JP2002052393A - Water cleaning apparatus - Google Patents

Water cleaning apparatus

Info

Publication number
JP2002052393A
JP2002052393A JP2000278898A JP2000278898A JP2002052393A JP 2002052393 A JP2002052393 A JP 2002052393A JP 2000278898 A JP2000278898 A JP 2000278898A JP 2000278898 A JP2000278898 A JP 2000278898A JP 2002052393 A JP2002052393 A JP 2002052393A
Authority
JP
Japan
Prior art keywords
water
photocatalyst
catalyst
ozone
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000278898A
Other languages
Japanese (ja)
Inventor
Mitsuru Matsui
満 松井
Shigenori Suzuki
重則 鈴木
Saburo Okamoto
三郎 岡本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EMUZU JAPAN KK
Original Assignee
EMUZU JAPAN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EMUZU JAPAN KK filed Critical EMUZU JAPAN KK
Priority to JP2000278898A priority Critical patent/JP2002052393A/en
Publication of JP2002052393A publication Critical patent/JP2002052393A/en
Pending legal-status Critical Current

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  • Catalysts (AREA)
  • Physical Water Treatments (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a water cleaning apparatus having high cleaning and sterilizing power, capable of keeping photochemical reaction effect possessed by a photocatalyst over a long period of time. SOLUTION: The photocatalyst is housed in a catalyst housing chamber in such a state that the filling ratio of the photocatalyst is lowered and raw water to be cleaned is allowed to flow in the catalyst housing chamber from the lower part thereof to stirr the photocatalyst by water streams to rub the particles of the photocatalyst. Thereby, the contamination of the photocatalyst is physically prevented and the contamination of an inner cylinder is also prevented by the contact of the particles of the photocatalyst with the inner cylinder and the attenuation of the transmissivity of a light source is prevented to make it possible to keep photochemical reaction effect over a long period of time. Further, an irradiation chance with ultraviolet rays is increased by stirring the photocatalyst by water streams to accelerate photochemical reaction to obtain high watger cleaning effect.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、水を浄化殺菌する
浄水装置に関するもので、水に空気またはオゾンを混入
した流れを発生し、紫外線を照射して光触媒で浄化殺菌
する、プールや浴槽等に適用される浄水装置に関するも
のである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water purifying apparatus for purifying and sterilizing water, which generates a flow in which air or ozone is mixed in water, and irradiates ultraviolet rays to purify and sterilize with a photocatalyst. The present invention relates to a water purification apparatus applied to

【0002】[0002]

【従来の技術】従来、プールや浴槽等において、入浴の
度に汚れや湯垢の浮遊や菌の繁殖が発生するため、湯を
交換したりあるいは浴槽の掃除をすることが必要とな
る。そこで、浄水装置を使って殺菌浄化する場合、水質
等によっては分解しきれない汚れ成分が触媒や浄化装置
の管壁表面に徐々に付着し、浄水機能の低下があった。
2. Description of the Related Art Conventionally, in a pool, a bathtub or the like, every time a person takes a bath, dirt and scales float and bacteria grow, so it is necessary to replace the hot water or clean the bathtub. Therefore, when sterilizing and purifying using a water purification device, dirt components that cannot be completely decomposed depending on the water quality and the like gradually adhere to the catalyst and the tube wall surface of the purification device, and the water purification function is reduced.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
光触媒浄化装置では紫外線の活用が低下して光化学反応
効果を長期的に維持することができなかった。本発明
は、以上のような欠点をなくすためになされたものであ
る。
However, in the conventional photocatalyst purifying apparatus, the utilization of ultraviolet rays is reduced, and the photochemical reaction effect cannot be maintained for a long time. The present invention has been made to eliminate the above disadvantages.

