JP2002060615A - Reflecting plate - Google Patents
Reflecting plateInfo
- Publication number
- JP2002060615A JP2002060615A JP2001139855A JP2001139855A JP2002060615A JP 2002060615 A JP2002060615 A JP 2002060615A JP 2001139855 A JP2001139855 A JP 2001139855A JP 2001139855 A JP2001139855 A JP 2001139855A JP 2002060615 A JP2002060615 A JP 2002060615A
- Authority
- JP
- Japan
- Prior art keywords
- component
- titanium oxide
- weight
- polycarbonate resin
- aromatic polycarbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229920001971 elastomer Polymers 0.000 claims abstract description 31
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 30
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 30
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 30
- 125000003118 aryl group Chemical group 0.000 claims abstract description 26
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 7
- 239000000178 monomer Substances 0.000 claims abstract description 7
- 239000011342 resin composition Substances 0.000 claims abstract description 7
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 5
- -1 alkyl hydrogen Chemical compound 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 22
- 238000011156 evaluation Methods 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 238000004898 kneading Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 10
- 230000007423 decrease Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 150000004650 carbonic acid diesters Chemical class 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 2
- ZDZYGYFHTPFREM-UHFFFAOYSA-N 3-[3-aminopropyl(dimethoxy)silyl]oxypropan-1-amine Chemical compound NCCC[Si](OC)(OC)OCCCN ZDZYGYFHTPFREM-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920005990 polystyrene resin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 2
- YAOMHRRYSRRRKP-UHFFFAOYSA-N 1,2-dichloropropyl 2,3-dichloropropyl 3,3-dichloropropyl phosphate Chemical compound ClC(Cl)CCOP(=O)(OC(Cl)C(Cl)C)OCC(Cl)CCl YAOMHRRYSRRRKP-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- JABCKXBEMZTLNI-UHFFFAOYSA-N 2-[[dimethoxy(methyl)silyl]methyl]butane-1,4-diamine Chemical compound CO[Si](C)(OC)CC(CN)CCN JABCKXBEMZTLNI-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 102100024522 Bladder cancer-associated protein Human genes 0.000 description 1
- 101150110835 Blcap gene Proteins 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 101100493740 Oryza sativa subsp. japonica BC10 gene Proteins 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920006361 Polyflon Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 101001062854 Rattus norvegicus Fatty acid-binding protein 5 Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- RAYIMXZLSRHMTK-UHFFFAOYSA-N bis(2,3-dibromopropyl) 2,3-dichloropropyl phosphate Chemical compound ClCC(Cl)COP(=O)(OCC(Br)CBr)OCC(Br)CBr RAYIMXZLSRHMTK-UHFFFAOYSA-N 0.000 description 1
- GPZPNAVMOODHSK-UHFFFAOYSA-N bis(3-chloropropyl) octyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCCl)OCCCCl GPZPNAVMOODHSK-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical class C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Optical Elements Other Than Lenses (AREA)
- Liquid Crystal (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は高反射性芳香族ポリ
カーボネート樹脂組成物から成形された反射板にに関す
る。[0001] The present invention relates to a reflector formed from a highly reflective aromatic polycarbonate resin composition.
【０００２】[0002]
【従来の技術】従来より液晶表示盤やＬＥＤ表示盤等の
反射板としては樹脂成形品にメッキ加工及び塗装された
ものが利用されてきた。しかしながら、樹脂成形品をメ
ッキ加工及び塗装するには時間と費用を要するため、樹
脂成形品自体が高い反射性を有し、メッキ加工・塗装を
必要としない反射板材料が望まれていた。芳香族ポリカ
ーボネート樹脂は機械的特性、寸法安定性、耐熱性等に
優れているので液晶表示盤やＬＥＤの表示盤等の反射板
用途に適している。芳香族ポリカーボネート樹脂に反射
性能を付与する方法として、酸化チタンを配合して白度
を向上させ、光遮蔽性を付与して反射率を上げる方法が
検討されている。しかし、酸化チタンの配合量が多くな
ると、酸化チタン表面に存在する化学的活性点が原因と
なって、加熱溶融条件下で芳香族ポリカーボネート樹脂
の分子量が低下し、機械的特性が低下すると同時に着色
してしまう為に満足する反射板を提供するには到らなか
った。また、製品の軽量化や軽薄化に伴い、芳香族ポリ
カーボネート樹脂反射板についても、より薄肉となり、
且つ難燃性も要求されるようになってきた。2. Description of the Related Art Conventionally, as a reflection plate for a liquid crystal display panel, an LED display panel, or the like, a resin molded product plated and coated has been used. However, since plating and coating of the resin molded product require time and expense, there has been a demand for a reflective plate material which has high reflectivity and does not require plating and coating. Aromatic polycarbonate resins are excellent in mechanical properties, dimensional stability, heat resistance, and the like, and are therefore suitable for use in reflectors such as liquid crystal display panels and LED display panels. As a method of imparting the reflective performance to the aromatic polycarbonate resin, a method of increasing the whiteness by adding titanium oxide and increasing the reflectance by imparting a light shielding property has been studied. However, when the blending amount of titanium oxide increases, the molecular weight of the aromatic polycarbonate resin decreases under heating and melting conditions due to the chemically active sites present on the titanium oxide surface, and the mechanical properties decrease and coloring occurs at the same time. However, it has not been possible to provide a satisfactory reflection plate. In addition, with the weight reduction and thinning of the product, the aromatic polycarbonate resin reflector also becomes thinner,
Also, flame retardancy has been required.
【０００３】上記問題点を解決する方法として、ポリカ
ーボネート樹脂に酸化チタンを配合する際、ポリオルガ
ノ水素シロキサンを添加する方法（特公昭６３−２６１
４０），アルミニウムの水和酸化物とポリオルガノシロ
キサンまたはアルカノールアミンとで表面処理された酸
化チタンをポリカーボネート樹脂に添加する方法（特公
昭６０−３４３０），また、特定のポリオルガノシロキ
サンで表面処理された酸化チタンをポリカーボネート樹
脂に添加する方法（特開平４−２０２４７６）等が提案
されている。しかしながら、いずれの方法も芳香族ポリ
カーボネート樹脂の分子量低下をある程度抑制すること
は可能であるがまだ十分ではなく、機械的特性（特に衝
撃強度）を改善する事ができず、また反射板としての性
能も不十分であった。As a method for solving the above problems, a method of adding a polyorganohydrogensiloxane when blending titanium oxide with a polycarbonate resin (JP-B-63-261)
40), a method of adding titanium oxide surface-treated with a hydrated oxide of aluminum and a polyorganosiloxane or an alkanolamine to a polycarbonate resin (Japanese Patent Publication No. 60-3430), or a method of surface-treating with a specific polyorganosiloxane. There has been proposed a method of adding titanium oxide to a polycarbonate resin (JP-A-4-202476). However, any of these methods can suppress the decrease in the molecular weight of the aromatic polycarbonate resin to some extent, but is still insufficient, and cannot improve the mechanical properties (particularly, impact strength). Was also inadequate.
【０００４】[0004]
【発明が解決しようとする課題】本発明の目的は、高い
光反射特性及び優れた機械的特性を有した反射板を提供
することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a reflector having high light reflection characteristics and excellent mechanical characteristics.
