JP2001162279A - Electrolytic cell for electrolytic water making apparatus - Google Patents

Electrolytic cell for electrolytic water making apparatus

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Publication number
JP2001162279A
JP2001162279A JP34709599A JP34709599A JP2001162279A JP 2001162279 A JP2001162279 A JP 2001162279A JP 34709599 A JP34709599 A JP 34709599A JP 34709599 A JP34709599 A JP 34709599A JP 2001162279 A JP2001162279 A JP 2001162279A
Authority
JP
Japan
Prior art keywords
electrolytic cell
electrolytic
plate
spacer
main body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP34709599A
Other languages
Japanese (ja)
Other versions
JP3583329B2 (en
Inventor
Hiroyuki Tsuchiya
博之 土屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amano Corp
Original Assignee
Amano Corp
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Publication date
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Priority to JP34709599A priority Critical patent/JP3583329B2/en
Publication of JP2001162279A publication Critical patent/JP2001162279A/en
Application granted granted Critical
Publication of JP3583329B2 publication Critical patent/JP3583329B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an electrolytic cell for an electrolytic water making apparatus capable of clamping and fixing left and right frame plates clamped and fixed in a laminated state and the respective electrode plates held between the frame plates in constant clamping balance to develop excellent sealability and constituted so as to be capable of realizing the simplification of assembling work and the mechanization thereof. SOLUTION: The main body of an electrolytic cell is constituted of two main body frames 3, 4 formed into an almost half-shell cross-sectional shape and electrode plates 8, 12, a spacer 10 and seal members 7, 9, 11, 13 are housed in the electrolytic chamber space Z constituted of two main body frames 3, 4 in a laminated state and both main body frames 3, 4 are clamped and fixed to assemble the electrolytic cell.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、食塩水等の被電解
液を電気分解して電解水を生成することができる電解水
生成装置の技術分野で利用されるものであって、具体的
には、電解水生成装置に使用して好適な電解槽の構造に
関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used in the technical field of an electrolyzed water generating apparatus capable of generating electrolyzed water by electrolyzing a liquid to be electrolyzed such as a saline solution. The present invention relates to a structure of an electrolytic cell suitable for use in an electrolyzed water generator.

【0002】[0002]

【従来の技術】従来のボックスタイプに構成した電解槽
に代えて、全体の部品点数を少くし、また、仕様が相違
する場合であっても部品点数を増加することなく、あら
ゆる用途に対応できるように工夫した電解水生成装置用
の電解槽として、例えば、特開平6−339683号公
報に示されているような構造の電解槽が存在する。
2. Description of the Related Art Instead of a conventional box-type electrolytic cell, the number of components can be reduced, and even if the specifications are different, it can be used for any application without increasing the number of components. As an electrolytic cell for an electrolyzed water generating apparatus devised as described above, for example, there is an electrolytic cell having a structure as disclosed in JP-A-6-339683.

【0003】この電解槽は、左右のフレーム板と陽極板
及び陰極板をいずれも略プレート状に造って、これ等各
部材をシール部材を間に挿入しながら積層して締付固定
することによって、内部に電解室と電極とを備えた電解
槽を組立てることができる仕組に成っている。
[0003] In this electrolytic cell, the left and right frame plates, the anode plate and the cathode plate are all formed in a substantially plate shape, and these members are laminated and tightened and fixed while inserting a sealing member therebetween. And an electrolytic cell having an electrolytic chamber and electrodes therein.

【0004】[0004]

【発明が解決しようとする課題】しかし、上述した従来
の電解槽は、左右のフレーム板を締付固定する際に、弾
性シール部材を間に挿入しながら積層してこれを締付固
定するため、締め付けの加減が難しくて、締め付け状態
に強弱のバラツキが発生する問題があった。つまり、弾
力のある弾性シール部材を間に介在させて締め付けるた
め、締め過ぎたり締め足らない場合が生じて、締め付け
バランスが一定せず、その結果、シール性を悪くして漏
水等の不都合が発生していた。
However, in the above-mentioned conventional electrolytic cell, when the left and right frame plates are fastened and fixed, an elastic sealing member is inserted between the laminated plates and the two are stacked and fixed. However, it is difficult to control the tightening, and there is a problem that the strength of the tightening varies. In other words, since the elastic sealing member with elasticity is interposed and tightened, it may be overtightened or insufficiently tightened, and the tightening balance may not be constant, resulting in poor sealing performance and inconvenience such as water leakage. Was.

【0005】加えて、各部品を積層して締付固定する際
に、各部品の外側を揃える必要があって、各部品の位置
決め作業が面倒でやりずらく、組立て作業に手間と時間
が掛ると共に、組立ての機械化を難しくしていた。
[0005] In addition, when the components are stacked and fixed by tightening, it is necessary to align the outsides of the components, and the positioning of the components is troublesome and difficult, and the assembling work takes time and effort. At the same time, it was difficult to mechanize the assembly.

【0006】従って本発明の技術的課題は、積層して締
付固定する左右のフレーム板と、これ等フレーム板の間
に挟持される各電極板を、一定の締付バランスで締付固
定して優れたシール性を発揮できると共に、組立て作業
が簡単で、組立て作業の機械化も容易に実現可能に構成
した電解水生成装置用電解槽を提供することである。
Accordingly, a technical problem of the present invention is that the left and right frame plates to be stacked and fastened and fixed and the electrode plates sandwiched between these frame plates are fastened and fixed with a fixed tightening balance. Another object of the present invention is to provide an electrolytic cell for an electrolyzed water generating apparatus, which can exhibit excellent sealing performance, can be easily assembled, and can be easily mechanized.

【0007】[0007]

【課題を解決するための手段】上記の技術的課題を解決
するために本発明で講じた手段は以下の如くである。
Means taken by the present invention to solve the above-mentioned technical problems are as follows.

