water to produce a liquid.
【００２０】本発明の液体浴用剤組成物は、例えば、次
のようにして製造することができる。先ず、水溶性高分
子及び有機酸を水に均一に溶解させる。この溶液に、前
記表面処理酸化チタンをそのまま、又は多価アルコール
に一次分散させてから加える。次いで、その他の添加成
分を加えて均一にすることにより、本発明の液体浴用剤
組成物とする。The liquid bath composition of the present invention can be produced, for example, as follows. First, a water-soluble polymer and an organic acid are uniformly dissolved in water. The surface-treated titanium oxide is added to this solution as it is or after it is first dispersed in a polyhydric alcohol. Next, other additive components are added to make the mixture uniform, thereby obtaining the liquid bath composition of the present invention.
【００２１】[0021]
【実施例】以下、実施例により本発明を具体的に説明す
るが、本発明はこれらの実施例に限定されるものではな
い。なお、以下に示す配合量（％）は重量基準である。
実施例及び比較例で用いた酸化チタンの等電点は、以下
のようにして測定した。EXAMPLES The present invention will be described below in detail with reference to examples, but the present invention is not limited to these examples. In addition, the compounding amount (%) shown below is based on weight.
The isoelectric point of the titanium oxide used in the examples and comparative examples was measured as follows.
【００２２】（等電点の測定方法）市販の酸化チタンを
予め塩酸、水酸化ナトリウムでｐＨ調整された水に浸漬
し、電場内での電気泳動によって界面電位を確認し、そ
の界面電位が０となるｐＨ（等電点）を求めた。(Measurement method of isoelectric point) A commercially available titanium oxide is immersed in water whose pH has been previously adjusted with hydrochloric acid and sodium hydroxide, and the interfacial potential is confirmed by electrophoresis in an electric field. PH (isoelectric point) was determined.
【００２３】（実施例１〜３）以下のようにして、表１
に示す組成の本発明の液体浴用剤組成物を製造した。先
ず、水溶性高分子及び有機酸を水に均一に溶解させた。
この溶液に、酸化チタンを加えた後、その他の成分を加
えて均一にすることにより、本発明の液体浴用剤組成物
とした。 （比較例１〜２）実施例と同様の方法で液体浴用剤組成
物を製造した。(Examples 1 to 3)
The liquid bath composition of the present invention having the composition shown in the following was produced. First, a water-soluble polymer and an organic acid were uniformly dissolved in water.
After adding titanium oxide to this solution, other components were added to make the solution uniform, thereby obtaining a liquid bath agent composition of the present invention. (Comparative Examples 1 and 2) A liquid bath composition was produced in the same manner as in Example.
【００２４】（試験例）実施例１〜３及び比較例１〜２
の液体浴用剤組成物について、以下の方法に従って製剤
中及び浴湯中の分散安定性を評価した。 ＜製剤中の分散安定性＞実施例１〜３及び比較例１〜２
の組成物をそれぞれガラスビンに入れ、５０℃保存１カ
月後の酸化チタンの分散状態を下記の基準に従って目視
にて評価した。 （評価基準）◎：安定に分散し、全く沈降なし、○：底
部にわずかに沈降あり、△：上層部と下層部に濃度差あ
り、×：大部分が沈降し、上層部に透明層あり ＜浴湯中の分散安定性＞実施例１〜３及び比較例１〜２
の組成物について、各３０ｇを２００Ｌのお湯に溶解
し、溶解直後Ｈ0と６時間後Ｈ6に上澄みの濁度を測定し
た。その時の濁度残存率［（Ｈ6／Ｈ0）×１００］を分
散安定性（％）として求めた。(Test Examples) Examples 1-3 and Comparative Examples 1-2
About the liquid bath composition of the above, the dispersion stability in the preparation and in the bath water was evaluated according to the following method. <Dispersion stability in formulation> Examples 1-3 and Comparative Examples 1-2
Each of the compositions was placed in a glass bottle, and the state of dispersion of titanium oxide after one month of storage at 50 ° C. was visually evaluated according to the following criteria. (Evaluation criteria) ◎: Stable dispersion, no sedimentation at all, 沈: Slight sedimentation at bottom, Δ: Density difference between upper and lower layers, ×: Mostly sedimented, transparent layer at upper part <Dispersion stability in bath water> Examples 1-3 and Comparative Examples 1-2
30 g of each of the compositions was dissolved in 200 L of hot water, and the turbidity of the supernatant was measured at H 0 immediately after dissolution and at 6 hours after H 6 . The turbidity residual ratio [(H 6 / H 0 ) × 100] at that time was determined as dispersion stability (%).
【００２５】[0025]
【表１】 [Table 1]
【００２６】[0026]
【発明の効果】本発明の組成物によれば、液体製剤中で
酸化チタンを長期にわたって分散安定化でき、浴湯に投
入した後も安定に分散させることができる。According to the composition of the present invention, titanium oxide can be stably dispersed in a liquid preparation for a long period of time, and can be stably dispersed even after being put into bath water.
Claims (2)
化チタンと、（Ｂ）有機酸の少なくとも一種とを含有す
る液体浴用剤組成物。1. A liquid bath composition comprising (A) a surface-treated titanium oxide having an isoelectric point of pH 7 or more and (B) at least one organic acid.
一種を含有する請求項１記載の液体浴用剤組成物。2. The liquid bath composition according to claim 1, further comprising (C) at least one water-soluble polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001007591A JP4499929B2 (en) | 2001-01-16 | 2001-01-16 | Liquid bath composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001007591A JP4499929B2 (en) | 2001-01-16 | 2001-01-16 | Liquid bath composition |
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| Publication Number | Publication Date |
|---|---|
| JP2002212055A true JP2002212055A (en) | 2002-07-31 |
| JP4499929B2 JP4499929B2 (en) | 2010-07-14 |
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ID=18875318
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001007591A Expired - Fee Related JP4499929B2 (en) | 2001-01-16 | 2001-01-16 | Liquid bath composition |
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| Country | Link |
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| JP (1) | JP4499929B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008024612A (en) * | 2006-07-19 | 2008-02-07 | Health Chemical:Kk | Bath preparation composition |
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| JPH06271458A (en) * | 1993-03-18 | 1994-09-27 | Dainichiseika Color & Chem Mfg Co Ltd | Pigment composition for bathing agent and its production |
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| JPH0797313A (en) * | 1993-09-29 | 1995-04-11 | Yotsuba Yuka Kk | Bathing agent |
| JPH07150083A (en) * | 1993-11-29 | 1995-06-13 | Pentel Kk | Aqueous white pigment composition |
| JPH07228519A (en) * | 1994-02-17 | 1995-08-29 | Tsumura & Co | Bathing agent for jet bath |
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| JPH11335262A (en) * | 1998-05-21 | 1999-12-07 | Rejino Color Kogyo Kk | Composition for bathing agent |
| JPH11343443A (en) * | 1998-05-29 | 1999-12-14 | Pentel Kk | Aqueous pigment composition |
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| JP2008024612A (en) * | 2006-07-19 | 2008-02-07 | Health Chemical:Kk | Bath preparation composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4499929B2 (en) | 2010-07-14 |
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