【０００５】[0005]
【課題を解決するための手段】本発明は、（Ａ）芳香族
ポリカーボネート樹脂（Ａ成分）９５〜６０重量％、
（Ｂ）酸化チタン（Ｂ成分）５〜４０重量％からなる樹
脂組成物１００重量部に対し、（Ｃ）ポリオルガノシロ
キサンゴム成分とポリアルキル（メタ）アクリレートゴ
ム成分とが分離できないように相互に絡み合った構造を
有している複合ゴムに一種または二種以上のビニル系単
量体がグラフト重合されてなる複合ゴム系グラフト共重
合体（Ｃ成分）０．５〜２０重量部を配合してなる高反
射性芳香族ポリカーボネート樹脂組成物から成形された
反射板に係わるものである。The present invention provides (A) an aromatic polycarbonate resin (A component) of 95 to 60% by weight,
With respect to 100 parts by weight of the resin composition comprising (B) 5 to 40% by weight of titanium oxide (B component), the (C) polyorganosiloxane rubber component and the polyalkyl (meth) acrylate rubber component are mutually separated so that they cannot be separated. 0.5 to 20 parts by weight of a composite rubber-based graft copolymer (component (C)) obtained by graft-polymerizing one or more vinyl monomers into a composite rubber having an entangled structure The present invention relates to a reflector formed from a highly reflective aromatic polycarbonate resin composition.
【０００６】本発明で使用される（Ａ）芳香族ポリカー
ボネート樹脂（以下、Ａ成分と称する。）は、２価フェ
ノールより誘導される粘度平均分子量１０，０００〜６
０，０００、好ましくは１５，０００〜３０，０００の
芳香族ポリカーボネート樹脂であり、通常２価フェノー
ルとカーボネート前駆体との溶液法又は溶融法で反応さ
せて製造される。次にこれらの製造方法について基本的
な手段を簡単に説明する。カーボネート前駆物質として
例えばホスゲンを使用する反応では、通常酸結合剤およ
び溶媒の存在下に反応を行う。酸結合剤としては例えば
水酸化ナトリウム、水酸化カリウム等のアルカリ金属水
酸化物またはピリジン等のアミン化合物が用いられる。
溶媒としては例えば塩化メチレン、クロロベンゼン等の
ハロゲン化炭化水素が用いられる。また反応促進のため
に例えば第三級アミンまたは第四級アンモニウム塩等の
触媒を用いることもできる。その際、反応温度は通常０
〜４０℃であり、反応時間は数分〜５時間である。The aromatic polycarbonate resin (A) used in the present invention (hereinafter referred to as "A component") has a viscosity average molecular weight of 10,000 to 6 derived from dihydric phenol.
It is an aromatic polycarbonate resin of 000, preferably 15,000 to 30,000, and is usually produced by reacting a dihydric phenol with a carbonate precursor by a solution method or a melting method. Next, basic means of these manufacturing methods will be briefly described. In a reaction using, for example, phosgene as a carbonate precursor, the reaction is usually performed in the presence of an acid binder and a solvent. Examples of the acid binder include alkali metal hydroxides such as sodium hydroxide and potassium hydroxide and amine compounds such as pyridine.
As the solvent, for example, halogenated hydrocarbons such as methylene chloride and chlorobenzene are used. For promoting the reaction, a catalyst such as a tertiary amine or a quaternary ammonium salt may be used. At that time, the reaction temperature is usually 0
４０40 ° C., and the reaction time is several minutes to 5 hours.
【０００７】カーボネート前駆物質として炭酸ジエステ
ルを用いるエステル交換反応は、不活性ガス雰囲気下所
定割合の芳香族ジヒドロキシ成分を炭酸ジエステルと加
熱しながら撹拌して、生成するアルコールまたはフェノ
ール類を留出させる方法により行われる。反応温度は生
成するアルコールまたはフェノール類の沸点等により異
なるが、通常１２０〜３００℃の範囲である。反応はそ
の初期から減圧にして生成するアルコールまたはフェノ
ール類を留出させながら反応を完結させる。また反応を
促進するために通常エステル交換反応に使用される触媒
を使用することもできる。前記エステル交換反応に使用
される炭酸ジエステルとしては、例えばジフェニルカー
ボネート、ジナフチルカーボネート、ビス（ジフェニ
ル）カーボネート、ジメチルカーボネート、ジエチルカ
ーボネート、ジブチルカーボネート等が挙げられる。こ
れらのうち特にジフェニルカーボネートが好ましい。The transesterification reaction using a carbonic acid diester as a carbonate precursor is a method in which a predetermined ratio of an aromatic dihydroxy component is stirred with a carbonic acid diester while heating under an inert gas atmosphere to distill off the alcohol or phenol to be produced. It is performed by The reaction temperature varies depending on the boiling point of the produced alcohol or phenol, and is usually in the range of 120 to 300 ° C. The reaction is completed under reduced pressure from the beginning while distilling off alcohol or phenols produced. Further, a catalyst usually used in a transesterification reaction to promote the reaction can be used. Examples of the carbonic acid diester used in the transesterification reaction include diphenyl carbonate, dinaphthyl carbonate, bis (diphenyl) carbonate, dimethyl carbonate, diethyl carbonate, dibutyl carbonate and the like. Of these, diphenyl carbonate is particularly preferred.
【０００８】ここで使用する２価フェノールとしては、
２，２−ビス（４−ヒドロキシフェニル）プロパン［通
称ビスフェノールＡ］を対象とするが、その一部又は全
部を他の二価フェノールで置換えてもよい。他の二価フ
ェノールとしては、例えばビス（４−ヒドロキシフェニ
ル）メタン、２，２−ビス（４−ヒドロキシ−３，５−
ジメチルフェニル）プロパン、２，２−ビス（４−ヒド
ロキシ−３−メチルフェニル）プロパン、ビス（４−ヒ
ドロキシフェニル）スルフォン等があげられる。また、
カーボネート前駆体としてはカルボニルハライド、カル
ボニルエステル又はハロホルメート等があげられ、具体
的にはホスゲン、ジフェニルカーボネート、二価フェノ
ールのジハロホルメート及びこれらの混合物である。芳
香族ポリカーボネート樹脂を製造するに当り、適当な分
子量調節剤、分岐剤、反応を促進するための触媒等も使
用できる。かくして得られた芳香族ポリカーボネート樹
脂の２種以上混合しても差し支えない。The dihydric phenol used here includes:
The target is 2,2-bis (4-hydroxyphenyl) propane [commonly known as bisphenol A], but a part or the whole thereof may be replaced with another dihydric phenol. Other dihydric phenols include, for example, bis (4-hydroxyphenyl) methane, 2,2-bis (4-hydroxy-3,5-
Dimethylphenyl) propane, 2,2-bis (4-hydroxy-3-methylphenyl) propane, bis (4-hydroxyphenyl) sulfone and the like. Also,
Examples of the carbonate precursor include carbonyl halide, carbonyl ester and haloformate, and specific examples thereof include phosgene, diphenyl carbonate, dihaloformate of dihydric phenol, and a mixture thereof. In producing the aromatic polycarbonate resin, an appropriate molecular weight regulator, a branching agent, a catalyst for accelerating the reaction, and the like can be used. Two or more aromatic polycarbonate resins thus obtained may be mixed.
