JP2002129153A - Cold storage agent of which cold storage degree can be detected by color comparison - Google Patents
Cold storage agent of which cold storage degree can be detected by color comparisonInfo
- Publication number
- JP2002129153A JP2002129153A JP2000360346A JP2000360346A JP2002129153A JP 2002129153 A JP2002129153 A JP 2002129153A JP 2000360346 A JP2000360346 A JP 2000360346A JP 2000360346 A JP2000360346 A JP 2000360346A JP 2002129153 A JP2002129153 A JP 2002129153A
- Authority
- JP
- Japan
- Prior art keywords
- cold storage
- color
- pigment
- temperature
- regenerator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2303/00—Details of devices using other cold materials; Details of devices using cold-storage bodies
- F25D2303/08—Devices using cold storage material, i.e. ice or other freezable liquid
- F25D2303/082—Devices using cold storage material, i.e. ice or other freezable liquid disposed in a cold storage element not forming part of a container for products to be cooled, e.g. ice pack or gel accumulator
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2400/00—General features of, or devices for refrigerators, cold rooms, ice-boxes, or for cooling or freezing apparatus not covered by any other subclass
- F25D2400/36—Visual displays
Landscapes
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、通常に用いられてい
る蓄冷剤の冷凍庫での強制蓄冷度合や利用時の残存蓄冷
能力を色彩によって、目視で判断できる蓄冷剤を提供す
るものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention provides a refrigerating agent which can visually determine the degree of forced refrigerating of a commonly used refrigerating agent in a freezer and the remaining regenerative capacity during use by color.
【０００２】[0002]
【従来の技術】従来の技術では、蓄冷剤の実用におい
て、通常は蓄冷剤がプラスチック容器に密閉内蔵されて
いるために、冷蔵庫や冷凍庫内で強制冷却して蓄冷する
のが普通であり、密閉内蔵された蓄冷剤の蓄冷度合を観
測する手段がないことから、蓄冷作業は−２５℃〜−３
５℃に恒温設定した冷凍庫内に、蓄冷剤を充填したケー
スや容器を収容して、確実に蓄冷できるように１０時間
〜１３時間の長時間保管した後で定性的判断で出庫した
ものを利用しているが通例である。なぜならば、ケース
や容器に充填した蓄冷剤の測温手段が未だに確立されて
いないためである。したがって、設定温度以下で発色し
設定温度以上で消色する示温顔料インキを塗布したシー
ルをケースや容器の表面に添付して、蓄冷効果を観測す
る手法も試みられたが、冷凍庫内が−２５℃〜−３５℃
の極低温に恒温設定されているために、表面に添付した
示温シールではケースや容器に充填された蓄冷剤が蓄冷
できていない段階においても、冷凍庫内気温に触れたシ
ールが感応して、あたかも十分に蓄冷されたかのごとく
発色を呈するが、冷凍庫から出して示温シールが外気に
触れると、たちまち発色が消えて、充填された蓄冷剤が
十分に蓄冷されていないことが分り、実用に供せない等
の欠点があった。さらに確実に蓄冷された蓄冷剤の利用
中での残存蓄冷度合の判断基準がなく、蓄冷剤の交換時
期の判断に苦慮する等の難点があった。2. Description of the Related Art In the prior art, in the practical use of a regenerator, the regenerator is usually hermetically sealed in a plastic container. Since there is no means for observing the degree of cold storage of the built-in cold storage agent, the cold storage operation is performed at -25 ° C to -3 ° C.
A case or container filled with a cold storage agent is stored in a freezer set at a constant temperature of 5 ° C, and used for a long time of 10 to 13 hours to ensure cold storage, and then used for qualitative judgment and then released. It is customary. This is because a means for measuring the temperature of the regenerator filled in the case or the container has not yet been established. Therefore, a method of observing the cool storage effect by attaching a seal coated with a temperature pigment ink that develops a color below the set temperature and erases the color above the set temperature was attached to the case or the surface of the container. ° C to -35 ° C
Because the temperature is set to a very low temperature, even when the temperature storage sticker attached to the surface is unable to store the cold storage agent filled in the case or container, the seal touching the temperature inside the freezer responds, as if It shows color as if it had been sufficiently stored cold, but when it comes out of the freezer and the temperature indicating sticker touches the outside air, the color immediately disappears, and it turns out that the filled cold storage agent is not sufficiently stored cold and it can not be used practically And the like. Further, there is no criterion for determining the degree of remaining cold storage during use of the cold storage agent that has been reliably stored, and there is a problem that it is difficult to determine when to replace the cold storage agent.