【0004】[0004]

【課題を解決するための手段】この目的を達成するため
に本発明に係る浄水装置は、水を浄化する水槽と、殺菌
作用のある紫外線ランプ、この紫外線ランプの周囲に設
けられ、紫外線の照射により浄化殺菌作用を発揮する光
触媒、前記光触媒を触媒収納室に充填率を下げた状態で
収納、浄化する原水を触媒収納室の下側より流入して光
触媒を水流で撹拌して光触媒同士を擦り合わせることに
より、光触媒の汚れを物理的に防止し、また、光源側の
内筒とも接触させることにより汚れを防ぎ光源の透過率
の減衰を防ぎ、また光触媒を水流で撹拌することにより
紫外線が当たる機会を増やし光化学反応を促進させ浄水
能力を高める。
In order to achieve this object, a water purifier according to the present invention comprises a water tank for purifying water, an ultraviolet lamp having a germicidal action, and provided around the ultraviolet lamp to irradiate ultraviolet light. The photocatalyst exerts a purification and disinfection action by the photocatalyst, the photocatalyst is stored in the catalyst storage chamber at a reduced filling rate, raw water to be purified flows in from below the catalyst storage chamber, and the photocatalyst is agitated by a water flow to rub the photocatalysts. Physically prevent contamination of the photocatalyst by matching, prevent contamination by preventing contact with the inner cylinder on the light source side, prevent attenuation of the transmittance of the light source, and irradiate ultraviolet rays by stirring the photocatalyst with a water flow. Increase opportunities and promote photochemical reactions to increase water purification capacity.

【0005】[0005]

【発明の実施形態】以下、図面を参照して本発明の実施
の形態を説明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0006】図1は、本発明に係る浄水装置Fの基本型
で1は外筒である、2は内筒で紫外線を透過する石英ガ
ラス等で出来ている、3上板、4下板で外筒1とフラン
ジで取り付けられており、また、内筒2をシール器具5
及びシールOリング6で保持している。7は紫外線を発
光する紫外線ランプで、内筒2の中にクリアランスを保
って設けられておりこのクリアランスに自然対流による
空気流または強制送風によって紫外線ランプの発熱を処
理している。
FIG. 1 shows a basic type of a water purifier F according to the present invention, wherein 1 is an outer cylinder, 2 is an inner cylinder made of quartz glass or the like that transmits ultraviolet light, 3 is an upper plate, and 4 is a lower plate. It is attached to the outer cylinder 1 with a flange, and the inner cylinder 2 is
And a seal O-ring 6. Reference numeral 7 denotes an ultraviolet lamp which emits ultraviolet light, which is provided with a clearance in the inner cylinder 2 and in which heat generated by the ultraviolet lamp is processed by an air flow by natural convection or forced air blowing.

【0007】8は光触媒で、担体はセラミックで酸化チ
タン等で処理されたものである。9はレデュサーで原水
流入口10より流入した原水の流れに空気またはオゾン
発生器11で発生したオゾンを混入する。この気泡12
を含んだ水は、光触媒8が逆流出しない様な触媒逆流出
防止網13を設置した流入口14より流入して、触媒収
納室15内の光触媒8を上方に持ち上げる。触媒収納室
15は、下板4と浄化した水が通過出来る様な小さな穴
が沢山明けられている触媒流出防止多孔板16の間で構
成されていて、水の流れで上方に持ち上げられた光触媒
8が流出しないようになっている。
Reference numeral 8 denotes a photocatalyst, whose carrier is a ceramic which is treated with titanium oxide or the like. A reducer 9 mixes air or ozone generated by an ozone generator 11 into a flow of raw water flowing from a raw water inlet 10. This bubble 12
Water flows in through an inlet 14 provided with a catalyst reverse outflow prevention network 13 so that the photocatalyst 8 does not flow backward, and lifts the photocatalyst 8 in the catalyst storage chamber 15 upward. The catalyst accommodating chamber 15 is formed between the lower plate 4 and a perforated plate 16 for preventing catalyst outflow that has many small holes through which purified water can pass, and the photocatalyst lifted upward by the flow of water. 8 does not escape.

【0008】触媒収納室15の下側から流入する流入口
14を浄水槽の中心より偏奇して設置、渦流が発生する
ようにすることにより光触媒8を水流でより撹拌して光
触媒同士を擦り合わせることにより、より一層の光触媒
8の汚れを物理的に防止し、また、光源側の内筒2の石
英ガラス管等とも積極的に接触させることにより内筒2
の石英ガラス管等の汚れを防ぎ光源の透過率の減衰を防
ぎ、また光触媒8を水流で撹拌することにより紫外線が
当たる機会を増やし光化学反応を促進させ浄水能力を高
める。
The photocatalyst 8 is more agitated by a water flow and the photocatalysts are rubbed against each other by setting the inflow port 14 flowing from the lower side of the catalyst accommodating chamber 15 to be deviated from the center of the water purification tank so that a vortex is generated. Thus, the contamination of the photocatalyst 8 is further prevented physically, and the inner tube 2 is positively brought into contact with the quartz glass tube or the like of the inner tube 2 on the light source side.
The dirt of the quartz glass tube and the like is prevented, the transmittance of the light source is prevented from attenuating, and the photocatalyst 8 is agitated by a water flow to increase the chance of being irradiated with ultraviolet rays, to promote a photochemical reaction and to enhance the water purification capacity.