【0008】内部に陽極と陰極を設けた電解槽に流入口
と流出口を形成し、流入口から電解槽の内部に供給した
被電解液を流出口から排出する迄の間に、被電解液を電
気分解するように構成した電解水生成装置用の電解槽で
あって、
An inflow port and an outflow port are formed in an electrolytic cell provided with an anode and a cathode therein, and the electrolytic solution supplied from the inflow port to the inside of the electrolytic cell is discharged from the outflow port. An electrolyzer for an electrolyzed water generator configured to electrolyze

【0009】(1) 上記電解槽の本体を、左右2つに
分割し、且つ、上記の流入口と流出口を設けると共に、
双方を合わせると内部に電解室空間を形成できるように
全体を断面略半殻体形状に形成した左右対称の本体フレ
ームによって構成する一方、上記の陽極と陰極を上記の
流入口と流出口に通じる通孔を設けた同じ形状の電極板
によって構成し、これ等の陽極板と陰極板を同じく流入
口と流出口に通じる通孔を設けたスペーサーを中間に介
在した状態で上記左右の本体フレームの内部に積層して
収納し、且つ、これ等左右の本体フレームを上記積層し
た陽極板と陰極板を両側から挟圧するように締付固定す
ることによって、上記の電解槽を構成すること。(請求
項1)
(1) The main body of the electrolytic cell is divided into two parts, left and right, and the above-mentioned inlet and outlet are provided.
When the two are combined, the whole is formed by a symmetrical main body frame formed in a substantially half-shell cross section so that an electrolytic chamber space can be formed inside, while the above anode and cathode are connected to the above inlet and outlet. The left and right body frames are constituted by electrode plates of the same shape provided with through holes, and these anode plates and cathode plates are also interposed with spacers provided with through holes communicating with the inflow port and the outflow port. The electrolytic cell described above is housed in a stacked state, and the left and right body frames are fastened and fixed so as to sandwich the stacked anode plate and cathode plate from both sides. (Claim 1)

【0010】(2) 中間にスペーサーを介在した状態
に積層した陽極板と陰極板を、左右のフレーム体の内部
に収納してこれを両側から締付固定するに当って、左右
の本体フレームと陽極板及び陰極板の各間、並びに、こ
れ等陽極板及び陰極板とスペーサーの各間の夫々にシー
ル部材を介在して締付固定するように構成すること。
(請求項2)
(2) The anode plate and the cathode plate laminated with a spacer interposed therebetween are housed in the left and right frame bodies, and are fastened and fixed from both sides. A structure in which a sealing member is interposed between each of the anode plate and the cathode plate and between each of the anode plate and the cathode plate and each of the spacers so as to be fastened and fixed.
(Claim 2)

【0011】(3) シール部材として、フッ素系ゴム
板を用いること。(請求項3)
(3) A fluorine rubber plate is used as the seal member. (Claim 3)

【0012】(4) 左右の本体フレームの内側外周面
に、締付固定する時に内側のシール部材に喰い込む鋭角
状の突起を環状に連続形成すること。(請求項4)
(4) On the inner peripheral surfaces of the left and right body frames, acute-angled projections that bite into the inner seal members when tightened and fixed are continuously formed in an annular shape. (Claim 4)

【0013】(5) スペーサーの中央部を上下に内壁
板を残した状態で大きく開口し、下部と上部の内壁板の
四隅に流入口に通じる左右2つの流入通孔と、流出口に
通じる左右2つの流出通孔を設け、これ等左右2つの流
入通孔のうちいずれか一方を上記内壁板の表面側に凹設
したガイド溝を通して上記の開口に連通し、他方を同じ
く内壁板の裏面側に凹設したガイド溝を通して上記の開
口に連通すると共に、上記左右2つの流出通孔のうち、
一方の流出通孔を上記内壁板の表面側に凹設したガイド
溝を通して上記の開口に連通し、他方の流出通孔を上記
内壁板の裏面に凹設したガイド溝を通して上記の開口に
連通すること。(請求項5)
(5) The central portion of the spacer is largely opened with the inner wall plate left and right at the top and bottom, and two inflow holes, left and right, leading to the inflow port at the four corners of the lower and upper inner wall plates, and left and right leading to the outflow port. Two outflow through-holes are provided, and one of these two inflow through-holes is communicated with the opening through a guide groove recessed on the surface side of the inner wall plate, and the other is also on the back side of the inner wall plate. And communicates with the opening through a guide groove recessed in
One of the outflow holes communicates with the opening through a guide groove recessed on the surface side of the inner wall plate, and the other outflow hole communicates with the opening through a guide groove recessed in the back surface of the inner wall plate. thing. (Claim 5)

【0014】(6) スペーサーの下側に設けた内壁板
の上面を、表裏両面に凹設した左右のガイド溝から夫々
斜め上方に向けて傾斜して中間で左右にクロスする傾斜
面に形成すると共に、上側に設けた内壁板の底面を、表
裏両面に凹設した左右のガイド溝に向けて夫々斜め上方
に向けて傾斜して中間で左右にクロスする傾斜面に形成
すること。(請求項6)
(6) The upper surface of the inner wall plate provided on the lower side of the spacer is formed as an inclined surface which inclines obliquely upward from the left and right guide grooves recessed on both front and rear surfaces and crosses right and left in the middle. In addition, the bottom surface of the inner wall plate provided on the upper side is formed as an inclined surface which is inclined obliquely upward toward the left and right guide grooves recessed on the front and back surfaces and crosses right and left in the middle. (Claim 6)

【0015】 上記(1)で述べた請求項1に係る手
段によれば、電解槽の本体を左右対称の断面略半殻体形
状に形成した左右2つの本体フレームによって構成し、
陽極板と陰極板並びにスペーサーをこれ等左右の本体フ
レームの内部に積層収納して締付固定すれば、内部に電
解室を備え、且つ、流入通路と流出通路を備えた電解槽
を組立てることができるものであって、各電極板やスペ
ーサーの外側を揃えたり位置合せを行ったりする必要が
なく、組立てを極めて簡単に行えて、組立ての機械化も
可能にする。
According to the means according to claim 1 described in the above (1), the main body of the electrolytic cell is constituted by two left and right main body frames formed in a bilaterally symmetrical substantially half-shell shape,
If the anode plate, the cathode plate, and the spacer are stacked and housed inside the left and right main body frames and fastened and fixed, it is possible to assemble an electrolytic cell having an electrolytic chamber therein and an inflow passage and an outflow passage. Since there is no need to align or align the outside of each electrode plate or spacer, assembly can be performed very easily, and assembly can be mechanized.