【０００３】[0003]
【発明が解決しようとする課題】（イ）蓄冷工程での蓄
冷度合の簡便な感知手段の確立。 （ロ）蓄冷剤使用時の残存蓄冷度合の簡便な感知手段の
確立。(A) Establishment of a simple means for sensing the degree of cold storage in the cold storage step. (B) Establishment of a simple means for sensing the degree of remaining cold storage when using a cold storage agent.
【０００４】[0004]
【課題を解決するための手段】（イ）蓄冷度合を蓄冷剤
充填容器の外側表面温度でなく、蓄冷剤本体の蓄冷温度
を告知する手法に変える。 （ロ）上記の手法を具体化するためには、液状あるいは
ゾル状の通常の蓄冷剤（１）に、設定蓄冷温度に見合う
示温領域温度に設定し、マイクロカプセル化した有機系
可逆性示温顔料（２ａ）を添加して均一に分散した蓄冷
剤を構成する。 （ハ）上記の手法では蓄冷効果が失せると色が消える
が、目立たないので、有機系可逆性示温顔料（２ａ）と
併用して、該有機系可逆性示温顔料とは異なる色の、温
度に感応しない普通顔料（３）を通常の蓄冷剤（１）に
添加して均一分散した蓄冷剤を構成する。 （ニ）蓄冷剤使用時の残存蓄冷度合を知るためには、極
限蓄冷温度領域を告知する有機系可逆性示温顔料（２
ａ）と、極限蓄冷温度領域以上の温度になっても、未だ
蓄冷剤の有効蓄冷温度範囲内にあることを告知する、該
有機系可逆性顔料（２ａ）よりも高い示温領域を設定し
た、異なる色に発色する有機系可逆性示温顔料（２ｂ）
を併用し、通常の蓄冷剤（１）に添加して均一分散した
蓄冷剤を構成する。Means for Solving the Problems (a) The degree of cold storage is changed to a method of notifying the cold storage temperature of the cold storage agent main body instead of the outer surface temperature of the cold storage agent filling container. (B) In order to embody the above-mentioned method, a microencapsulated organic reversible thermochromic pigment is set in a liquid or sol-type ordinary cold accumulating agent (1) at a temperature indicating a temperature range corresponding to a set cold accumulating temperature. (2a) is added to form a uniformly dispersed regenerator. (C) In the above-mentioned method, the color disappears when the regenerative effect is lost, but it is inconspicuous, so that it is used in combination with the organic reversible thermochromic pigment (2a) to reduce the temperature to a color different from that of the organic reversible thermochromic pigment. The non-sensitive ordinary pigment (3) is added to the ordinary regenerator (1) to form a homogeneous regenerator. (D) In order to know the remaining cold storage degree when using the cold storage agent, an organic reversible thermochromic pigment (2
a), even when the temperature reaches or exceeds the extreme cold storage temperature range, a temperature range higher than that of the organic reversible pigment (2a) is set to notify that the temperature is still within the effective cold storage temperature range of the cold storage agent. Organic reversible thermochromic pigment that develops different colors (2b)
Are combined and added to the ordinary regenerator (1) to form a regenerator uniformly dispersed.