【0009】17は気液分離室で分離した空気またはオ
ゾンは、上板3に設けられた自動空気抜き18より直接
またはオゾン分解触媒装置(図示せず)を通して大気に
放出され、浄化された水は、浄水流出口19よりプール
または浴槽等に供給される。20は触媒室仕切多孔板で
触媒室を分割することにより触媒の上下方向の分散を向
上することが出来る。
Reference numeral 17 denotes air or ozone separated in the gas-liquid separation chamber, which is discharged to the atmosphere directly from an automatic air vent 18 provided on the upper plate 3 or through an ozone decomposition catalyst device (not shown). The water is supplied from a purified water outlet 19 to a pool or a bathtub. Reference numeral 20 denotes a catalyst chamber partitioning perforated plate which divides the catalyst chamber to improve the vertical dispersion of the catalyst.

【0010】図2は、本発明に係る浄水装置Fの他の実
施例で、気液分離室17の浄水の一部を循環ポンプ22
によって循環パイプA23・緩衝室24・循環パイプB
25を介してレデュサー9で空気またはオゾン発生器1
1で発生したオゾンを混合、混合水となって、整流室2
6に送達して触媒支持多孔板21を通して触媒収納室1
5に送り込み、また、触媒収納室15の下方より流入し
た原水と混合して光触媒8を水流で撹拌して光触媒8同
士を擦り合わせることにより、光触媒8の汚れを物理的
に防止し、また、光源側の内筒2の石英ガラス管等とも
積極的に接触させることにより汚れを防ぎ光源の減衰を
防ぎ、また光触媒8を水流で撹拌することにより紫外線
が当たる機会を増やし光化学反応を促進させ浄水能力を
高める。
FIG. 2 shows another embodiment of the water purifier F according to the present invention.
Circulation pipe A23, buffer chamber 24, circulation pipe B
25 or air or ozone generator 1 with reducer 9
The ozone generated in step 1 is mixed to form mixed water, and the flow is adjusted to
6 and the catalyst storage chamber 1 through the catalyst supporting porous plate 21.
5 and mixed with raw water flowing from below the catalyst storage chamber 15 to stir the photocatalyst 8 with a water flow to rub the photocatalysts 8 together, thereby physically preventing the photocatalysts 8 from being stained. Active contact with the quartz glass tube etc. of the inner cylinder 2 on the light source side prevents contamination and prevents attenuation of the light source, and agitates the photocatalyst 8 with a water flow to increase the chances of being exposed to ultraviolet rays, promote photochemical reactions, and purify water. Improve ability.

【0011】21は触媒支持多孔板でレデュサー9で空
気またはオゾンを混入した水が通過出来、光触媒8が触
媒収納室15より脱落しない様な小さな穴が沢山明けら
れている、16は触媒流出防止多孔板で浄化した水が通
過出来る様小さな穴が沢山明けられている、光触媒8は
原水流入口14より流入した原水の流れで上方に持ち上
げられるが、この触媒流出防止多孔板16で流出しない
ようになっている。空気またはオゾンの混入は原水では
なく、気液分離室17の浄水の一部を循環ポンプ22に
よって環水してレデュサー9で空気またはオゾンを混合
するため安定した混入が出来る。
Reference numeral 21 denotes a catalyst-supporting perforated plate through which a water containing air or ozone is allowed to pass through a reducer 9 and a number of small holes are formed so that the photocatalyst 8 does not fall out of the catalyst storage chamber 15. The photocatalyst 8 is lifted upward by the flow of the raw water flowing through the raw water inlet 14, but has a small hole so that the water purified by the perforated plate can pass through. It has become. The mixing of air or ozone is not raw water, but a part of the purified water in the gas-liquid separation chamber 17 is circulated by the circulation pump 22 and mixed with air or ozone by the reducer 9, so that stable mixing can be performed.