【0016】 更に上記(1)で述べた手段によれ
ば、断面略半殻体形状に形成した左右の本体フレーム
を、その接合面同士が完全に密着するまで締め付けれ
ば、電解槽の組立てが完了するため、締め過ぎや締め不
足の問題が発生する余地がなく、全体を一定の締付力に
よってバランスよく締付固定できるため、水漏れ等の問
題も発生することなく優れたシール性を発揮することを
可能にする。
Further, according to the means described in the above (1), assembling of the electrolytic cell is achieved by tightening the left and right body frames formed in a substantially half-shell shape in cross section until their joining surfaces are completely adhered to each other. Because it is completed, there is no room for overtightening or undertightening, and the entire body can be tightened and fixed with a fixed tightening force, so that it exhibits excellent sealing performance without problems such as water leakage To be able to

【0017】 上記(2)で述べた請求項2に係る手
段によれば、各部材を左右のフレーム本体の間に締付固
定するに当って、各部材の間にシール部材を介在して締
付固定するため、各部材間からの水漏れを確実に防止す
ることができる一方、各部材の間にシール部材を介在し
ても左右の本体フレームの接合面同士が密着するまで締
め付ければ、これにて締め付け力は足りるため、シール
部材を介在しても常に安定した締め具合にすることがで
きると共に、締め付けによるシール部材の破損も無くす
ことができる。
According to the means according to claim 2 described in the above (2), when each member is tightened and fixed between the left and right frame main bodies, a sealing member is interposed between the members and tightened. For fixing, it is possible to reliably prevent water leakage from between each member, while tightening until the joining surfaces of the left and right main body frames come into close contact even if a seal member is interposed between the members, With this, the tightening force is sufficient, so that a stable tightening state can be maintained even with the seal member interposed, and the seal member can be prevented from being damaged by the tightening.

【0018】 上記(3)で述べた請求項3に係る手
段によれば、シール部材としてフッ素系ゴム板を使用す
ることで、各電極板の接触部に於ける耐熱性を向上し、
且つ、打ち抜き等による加工性も向上することを可能に
する。
According to the means according to claim 3 described in the above (3), by using a fluorine-based rubber plate as the sealing member, the heat resistance at the contact portion of each electrode plate is improved,
In addition, it is possible to improve workability by punching or the like.

【0019】 上記(4)で述べた請求項4に係る手
段によれば、各部材を左右のフレーム本体の間に締め付
け固定するに当って、各フレーム本体の内側面に環状に
突出形成した突起が内側のシール部材に喰い込むため、
電解槽のシール性を更に向上させることを可能にする。
According to the means according to the fourth aspect described in the above (4), when each member is tightened and fixed between the left and right frame bodies, the protrusions formed to project annularly on the inner surface of each frame body. Bites into the inner seal member,
It is possible to further improve the sealing performance of the electrolytic cell.

【0020】 上記(5)で述べた請求項5に係る手
段によれば、流入口から左右の流入通孔を通してスペー
サーの中央部に開口形成した電解室空間に送り込まれる
被電解液は、左右の流入通孔の表面側と裏面側に凹設し
たガイド溝を通してスペーサーの表裏両側から順次送り
込まれ、また、電解室空間で電解された電解水も、同様
に左右の流出通孔の表面側と裏面側に凹設したガイド溝
を通してスペーサーの表裏両側から流出口に向けて順次
送り出すことができるため、被電解室空間内で被電解液
を均一に電気分解して均一な濃度の電解水を生成するこ
とができると共に、これ等生成された電解水を均一な濃
度のまま流出口から電解槽の外に排出(供給)すること
を可能にする。
According to the means according to claim 5 described in the above (5), the electrolyte to be fed from the inflow port through the left and right inflow holes into the electrolytic chamber space formed at the center of the spacer is formed by the left and right. Through the guide grooves recessed on the front side and back side of the inflow hole, the water is sequentially fed from both the front and back sides of the spacer, and the electrolyzed water electrolyzed in the electrolysis chamber space is also the front side and back side of the left and right outflow holes. Since the spacer can be sequentially sent out from the front and back sides of the spacer toward the outflow port through the guide groove recessed on the side, the electrolyzed liquid is uniformly electrolyzed in the electrolyzed chamber space to generate a uniform concentration of electrolyzed water. In addition, it is possible to discharge (supply) the generated electrolyzed water out of the electrolytic cell from the outlet with a uniform concentration.

【0021】 上記(6)で述べた請求項6に係る手
段によれば、電解運転中に発生した次亜塩素酸がエアー
ポケットに溜ることなく、内壁板に形成した傾斜面に沿
って徐々に排出されることになるため、一定の濃度の電
解水を生成してこれを送り出すことを可能にする。
According to the means of claim 6 described in the above (6), hypochlorous acid generated during the electrolysis operation does not accumulate in the air pocket, but gradually along the inclined surface formed on the inner wall plate. Since the water is discharged, a certain concentration of electrolyzed water can be generated and sent out.

【0022】以上の如くであるから、上記(1)〜
(6)の手段によって上述した技術的課題を解決して、
前記従来の技術の問題点を解消することができる。
As described above, the above (1) to (1)
By solving the above technical problem by means of (6),
The problem of the conventional technique can be solved.

【0023】[0023]

【発明の実施の形態】以下に、本発明に係る電解水生成
装置用電解槽の実施の形態を図面と共に説明すると、図
1は本発明の全体を分解して示した斜視図、図2は同じ
く各部品の正面図、図3は組立てた状態を拡大して示し
た側断面図であって、これ等の図面に於いて、3と4は
左右2つに分割し、且つ、下側と上側に夫々流入口3
A,3A′及び4A,4A′と、流出口3B,3B′及
び4B,4B′を設けると共に、双方を合わせると内部
に電解室空間Z(図3参照)を形成できるように全体を
断面略半殻体形状に形成した左右対称の本体フレーム
で、その表裏表面には材料の使用量と重量を少くし、且
つ、強度性を増すための細かな凹凸が形成されている。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is an exploded perspective view showing an embodiment of an electrolytic cell for an electrolyzed water generating apparatus according to the present invention. Similarly, FIG. 3 is an enlarged side sectional view showing the assembled state. In these drawings, 3 and 4 are divided into two right and left parts, and Inlet 3 on the upper side
A, 3A 'and 4A, 4A' and outlets 3B, 3B 'and 4B, 4B' are provided, and when they are combined together, the entire cross section is substantially omitted so that an electrolytic chamber space Z (see FIG. 3) can be formed therein. A left-right symmetrical body frame formed in a half-shell shape, and fine irregularities are formed on the front and back surfaces to reduce the amount and weight of the material and to increase the strength.