【０００５】[0005]
【作用】前項（ロ）の作用は、蓄冷剤（１）の蓄冷工程
で極限の蓄冷効果を確認するための目安とするもので、
有機系可逆性示温顔料（２ａ）の設定示温領域以下では
発色し、示温領域温度以上になると該有機系可逆性示温
顔料の色が消える作用を示す。前項（ハ）の作用は、前
項（ロ）と同じ目的あるが、有機系可逆性示温顔料（２
ａ）の設定示温領域温度以下では、該有機系可逆性示温
顔料が発色して、別の色の通常顔料（３）を隠蔽し、設
定示温領域温度以上になると、該有機系可逆性示温顔料
の色が消えて、通常顔料（３）の色が単独で発色を呈す
る。前項（ニ）の作用は、（ロ）、（ハ）とは異なり、
極限の蓄冷効果を確認するための目安とした、有機系可
逆性示温顔料（２ａ）の示温領域温度以下では、別に配
合した有機系可逆性示温顔料（２ｂ）と同時に発色し、
有機系可逆性示温顔料（２ａ）の色が、有機系可逆性示
温顔料（２ｂ）の色を隠蔽する。又、有機系可逆性示温
顔料（２ａ）の示温領域温度以上になると、該有機系可
逆性示温顔料の色が消え、隠蔽されていた有機系可逆性
示温顔料（２ｂ）の色が単独で露顕する。さらに、有機
系可逆性示温顔料（２ｂ）の示温領域温度以上に蓄冷温
度が上昇すると、該有機系可逆性示温顔料の色も消え、
蓄冷剤（１）の無彩色を呈する作用を有する。以上の
（ロ）、（ハ）、（ニ）のそれぞれが可逆性示温顔料を
利用しているので、示温領域温度帯での温度の上下によ
って、発色及び消色あるいは変色を何度も繰り返す作用
を保有する。[Action] The action of the above item (b) is a measure for confirming the ultimate cold storage effect in the cold storage step of the cold storage agent (1).
When the temperature is lower than the set temperature range of the organic reversible thermochromic pigment (2a), the color develops, and when the temperature exceeds the temperature range, the color of the organic reversible thermochromic pigment disappears. The function of the above item (c) has the same purpose as that of the above item (b), but the organic reversible thermochromic pigment (2)
Below the set temperature range of a), the organic reversible thermochromic pigment develops a color and conceals another pigment (3) of another color. Disappears, and the color of the pigment (3) usually develops independently. The effect of the preceding paragraph (d) is different from (b) and (c),
Below the temperature range of the organic reversible thermochromic pigment (2a), which was used as a guide for confirming the extreme cold storage effect, the color was formed simultaneously with the separately added organic reversible thermochromic pigment (2b),
The color of the organic reversible thermochromic pigment (2a) masks the color of the organic reversible thermochromic pigment (2b). When the temperature of the organic reversible thermochromic pigment (2a) becomes higher than the temperature range of the organic reversible thermochromic pigment (2a), the color of the organic reversible thermochromic pigment disappears, and the color of the concealed organic reversible thermochromic pigment (2b) alone becomes visible. I do. Furthermore, when the cold storage temperature rises above the temperature range of the organic reversible thermochromic pigment (2b), the color of the organic reversible thermochromic pigment also disappears,
It has the function of exhibiting an achromatic color of the regenerator (1). Since each of (b), (c), and (d) above uses a reversible thermochromic pigment, the coloring, decoloring, or discoloring is repeated many times depending on the temperature in the temperature range. Hold.
【０００６】[0006]
【実施例】（イ）化学物質を原料素材とする、蓄冷剤
（１）に、マイクロカプセル化した有機系可逆性示温顔
料（２ａ）を添加して、均一に分散配合した成分構成か
ら成る該有機系可逆性示温顔料の、示温領域における発
色および消色する機能を利用して、蓄冷度合を比色によ
り感知できる蓄冷剤。 （ロ）通常の蓄冷剤（１）に、マイクロカプセル化した
有機系可逆性示温顔料（２ａ）と、色彩の異なる普通顔
料（３）を均一に分散配合した成分構成から成る、
（イ）記載の蓄冷剤。 （ハ）通常の蓄冷剤（１）に、示温領域と色彩が異なる
複数のマイクロカプセル化した、有機可逆性示温顔料
（２ａ）と（２ｂ）を配合した成分構成から成る、
（イ）記載の蓄冷剤。EXAMPLE (a) A micro-encapsulated organic reversible thermochromic pigment (2a) was added to a regenerator (1) using a chemical substance as a raw material, and the components were uniformly dispersed and blended. A regenerator that can sense the degree of regenerative colorimetry by utilizing the function of an organic reversible thermochromic pigment to develop and decolor in the thermochromic region. (B) a component composition in which a microencapsulated organic reversible thermochromic pigment (2a) and an ordinary pigment (3) having a different color are uniformly dispersed and mixed in a normal regenerator (1);
(B) The cold storage agent as described above. (C) a plurality of microencapsulated organic reversible thermochromic pigments (2a) and (2b), each of which has a different color from the temperature indicating region, is mixed with the ordinary regenerator (1).