【０００９】本発明で使用される（Ｂ）酸化チタン（以
下、Ｂ成分と称する。）は、製造方法，結晶構造及び粒
子径によって限定されるものではないが、塩素法により
製造された酸化チタンであり、ルチル形の結晶構造をと
るものがより好ましい。一般的に顔料用酸化チタンの粒
子径は、０．１〜０．４μｍであるが、粒子径０．１μ
ｍ未満のものでも構わない。これらの酸化チタンは一般
的には、無機系表面処理剤（アルミナ及び／又はシリ
カ）で表面処理されている。これらの酸化チタンは更に
有機系表面処理剤で処理されているものが好ましい。有
機表面処理剤としては、アルキルポリシロキサン、アル
キルアリールポリシロキサン、アルキルハイドロジェン
ポリシロキサンなどのシロキサン類やアルキルアルコキ
シシラン、アミノ系シランカップリング剤等のオルガノ
シリコンが挙げられる。好ましい処理剤としては、メチ
ルハイドロジェンポリシロキサンやメチルトリメトキシ
シラン、トリメチルメトキシシラン、Ｎ−β（アミノエ
チル）−γ−アミノプロピルトリメトキシシラン、Ｎ−
β（アミノエチル）−γ−アミノプロピルメチルジメト
キシシラン等での表面処理が挙げられる。なお、表面処
理剤中には、本発明を阻害しない程度の量で安定剤や分
散剤等が含まれていてもよい。また、表面処理の方法と
しては、酸化チタンと表面処理剤を水又は有機溶剤中に
分散させ湿式処理する方法あるいは、スーパーミキサ
ー，ヘンシルミキサー等により乾式処理する方法あるい
は、表面処理剤，酸化チタン，芳香族ポリカーボネート
樹脂及びゴム質重合体を同時にＶ型ブレンダーで混合す
る方法や、同時に押出機中に投入し押出する方法も有効
である。The titanium oxide (B) (B component) used in the present invention is not limited by the production method, crystal structure and particle size, but titanium oxide produced by the chlorine method. And those having a rutile crystal structure are more preferable. Generally, the particle diameter of the titanium oxide for pigment is 0.1 to 0.4 μm, but the particle diameter is 0.1 μm.
m. These titanium oxides are generally surface-treated with an inorganic surface treating agent (alumina and / or silica). It is preferable that these titanium oxides are further treated with an organic surface treating agent. Examples of the organic surface treating agent include siloxanes such as alkylpolysiloxane, alkylarylpolysiloxane, and alkylhydrogenpolysiloxane, and organosilicon such as alkylalkoxysilane and amino-based silane coupling agent. Preferred treating agents include methylhydrogenpolysiloxane, methyltrimethoxysilane, trimethylmethoxysilane, N-β (aminoethyl) -γ-aminopropyltrimethoxysilane, N-
Surface treatment with β (aminoethyl) -γ-aminopropylmethyldimethoxysilane and the like can be mentioned. The surface treatment agent may contain a stabilizer, a dispersant, and the like in an amount that does not impair the present invention. Examples of the surface treatment method include a method of dispersing titanium oxide and a surface treating agent in water or an organic solvent and performing a wet treatment, a method of performing a dry treatment using a super mixer, a Hensyl mixer, or the like; It is also effective to simultaneously mix the aromatic polycarbonate resin and the rubbery polymer with a V-type blender, or to simultaneously charge and extrude the mixture into an extruder.
【００１０】本発明で使用される（Ａ）芳香族ポリカー
ボネート樹脂と（Ｂ）酸化チタンの混合割合は、Ａ成分
が９５〜６０重量％、Ｂ成分が５〜４０重量％、好まし
くは、Ａ成分が９５〜７０重量％、Ｂ成分が５〜３０重
量％である。Ｂ成分の割合が、５重量％未満では透過光
量が多くなり、要求される高い反射率が得られない。ま
た、４０重量％を越えるとポリカ−ボネ−ト樹脂の分子
量低下や物性（特に衝撃強度）が低下する。The mixing ratio of the aromatic polycarbonate resin (A) and the titanium oxide (B) used in the present invention is such that the A component is 95 to 60% by weight, the B component is 5 to 40% by weight, preferably the A component. Is 95 to 70% by weight, and the B component is 5 to 30% by weight. If the proportion of the B component is less than 5% by weight, the amount of transmitted light increases, and the required high reflectance cannot be obtained. If it exceeds 40% by weight, the molecular weight and physical properties (particularly, impact strength) of the polycarbonate resin decrease.
【００１１】本発明で使用される（Ｃ）ゴム質重合体
（以下、Ｃ成分と称する。）は、ポリオルガノシロキサ
ンゴム成分とポリアルキル（メタ）アクリレートゴム成
分とが分離できないように相互に絡み合った構造を有し
ている複合ゴムに一種または二種以上のビニル系単量体
がグラフト重合されてなる複合ゴム系グラフト共重合体
が挙げられる。The rubbery polymer (C) used in the present invention (hereinafter referred to as "C component") is entangled with each other so that the polyorganosiloxane rubber component and the polyalkyl (meth) acrylate rubber component cannot be separated. Rubber-based graft copolymers obtained by graft-polymerizing one or more vinyl-based monomers onto a composite rubber having a modified structure.