【0024】また、1と2は上記各本体ケース3,4の
外側面に沿設される補強板で、外形を本体ケース3,4
と同一形状に形成したこれ等各補強板1,2の下側と上
側には、上記本体フレーム3,4の各流入口3A,3
A′、4A,4A′と流出口3B,3B′、4B,4
B′に通じる通孔1A,1A′、2A,2A′及び1
B,1B′、2B,2B′が夫々設けられ、更に、これ
等補強板1,2と本体フレーム3,4の周縁には両補強
板1,2と両本体ケース3,4を合せて締め付け固定す
る場合に用いる締付ネジ5…用のネジ孔1C…,2C…
と、3C…,4C…が設けられている。
Reference numerals 1 and 2 denote reinforcing plates provided along the outer surfaces of the main body cases 3 and 4, respectively.
On the lower side and the upper side of each of these reinforcing plates 1, 2 formed in the same shape as the above, the respective inlets 3A, 3 of the main body frames 3, 4 are provided.
A ', 4A, 4A' and outlets 3B, 3B ', 4B, 4
Through holes 1A, 1A ', 2A, 2A' and 1 leading to B '
B, 1B ', 2B, 2B' are provided respectively, and the reinforcing plates 1, 2 and the main body cases 3, 4 are tightened together on the peripheral edges of the reinforcing plates 1, 2 and the main body frames 3, 4. Screw holes 1C, 2C for tightening screws 5 used for fixing
, 3C ..., 4C ... are provided.

【0025】更に図中、8と12は金属薄板を用いて全
体を上記電解室空間Zの内部に嵌込むことができる大き
さに形成した電極板で、これ等各電極板8と12の下側
部と上側部にも上記本体フレーム3,4の各流入口3A
〜4A′と流出口3B〜4B′に通じる通孔8A,8
A′、12A,12A′及び8B,8B′、12B,1
2B′が設けられ、また、その一側縁には電源部を接続
するための端子片8X,12Xが突設されていて、いず
れか一方の電極板8又は12を陽極板とすると、他の電
極板8又は12が陰極板と成るように構成されている。
Further, in the drawing, reference numerals 8 and 12 denote electrode plates formed by using a thin metal plate so as to fit into the inside of the electrolytic chamber space Z. Each of the inlets 3A of the main body frames 3 and 4 are also provided on the side part and the upper part.
Through holes 8A, 8 communicating with .about.4A 'and outlets 3B.about.4B'.
A ', 12A, 12A' and 8B, 8B ', 12B, 1
2B 'is provided, and terminal strips 8X and 12X for connecting a power supply unit are protruded from one side edge thereof. If one of the electrode plates 8 or 12 is used as an anode plate, the other is used. The electrode plate 8 or 12 is configured to be a cathode plate.

【0026】10は上記電極板8,12の間に介在され
るスペーサーで、外形を上記電解室空間Zの内部に嵌込
める大きさに形成したこのスペーサー10の中央は大き
く開口10Hされ、且つ、全体が若干幅広(肉厚)に構
成した略枠形状に形成されていて、その下側部と上側部
に設けた内壁板10′,10′の四隅には、上記本体フ
レーム3,4の各流入口3A〜4A′と各流出口3B〜
4B′に通じる流入通孔10A,10A′及び流出通孔
10B,10B′が設けられている。
Reference numeral 10 denotes a spacer interposed between the electrode plates 8 and 12. The outer shape of the spacer 10 is formed so as to fit into the electrolytic chamber space Z. The center of the spacer 10 has a large opening 10H. The entire body is formed in a substantially frame shape which is slightly wide (thick), and four corners of the main body frames 3 and 4 are provided at four corners of inner wall plates 10 'and 10' provided on the lower side and the upper side. Inlets 3A-4A 'and each outlet 3B-
4B 'are provided with inflow holes 10A and 10A' and outflow holes 10B and 10B '.

【0027】次に、10Eと10Fは、上記スペーサー
10の内壁板10′,10′に設けた左右の流入通孔1
0A,10A′及び流出通孔10B,10B′と、上記
の開口10Hの間を結ぶガイド溝であって、左右の流入
通孔10A,10A′と開口10Hの間を結ぶ左右のガ
イド溝10Eのうち、左側のガイド溝10E(図1と図
2では裏面側のため見えない)は図3に示すようにスペ
ーサー10の裏面側に設けられ、また、右側のガイド溝
10Eは図1並びに図2に示すようにスペーサー10の
表面側に設けられている。
Next, 10E and 10F are the left and right inflow holes 1 provided in the inner wall plates 10 ', 10' of the spacer 10.
0A, 10A 'and outflow holes 10B, 10B' and guide grooves connecting the openings 10H, and the left and right guide grooves 10E connecting the left and right inflow holes 10A, 10A 'and the openings 10H. Of these, the left guide groove 10E (not visible in FIGS. 1 and 2 because of the back side) is provided on the back side of the spacer 10 as shown in FIG. 3, and the right guide groove 10E is provided in FIGS. Are provided on the surface side of the spacer 10 as shown in FIG.

【0028】一方、上記左右の流出通孔10B,10
B′と開口10Hの間を結ぶ左右のガイド溝10Fのう
ち、左側のガイド溝10Fは図1乃至図3に示すように
スペーサー10の表面側に設けられ、また、右側のガイ
ド溝10F(図1乃至図3では裏側のため見えない)は
スペーサー10の裏面側に設けられていて、被電解液の
流入路と電解水の流出路が、スペーサー10の表裏に於
いて左右対称に構成されている。
On the other hand, the left and right outflow holes 10B, 10B
Of the left and right guide grooves 10F connecting between B ′ and the opening 10H, the left guide groove 10F is provided on the surface side of the spacer 10 as shown in FIGS. 1 to 3 and the right guide groove 10F (FIG. 1 to 3 are provided on the back side of the spacer 10, and the inflow path of the electrolytic solution and the outflow path of the electrolyzed water are configured symmetrically on the front and back of the spacer 10. I have.