(B) The cold storage agent as described above.
【０００７】有機系可逆性示温顔料（２ａ）、（２ｂ）
は、ロイコ系染料に顕色剤として作用するビスフェノー
ルなどのフェノール化合物と、融点により有機系可逆性
示温顔料（２ａ）、（２ｂ）の示温領域を設定するアル
コール化合物を、それぞれ所定量配合した発色原体をマ
イクロカプセル中に包含してなる、通常市販されてい
る、水系カプセルスラリー又はこれをスプレードライヤ
ーで乾燥したカプセルパウダーを材料とする。Organic reversible thermochromic pigments (2a), (2b)
Is a mixture of a predetermined amount of a phenolic compound such as bisphenol acting as a color developing agent on a leuco dye and an alcoholic compound which sets the temperature indicating region of the organic reversible thermochromic pigments (2a) and (2b) according to their melting points. A water-based capsule slurry, which contains the active ingredient in microcapsules and is usually commercially available, or a capsule powder obtained by drying the slurry with a spray drier is used as a material.
【０００８】請求項１の蓄冷剤の製法とその作用例 通常の蓄冷剤（１）１００部に、−２５℃以下の温度に
おいて黒色に発色する有機系可逆性示温顔料（２ａ）を
０．３部〜３．０部を混ぜ合わせ、均一に分散して、蓄
冷度合を比色により感知できる蓄冷剤を構成する。これ
を−３５℃に恒温設定した冷凍庫に保管して蓄冷する
と、該蓄冷剤が−２５℃以下に蓄冷されると黒色に発色
し、設定温度に蓄冷されたことを告知する。さらに設定
温度に蓄冷された該蓄冷剤の使用中に−２５℃以上に蓄
冷温度が上昇すると、該蓄冷剤の黒色が消えて、通常の
蓄冷剤（１）の固有の無彩色に戻り、蓄冷効果がなくな
ったことを告知する。さらに示温顔料が可逆性であるの
で、設定示温領域を境に温度の上下により、この変化が
繰り返される。A method for producing the regenerator according to claim 1 and an example of its operation. 100 parts of the ordinary regenerator (1) contain 0.3 parts of an organic reversible thermochromic pigment (2a) which develops a black color at a temperature of -25 ° C. or lower. Parts to 3.0 parts are mixed and uniformly dispersed to constitute a regenerator that can detect the degree of regenerative storage by colorimetry. When this is stored in a freezer set at a constant temperature of −35 ° C. and stored in the refrigerator, when the regenerator is stored in a temperature of −25 ° C. or lower, the color changes to black, and it is notified that the stored temperature has been stored. Further, when the cold storage temperature rises to -25 ° C. or more during use of the cold storage agent that has been stored at the set temperature, the black color of the cold storage agent disappears and returns to the achromatic color unique to the normal cold storage agent (1). Announce that the effect has ceased. Further, since the temperature indicator pigment is reversible, this change is repeated depending on whether the temperature rises or falls below the set temperature indicator region.