【００１２】前記複合ゴム系グラフト共重合体におい
て、複合化ゴムの平均粒子径は０．０８〜０．６μｍで
あることが好ましい。複合ゴムの平均粒子径が０．０８
μｍ未満では得られる樹脂組成物の耐衝撃性が低下し、
平均粒子径が０．６μｍを超えると、得られる樹脂組成
物の成形品の表面外観が悪化する。本発明において使用
される複合ゴム系グラフト共重合体を得るには、まず３
員環以上の各種の環状オルガノシロキサン、例えばヘキ
サメチルシクロトリシロキサン、オクタメチルシクロテ
トラシロキサン、デカメチルシクロペンタシロキサン、
等と、架橋剤及び／またはグラフト交叉剤を用いて乳化
重合によりポリオルガノシロキサンゴムのラテックスを
調整し、次にアルキル（メタ）アクリレート単量体、架
橋剤及びグラフト交叉剤とをポリオルガノシロキサンゴ
ムのラテックスに含浸させてから重合することによって
得られる。ここで用いられるアルキル（メタ）アクリレ
ート単量体としては、メチルアクリレート、エチルアク
リレート、ｎ−プロピルアクリレート、ｎ−ブチルアク
リレート、２−エチルヘキシルアクリレート等のアルキ
ルアクリレートおよびヘキシルメタクリレート、２−エ
チルヘキシルメタクリレート等のアルキルメタクリレー
トが挙げられるが、特にｎ−ブチルアクリレートを用い
ることが好ましい。この複合ゴムにグラフト重合させる
ビニル系単量体としては、スチレン、α−メチルスチレ
ン等の芳香族ビニル化合物、アクリロニトリル、メタク
リロニトリル等のシアン化ビニル化合物、メチルメタク
リレート、２−エチルヘキシルメタクリレート等のメタ
クリル酸エステル、メチルアクリレート、エチルアクリ
レート、ブチルアクリレート等のアクリル酸エステル等
が挙げられ、これらは単独もしくは２種以上組み合わせ
て用いられる。なかでも、特に好ましいものとしては、
三菱レイヨン（株）よりメタブレンＳ−２００１という
商品名で市販されているものが挙げられる。In the composite rubber-based graft copolymer, the composite rubber preferably has an average particle size of 0.08 to 0.6 μm. The average particle size of the composite rubber is 0.08
If it is less than μm, the impact resistance of the obtained resin composition decreases,
When the average particle diameter exceeds 0.6 μm, the surface appearance of a molded article of the obtained resin composition deteriorates. To obtain the composite rubber-based graft copolymer used in the present invention, first, 3
Various cyclic organosiloxanes having at least a member ring, for example, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane,
And the like, and a latex of a polyorganosiloxane rubber is prepared by emulsion polymerization using a crosslinking agent and / or a graft crosslinking agent. Then, an alkyl (meth) acrylate monomer, a crosslinking agent and a graft crosslinking agent are combined with the polyorganosiloxane rubber. And then polymerized. Examples of the alkyl (meth) acrylate monomer used here include alkyl acrylates such as methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, and 2-ethylhexyl acrylate, and alkyls such as hexyl methacrylate and 2-ethylhexyl methacrylate. Although methacrylate is mentioned, it is particularly preferable to use n-butyl acrylate. Examples of the vinyl monomer to be graft-polymerized on the composite rubber include aromatic vinyl compounds such as styrene and α-methylstyrene, vinyl cyanide compounds such as acrylonitrile and methacrylonitrile, and methacrylic compounds such as methyl methacrylate and 2-ethylhexyl methacrylate. Acrylic esters such as acid esters, methyl acrylate, ethyl acrylate, and butyl acrylate are exemplified, and these may be used alone or in combination of two or more. Among them, particularly preferred are:
A product commercially available from Mitsubishi Rayon Co., Ltd. under the trade name Metablen S-2001 can be used.
【００１３】本発明におけるＣ成分の効果は、衝撃強度
を向上させるのみでなく芳香族ポリカーボネート樹脂の
分子量低下を抑制する効果を有する。その効果は、Ｃ成
分が芳香族ポリカーボネート樹脂と比較し酸化チタンと
の親和性が高く、溶融混練時芳香族ポリカーボネート樹
脂と酸化チタンとの接触面積を低下させていることに起
因すると考えられる。The effect of the component C in the present invention not only improves the impact strength but also has the effect of suppressing a decrease in the molecular weight of the aromatic polycarbonate resin. It is considered that the effect is due to the fact that the C component has a higher affinity for titanium oxide than the aromatic polycarbonate resin, and reduces the contact area between the aromatic polycarbonate resin and titanium oxide during melt-kneading.
【００１４】本発明に使用するＣ成分の配合割合はＡ成
分及Ｂ成分の合計量１００重量部に対して、０．５〜２
０重量部であり、好ましくは１〜１０重量部である。
０．５重量部未満では機械的特性（特に衝撃強度）が不
十分であり、また分子量低下抑制効果が不十分である。
２０重量部を越えると耐熱性・剛性が低下してしまう。The compounding ratio of the component C used in the present invention is 0.5 to 2 with respect to 100 parts by weight of the total amount of the component A and the component B.
0 parts by weight, preferably 1 to 10 parts by weight.
If the amount is less than 0.5 part by weight, the mechanical properties (particularly, impact strength) are insufficient, and the effect of suppressing a decrease in molecular weight is insufficient.
If it exceeds 20 parts by weight, heat resistance and rigidity will be reduced.
【００１５】本発明で使用される（Ｄ）難燃剤（以下、
Ｄ成分と称する。）としては、本発明の効果の範囲で燃
焼性を向上させる効果のあるものであれば特に制限はな
いが、好ましくは、ハロゲン系難燃剤及び／又は、リン
酸エステル系難燃剤から選ばれるものである。ハロゲン
系難燃剤としては、芳香族ハロゲン化合物、ハロゲン化
エポキシ樹脂、ハロゲン化ポリカーボネート樹脂、ハロ
ゲン化芳香族ビニル系重合体、ハロゲン化シアヌレート
樹脂、ハロゲン化ポリフェニルエーテル、ハロゲン化ポ
リフェニルチオエーテル等があげられ、好ましくはデカ
ブロモジフェニルオキサイド、ブロム化ビスフェノール
系エポキシ樹脂、ブロム化ビスフェノール系フェノキシ
樹脂、ブロム化ビスフェノール系ポリカーボネート樹
脂、ブロム化ポリスチレン樹脂、ブロム化架橋ポリスチ
レン樹脂、ブロム化ビスフェノールシアヌレート樹脂、
ブロム化ポリフェニレンオキサイド、ポリジブロムフェ
ニレンオキサイド、デカブロモジフェニルオキサイドビ
スフェノール縮合物（テトラブロムビスフェノールＡ、
そのオリゴマーなど）である。またリン酸エステル系難
燃剤としては、リン酸エステル或いはオリゴマー状のリ
ン酸エステルを使用することができる。それらリン酸エ
ステルは、アルコール或いはフェノール化合物と、オキ
シ塩化リン或いは五塩化リンの如きリン化合物との反応
によって得られたリン酸エステルが挙げられ、この際フ
ェノール化合物として１価のフェノール化合物と共に、
２価のフェノール化合物（例えばレゾルシン、ハイドロ
キノン、ジフェノール化合物）を使用すると、オリゴマ
ー状のリン酸エステルが得られる。リン酸エステル系難
燃剤の具体例としては、トリメチルホスフェート、トリ
エチルホスフェート、トリブチルホスフェート、トリオ
クチルホスフェート、トリブトキシコチルホスフェー
ト、トリフェニルホスフェート、トリクレジルホスフェ
ート、クレジルジフェニルホスフェート、オクチルジフ
ェニルホスフェートなどの非ハロゲンリン酸エステル、
トリス（クロロエチル）ホスフェート、トリス（ジクロ
ロプロピル）ホスフェート、ビス（２，３ジブロモプロ
ピル）２，３−ジクロロプロピルホスフェート、トリス
（２，３−ジブロモプロピル）ホスフェート、ビス（ク
ロロプロピル）モノオクチルホスフェートなど含ハロゲ
ンリン酸エステルなどが挙げられる。The flame retardant (D) used in the present invention (hereinafter referred to as “D”)
It is called D component. ) Is not particularly limited as long as it has an effect of improving flammability within the range of the effect of the present invention, but is preferably selected from halogen-based flame retardants and / or phosphate ester-based flame retardants. It is. Examples of the halogen-based flame retardant include aromatic halogen compounds, halogenated epoxy resins, halogenated polycarbonate resins, halogenated aromatic vinyl polymers, halogenated cyanurate resins, halogenated polyphenyl ethers, halogenated polyphenyl thioethers, and the like. Preferably, decabromodiphenyl oxide, brominated bisphenol-based epoxy resin, brominated bisphenol-based phenoxy resin, brominated bisphenol-based polycarbonate resin, brominated polystyrene resin, brominated cross-linked polystyrene resin, brominated bisphenol cyanurate resin,
Brominated polyphenylene oxide, polydibromophenylene oxide, decabromodiphenyl oxide bisphenol condensate (tetrabromobisphenol A,
Oligomers thereof). Phosphate esters or oligomeric phosphate esters can be used as the phosphate ester flame retardant. Examples of the phosphoric acid ester include a phosphoric acid ester obtained by reacting an alcohol or a phenol compound with a phosphorus compound such as phosphorus oxychloride or phosphorus pentachloride.