【0029】また、10Sと10S′並びに10Tと1
0T′は、上記スペーサー10の下側と上側の各内壁板
10′,10′の上面及び底面に形成した傾斜面で、図
1と図2並びにこの傾斜面の部分を拡大して示した図5
に於いて、スペーサー10の一側面(図面では表面側)
の下側内壁板10′の上面には、その下側右側の流入通
孔10A′に設けたガイド溝10Eから、左側に設けた
流入通孔10Aの上側部に向けて斜め上方に傾斜する上
り傾斜面10Sが形成され、他側面(図面では裏面側)
には、その左側の流入通孔10Aに設けたガイド溝10
Eから右側の流入通孔10A′の上側部に向けて斜め上
方に傾斜する上り傾斜面10S′が、上記の上り傾斜面
10Sと中間部で左右に交差するように形成されてい
る。
Also, 10S and 10S 'and 10T and 1
0T 'is an inclined surface formed on the upper surface and the bottom surface of each of the inner wall plates 10', 10 'on the lower side and the upper side of the spacer 10, and FIG. 1 and FIG. 2 and an enlarged view of this inclined surface portion. 5
In one side of the spacer 10 (the front side in the drawing)
On the upper surface of the lower inner wall plate 10 ′, an ascending diagonally upward from the guide groove 10 E provided in the lower right inflow hole 10 A ′ toward the upper part of the inflow hole 10 A provided in the left side. An inclined surface 10S is formed, and the other side surface (the back surface side in the drawing).
Has a guide groove 10 provided in the inflow hole 10A on the left side thereof.
An upwardly inclined surface 10S 'that is inclined obliquely upward from E to the upper side of the inflow through hole 10A' on the right side is formed so as to intersect the upwardly inclined surface 10S and the left and right at an intermediate portion.

【0030】一方、スペーサー10の一側面(図面では
表面側)の上側内壁板10′の底面には、その右側の流
出通路10B′の下側部から、左側の流出通孔10Bに
設けたガイド溝10Fに向けて斜め上側に傾斜する上り
傾斜面10Tが形成され、他側面(図面では裏面側)の
上側内壁板10′の底面には、左側の流出通路10Bの
下側部から右側の流出通孔10B′に設けたガイド溝1
0F(図面では裏に隠れて見えない)に向けて斜め上側
に傾斜する上り傾斜面10T′が、上記上り傾斜面10
Tと中間部で左右に交差するように形成されている。
On the other hand, on the bottom surface of the upper inner wall plate 10 'on one side surface (the front surface side in the drawing) of the spacer 10, a guide provided in the left outflow hole 10B from the lower part of the right outflow passage 10B'. An upwardly inclined surface 10T which is inclined obliquely upward toward the groove 10F is formed. On the bottom surface of the upper inner wall plate 10 'on the other side surface (the back surface side in the drawing), the right outflow passage is formed from the lower portion of the left outflow passage 10B. Guide groove 1 provided in through hole 10B '
0F (in the drawing, hidden behind and invisible), the upwardly inclined surface 10T ′ that is inclined upward and obliquely upwards.
It is formed so as to intersect right and left at the intermediate portion with T.

【0031】次に、6A,6A′と6B,6B′は、上
記一方の本体ケース3の各流入口3A,3A′と流出口
3B,3B′に取付けた外部配管接続用の接続口であっ
て、流入用の接続口6A,6A′からは流入孔6Eを通
して被電解液が送り込まれ、流出用の接続口6B,6
B′からは電解水が流出孔6Fを通って送り出される仕
組に成っている。
Next, 6A, 6A 'and 6B, 6B' are connection ports for connecting external piping attached to the respective inlets 3A, 3A 'and outlets 3B, 3B' of the one main body case 3. Then, the electrolyte is fed from the inflow connection ports 6A and 6A 'through the inflow hole 6E, and the outflow connection ports 6B and 6A.
From B ', the electrolysis water is sent out through the outflow hole 6F.

【0032】また、7,9,11,13は一方の本体フ
レーム3と一方の電極板8の間、この電極板8とスペー
サー10の間、スペーサー10と他方の電極板12の
間、並びに、この電極板12と他方の本体フレーム4と
の間に夫々介在するシール部材であって、打ち抜き形成
が可能で、且つ、耐熱性を備えた薄いフッ素系ゴム板を
用いて全体を上記電解室空間Zの内部に嵌込むことがで
きる大きさに構成したこれ等のシール部材のうち、符号
7,9,11で示した第1、第2、第3の各シール部材
の中央部は大きく開口7H,9H,11Hされていて、
第1のシール部材7の四隅には流入通孔7A,7A′と
流出通孔7B,7B′が形成され、第2のシール部材9
の下部と上部の対称位置には、流入通孔9Aと流出通孔
9B′が形成されると共に、第3のシール部材11の下
部と上部の対称位置には、流入通孔11A′と流出通孔
11Bが形成されている。
Reference numerals 7, 9, 11, and 13 denote between one body frame 3 and one electrode plate 8, between the electrode plate 8 and the spacer 10, between the spacer 10 and the other electrode plate 12, and Sealing members interposed between the electrode plate 12 and the other main body frame 4 are formed by using a thin fluorine-based rubber plate which can be punched out and has heat resistance. Of these seal members configured to fit inside Z, the central portions of the first, second, and third seal members indicated by reference numerals 7, 9, and 11 have large openings 7H. , 9H, 11H,
At four corners of the first seal member 7, inflow through holes 7A, 7A 'and outflow through holes 7B, 7B' are formed.
An inflow through-hole 9A and an outflow through-hole 9B 'are formed at the symmetrical positions of the lower and upper portions of the third seal member 11, and the inflow through-hole 11A' and the outflow through-hole are formed at the lower and upper symmetrical positions of the third seal member 11. A hole 11B is formed.

