JP2001131874A - Method for producing flame-retardant mildewproof fabric comprising polyester fiber - Google Patents
Method for producing flame-retardant mildewproof fabric comprising polyester fiberInfo
- Publication number
- JP2001131874A JP2001131874A JP31085799A JP31085799A JP2001131874A JP 2001131874 A JP2001131874 A JP 2001131874A JP 31085799 A JP31085799 A JP 31085799A JP 31085799 A JP31085799 A JP 31085799A JP 2001131874 A JP2001131874 A JP 2001131874A
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- Prior art keywords
- flame
- retardant
- polyester fiber
- treated
- fabric
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Fireproofing Substances (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、ポリエステル繊維
からなる難燃・防黴性布帛の製造方法に関し、さらに詳
しくは、ホテル、旅館などのシャワーカーテン、工事用
シート、軒出しテントなどに使用されるポリエステル繊
維からなる難燃・防黴性布帛に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a flame-retardant / mold-resistant fabric made of polyester fibers, and more particularly, to a method for manufacturing shower curtains, construction sheets, and eaves tents for hotels and inns. The present invention relates to a flame-retardant / mold-resistant fabric made of polyester fibers.
【０００２】[0002]
【従来の技術】従来から、ポリエステル繊維用の防黴剤
としては、ベンゾイミダゾール系化合物が主に使用され
ている。これらの防黴剤は、いずれもポリエステル繊維
との相溶性が無いためにアクリル酸エステル樹脂、ウレ
タン樹脂などのバインダーにより固着している。このた
め、得られる布帛は、洗濯耐久性が少なかったり、バイ
ンダーで防黴剤が覆われため充分な防黴性が得られない
という欠点があり、未だに洗濯耐久性のあるポリエステ
ル繊維からなる防黴性布帛が得られていないのが現状で
ある。Conventionally, benzimidazole compounds have been mainly used as a fungicide for polyester fibers. Since these antifungal agents are not compatible with the polyester fiber, they are fixed by a binder such as an acrylate resin or a urethane resin. For this reason, the obtained fabric has a drawback that the washing durability is low, and the fungicide is not sufficiently obtained because the fungicide is covered with the binder. It is the present situation that a nonwoven fabric has not been obtained.
【０００３】一方、ホテル、旅館、学校、病院等の防火
規制対象の建物に使用されるカーテン、敷物、合板類等
の防炎物品は消防法により防炎規制がなされているの
で、これらの用途には防炎性が必要である。前記のホテ
ル、旅館などのシャワーカーテンには、従来からポリ塩
化ビニール製シートが使用されている。しかし、シャワ
ーカーテンに対する高級品志向の傾向やポリ塩化ビニー
ル製シャワーカーテンは焼却時に多量の塩化水素ガス、
ダイオキシンなどの有毒ガスを発生し環境汚染を引き起
こすため、近年では脱塩ビ化の動きが益々増大してい
る。従って、耐熱性、寸法安定性、染色堅牢度などの優
れた特性を有するポリエステル繊維からなる布帛に、さ
らに難燃性、且つ、防黴性を併せ持つ布帛の開発が要請
されている。On the other hand, flame-retardant articles such as curtains, rugs, plywood and the like used in buildings subject to fire prevention regulations, such as hotels, inns, schools, and hospitals, are regulated by the Fire Services Act. Must be flameproof. Conventionally, polyvinyl chloride sheets have been used for shower curtains of the above-mentioned hotels and inns. However, there is a tendency toward luxury goods for shower curtains and a large amount of hydrogen chloride gas when incinerating PVC shower curtains.
In recent years, toxic gas such as dioxin is generated to cause environmental pollution. Therefore, there is a demand for the development of a fabric made of polyester fibers having excellent properties such as heat resistance, dimensional stability, and color fastness, as well as having flame retardancy and fungicide resistance.