When a divalent phenol compound (for example, resorcin, hydroquinone, diphenol compound) is used, an oligomeric phosphate ester can be obtained. Specific examples of the phosphate ester-based flame retardant include trimethyl phosphate, triethyl phosphate, tributyl phosphate, trioctyl phosphate, tributoxycotyl phosphate, triphenyl phosphate, tricresyl phosphate, cresyl diphenyl phosphate, octyl diphenyl phosphate, and the like. Non-halogen phosphate,
Tris (chloroethyl) phosphate, tris (dichloropropyl) phosphate, bis (2,3 dibromopropyl) 2,3-dichloropropylphosphate, tris (2,3-dibromopropyl) phosphate, bis (chloropropyl) monooctyl phosphate, etc. Halogen phosphate esters and the like.
【００１６】特に好ましい難燃剤としては、テトラブロ
モビスフェノールＡを主体とするカーボネートオリゴマ
ーが挙げられ、例えばテトラブロモビスフェノールＡの
カーボネートオリゴマー及びテトラブロモビスフェノー
ルＡとビスフェノールＡとの共重合ポリカーボネートオ
リゴマー等が挙げられる。Particularly preferred flame retardants include carbonate oligomers mainly composed of tetrabromobisphenol A, such as carbonate oligomers of tetrabromobisphenol A and copolymerized polycarbonate oligomers of tetrabromobisphenol A and bisphenol A. .
【００１７】本発明で使用される（Ｅ）ポリテトラフル
オロエチレン（以下、Ｅ成分と称する。）は、フィブリ
ル形成能を有するものでＡＳＴＭ規格でタイプ３に分類
されているものである。フィブリル形成能を有しないも
のでは本発明の目的が達成されない。上記のフィブリル
形成能を有するポリテトラフルオロエチレンは、例えば
三井・デュポンフロロケミカル（株）よりテフロン６Ｊ
として、あるいはダイキン工業（株）よりポリフロンＴ
ＦＥＦ−２０１Ｌとして市販されており、容易に入手で
きる。The (E) polytetrafluoroethylene (hereinafter referred to as "E component") used in the present invention has fibril-forming ability and is classified into Type 3 according to the ASTM standard. The object of the present invention cannot be attained without a fibril-forming ability. Polytetrafluoroethylene having the above fibril-forming ability can be obtained from, for example, Teflon 6J by DuPont Fluorochemicals, Ltd.
Or from Daikin Industries, Ltd.
It is commercially available as FEF-201L and can be easily obtained.
【００１８】本発明に使用するＤ成分の配合割合はＡ成
分，Ｂ成分及びＣ成分の合計１００重量部に対して、２
〜２０重量部であり、好ましくは、３〜１５重量部であ
る。２重量未満では十分な難燃効果が発現せず、２０重
量部を越えると耐熱性・機械的強度が低下してしまう。The mixing ratio of the component D used in the present invention is 2 parts per 100 parts by weight of the total of the components A, B and C.
To 20 parts by weight, preferably 3 to 15 parts by weight. If the amount is less than 2 parts by weight, a sufficient flame retardant effect is not exhibited, and if it exceeds 20 parts by weight, heat resistance and mechanical strength are reduced.
【００１９】また、本発明に使用するＥ成分の配合割合
はＡ成分，Ｂ成分及びＣ成分の合計１００重量部に対し
て、０〜２重量部である。Ｅ成分は目的とする難燃レベ
ルによって配合割合が異なり、添加量が増加するに従い
難燃レベルは向上する傾向にある。しかし、２重量部を
越えると難燃レベルの大きな向上は見られず、成形品外
観の悪化・機械的強度の低下が起こるので、２重量部以
下での使用が好ましい。The mixing ratio of the component E used in the present invention is 0 to 2 parts by weight based on 100 parts by weight of the total of the components A, B and C. The proportion of the component E varies depending on the intended flame retardant level, and the flame retardant level tends to increase as the amount added increases. However, if the amount exceeds 2 parts by weight, no significant improvement in the flame retardant level is observed, and the appearance of the molded article is deteriorated and the mechanical strength is reduced. Therefore, the use of 2 parts by weight or less is preferable.
【００２０】本発明の芳香族ポリカーボネート樹脂組成
物は、上記各成分を混合することにより製造される。例
えば各成分をＶ型ブレンダー、リボンミキサー又はタン
ブラー等に投入して均一に混合した後、一軸又は二軸の
通常の押出機等で溶融混練し、冷却した後ペレット状に
切断する。このとき、酸化チタン等の充填剤や他の成分
の一部を押出機の途中から添加してもよい。また、成分
の一部を予め混合、混練した後、更に残りの成分を添加
し押出してもよい。The aromatic polycarbonate resin composition of the present invention is produced by mixing the above components. For example, each component is charged into a V-blender, a ribbon mixer, a tumbler, or the like, uniformly mixed, melted and kneaded with a single-screw or twin-screw ordinary extruder, cooled, and cut into pellets. At this time, a filler such as titanium oxide or a part of other components may be added in the middle of the extruder. Alternatively, after some of the components are previously mixed and kneaded, the remaining components may be added and extruded.
【００２１】本発明の組成物には、本発明の目的を損な
わない範囲でポリエステル、ポリアミド、ＡＢＳ、ポリ
フェニレンエーテル等の他の樹脂、また例えばタルク、
マイカ、ガラス繊維、カーボン繊維、ウイスカー（繊維
状酸化チタン、チタン酸カリウムウイスカー、ホウ酸ア
ルミニウムウイスカー等）等の強化剤を配合することも
可能である。本発明の樹脂組成物には必要に応じてその
効果が発現する量の種々の添加剤、例えば、安定剤とし
て亜燐酸エステル系、燐酸エステル系等、酸化防止剤と
してヒンダーフェノール系化合物等、またポリカプロラ
クトン等の流動性改質剤、その他離型剤、紫外線吸収
剤、帯電防止剤、染顔料等が含まれても差し支えない。The composition of the present invention may contain other resins such as polyester, polyamide, ABS, polyphenylene ether and the like, for example, talc, as long as the object of the present invention is not impaired.
A reinforcing agent such as mica, glass fiber, carbon fiber, or whisker (such as fibrous titanium oxide, potassium titanate whisker, and aluminum borate whisker) can be blended. In the resin composition of the present invention, if necessary, various effects of the various additives are exhibited, for example, a phosphite ester, a phosphate ester or the like as a stabilizer, a hinder phenol compound or the like as an antioxidant, or A fluidity modifier such as polycaprolactone, a release agent, an ultraviolet absorber, an antistatic agent, a dye or pigment may be included.