【0012】次に、本発明の浄水装置Fの作動を図2に
ついて説明する。プールや浴槽等の浄化すべき原水は浄
水装置Fの原水の流入口10より流入し、触媒収納室1
5の下側に設けられた整流室26より空気またはオゾン
を混合した水を触媒支持多孔板21を通して触媒収納室
15に送り込まれた水と混流して光触媒8と接触、この
時、光触媒8の表面に紫外線照射することにより、光触
媒8の表面に活性電子が現れその活性電子が、溶存酸素
とかレデュサー9で混入させたオゾンまたは空気の酸素
の一部を極酸素化し、あるいは水を活性なOHラジカル
(励起現象)にして、これら活性化した極酸素・OHラ
ジカルが原水中の有機物・細菌を安全な炭酸ガスと水に
分解する。
Next, the operation of the water purification apparatus F of the present invention will be described with reference to FIG. Raw water to be purified, such as a pool or a bathtub, flows into the raw water inlet 10 of the water purification device F from the catalyst storage chamber 1.
The water mixed with air or ozone from the rectification chamber 26 provided below 5 is mixed with the water fed into the catalyst storage chamber 15 through the catalyst supporting porous plate 21 to come into contact with the photocatalyst 8, and at this time, the photocatalyst 8 By irradiating the surface with ultraviolet rays, active electrons appear on the surface of the photocatalyst 8, and the active electrons polarize dissolved oxygen, a part of ozone mixed with the reducer 9 or oxygen of air, or convert water to active OH. As radicals (excitation phenomena), these activated polar oxygen and OH radicals decompose organic substances and bacteria in raw water into safe carbon dioxide and water.

【0013】光触媒8は充填率を下げた状態で充填して
いるので触媒収納室15の下側より流入した水と触媒8
はよく接触するので前記分解作用が促進される。このと
き撹拌によって光触媒8同士を擦り合わせることによ
り、光触媒8の汚れを物理的に防止し、また、光源側の
内筒2の石英ガラス管等とも接触させることにより汚れ
を防ぎ光源の透過率の減衰を防ぎ、また光触媒8を水流
で撹拌することにより紫外線が当たる機会を増やし光化
学反応を促進させ浄水能力を高めることが出来、耐久性
のある高性能な浄水装置が出来る。
Since the photocatalyst 8 is filled at a reduced filling rate, the water flowing from the lower side of the catalyst storage chamber 15 and the catalyst 8
Are in good contact with each other, so that the decomposition action is promoted. At this time, the photocatalysts 8 are rubbed against each other by stirring to physically prevent the photocatalysts 8 from being stained, and are also brought into contact with the quartz glass tube or the like of the inner cylinder 2 on the light source side to prevent the contamination and prevent the light source from transmitting. By preventing the attenuation and stirring the photocatalyst 8 with a water flow, the chance of exposure to ultraviolet rays is increased, the photochemical reaction is promoted, and the water purification capacity can be increased, so that a durable, high-performance water purification device can be obtained.

【0014】運転を停止する場合、操作盤28を操作し
て、循環ポンプ22・紫外線ランプ7・オゾン発生器1
1を停止すると共に逆止弁29を作動してレデュサー9
よりオゾン発生器11等への水の逆流を防ぐことが出来
る。
When the operation is stopped, the operation panel 28 is operated to operate the circulation pump 22, the ultraviolet lamp 7, the ozone generator 1, and the like.
1 is stopped and the check valve 29 is operated to reduce the reducer 9.
It is possible to prevent the backflow of water to the ozone generator 11 and the like.

【0015】[0015]