【０００４】これらに関する公知の技術として、ポリエ
ステル繊維の難燃化方法については、例えば、特公昭５
３−１３４７９号公報等に開示されているように重合工
程で燐、或いは、ハロゲン等を含有する難燃剤を添加す
る共重合法により難燃性素材を得る素材難燃化法と、例
えば、特開昭５９−２３６５１号公報等に開示されてい
るように成形後に燐、又は、ハロゲン等を含有する難燃
剤の水分散体で処理する後加工法等がある。これら方法
によるポリエステル繊維の難燃機構はいずれも主として
ポリエステル繊維の溶融特性を高めることにある。[0004] As a known technique relating to these, a method for flame retarding polyester fibers is described in, for example, Japanese Patent Publication No. Sho 5
A material flame-retarding method for obtaining a flame-retardant material by a copolymerization method in which a flame retardant containing phosphorus or halogen is added in a polymerization step as disclosed in JP-A-3-13479 and the like. As disclosed in, for example, JP-A-59-23651, there is a post-processing method or the like in which after molding, the resultant is treated with an aqueous dispersion of a flame retardant containing phosphorus or halogen. The flame-retarding mechanism of the polyester fiber by these methods is mainly to enhance the melting property of the polyester fiber.
【０００５】さらに、撥水加工法としては、パラフィン
系、ジルコニウム系、フッ素系撥水剤などによる後加工
法がある。しかし、これらの加工法では、加工処理によ
りいずれも難燃ポリエステル繊維の溶融特性が損なわれ
防炎性が低下するという問題がある。Further, as a water repellent method, there is a post-process method using a paraffin-based, zirconium-based, fluorine-based water-repellent or the like. However, in these processing methods, there is a problem that the melting property of the flame-retardant polyester fiber is impaired by any of the processing, and the flame resistance is reduced.
【０００６】また、防炎性と撥水性を同時に付与する方
法については、例えば、特開平７−１４５５６２号公
報、特開平８−２６０３５１号公報に開示されているよ
うに、燐化合物と撥水剤との混合物で処理する方法があ
るが、これらの方法では初期の撥水性は良好であるが、
洗濯耐久性が乏しいという問題点があり、ポリエステル
繊維布帛に関しては防黴性、撥水性、防炎性を同時に付
与し、且つ、その洗濯耐久性にも優れた布帛を得ること
は極めて難しいのが現状である。[0006] Further, as to a method for simultaneously imparting flameproofness and water repellency, for example, as disclosed in JP-A-7-145562 and JP-A-8-260351, a phosphorus compound and a water repellent are disclosed. There is a method of treating with a mixture with the above, these methods have good initial water repellency,
There is a problem that washing durability is poor, and it is extremely difficult to obtain a polyester fiber cloth which simultaneously imparts antifungal property, water repellency and flame resistance, and also has excellent washing durability. It is the current situation.
【０００７】[0007]
【発明が解決しようとする課題】本発明は、審美性に優
れ、且つ、洗濯耐久性の良好な防炎性、防黴性、撥水性
を同時に兼ね備え、且つ、焼却時に有毒ガスの発生が極
めて少ないポリエステル繊維からなる難燃・防黴性布帛
の製造方法を提案することにある。DISCLOSURE OF THE INVENTION The present invention is excellent in aesthetics and simultaneously has good flame resistance, mildew resistance and water repellency with good washing durability, and extremely generates toxic gas during incineration. An object of the present invention is to propose a method for producing a flame-retardant / mold-resistant fabric comprising a small amount of polyester fiber.
【０００８】[0008]
【課題を解決するための手段】本発明者らは、前記の課
題を解決するために鋭意検討した結果、特定の防黴剤、
防炎剤、撥水剤を組合わせることにより本発明の難燃・
防黴性布帛の製造方法に到達したものである。Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, a specific antifungal agent,
Flame retardant and flame retardant of the present invention by combining a water repellent
It has reached a method for producing a mold-resistant fabric.
【０００９】すなわち、本発明は、下記一般式（１）で
示される燐化合物を燐元素として対ポリマー重量で０．
３〜１．５重量％共重合した難燃性ポリエステル繊維を
ハロゲン化シクロアルカン系防炎剤及び有機窒素・硫黄
含有化合物で処理した後、有機フッ素化ポリマー系撥水
剤で処理することを特徴とするポリエステル繊維からな
る難燃・防黴性布帛の製造方法にある。That is, in the present invention, a phosphorus compound represented by the following general formula (1) is used as a phosphorus element in an amount of 0.