【００２２】かくして得られた樹脂組成物は、押出成
形、射出成形、圧縮成形等の方法で容易に成形可能であ
り、またブロー成形、真空成形等にも適用でき、電子電
気・ＯＡの液晶バックライト反射板となる。The resin composition thus obtained can be easily molded by methods such as extrusion molding, injection molding, and compression molding, and can also be applied to blow molding, vacuum molding, and the like. It becomes a light reflector.
【００２３】[0023]
【実施例】以下に実施例をあげて更に説明する。なお、
実施例中の部は重量部であり、各特性値の測定は下記の
方法により求めた。EXAMPLES Examples will be further described below with reference to examples. In addition,
Parts in the examples are parts by weight, and measurement of each characteristic value was obtained by the following method.
【００２４】（ａ）試験片及び見本板の作成：射出成形
機［住友重機械工業（株）製ＳＧ−１５０Ｕ］によりシ
リンダー温度２８０℃、金型温度８０℃で見本板・衝撃
強度及び荷重たわみ温度測定用試験片・燃焼試験片を成
形した。衝撃強度及び荷重たわみ温度測定用試験片・燃
焼試験片は成形後２３℃，５０％ＲＨの条件下で４８時
間状態調整した後測定に供した。(A) Preparation of test piece and sample plate: Sample plate, impact strength and load deflection at 280 ° C. cylinder temperature and 80 ° C. mold temperature by injection molding machine [SG-150U manufactured by Sumitomo Heavy Industries, Ltd.] Test pieces for temperature measurement and combustion test pieces were formed. The test piece for measuring the impact strength and the deflection temperature under load and the combustion test piece were subjected to condition adjustment at 23 ° C. and 50% RH for 48 hours after molding, and then subjected to measurement.
【００２５】（ｂ）粘度平均分子量：粘度平均分子量
（Ｍｖ）は、塩化メチレンに２０℃で試料０．７ｇを１
００ｍｌ（１ｄｌ）に溶解した溶液から求めた比粘度η
SPを下記式に挿入して求めた。 ηSP／Ｃ＝［η］＋０．４５［η］2Ｃ ［η］＝１．２３×１０-4Ｍｖ0.83 但しＣ＝０．７(B) Viscosity-average molecular weight: The viscosity-average molecular weight (Mv) was determined by adding 0.7 g of a sample to 1 methylene chloride at 20 ° C.
Specific viscosity η obtained from a solution dissolved in 00 ml (1 dl)
SP was obtained by inserting the following equation. ηSP / C = [η] +0.45 [η] 2 C [η] = 1.23 × 10 −4 Mv 0.83 where C = 0.7
【００２６】（ｃ）衝撃強度：ＡＳＴＭ Ｄ２５６に従
い、厚さ１／８″試験片のアイゾット・ノッチ付き衝撃
強度を測定した(Ｊ／ｍ、但しkgf・cm/cmの換算値を併
記)。(C) Impact strength: Izod notched impact strength of a 1/8 ″ thick test piece was measured in accordance with ASTM D256 (J / m, with the converted value in kgf · cm / cm).
【００２７】（ｄ）荷重たわみ温度：ＪＩＳ Ｋ７２０
７に従い、荷重１．８１２ＭＰａ（１８．５kgf/cm2）
で測定した。(D) Deflection temperature under load: JIS K720
According to No. 7, the load is 1.812 MPa (18.5 kgf / cm 2 )
Was measured.
【００２８】（ｅ）光線反射率：マクベス社製のカラー
アイＭＳ２０２０ＰＬＵＳにより厚さ２ｍｍの見本板を
使用し、波長４５０〜８００ｎｍにおける最も低い反射
率の値で評価した。９２％以上になるものを合格とし
た。(E) Light reflectivity: Evaluation was made by using a sample plate having a thickness of 2 mm with a color eye MS2020PLUS manufactured by Macbeth Co., Ltd., using the lowest reflectance value at a wavelength of 450 to 800 nm. Those which became 92% or more were judged as pass.
【００２９】（ｆ）燃焼試験：１２７ｍｍ×１２．７ｍ
ｍ×１．０６ｍｍ（５″×１／２″×１／２４″）のＵ
Ｌ規格９４−Ｖ燃焼試験片を使用し、ＵＬ規格９４−Ｖ
プラスチック燃焼試験法により評価した。(F) Combustion test: 127 mm × 12.7 m
mx 1.06mm (5 "x 1/2" x 1/24 ") U
Using UL standard 94-V combustion test piece, UL standard 94-V
It was evaluated by the plastic combustion test method.
【００３０】［実施例１〜１５及び比較例１〜７］芳香
族ポリカーボネート樹脂（Ａ成分）を１２０℃で５時間
乾燥した後、これに酸化チタン（Ｂ成分）、ゴム質重合
体（Ｃ成分）、及び各種難燃剤（Ｄ成分）とフィブリル
化ポリテトラフルオロエチレン（Ｅ成分）を表１記載の
量及びリン系安定剤（トリメチルフォスフェート：大八
化学工業（株）製ＴＭＰ）を表１、３、５記載の量１０
０重量部に対し、０．０５重量部を添加してブレンダ−
により混合した後、ベント式二軸押出機［日本製鋼所
（株）製 ＴＥＸ３０ＸＳＳＴ］によりシリンダー温度
２８０℃で脱気しながら押出してペレット化した。得ら
れたペレットを１２０℃の熱風循環式乾燥機により６時
間乾燥した後、試験片及び見本板を作成した。評価結果
を表２、４、６に示す。[Examples 1 to 15 and Comparative Examples 1 to 7] An aromatic polycarbonate resin (component A) was dried at 120 ° C for 5 hours, and then titanium oxide (component B) and a rubbery polymer (component C) were added thereto. ) And various flame retardants (D component) and fibrillated polytetrafluoroethylene (E component) in the amounts shown in Table 1 and phosphorus-based stabilizers (trimethyl phosphate: TMP manufactured by Daihachi Chemical Industry Co., Ltd.) in Table 1. Amount 10 described in 3, 5
Add 0.05 parts by weight to 0 parts by weight and blender
The mixture was extruded with a vented twin-screw extruder [TEX30XSST manufactured by Nippon Steel Works Co., Ltd.] while degassing at a cylinder temperature of 280 ° C., and pelletized. After the obtained pellets were dried for 6 hours using a hot air circulating dryer at 120 ° C., test pieces and sample boards were prepared. The evaluation results are shown in Tables 2, 4, and 6.