【発明の効果】本発明に係る装置は、触媒収納容器に光
触媒の充填率を下げて収納して浄水する原水を触媒収納
室の下側より流入して該触媒を水流で撹拌して光触媒同
士を擦り合わせることにより、光触媒の汚れを物理的に
防止し、また内筒とも接触させることにより内筒の汚れ
を防ぎ光源の透過度の減衰を防ぎ光触媒の光化学反応効
果が長期的に維持できる、また触媒を水流で撹拌するこ
とにより紫外線が光触媒同士の間を透過して個々の光触
媒に対しても当たる機会を増やし光化学反応を促進させ
高い浄水効果が得られる。
According to the apparatus of the present invention, raw water for storing and purifying the photocatalyst in a catalyst container at a reduced filling rate flows in from the lower side of the catalyst storage chamber and agitates the catalyst with a water stream to form the photocatalysts. By rubbing each other, the contamination of the photocatalyst is physically prevented, and the contact with the inner cylinder also prevents the contamination of the inner cylinder, prevents the attenuation of the transmittance of the light source, and maintains the photochemical reaction effect of the photocatalyst for a long time. Further, by stirring the catalyst with a water stream, the chance of ultraviolet rays passing between the photocatalysts and hitting the individual photocatalysts is increased, so that the photochemical reaction is promoted and a high water purification effect is obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明の一実施の形態に係る浄水装置の概略
構成を示す図。
FIG. 1 is a diagram showing a schematic configuration of a water purification device according to an embodiment of the present invention.

【図2】 本発明の他の一実施の形態に係る浄水装置の
概略構成を示す図。
FIG. 2 is a diagram showing a schematic configuration of a water purification device according to another embodiment of the present invention.

【符号の説明】[Explanation of symbols]

F 浄水装置 1 外筒 2 内筒 3 上板 4 下板 5 シール器具 6 シールOリング 7 紫外線ランプ 8 光触媒 9 レデュサー 10 原水流入口 11 オゾン発生器 12 気泡 13 触媒逆流出防止網 14 流入口 15 触媒収納室 16 触媒流出防止多孔板 17 気液分離室 18 自動空気抜き 19 浄水流出口 20 触媒室仕切多孔板 21 触媒支持多孔板 22 循環ポンプ 23 循環パイプA 24 緩衝室 25 循環パイプB 26 整流室 27 遮蔽板 28 操作盤 29 逆止弁 F Water purification device 1 Outer tube 2 Inner tube 3 Upper plate 4 Lower plate 5 Sealing device 6 Seal O-ring 7 Ultraviolet lamp 8 Photocatalyst 9 Reducer 10 Raw water inlet 11 Ozone generator 12 Bubbles 13 Catalyst reverse outflow prevention network 14 Inlet 15 Catalyst Storage chamber 16 Perforated plate for preventing catalyst outflow 17 Gas-liquid separation chamber 18 Automatic air release 19 Purified water outlet 20 Catalyst perforated plate for partition 21 Catalyst perforated plate 22 Circulation pump 23 Circulation pipe A 24 Buffer chamber 25 Circulation pipe B 26 Rectification chamber 27 Shielding Plate 28 Operation panel 29 Check valve

─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成12年8月24日(2000.8.2
4)
[Submission date] August 24, 2000 (2008.2.
4)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】全図[Correction target item name] All figures

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図1】 FIG.

【図2】 FIG. 2

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C02F 1/50 531 C02F 1/50 531R 540 540A 550 550B 560 560C 1/78 1/78 (72)発明者 岡本 三郎 神奈川県藤沢市鵠沼橘2−4−12 Fターム(参考) 4D037 AA09 AB03 BA18 CA12 4D050 AA10 AB06 BB01 BB02 BC06 BC09 BD02 CA07 4G069 AA03 BA04A BA04B BA13B BA48A CA05 CA10 CA11 DA08 EA02Y EE07 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C02F 1/50 531 C02F 1/50 531R 540 540A 550 550B 560 560C 1/78 1/78 (72) Inventor Saburo Okamoto 2-4-12 Tsubasa Kugenuma, Fujisawa-shi, Kanagawa F-term (reference) 4D037 AA09 AB03 BA18 CA12 4D050 AA10 AB06 BB01 BB02 BC06 BC09 BD02 CA07 4G069 AA03 BA04A BA04B BA13B BA48A CA05 CA10 CA11 DA08 EA02Y EE07