The flame-retardant polyester fiber copolymerized at 3 to 1.5% by weight is treated with a halogenated cycloalkane flame retardant and an organic nitrogen / sulfur-containing compound, and then treated with an organic fluorinated polymer water repellent. The present invention relates to a method for producing a flame-retardant / mold-resistant fabric made of polyester fiber.
【００１０】[0010]
【化２】 Embedded image
【００１１】（但し、Ｒは飽和、開鎖状又は環状アルキ
レン、アリレーン又はアルアルキレン残基を、Ｒ1は６
個までの炭素原子を有するアルキル基、アリール又はア
ルアルキル基を意味する。また、残基Ｒ及び／又はＲ1
は１個又は多数個のヘテロ原子、特にＦ，Ｃｌ，Ｂｒ，
Ｏ及びＳを含有しても良い。Ｒ2、Ｒ3は炭素数が１〜１
８のアルキル基、アリール基、又は水素原子を表す）(Where R is a saturated, open-chain or cyclic alkylene, arylene or aralkylene residue, R 1 is 6
Alkyl, aryl or aralkyl having up to carbon atoms. Also, residues R and / or R 1
Is one or more heteroatoms, especially F, Cl, Br,
O and S may be contained. R 2 and R 3 each have 1 to 1 carbon atoms.
8 represents an alkyl group, an aryl group, or a hydrogen atom)
【００１２】[0012]
【発明の実施の形態】以下、本発明を詳細に説明する。
本発明に使用するポリエステル繊維は、前記の一般式
（１）で示される燐化合物を共重合したものである。一
般式（１）で示される燐化合物の具体例としては、例え
ば、下記式（化３）で示される２−カルボキシ−エチル
−メチル−ホスフィン酸、及び、その環状無水物などが
例示される。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The polyester fiber used in the present invention is obtained by copolymerizing the phosphorus compound represented by the general formula (1). Specific examples of the phosphorus compound represented by the general formula (1) include, for example, 2-carboxy-ethyl-methyl-phosphinic acid represented by the following formula (Chemical Formula 3) and a cyclic anhydride thereof.
【００１３】[0013]
【化３】 Embedded image
【００１４】これらの燐化合物は、燐元素として対ポリ
マー重量で０．３〜１．５重量％の範囲で共重合してい
るものが必要である。該燐化合物の量が、０．３重量％
未満の場合には、充分な難燃性が得られない。また、該
燐化合物の量が、１．５重量％を超える場合は、ポリマ
ーが着色したり、強力、耐熱性、染色堅牢度等の物性が
低下するので好ましくない。It is necessary that these phosphorus compounds are copolymerized as a phosphorus element in a range of 0.3 to 1.5% by weight based on the weight of the polymer. When the amount of the phosphorus compound is 0.3% by weight
If it is less than 1, sufficient flame retardancy cannot be obtained. On the other hand, when the amount of the phosphorus compound exceeds 1.5% by weight, it is not preferable because the polymer is colored and physical properties such as strength, heat resistance, and color fastness are deteriorated.
【００１５】次に、本発明で防炎剤として使用するハロ
ゲン化シクロアルカン化合物とは、環状飽和炭化水素、
或いは、少なくとも１個の環状飽和炭化水素を有する飽
和炭化水素化合物の水素原子の少なくとも１部分がハロ
ゲンにより置換された化合物である。Next, the halogenated cycloalkane compound used as a flame retardant in the present invention includes cyclic saturated hydrocarbon,
Alternatively, the compound is a saturated hydrocarbon compound having at least one cyclic saturated hydrocarbon in which at least a part of a hydrogen atom is substituted by halogen.