【０００９】請求項２の蓄冷剤の製法とその作用例 通常の蓄冷剤（１）１００部に、−５℃以下の温度にお
いて青色に発色する有機系可逆性示温顔料（２ａ）を
０．３部〜３．０部と、温度に感応しないピンク色の普
通顔料（３）を０．１部〜１．０部を混ぜ合わせ均一に
分散し、蓄冷度合を比色により感知できる蓄冷剤を構成
する。この蓄冷剤は−５℃以下で有機系可逆性示温顔料
（２ａ）の青色が発色し、普通顔料の（３）のピンク色
を隠蔽するが、−５℃以上になると、有機系可逆性示温
顔料（２ａ）の青色が消えて、普通顔料（３）のピンク
色が露顕して蓄冷効果がなくなったことを告知する。A method for producing the regenerator according to claim 2 and an example of its operation. 100 parts of the ordinary regenerator (1) contain 0.3 parts of an organic reversible thermochromic pigment (2a) which develops a blue color at a temperature of -5 ° C. or lower. Parts to 3.0 parts and 0.1 parts to 1.0 parts of a pink ordinary pigment (3) that is insensitive to temperature are mixed and dispersed uniformly to constitute a regenerator that can detect the degree of regenerative storage by colorimetry. I do. This regenerator emits the blue color of the organic reversible thermochromic pigment (2a) below −5 ° C. and masks the pink color of the ordinary pigment (3). The blue color of the pigment (2a) disappears, and the pink color of the ordinary pigment (3) is revealed to notify that the cool storage effect has been lost.
【００１０】請求項３の蓄冷剤の製法とその作用例 通常の蓄冷剤（１）１００部に、−２５℃以下の温度に
おいて青色に発色する有機系可逆性示温顔料（２ａ）を
０．１部〜３．０部と、−１０℃以下でピンク色に発色
する有機系可逆性示温顔料（２ｂ）を０．１部〜３．０
部を配合し、掻き混ぜて均一に分散して、蓄冷度合を比
色により感知できる蓄冷剤を構成する。この蓄冷剤は、
−２５℃以下になると２種類の有機系可逆性示温顔料
（２ａ）、（２ｂ）が同時に発色するが、−１０℃以下
で発色する有機系可逆性示温顔料（２ｂ）のピンク色
が、有機系可逆性示温顔料（２ａ）の青色に隠蔽され
て、青色とピンク色が混ざった青紫色に発色して、−２
５℃以下に蓄冷されたことを告知するが、該蓄冷剤を使
用中に蓄冷温度が−２５℃以上に上昇すると、有機系可
逆性示温顔料（２ａ）の青色が消え、−１０℃以下で発
色する有機系可逆性示温顔料（２ｂ）のピンク色が単独
で発色し、該蓄冷剤が−２５℃以上、−１０℃以下の領
域においての保冷効果が残存することを告知する。さら
に−１０℃以上に蓄冷温度が上昇すると、有機系可逆性
示温顔料（２ｂ）のピンク色も消えて、該蓄冷剤の蓄冷
効果が消滅したことを告知する。A method for producing the regenerator according to claim 3 and an example of its operation. 100 parts of the ordinary regenerator (1) contain 0.1 parts of an organic reversible thermochromic pigment (2a) which develops a blue color at a temperature of -25 ° C. or lower. Part to 3.0 parts, and 0.1 part to 3.0 parts of the organic reversible thermochromic pigment (2b) which develops a pink color at -10 ° C or lower.
The components are blended, stirred and dispersed uniformly to constitute a regenerator that can detect the degree of regenerative colorimetry. This regenerator
At −25 ° C. or lower, the two types of organic reversible thermochromic pigments (2a) and (2b) simultaneously develop color. However, the pink color of the organic reversible thermochromic pigment (2b) that develops at −10 ° C. or lower has an organic color. It is concealed by the blue color of the system reversible thermochromic pigment (2a) and develops a blue-violet color in which blue and pink colors are mixed, and -2.
When the cold storage temperature rises to -25 ° C or higher while using the cold storage agent, the blue color of the organic reversible thermochromic pigment (2a) disappears and the cold storage temperature decreases to -10 ° C or lower. The pink color of the organic reversible thermochromic pigment (2b) that forms a color develops alone, and the cold storage agent informs that the cooling effect remains in the region of −25 ° C. or more and −10 ° C. or less. Further, when the cold storage temperature rises to -10 ° C or more, the pink color of the organic reversible thermochromic pigment (2b) also disappears, and it is notified that the cold storage effect of the cold storage agent has disappeared.