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】浄水槽の内側に紫外線を透過する石英ガラ
ス等で出来た内筒を配し、この中に紫外線ランプを設
置、浄水槽の内の触媒室に光触媒を少量収納して浄化す
べき水を触媒室の下側から流入して光触媒を水流で撹拌
することにより光化学反応を促進させることを特徴とす
る浄水装置。
1. An inner cylinder made of quartz glass or the like that transmits ultraviolet light is disposed inside a water purification tank, and an ultraviolet lamp is installed therein, and a small amount of a photocatalyst is stored in a catalyst chamber in the water purification tank for purification. A water purifier characterized in that photochemical reaction is promoted by injecting water to be introduced from below the catalyst chamber and agitating the photocatalyst by a water flow.
【請求項2】光触媒の収納棚を多段にしたことを特徴と
する請求項1に記載の浄水装置。
2. The water purification apparatus according to claim 1, wherein the storage shelves for the photocatalyst are arranged in multiple stages.
【請求項3】触媒室の下側から流入する浄化すべき水の
流入口を浄水槽の中心より偏奇して設置、渦流が発生す
るようにしたことを特徴とする請求項1及び請求項2に
記載の浄水装置。
3. An inflow port for water to be purified, which is introduced from a lower side of the catalyst chamber, is disposed so as to be deviated from the center of the water purification tank, so that a vortex is generated. A water purification device according to claim 1.
【請求項4】光触媒の効果を上げるため原水に空気又は
オゾンを注入するようにしたことを特徴とする請求項1
〜3に記載の浄水装置。
4. The method according to claim 1, wherein air or ozone is injected into the raw water to enhance the effect of the photocatalyst.
The water purifier according to any one of Items 1 to 3.
【請求項5】浄水の一部を還流してこの還流水に空気又
はオゾンを注入、これを原水流入の触媒室の底部より原
水に流入、混流するようにしたことを特徴とする請求項
1〜3に記載の浄水装置。
5. A method according to claim 1, wherein air or ozone is injected into said reflux water by recirculating a part of the purified water, and the air or ozone flows into the raw water from the bottom of the catalyst chamber for inflow of the raw water and is mixed therewith. The water purifier according to any one of Items 1 to 3.
JP2000278898A 2000-08-09 2000-08-09 Water cleaning apparatus Pending JP2002052393A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014117669A (en) * 2012-12-18 2014-06-30 Ricoh Co Ltd Fluid purification apparatus
WO2015037538A1 (en) * 2013-09-13 2015-03-19 株式会社 東芝 Washing machine
JP2015054194A (en) * 2013-09-13 2015-03-23 株式会社東芝 Washing machine
JP2015116296A (en) * 2013-12-18 2015-06-25 株式会社東芝 Washing machine
CN106315756A (en) * 2016-10-18 2017-01-11 南昌航空大学 Device for advanced treatment of organic wastewater through coordination of photocatalysis and fenton oxidation
CN107445246A (en) * 2017-09-11 2017-12-08 郑州大学 A kind of safe and efficient pollution-free sewage disposal device
CN108773895A (en) * 2018-07-19 2018-11-09 苏州方舟环保科技有限公司 A kind of boracic organic waste water treating device
CN108821424A (en) * 2018-07-17 2018-11-16 苏州方舟环境发展有限公司 A kind of photocatalytic oxidation reactor
CN112808177A (en) * 2021-01-05 2021-05-18 广东环境保护工程职业学院 Reactor and VOC processing system containing same
CN113149176A (en) * 2021-04-20 2021-07-23 上海瑜科环境工程有限公司 Catalytic wet oxidation reactor

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014117669A (en) * 2012-12-18 2014-06-30 Ricoh Co Ltd Fluid purification apparatus
WO2015037538A1 (en) * 2013-09-13 2015-03-19 株式会社 東芝 Washing machine
JP2015054194A (en) * 2013-09-13 2015-03-23 株式会社東芝 Washing machine
JP2015116296A (en) * 2013-12-18 2015-06-25 株式会社東芝 Washing machine
CN106315756A (en) * 2016-10-18 2017-01-11 南昌航空大学 Device for advanced treatment of organic wastewater through coordination of photocatalysis and fenton oxidation
CN107445246A (en) * 2017-09-11 2017-12-08 郑州大学 A kind of safe and efficient pollution-free sewage disposal device
CN108821424A (en) * 2018-07-17 2018-11-16 苏州方舟环境发展有限公司 A kind of photocatalytic oxidation reactor
CN108773895A (en) * 2018-07-19 2018-11-09 苏州方舟环保科技有限公司 A kind of boracic organic waste water treating device
CN112808177A (en) * 2021-01-05 2021-05-18 广东环境保护工程职业学院 Reactor and VOC processing system containing same
CN113149176A (en) * 2021-04-20 2021-07-23 上海瑜科环境工程有限公司 Catalytic wet oxidation reactor

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