【００１６】かかる化合物の具体例としては、例えば、
１，２，３，４，５，６ヘキサブロモシクロヘキサン、
１，２，３，４、又は、１，２，４，６テトラブロモシ
クロオクタン、又は、１，２，５，６，９，１０ヘキサ
ブロモシクロドデカン、１，２ビス（３，４ジブロモシ
クロヘキシル）１，２ジブロモエタンや、これらの臭素
が塩素で置き替わったものなどを挙げることができる。Specific examples of such compounds include, for example,
1,2,3,4,5,6 hexabromocyclohexane,
1,2,3,4 or 1,2,4,6 tetrabromocyclooctane or 1,2,5,6,9,10 hexabromocyclododecane, 1,2 bis (3,4 dibromocyclohexyl) ) 1,2 dibromoethane and those obtained by replacing bromine with chlorine.
【００１７】かかる化合物のなかでも、ハロゲンが臭素
であるものが吸尽効率及び防炎性が高く、本発明には好
適である。とりわけ、１，２，５，６，９，１０ヘキサ
ブロモシクロドデカンは吸尽効率が高く、且つ、防炎性
も特に優れている。かかるハロゲン化シクロアルカン化
合物は、分散系難燃性組成物として用いられ、とりわけ
水分散系難燃性組成物として好ましく用いられる。Among these compounds, those in which halogen is bromine have high exhaustion efficiency and flame resistance and are suitable for the present invention. In particular, 1,2,5,6,9,10 hexabromocyclododecane has a high exhaustion efficiency and a particularly excellent flameproofing property. Such a halogenated cycloalkane compound is used as a dispersion-based flame retardant composition, and is particularly preferably used as an aqueous dispersion-based flame retardant composition.
【００１８】このようなハロゲン化シクロアルカン化合
物の付与量は、０．５〜５％ｏｗｆの範囲で用いるもの
が好ましく、より好ましくは１．０〜３．０％ｏｗｆの
範囲である。該付与量が０．５％ｏｗｆ未満であると防
炎性が不良となり、また、５％ｏｗｆを超えると風合い
の硬化や、耐光性の低下を招来するので好ましくない。The amount of the halogenated cycloalkane compound to be applied is preferably in the range of 0.5 to 5% owf, more preferably in the range of 1.0 to 3.0% owf. If the applied amount is less than 0.5% owf, the flame resistance becomes poor, and if it exceeds 5% owf, the texture hardens and the light resistance decreases, which is not preferable.
【００１９】次に、本発明で防黴剤として使用する有機
窒素・硫黄含有化合物は、ベンズイミダゾール系、チア
ベンダゾール（ＴＢＺ）、スルフィド系、ピリチオン等
が挙げられるが、なかでも、防黴性、防炎性等の点から
ジンクピリチオン系が最も好適である。かかる有機窒素
・硫黄含有化合物の付与量としては、例えば、固形分：
１０％ｓｏｌのものを０．５〜２％ｏｗｆの範囲で行う
ものが例示される。また、該付与処理の加工法は、浸漬
・パッド法により行ってもよいが、染色加工などの処理
と同時に処理するものが好ましく例示される。The organic nitrogen / sulfur-containing compound used as a fungicide in the present invention includes benzimidazole compounds, thiabendazole (TBZ), sulfide compounds, pyrithione and the like. Zinc pyrithione is most preferred from the viewpoint of flammability and the like. The amount of the organic nitrogen / sulfur-containing compound to be applied is, for example, solid content:
The method of performing 10% sol in the range of 0.5 to 2% owf is exemplified. Further, the processing method of the applying treatment may be performed by a dipping / pad method, but a processing method performed simultaneously with a processing such as a dyeing processing is preferably exemplified.
【００２０】次に、本発明で使用する有機フッ素化ポリ
マー系撥水剤としては、パーフルオロアルキル基やポリ
フルオロアルキル基を有する（メタ）アクリレートを単
独で、若しくは、ビニルエステル、ビニルエーテルやア
クリルアミドと共重合させたものと脂肪族イソシアネー
トのパーフルオロメタクリレートとの共重合体系撥水剤
が挙げられる。なかでも、熱溶融特性の良好なパーフル
オロメタクリレートと脂肪族イソシアネートとの共重合
体系撥水剤が防炎性の点から好ましい。Next, as the organic fluorinated polymer-based water repellent used in the present invention, a (meth) acrylate having a perfluoroalkyl group or a polyfluoroalkyl group alone, or a vinyl ester, vinyl ether or acrylamide is used. Copolymer-based water repellents of copolymerized products and perfluoromethacrylate of aliphatic isocyanate are exemplified. Among them, a copolymer water repellent of perfluoromethacrylate and aliphatic isocyanate having good heat melting properties is preferable from the viewpoint of flameproofing.