【００１１】前記した本発明の、蓄冷度合を比色により
感知できる蓄冷剤は、可逆性であるので、設定した示温
領域を境にして温度の上下によって、発色、消色、変色
を何度も繰り返すことができる。The regenerator according to the present invention, which is capable of detecting the degree of regenerative storage by colorimetry, is reversible, so that color development, decolorization, and discoloration occur many times depending on the temperature rise and fall over a set temperature range. Can be repeated.
【００１２】本発明の、蓄冷度合を比色により感知でき
る蓄冷剤は、透明あるいは半透明なる硬質、半硬質ある
いは軟質のプラスチック素材により構成される、袋やケ
ースなどの容器（４）の蓄冷剤注入弁（５）から充填密
閉して利用する。The regenerator of the present invention, which is capable of sensing the degree of regenerative storage by colorimetry, is a regenerator for containers (4) such as bags and cases made of transparent or translucent hard, semi-hard or soft plastic materials. Fill and seal from the injection valve (5) for use.
【００１３】[0013]
【発明の効果】容器（４）に充填密閉された本発明の、
蓄冷度合を比色により感知できる蓄冷剤は、冷凍庫内で
の強制蓄冷工程において、容器（４）の表面周辺外気の
影響を受けず、蓄冷剤その物の温度を色によって直接告
知する効果があるので、蓄冷工程において、従来のよう
に蓄冷剤容器を一括して冷凍庫内に収納して、過冷却に
なるまで長時間保管しなければ蓄冷効果を保証できない
などの、煩わしさを解消する効果が得られる。何故なら
ば、本発明の、蓄冷温度を比色により感知できる蓄冷剤
を用いることによって、過冷却による定性的な蓄冷効果
判断による非効率性を改善できる。例えば蓄冷剤を充填
した容器（４）を一括して冷凍庫に収納しなくても、蓄
冷されたことを告知する発色によって分別できる。さら
に蓄冷剤の使用中においても色が消えたり、変色するこ
とによって残存蓄冷能力を判定できる効果がある。According to the present invention, the container (4) is sealed and filled.
The regenerator capable of sensing the degree of regenerative storage by colorimetry has the effect of directly informing the temperature of the regenerator itself by color in the forced regenerative storage process in the freezer, without being affected by outside air around the surface of the container (4). Therefore, in the cold storage process, the cold storage agent containers are collectively housed in a freezer as in the conventional case, and the effect of eliminating the troublesomeness such as not being able to guarantee the cold storage effect unless it is stored for a long time until it becomes supercooled is effective. can get. This is because the use of the cold storage agent of the present invention, which can detect the cold storage temperature by colorimetry, can improve the inefficiency due to the qualitative determination of the cold storage effect due to supercooling. For example, even if the container (4) filled with the cool storage agent is not stored in the freezer at a time, it is possible to separate the containers by the color for notifying that the cool storage is performed. Further, even when the cool storage agent is used, there is an effect that the remaining cool storage ability can be determined by disappearing or discoloring the color.
【図１】本発明請求項１の蓄冷剤成分構成を表す模擬図FIG. 1 is a schematic diagram showing the configuration of a regenerator component according to claim 1 of the present invention.
【図２】本発明請求項２の蓄冷剤成分構成を表す模擬図FIG. 2 is a schematic diagram showing the configuration of a regenerator component according to claim 2 of the present invention.
【図３】本発明請求項３の蓄冷剤成分構成を表す模擬図FIG. 3 is a schematic diagram showing the composition of a regenerator component according to claim 3 of the present invention.
【図４】本発明の実施例斜視図FIG. 4 is a perspective view of an embodiment of the present invention.
【図５】本発明の更なる実施例斜視図FIG. 5 is a perspective view of a further embodiment of the present invention.