【００３１】なお、表１、３、５記載の各成分を示す記
号は以下の通りである。 （Ａ）芳香族ポリカーボネート樹脂（Ａ成分） ビスフェノールＡ型ポリカーボネート：パンライトＬ−
１２２５；帝人化成（株）製、粘度平均分子量２２，５
００（以下ＰＣと称す）The symbols for the components shown in Tables 1, 3 and 5 are as follows. (A) Aromatic polycarbonate resin (A component) Bisphenol A type polycarbonate: Panlite L-
1225; Teijin Chemicals Ltd., viscosity average molecular weight 22.5
00 (hereinafter referred to as PC)
【００３２】（Ｂ）酸化チタン（Ｂ成分） 酸化チタン：ＲＴＣ−２；タイオキサイド社製、結晶
系＝ルチル、製造法＝塩素法、主要処理剤＝アルミナ・
シリカ・ジメチルポリシロキサン（以下Ｔｉ−１と称
す） 酸化チタン：ＣＲ−６０；石原産業（株）製、結晶系
＝ルチル、製造法＝塩素法、主要処理剤＝アルミナ（以
下Ｔｉ−２と称す） 酸化チタン：ＣＲ−９３；石原産業（株）製、結晶系
＝ルチル、製造法＝塩素法、主要処理剤＝アルミナ・シ
リカ（以下Ｔｉ−３と称す） 酸化チタン：ＰＣ−２；石原産業（株）製、結晶系＝
ルチル、製造法＝塩素法、主要処理剤＝アルミナ・シリ
カ・メチルハイドロジェンポリシロキサン（以下Ｔｉ−
４と称す）(B) Titanium oxide (component B) Titanium oxide: RTC-2; manufactured by Taioxide Co., crystal system = rutile, production method = chlorine method, main treatment agent = alumina.
Silica dimethylpolysiloxane (hereinafter referred to as Ti-1) Titanium oxide: CR-60; manufactured by Ishihara Sangyo Co., Ltd., crystal system = rutile, production method = chlorine method, main treatment agent = alumina (hereinafter referred to as Ti-2) Titanium oxide: CR-93; manufactured by Ishihara Sangyo Co., Ltd., crystal system = rutile, production method = chlorine method, main treating agent = alumina / silica (hereinafter referred to as Ti-3) Titanium oxide: PC-2; Co., Ltd., crystal system =
Rutile, production method = chlorine method, main treating agent = alumina, silica, methyl hydrogen polysiloxane (hereinafter Ti-
4)
【００３３】（Ｃ）ゴム質重合体（Ｃ成分） ポリオルガノシロキサン成分及びポリアルキル（メ
タ）アクリレートゴム成分が相互侵入網目構造を有して
いる複合ゴム系グラフト共重合体：メタブレンＳ２００
１；三菱レーヨン（株）製（以下Ｓ剤と称す） エチレン−エチルアクリレート共重合体：レクスロン
Ａ４２５０；日本石油化学工業（株）製（以下ＥＥＡと
称す） ブタジエン−アルキルアクリレート−アルキルメタア
クリレート共重合体：ＥＸＬ−２６０２；呉羽化学工業
（株）製（以下ＭＢＳと称す） ポリエチレン樹脂；ハイゼックス２１００ＪＰ：三井
石油化学工業（株）製（以下ＰＥと称す）(C) Rubbery Polymer (Component C) Composite rubber-based graft copolymer in which a polyorganosiloxane component and a polyalkyl (meth) acrylate rubber component have an interpenetrating network structure: Metablen S200
1; manufactured by Mitsubishi Rayon Co., Ltd. (hereinafter referred to as S agent) Ethylene-ethyl acrylate copolymer: Lexlon A4250; manufactured by Nippon Petrochemical Co., Ltd. (hereinafter referred to as EEA) Butadiene-alkyl acrylate-alkyl methacrylate copolymer Combined: EXL-2602; manufactured by Kureha Chemical Industry Co., Ltd. (hereinafter referred to as MBS) Polyethylene resin; HIZEX 2100JP: manufactured by Mitsui Petrochemical Industry Co., Ltd. (hereinafter referred to as PE)
【００３４】（Ｄ）難燃剤（Ｄ成分） テトラブロモビスフェノールＡポリカーボネートオリ
ゴマー：ファイヤーガードＦＧ−７０００；帝人化成
（株）製（以下ＦＲ−１と称する） ブロム化エポキシ樹脂：プラサームＥＰ−１００；大
日本インキ（株）製（以下ＦＲ−２と称す） トリフェニルフォスフェート：ＴＰＰ；大八化学工業
（株）製（以下ＦＲ−３と称す） オリゴマー状のリン酸エステル：ＰＸ−２００；大八
化学工業（株）製（以下ＦＲ−４と称す）(D) Flame retardant (D component) Tetrabromobisphenol A polycarbonate oligomer: Fireguard FG-7000; manufactured by Teijin Chemicals Ltd. (hereinafter referred to as FR-1) Brominated epoxy resin: Pratherm EP-100; Nippon Ink Co., Ltd. (hereinafter referred to as FR-2) Triphenyl phosphate: TPP; Daihachi Chemical Industry Co., Ltd. (hereinafter referred to as FR-3) Oligomeric phosphate ester: PX-200; Chemical Industry Co., Ltd. (hereinafter referred to as FR-4)
【００３５】（Ｅ）ポリテトラフルオロエチレン（Ｅ成
分） フィブリル化ポリテトラフルオロエチレン：ポリフロン
ＴＦＥ Ｆ−２０１Ｌ；ダイキン工業（株）製（以下Ｐ
ＴＦＥと称す）(E) Polytetrafluoroethylene (E component) Fibrillated polytetrafluoroethylene: Polyflon TFE F-201L; manufactured by Daikin Industries, Ltd.
TFE)
【００３６】（Ｆ）ガラス繊維チョップドガラスファイ
バー：ＥＣＳ０３Ｔ−５１１／Ｐ；日本電気硝子（株）
製、直径１３μｍ、長さ３ｍｍ（以下ＧＦと称す）(F) Glass fiber Chopped glass fiber: ECS03T-511 / P; Nippon Electric Glass Co., Ltd.
13 μm in diameter and 3 mm in length (hereinafter referred to as GF)
【００３７】（Ｇ）珪素化合物 メチルトリメトキシシラン：ＫＢＭ−１３；信越化学
工業（株）製（以下Ｓｉと称す） Ｎ−β（アミノエチル）−γ−アミノプロピルトリメ
トキシシラン：ＫＢＭ−６０３；信越化学工業（株）製
（以下Ｓｉと称す）(G) Silicon compound Methyl trimethoxy silane: KBM-13; N-β (aminoethyl) -γ-aminopropyl trimethoxy silane: KBM-603 manufactured by Shin-Etsu Chemical Co., Ltd. (hereinafter referred to as Si) Shin-Etsu Chemical Co., Ltd. (hereinafter referred to as Si)
【００３８】[0038]
【表１】 [Table 1]
【００３９】[0039]
【表２】 [Table 2]
【００４０】[0040]
【表３】 [Table 3]
【００４１】[0041]
【表４】 [Table 4]
【００４２】[0042]
【表５】 [Table 5]
【００４３】[0043]
【表６】 [Table 6]
【００４４】表より明らかなように全実施例においては
衝撃強度、光線反射率及び耐熱性のいずれも充分に満足
でき、押出時・成形時の分子量低下も小さい。また、難
燃剤及びＰＴＦＥを添加したものについては、高度な難
燃性能を有している。しかるに比較例１、４、５では衝
撃強度、光線反射率のいずれも悪く、また分子量低下も
大きい。比較例２では光線反射率が悪く、比較例３では
衝撃強度が低いという問題点がある。また、比較例６で
は耐熱性が低いという問題点がある。更に、ガラス繊維
が添加された系においても、同様の傾向が見られる。As is clear from the table, in all the examples, the impact strength, the light reflectance and the heat resistance are all sufficiently satisfied, and the decrease in molecular weight during extrusion and molding is small. Further, those to which a flame retardant and PTFE are added have high flame retardancy. However, in Comparative Examples 1, 4, and 5, both the impact strength and the light reflectance were poor, and the molecular weight was significantly reduced. Comparative Example 2 has a problem that the light reflectance is poor, and Comparative Example 3 has a problem that the impact strength is low. Further, Comparative Example 6 has a problem that heat resistance is low. Further, a similar tendency is observed in a system to which glass fiber is added.