【００２１】該有機フッ素化ポリマー系撥水剤の付与処
理は、ポリエステル繊維の布帛の形態で行うものがよ
く、前記のような防炎剤で処理した後に撥水剤の付与処
理を行う。該ポリエステル繊維の布帛への付与方法は、
浸漬法、スプレー法、ロールタッチ法等のいずれを使用
してもよい。また、該有機フッ素化ポリマー系撥水剤の
付与量は、固形分として、０．１〜１．０％ｏｗｆの範
囲が好ましく使用され、さらに好ましくは、０．１５〜
０．５％ｏｗｆの範囲である。なお、必要に応じて防炎
性を損なわない範囲で吸水剤、帯電防止剤、柔軟剤、硬
仕上剤等を併用することも可能である。The treatment for applying the organic fluorinated polymer-based water repellent is preferably performed in the form of a polyester fiber cloth. The treatment for applying the water-repellent is performed after the treatment with the flame retardant as described above. The method of applying the polyester fiber to the fabric,
Any of an immersion method, a spray method, a roll touch method and the like may be used. The amount of the organic fluorinated polymer-based water repellent to be applied is preferably in the range of 0.1 to 1.0% owf as a solid content, more preferably 0.15 to 1.05%.
The range is 0.5% owf. If necessary, a water-absorbing agent, an antistatic agent, a softening agent, a hard finishing agent and the like can be used in combination as long as the flame resistance is not impaired.
【００２２】[0022]
【発明の作用】このように難燃ポリエステル繊維布帛を
ハロゲン化シクロアルカン化合物及び有機窒素・硫黄系
防黴剤で処理した後に、有機フッ素化ポリマー系撥水剤
で処理することにより従来得られなかった洗濯耐久性の
良好な防炎性、防黴性、撥水性が同時に得られたもので
ある。As described above, a flame-retardant polyester fiber fabric cannot be obtained conventionally by treating with a halogenated cycloalkane compound and an organic nitrogen / sulfur-based fungicide and then with an organic fluorinated polymer-based water repellent. Good flame resistance, mold resistance and water repellency with good washing durability.
【００２３】かかる防炎性、防黴性、撥水性が同時に得
られる理由は明らかではないが、燐化合物を含んだ難燃
ポリエステル繊維をさらに後加工法によりハロゲン系防
炎剤を吸尽させることにより燐とハロゲンによる相乗効
果により飛躍的に防炎性が向上し、さらにポリエステル
繊維に吸尽可能な防黴剤で処理するのでバインダーが不
要で且つ洗濯耐久性が良好な防黴性が得られ、さらに、
熱溶融性の優れた有機フッ素化ポリマー系撥水剤で処理
したために、難燃ポリエステル繊維の熱溶融性の低下が
少なくなり防炎性と相反する性能である撥水性も同時に
付与することが出来、複合機能加工が達成されたものと
推定される。It is not clear why such flame retardancy, fungicide resistance and water repellency can be obtained at the same time, but the flame retardant polyester fiber containing the phosphorus compound is further exhausted with a halogen-based flame retardant by a post-processing method. As a result, the synergistic effect of phosphorus and halogen dramatically improves the flame resistance, and the polyester fiber is treated with a fungicide that can be exhausted, so that no binder is required and good mold resistance with good washing durability is obtained. ,further,
Treated with an organic fluorinated polymer water-repellent with excellent heat-melting properties, the decrease in heat-melting properties of flame-retardant polyester fibers is reduced, and water-repellency, which is a performance contradictory to flame resistance, can also be given at the same time. It is presumed that multifunctional machining has been achieved.