１は蓄冷剤 ２ａは有機系可逆性示温顔料 ２ｂは有機系可逆性示温顔料 ３は普通顔料 ４は容器 ５は蓄冷剤注入弁 ６は冷凍庫 ７は蓄冷前の蓄冷剤 ８は蓄冷されて発色した蓄冷剤 1 is a regenerator 2a is an organic reversible thermal pigment 2b is an organic reversible thermal pigment 3 is a regular pigment 4 is a container 5 is a regenerator injection valve 6 is a freezer 7 is a regenerator before regenerator 8 is regenerative and develops color Cool storage agent
【手続補正書】[Procedure amendment]
【提出日】平成１３年１月１７日（２００１．１．１
７）[Submission date] January 17, 2001 (2001.1.1)
7)
【手続補正１】[Procedure amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】〔０００７〕[Correction target item name] [0007]
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【０００７】有機系可逆性示温顔料（２ａ）、（２ｂ）
は、ロイコ系染料に顕色剤として作用するフノール系化
合物と、それぞれの融点により有機系可逆性示温顔料
（２ａ）、（２ｂ）の示温領域を設定するアルコール化
合物、エステル化合物、又は有機酸グリセリド化合物等
を、それぞれ所定量配合した発色原体をマイクロカプセ
ル中に包含してなる、通常市販されている示温顔料の水
系カプセルスラリー又はこれをスプレードライヤーで乾
燥したカプセルパウダーを材料とする。Organic reversible thermochromic pigments (2a), (2b)
Is a phenolic compound acting as a developer for a leuco dye, and an alcohol compound, an ester compound, or an organic acid glyceride, which sets the temperature indicating region of the organic reversible thermochromic pigments (2a) and (2b) according to their melting points. A commercially available aqueous capsule slurry of a thermochromic pigment or a capsule powder obtained by drying the slurry with a spray drier, which contains a chromogen in which a compound or the like is blended in a predetermined amount, is contained in a microcapsule.
Claims (3)
に、マイクロカプセル化した有機系可逆性示温顔料（２
ａ）を添加して、均一に分散配合した成分構成から成る
該有機系可逆性示温顔料の、示温領域における発色およ
び消色する機能を利用して、蓄冷度合を比色により感知
できる蓄冷剤。A regenerator (1) using a chemical substance as a raw material.
A microencapsulated organic reversible thermochromic pigment (2
A regenerator which can detect the degree of regenerative colorimetrically by utilizing the function of the organic reversible thermochromic pigment having the component constitution added with a) and uniformly dispersing and blending in the thermochromic region to develop and decolor.
有機系可逆性示温顔料（２ａ）と、色彩の異なる普通顔
料（３）を均一に分散配合した成分構成から成る、請求
項１記載の蓄冷剤。2. The composition according to claim 1, wherein a microencapsulated organic reversible thermochromic pigment (2a) and a common pigment (3) having a different color are uniformly dispersed and compounded in the regenerator (1). Cool storage agent.