【0033】一方、第4のシール部材13の中央部は、
上記他のシール部材と同様に大きく開口されているが、
その四隅は上記流入及び流出の各口を塞じる閉塞片13
X…が形成されており、且つ、他方の本体フレーム4の
流入口4A,4A′と流出口4B,4B′はいずれも栓
14A,14A′,14B,14B′によって塞がれて
いる。
On the other hand, the central portion of the fourth seal member 13
Like the other seal members above, it is open large,
The four corners are blocking pieces 13 for closing the inlet and outlet.
X are formed, and the inflow ports 4A, 4A 'and the outflow ports 4B, 4B' of the other main body frame 4 are all closed by plugs 14A, 14A ', 14B, 14B'.

【0034】従って、図示した実施例では、一方の本体
フレーム3側に取付けた流入用接続口6A,6A′から
電解室空間Z内に流入した被電解液を電気分解した後、
その電解水を同じく一方の本体フレーム3側に取付けた
流出用接続口6B,6B′から取出す仕組に成っている
が、これは実施の一例であって、栓14A〜14B′の
嵌込み位置を代えたり、上記第4のシール部材13の位
置を代えたり、或は、各接続口6A〜6B′の取付位置
を代えることによって、被電解液の流入方向と電解水の
取出し方向を任意の方向に変更可能てあることは勿論で
ある。
Therefore, in the illustrated embodiment, after the electrolyte to be introduced into the electrolytic chamber space Z from the inflow connection ports 6A and 6A 'attached to the one main body frame 3 is electrolyzed,
The mechanism is such that the electrolytic water is taken out from the outflow connection ports 6B, 6B 'also attached to one of the main body frames 3, but this is an example of the embodiment, and the fitting positions of the plugs 14A to 14B' are changed. By changing the position of the fourth seal member 13 or changing the mounting position of each of the connection ports 6A to 6B ', the inflow direction of the electrolytic solution and the removal direction of the electrolytic water can be changed in any direction. Of course, it can be changed to

【0035】更に図面に於いて、3T(図3、図4参
照)と4Tは、上記各本体フレーム3,4の各内側外周
面に環状に、且つ、鋭角状に突設形成した突起で、これ
等の各突起3T,4Tは、上述した各部材を両本体フレ
ーム3,4の内部に積層収納して締付ネジ5…で締付固
定する時に、図4に示すように各本体フレーム3,4の
内側に介在するシール部材7並びに13に喰い込んで、
シール性能を向上する仕組に成っている。
Further, in the drawings, 3T (see FIGS. 3 and 4) and 4T are projections formed on the inner outer peripheral surfaces of the main body frames 3 and 4 at an annular and acute angle, respectively. Each of the projections 3T, 4T is used to store the above-described members in the main body frames 3, 4 in a stacked state and to fix them with the tightening screws 5, as shown in FIG. , 4 bite into the sealing members 7 and 13 interposed inside,
It is designed to improve sealing performance.

【0036】本発明に係る電解水生成装置用電解槽は以
上述べた如き構成であって、締付ネジ5…の締付けによ
って2つの本体フレーム3,4の間に積層されて締付固
定される電極板8,12とスペーサー10、並びに、シ
ール部材7,9,11,13は、いずれも両本体フレー
ム3,4によって構成される電解室空間Zに収納できる
大きさに形成され、且つ、これ等各電極板8,12とス
ペーサー10並びにシール部材7〜13には、本体フレ
ーム3,4に設けた流入口3A,3A′,4A,4A′
と、流出口3B,3B′,4B,4B′に通じる通孔8
A〜8B′,12A〜12B′,7A〜7B′,9A,
9B′,11A′,11Bが設けられているため、上記
の各部材を両本体フレーム3,4間の電解室空間Z内に
積層収納して、各ネジ5…で締付固定するだけで、各部
材の外側を揃えたり位置決めしたりすることなく、内部
に陽極と陰極の各電極板8,12を設け、且つ、被電解
液の流入通路と電解水の流出通路を備えた電解水生成装
置用の電解槽を組立てることができる。
The electrolytic cell for the electrolyzed water generating apparatus according to the present invention has the above-described structure, and is laminated between the two main body frames 3 and 4 by tightening the tightening screws 5. The electrode plates 8 and 12, the spacer 10, and the seal members 7, 9, 11, and 13 are all formed in a size that can be accommodated in the electrolytic chamber space Z constituted by the two main body frames 3 and 4. The inflow ports 3A, 3A ', 4A, 4A' provided in the main body frames 3, 4 are provided in the respective electrode plates 8, 12, the spacer 10, and the sealing members 7 to 13.
And a through hole 8 communicating with the outlets 3B, 3B ', 4B, 4B'.
A to 8B ', 12A to 12B', 7A to 7B ', 9A,
9B ', 11A', and 11B, the above members are stacked and housed in the electrolytic chamber space Z between the two main body frames 3 and 4, and are simply fastened and fixed with the screws 5. Electrolyte water generating apparatus provided with anode and cathode electrode plates 8 and 12 therein without aligning or positioning the outside of each member, and having an inflow passage for a liquid to be electrolyzed and an outflow passage for electrolyzed water. Electrolyzer can be assembled.

【0037】更に本発明では、図面に於いてスペーサー
10の左右の流入通孔10A,10A′からは、その裏
面と表面に設けたガイド溝10E,10Eを通ってスペ
ーサー10の表裏両側から被電解液が流入され、また、
左右の流出通孔10B,10B′からも、同じくその表
面と裏面に設けたガイド溝10F,10Fを通ってスペ
ーサー10の表裏両側から電解水が排出されるため、こ
れ等流入と排出の各ルートが電解室空間Zの一側(一
部)に片寄ることがなく、内部で均一に電気分解されて
均一な濃度の電解水を生成することができる。
Further, according to the present invention, in the drawing, the left and right inflow holes 10A, 10A 'of the spacer 10 pass through the guide grooves 10E, 10E provided on the back surface and the front surface of the spacer 10 from both the front and back sides of the spacer 10. Liquid flows in, and
Electrolyzed water is also discharged from the left and right outflow holes 10B and 10B 'through the guide grooves 10F and 10F provided on the front and rear surfaces, respectively. Is not deviated to one side (part) of the electrolytic chamber space Z, and is uniformly electrolyzed inside to generate electrolytic water having a uniform concentration.