【００２４】[0024]
【発明の効果】かくして本発明によれば、審美性に優
れ、洗濯耐久性の良好な防炎性、防黴性、撥水性を同時
に兼ね備え、且つ、焼却時に有毒ガスの発生が極めて少
ないポリエステル繊維の難燃・防黴性布帛が得られる。
この様な難燃・防黴性布帛は、ホテル、旅館のシャワー
カーテン、工事用シート、軒出しテントなどの用途に好
適に使用されるものである。As described above, according to the present invention, polyester fiber which is excellent in aesthetics, has good washing durability, has good flameproofing properties, mildewproofing properties and water repellency at the same time, and generates very little toxic gas when incinerated. A flame-retardant / mold-resistant fabric of the formula (1) is obtained.
Such a flame-retardant / mold-resistant fabric is suitably used for applications such as shower curtains for hotels and inns, construction sheets, eaves tents, and the like.
【００２５】[0025]
【実施例】以下、実施例により本発明をさらに詳細に説
明する。なお、実施例における部は全て重量部を示し、
評価項目に使用した特性値は下記の測定方法によった。 （１）防炎性 ＪＩＳ Ｌ１０９１のＤ法による。 （２）防黴性 ＪＩＳ Ｌ−０２１７ ＃１０３法に準じて測定し、効
力判定法はＪＩＳ Ｌ−２９１１の黴抵抗性試験に基づ
き行った。判定グレード「３」の試験布に黴の発育が認
められないものを合格とした。 （３）撥水性 ＪＩＳ Ｌ１０９１のＤ法（スプレー法）による。The present invention will be described in more detail with reference to the following examples. In addition, all the parts in an Example show a weight part,
The characteristic values used for the evaluation items were determined by the following measurement methods. (1) Flameproofness According to the D method of JIS L1091. (2) Antifungal property It was measured according to JIS L-0217 # 103 method, and the efficacy was determined based on the mold resistance test of JIS L-2911. A test cloth of grade 3 where no mold growth was observed was judged as acceptable. (3) Water repellency According to the D method (spray method) of JIS L1091.
【００２６】［実施例１］経糸及び緯糸に、２−カルボ
キシ−エチル−メチル−ホスフィン酸を燐として０．６
５重量％共重合した難燃ポリエステルフィラメント（８
３．３３ｄｔｅｘ（７５ｄｅ）／２４ｆｉｌ）を１００
％で使用してタフタ（経糸密度：１１０本／２．５４ｃ
ｍ、緯糸密度：９０本／２．５４ｃｍ）を織成し、該織
物を常法により精練した後、ＹＭ８８（第一工業製薬
（株）製防炎剤、ヘキサブロムシクロドデカンの４５％
水分散体）：１０％ｏｗｆ及びニッカノンＳＫＴ（日華
化学（株）製防黴剤、ジンクピリチオンの１０％乳化分
散体）：１％ｏｗｆ、スミカロンネービーブルーＳ２Ｇ
Ｌ（住友化学（株）製、分散染料）：０．５％ｏｗｆ、
ディスパーＶＧ（明成化学製、分散剤）：０．５ｃｃ／
リットル、酢酸：０．３ｃｃ／リットル、浴比：１：１
５により、温度：１３０℃で３０分間処理した後、水洗
し脱水乾燥後、表１に示すように撥水剤パナガードＲＥ
３０１（大和化学（株）製、ウレタンフッ素系撥水剤、
固形分：２０％）の配合液によりパッド（絞り率：４０
％）し、温度：１００℃で１０分間乾燥させた後、温
度：１８０℃で１分間熱処理した。得られた加工布の防
炎剤、防黴剤、撥水剤の付着量、及び加工布の性能を表
１に示す。[Example 1] 2-carboxy-ethyl-methyl-phosphinic acid was added to warp and weft yarns using 0.6% phosphorus.
5% by weight copolymerized flame retardant polyester filament (8
3.33dtex (75de) / 24fil) to 100
% Taffeta (warp density: 110 yarns / 2.54c
m, weft density: 90 yarns / 2.54 cm), and after scouring the woven fabric by a conventional method, YM88 (a flame retardant manufactured by Daiichi Kogyo Seiyaku Co., Ltd., 45% of hexabromocyclododecane) was used.