【００４５】本発明によれば、製造が容易で優れた機械
的特性を有し且つ黄変による反射性能の低下がなく、更
に優れた熱安定性を有する反射板を提供することが可能
になり、その奏する工業的効果は格別なものである。According to the present invention, it is possible to provide a reflection plate which is easy to manufacture, has excellent mechanical properties, does not cause a decrease in reflection performance due to yellowing, and has further excellent thermal stability. The industrial effects they produce are extraordinary.
フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｇ０２Ｆ 1/1335 ５２０ Ｇ０２Ｆ 1/1335 ５２０ //(Ｃ０８Ｌ 69/00 (Ｃ０８Ｌ 69/00 51:00） 51:00） Ｆターム(参考） 2H042 DA01 DA11 DE00 2H091 FA14 FB02 FB06 LA02 LA17 4F071 AA33 AA50 AA67 AA77 AB18 AB28 AC15 AC16 AD01 AE05 AE07 AF29 AH19 BA01 BB03 BB05 BB06 BC01 BC10 4J002 BN222 CG011 CG021 DE136 FB096 FB146 FB266 FD010 FD030 FD130 GP00 Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat II (Reference) G02F 1/1335 520 G02F 1/1335 520 // (C08L 69/00 (C08L 69/00 51:00) 51:00) F-term (Reference) 2H042 DA01 DA11 DE00 2H091 FA14 FB02 FB06 LA02 LA17 4F071 AA33 AA50 AA67 AA77 AB18 AB28 AC15 AC16 AD01 AE05 AE07 AF29 AH19 BA01 BB03 BB05 BB06 BC01 BC10 4J002 BN222 CG01130 FB02 CB01 FB01 FB02
Claims (5)
成分）９５〜６０重量％、（Ｂ）酸化チタン（Ｂ成分）
５〜４０重量％からなる樹脂組成物１００重量部に対
し、（Ｃ）ポリオルガノシロキサンゴム成分とポリアル
キル（メタ）アクリレートゴム成分とが分離できないよ
うに相互に絡み合った構造を有している複合ゴムに一種
または二種以上のビニル系単量体がグラフト重合されて
なる複合ゴム系グラフト共重合体（Ｃ成分）０．５〜２
０重量部を配合してなる高反射性芳香族ポリカーボネー
ト樹脂組成物から成形された反射板。(A) An aromatic polycarbonate resin (A)
Component) 95 to 60% by weight, (B) titanium oxide (B component)
A composite having a structure in which (C) a polyorganosiloxane rubber component and a polyalkyl (meth) acrylate rubber component are entangled with each other so that the polyorganosiloxane rubber component and the polyalkyl (meth) acrylate rubber component cannot be separated from 100 parts by weight of the resin composition composed of 5 to 40% by weight. Composite rubber-based graft copolymer (C component) obtained by graft-polymerizing one or two or more vinyl-based monomers to rubber
A reflector formed from a highly reflective aromatic polycarbonate resin composition containing 0 parts by weight.
キシシラン及び／又は、アミノ系シランカップリング剤
で処理された酸化チタンである請求項１に記載の反射
板。2. The reflector according to claim 1, wherein the titanium oxide as the component B is titanium oxide treated with an alkylalkoxysilane and / or an amino-based silane coupling agent.
ロジェンポリシロキサンで処理された酸化チタンである
請求項１に記載の反射板。3. The reflection plate according to claim 1, wherein the titanium oxide as the component B is titanium oxide treated with an alkyl hydrogen polysiloxane.
出機で溶融混練したペレットから射出成形して得られた
ものである請求項１〜３のいずれか１項に記載の反射
板。4. The reflection plate according to claim 1, wherein the reflection plate is obtained by injection molding a pellet obtained by melting and kneading the components A to C with a twin-screw extruder. Board.
における最も低い反射率が９２％以上の場合合格とする
光線反射率の評価方法において、合格となる請求項１〜
４のいずれか１項に記載の反射板。5. The reflecting plate has a wavelength of 450 to 800 nm.
In the method for evaluating a light reflectance, the lowest reflectance in the above is 92% or more, the evaluation is acceptable.
5. The reflector according to any one of 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001139855A JP3563710B2 (en) | 2001-05-10 | 2001-05-10 | reflector |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001139855A JP3563710B2 (en) | 2001-05-10 | 2001-05-10 | reflector |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15919095A Division JP3494323B2 (en) | 1995-06-26 | 1995-06-26 | Highly reflective aromatic polycarbonate resin composition and molded article thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002060615A true JP2002060615A (en) | 2002-02-26 |
| JP3563710B2 JP3563710B2 (en) | 2004-09-08 |
Family
ID=18986558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001139855A Expired - Fee Related JP3563710B2 (en) | 2001-05-10 | 2001-05-10 | reflector |
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| Country | Link |
|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010077379A (en) * | 2008-08-27 | 2010-04-08 | Mitsubishi Rayon Co Ltd | Polycarbonate resin composition and method of producing molding |
| US7928168B2 (en) | 2007-03-23 | 2011-04-19 | Sabic Innovative Plastics Ip B.V. | White light-shielding compositions and articles comprising same |
| JP2014111792A (en) * | 2007-11-30 | 2014-06-19 | Taiyo Holdings Co Ltd | White curable resin composition for a print wire board for packaging light emitters, cured product of the same, print wire board possessing the cured product, and reflection plate consisting of the cured product |
-
2001
- 2001-05-10 JP JP2001139855A patent/JP3563710B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7928168B2 (en) | 2007-03-23 | 2011-04-19 | Sabic Innovative Plastics Ip B.V. | White light-shielding compositions and articles comprising same |
| JP2014111792A (en) * | 2007-11-30 | 2014-06-19 | Taiyo Holdings Co Ltd | White curable resin composition for a print wire board for packaging light emitters, cured product of the same, print wire board possessing the cured product, and reflection plate consisting of the cured product |
| JP2014129547A (en) * | 2007-11-30 | 2014-07-10 | Taiyo Holdings Co Ltd | White curable resin composition for printed circuit board mounted with light-emitting device, cured product thereof, printed circuit board including cured product and reflection board for light emitting device comprised of cured product |
| JP2016129234A (en) * | 2007-11-30 | 2016-07-14 | 太陽ホールディングス株式会社 | White curable resin composition for printed circuit board mounted with light-emitting device, cured product thereof, printed circuit board including cured product and reflection board for light emitting device composed of cured product |
| JP2010077379A (en) * | 2008-08-27 | 2010-04-08 | Mitsubishi Rayon Co Ltd | Polycarbonate resin composition and method of producing molding |
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| Publication number | Publication date |
|---|---|
| JP3563710B2 (en) | 2004-09-08 |
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