複数のマイクロカプセル化した有機系可逆性示温顔料
（２ａ）と（２ｂ）を均一に分散配合した成分構成から
成る、請求項１記載の蓄冷剤。3. A component composition in which a plurality of microencapsulated organic reversible thermochromic pigments (2a) and (2b) having different colors from the thermodynamic region are uniformly dispersed and mixed in the regenerator (1). 1. The regenerator according to 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000360346A JP2002129153A (en) | 2000-10-20 | 2000-10-20 | Cold storage agent of which cold storage degree can be detected by color comparison |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000360346A JP2002129153A (en) | 2000-10-20 | 2000-10-20 | Cold storage agent of which cold storage degree can be detected by color comparison |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2002129153A true JP2002129153A (en) | 2002-05-09 |
Family
ID=18831965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000360346A Pending JP2002129153A (en) | 2000-10-20 | 2000-10-20 | Cold storage agent of which cold storage degree can be detected by color comparison |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2002129153A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004042299A1 (en) | 2002-11-05 | 2004-05-21 | BSH Bosch und Siemens Hausgeräte GmbH | Method and device for monitoring the temperature in a refrigerator |
| JP2006045408A (en) * | 2004-08-06 | 2006-02-16 | Toppan Forms Co Ltd | Coolant containing reversibly temperature-indicating agent and coolant pack using the same |
| JP2006057911A (en) * | 2004-08-20 | 2006-03-02 | Sharp Corp | Refrigerator |
| JP2006057909A (en) * | 2004-07-23 | 2006-03-02 | Sharp Corp | Refrigerator |
| JP2006057910A (en) * | 2004-08-20 | 2006-03-02 | Sharp Corp | Refrigerator |
| WO2006079828A1 (en) * | 2005-01-28 | 2006-08-03 | Sean Flanagan | An eutectic plate |
| JP2015087060A (en) * | 2013-10-31 | 2015-05-07 | トッパン・フォームズ株式会社 | Cold storage sheet |
| WO2015141436A1 (en) * | 2014-03-20 | 2015-09-24 | トッパン・フォームズ株式会社 | Cold-insulating tool |
| JP2015189816A (en) * | 2014-03-27 | 2015-11-02 | トッパン・フォームズ株式会社 | Cold insulation tool |
| WO2017047648A1 (en) * | 2015-09-18 | 2017-03-23 | トッパン・フォームズ株式会社 | Cold insulation tool |
| CN111149856A (en) * | 2020-01-08 | 2020-05-15 | 浙江省农业科学院 | Cold-storage agent and application thereof in fruit and vegetable fresh-keeping |
-
2000
- 2000-10-20 JP JP2000360346A patent/JP2002129153A/en active Pending
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004042299A1 (en) | 2002-11-05 | 2004-05-21 | BSH Bosch und Siemens Hausgeräte GmbH | Method and device for monitoring the temperature in a refrigerator |
| US7814755B2 (en) | 2002-11-05 | 2010-10-19 | Bsh Bosch Und Siemens Hausgeraete Gmbh | Method and device for monitoring the temperature in a refrigerator |
| JP2006057909A (en) * | 2004-07-23 | 2006-03-02 | Sharp Corp | Refrigerator |
| JP2006045408A (en) * | 2004-08-06 | 2006-02-16 | Toppan Forms Co Ltd | Coolant containing reversibly temperature-indicating agent and coolant pack using the same |
| JP2006057910A (en) * | 2004-08-20 | 2006-03-02 | Sharp Corp | Refrigerator |
| JP4514557B2 (en) * | 2004-08-20 | 2010-07-28 | シャープ株式会社 | refrigerator |
| JP2006057911A (en) * | 2004-08-20 | 2006-03-02 | Sharp Corp | Refrigerator |
| WO2006079828A1 (en) * | 2005-01-28 | 2006-08-03 | Sean Flanagan | An eutectic plate |
| GB2422657B (en) * | 2005-01-28 | 2009-11-18 | Sean Flanagan | An eutectic plate |
| JP2015087060A (en) * | 2013-10-31 | 2015-05-07 | トッパン・フォームズ株式会社 | Cold storage sheet |
| WO2015141436A1 (en) * | 2014-03-20 | 2015-09-24 | トッパン・フォームズ株式会社 | Cold-insulating tool |
| JP2015194331A (en) * | 2014-03-20 | 2015-11-05 | トッパン・フォームズ株式会社 | Cold insulation tool |
| US10094609B2 (en) | 2014-03-20 | 2018-10-09 | Toppan Forms Co., Ltd. | Refrigerant pack |
| JP2015189816A (en) * | 2014-03-27 | 2015-11-02 | トッパン・フォームズ株式会社 | Cold insulation tool |
| WO2017047648A1 (en) * | 2015-09-18 | 2017-03-23 | トッパン・フォームズ株式会社 | Cold insulation tool |
| CN111149856A (en) * | 2020-01-08 | 2020-05-15 | 浙江省农业科学院 | Cold-storage agent and application thereof in fruit and vegetable fresh-keeping |
| CN111149856B (en) * | 2020-01-08 | 2023-03-07 | 浙江省农业科学院 | Cold-storage agent and application thereof in fruit and vegetable fresh-keeping |
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