【0038】また、スペーサー10の各流入通孔10
A,10A′からガイド溝10E,10Eを通って流入
する被電解液は、各ガイド溝10E,10Eより各上り
傾斜面10S,10S′にガイドされながら電解室空間
Z徐々にに送り出される一方、電解室空間Z内で電気分
解された電解水は、各上り傾斜面10T,10T′にガ
イドされながら各ガイド溝10F,10Fを通って流出
通孔10B,10B′に流出されるため、電解によって
電解室空間Zに発生した次亜塩素酸ガスがエアーポケッ
トに溜ることがなく、これ等各傾斜面10S,10
S′,10T,10T′に案内されて各通路から順次電
解槽1の外部に排出されるから、常に一定濃度の電解水
を生成することができる。
Each of the inflow holes 10 of the spacer 10
The electrolyzed liquid flowing from A, 10A 'through the guide grooves 10E, 10E is gradually sent out from the guide grooves 10E, 10E to the electrolytic chamber space Z while being guided by the upwardly inclined surfaces 10S, 10S'. The electrolyzed water electrolyzed in the electrolysis chamber space Z flows through the guide grooves 10F and 10F to the outflow holes 10B and 10B 'while being guided by the upwardly inclined surfaces 10T and 10T'. Hypochlorous acid gas generated in the electrolysis chamber space Z does not accumulate in the air pockets.
Since the water is guided to S ', 10T, and 10T' and sequentially discharged from each passage to the outside of the electrolytic cell 1, electrolytic water having a constant concentration can always be generated.

【0039】[0039]

【発明の効果】以上述べた次第で、本発明に係る電解水
生成装置用電解槽によれば、両本体フレームの間に各部
材を積層した後、両本体フレームを締付固定するだけで
電解槽を簡単に組立てることができるため、組立ての機
械化を可能にして製造コストを安くできる利点を発揮で
きるものであって、優れたシール性を備える点、並び
に、一定濃度の電解水を生成できる点と相俟って、各種
用途に対応できる極めて有益な電解槽を提供することが
できる。
As described above, according to the electrolytic cell for an electrolyzed water generating apparatus of the present invention, after laminating each member between both body frames, electrolysis is performed only by fastening and fixing both body frames. Since the tank can be easily assembled, the advantages of being able to mechanize the assembly and lowering the manufacturing cost can be exhibited, and that it has an excellent sealing property and that it can generate a constant concentration of electrolytic water. Together with this, it is possible to provide an extremely useful electrolytic cell capable of coping with various uses.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に係る電解水生成装置用電解槽の全体を
分解して示した斜視図である。
FIG. 1 is an exploded perspective view showing an entire electrolyzer for an electrolyzed water generator according to the present invention.

【図2】本発明に係る電解水生成装置用電解槽の全体を
分解して示した正面図である。
FIG. 2 is an exploded front view showing an entire electrolytic cell for an electrolyzed water generating apparatus according to the present invention.

【図3】本発明の全体を拡大して示した断面図である。FIG. 3 is an enlarged cross-sectional view of the present invention.

【図4】本発明の要部を拡大して示した断面図である。FIG. 4 is an enlarged sectional view showing a main part of the present invention.

【図5】スペーサーの要部を拡大して示した斜視図であ
る。
FIG. 5 is an enlarged perspective view showing a main part of a spacer.

【符号の説明】[Explanation of symbols]

3,4 本体フレーム 3A,3A′,4A,4A′ 流入口 3B,3B′,4B,4B′ 流出口 3T,4T 突起 5 締付ネジ 7,9,11,13 シール部材 8,12 電極板 8A,8A′,12A,12A′ 通孔 10 スペーサー 10A,10A′ 流入通孔 10B,10B′ 流出通孔 10′ 内壁板 10S,10S′,10T,10T′ 傾斜面 10E,10F ガイド溝 Z 電解室空間 3, 4 Body frame 3A, 3A ', 4A, 4A' Inlet 3B, 3B ', 4B, 4B' Outlet 3T, 4T Projection 5 Tightening screw 7, 9, 11, 13 Seal member 8, 12 Electrode plate 8A , 8A ', 12A, 12A' Through hole 10 Spacer 10A, 10A 'Inlet hole 10B, 10B' Outlet hole 10 'Inner wall plate 10S, 10S', 10T, 10T 'Inclined surface 10E, 10F Guide groove Z Electrolytic chamber space

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 内部に陽極と陰極を設けた電解槽に流入
口と流出口を形成し、流入口から電解槽の内部に供給し
た被電解液を流出口から排出する迄の間に、被電解液を
電気分解するように構成した電解水生成装置用の電解槽
であって、 上記電解槽の本体を、左右2つに分割し、且つ、上記の
流入口と流出口を設けると共に、双方を合わせると内部
に電解室空間を形成できるように全体を断面略半殻体形
状に形成した左右対称の本体フレームによって構成する
一方、上記の陽極と陰極を上記の流入口と流出口に通じ
る通孔を設けた同じ形状の電極板によって構成し、これ
等の陽極板と陰極板を同じく流入口と流出口に通じる通
孔を設けたスペーサーを中間に介在した状態で上記左右
の本体フレームの内部に積層して収納し、且つ、これ等
左右の本体フレームを上記積層した陽極板と陰極板を両
側から挟圧するように締付固定することによって、上記
の電解槽を構成したことを特徴とする電解水生成装置用
電解槽。
An inflow port and an outflow port are formed in an electrolytic cell having an anode and a cathode provided therein, and the electrolyte is supplied from the inflow port to the inside of the electrolytic cell until the electrolytic solution is discharged from the outflow port. An electrolytic cell for an electrolyzed water generator configured to electrolyze an electrolytic solution, wherein the main body of the electrolytic cell is divided into two right and left parts, and the inlet and the outlet are provided. And a symmetrical main body frame having a substantially half-shell cross-section so that an electrolytic chamber space can be formed inside, while the anode and cathode pass through the inlet and outlet. The left and right body frames are constituted by electrode plates of the same shape provided with holes, and these anode plates and cathode plates are also interposed with spacers provided with through holes communicating with the inlet and outlet. On the left and right The body frame by tightening fixing as pressed between the two sides of the anode plate and the cathode plate described above stacked, electrolytic water generation apparatus for electrolytic cells, characterized by being configured the electrolytic cell described above.
【請求項2】 中間にスペーサーを介在した状態に積層
した陽極板と陰極板を、左右のフレーム体の内部に収納
してこれを両側から締付固定するに当って、左右の本体
フレームと陽極板及び陰極板の各間、並びに、これ等陽
極板及び陰極板とスペーサーの各間の夫々にシール部材
を介在して締付固定するように構成したことを特徴とす
る請求項1記載の電解水生成装置用電解槽。
2. An anode plate and a cathode plate, which are stacked with a spacer interposed therebetween, are housed in left and right frame bodies, and are fastened and fixed from both sides. 2. The electrolysis according to claim 1, wherein the plate and the cathode plate and between the anode plate and the cathode plate and the spacer are fastened and fixed with a sealing member interposed therebetween. Electrolyzer for water generator.
【請求項3】 シール部材として、フッ素系ゴム板を用
いたことを特徴とする請求項2記載の電解水生成装置用
電解槽。
3. The electrolytic cell for an electrolyzed water generator according to claim 2, wherein a fluorine-based rubber plate is used as the seal member.
【請求項4】 左右の本体フレームの内側外周面に、締
付固定する時に内側のシール部材に喰い込む鋭角状の突
起を環状に連続形成したことを特徴とする請求項2又は
3記載の電解水生成装置用電解槽。
4. The electrolysis according to claim 2, wherein acute-angled projections that bite into the inner seal member when tightened and fixed are continuously formed in an annular shape on the inner outer peripheral surfaces of the left and right body frames. Electrolyzer for water generator.
【請求項5】 スペーサーの中央部を上下に内壁板を残
した状態で大きく開口し、下部と上部の内壁板の四隅に
流入口に通じる左右2つの流入通孔と、流出口に通じる
左右2つの流出通孔を設け、これ等左右2つの流入通孔
のうちいずれか一方を上記内壁板の表面側に凹設したガ
イド溝を通して上記の開口に連通し、他方を同じく内壁
板の裏面側に凹設したガイド溝を通して上記の開口に連
通すると共に、上記左右2つの流出通孔のうち、一方の
流出通孔を上記内壁板の表面側に凹設したガイド溝を通
して上記の開口に連通し、他方の流出通孔を上記内壁板
の裏面に凹設したガイド溝を通して上記の開口に連通せ
しめたことを特徴とする請求項1又は2記載の電解水生
成装置用電解槽。
5. A central portion of the spacer is largely opened with an inner wall plate left and right, and two left and right inflow holes communicating with the inflow port and four right and left holes communicating with the outflow port are provided at four corners of the lower and upper inner wall plates. One of the two left and right inflow holes is communicated with the opening through a guide groove recessed on the surface side of the inner wall plate, and the other is also on the back side of the inner wall plate. Along with communicating with the opening through the recessed guide groove, one of the two left and right outflow holes communicates with the opening through a guide groove recessed on the surface side of the inner wall plate, 3. The electrolytic cell for an electrolyzed water generating apparatus according to claim 1, wherein the other outflow hole is communicated with the opening through a guide groove formed in the back surface of the inner wall plate.
【請求項6】 スペーサーの下側に設けた内壁板の上面
を、表裏両面に凹設した左右のガイド溝から夫々斜め上
方に向けて傾斜して中間で左右にクロスする傾斜面に形
成すると共に、上側に設けた内壁板の底面を、表裏両面
に凹設した左右のガイド溝に向けて夫々斜め上方に向け
て傾斜して中間で左右にクロスする傾斜面に形成したこ
とを特徴とする請求項5記載の電解水生成装置用電解
槽。
6. An upper surface of an inner wall plate provided on a lower side of the spacer is formed as an inclined surface which is inclined obliquely upward from left and right guide grooves recessed on both front and back surfaces and crosses right and left in the middle. , Wherein the bottom surface of the inner wall plate provided on the upper side is formed as an inclined surface which is inclined obliquely upward toward the left and right guide grooves recessed on the front and back surfaces and crosses right and left at the middle. Item 6. An electrolytic cell for an electrolyzed water generator according to Item 5.
JP34709599A 1999-12-07 1999-12-07 Electrolyzer for electrolyzed water generator Expired - Fee Related JP3583329B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34709599A JP3583329B2 (en) 1999-12-07 1999-12-07 Electrolyzer for electrolyzed water generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34709599A JP3583329B2 (en) 1999-12-07 1999-12-07 Electrolyzer for electrolyzed water generator

Publications (2)

Publication Number Publication Date
JP2001162279A true JP2001162279A (en) 2001-06-19
JP3583329B2 JP3583329B2 (en) 2004-11-04

Family

ID=18387884

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP3583329B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013173995A (en) * 2012-02-27 2013-09-05 Vantec:Kk Electrolysis chamber structure, electrolysis cell unit, electrolysis cell stack, and hydrogen generator
JP5753638B1 (en) * 2015-03-02 2015-07-22 株式会社日本トリム Electrolyzed water generator
WO2017006911A1 (en) * 2015-07-07 2017-01-12 株式会社日本トリム Electrolytic cell and electrolyzed-water generation device

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013173995A (en) * 2012-02-27 2013-09-05 Vantec:Kk Electrolysis chamber structure, electrolysis cell unit, electrolysis cell stack, and hydrogen generator
JP5753638B1 (en) * 2015-03-02 2015-07-22 株式会社日本トリム Electrolyzed water generator
WO2016140102A1 (en) * 2015-03-02 2016-09-09 株式会社日本トリム Electrolyzed water-generating device
WO2017006911A1 (en) * 2015-07-07 2017-01-12 株式会社日本トリム Electrolytic cell and electrolyzed-water generation device
JP2017018852A (en) * 2015-07-07 2017-01-26 株式会社日本トリム Electric cell and electrolysis water generation device
CN107531517A (en) * 2015-07-07 2018-01-02 日本多宁股份有限公司 electrolytic cell and electrolytic water generating device
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CN107531517B (en) * 2015-07-07 2021-04-30 日本多宁股份有限公司 Electrolytic cell and electrolyzed water generation device
KR102567678B1 (en) * 2015-07-07 2023-08-16 가부시키가이샤니혼트림 Electrolyzer and electrolyzed water generator

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