Aqueous dispersion): 10% owf and Nicanon SKT (10% emulsified dispersion of antifungal agent, zinc pyrithione manufactured by Nika Chemicals Co., Ltd.): 1% owf, Sumikalone Navy Blue S2G
L (disperse dye, manufactured by Sumitomo Chemical Co., Ltd.): 0.5% owf,
Disper VG (manufactured by Meisei Chemical, dispersant): 0.5 cc /
Liter, acetic acid: 0.3 cc / liter, bath ratio: 1: 1
5, treated at a temperature of 130 ° C. for 30 minutes, washed with water, dehydrated and dried, and as shown in Table 1, a water repellent Panagard RE
301 (manufactured by Daiwa Chemical Co., Ltd., urethane fluorine-based water repellent,
Pad (squeezing rate: 40)
%) And dried at a temperature of 100 ° C. for 10 minutes, followed by a heat treatment at a temperature of 180 ° C. for 1 minute. Table 1 shows the amounts of the flame retardant, the fungicide, and the water repellent attached to the obtained work cloth and the performance of the work cloth.
【００２７】［実施例２］実施例１において、防炎剤の
ＹＭ８８及び防黴剤の使用量を表１に示すように変更し
た以外は実施例１と同様にして処理を行った。得られた
加工布の防炎剤、防黴剤、撥水剤の付着量、及び加工布
の性能を表１に併せて示す。Example 2 A treatment was carried out in the same manner as in Example 1 except that the amounts of the flame retardant YM88 and the fungicide used were changed as shown in Table 1. Table 1 also shows the amounts of the flameproofing agent, the fungicide, and the water repellent attached to the obtained work cloth and the performance of the work cloth.
【００２８】［実施例３］経糸及び緯糸に、２−カルボ
キシ−エチル−メチル−ホスフィン酸を燐として０．６
５重量％共重合した難燃ポリエステルフィラメント（８
３．３３ｄｔｅｘ（７５ｄｅ）／２４ｆｉｌ）を１００
％で使用してタフタ（経糸密度：１１０本／２．５４ｃ
ｍ、緯糸密度：９０本／２．５４ｃｍ）を織成し、該織
物を常法により精練した後、ＹＭ８８（第一工業製薬
（株）製防炎剤、ヘキサブロムシクロドデカンの４５％
水分散体）：１０％ｏｗｆ、スミカロンネービーブルー
Ｓ２ＧＬ（住友化学（株）製、分散染料）：２．０％ｏ
ｗｆ、ディスパーＶＧ（明成化学製、分散剤）：０．５
ｃｃ／リットル、酢酸：０．３ｃｃ／リットル、浴比：
１：１５により、温度：１３０℃で３０分間処理した
後、表１に示す組成の防黴剤ニッカノンＳＫＴと撥水剤
パナガードＲＥ３０１（大和化学（株）製、ウレタンフ
ッ素系撥水剤、固形分：２０％）の配合液によりパッド
し（絞り率：４０％）、温度：１００℃で１０分間乾燥
させた後、温度：１８０℃で１分間熱処理した。得られ
た加工布の防炎剤、防黴剤、撥水剤の付着量、及び加工
布の性能を表１に併せて示す。Example 3 2-carboxy-ethyl-methyl-phosphinic acid was added to the warp and the weft using 0.6 as a phosphorous.
5% by weight copolymerized flame retardant polyester filament (8
3.33dtex (75de) / 24fil) to 100
% Taffeta (warp density: 110 yarns / 2.54c
m, weft density: 90 yarns / 2.54 cm), and after scouring the woven fabric by a conventional method, YM88 (a flame retardant manufactured by Daiichi Kogyo Seiyaku Co., Ltd., 45% of hexabromocyclododecane) was used.
Water dispersion): 10% owf, Sumicaron Navy Blue S2GL (manufactured by Sumitomo Chemical Co., Ltd., disperse dye): 2.0% o
wf, Disper VG (manufactured by Meisei Chemical Co., Ltd., dispersant): 0.5
cc / liter, acetic acid: 0.3 cc / liter, bath ratio:
After treating at a temperature of 130 ° C. for 30 minutes at a temperature of 1:15, the antifungal agent Nicanon SKT having the composition shown in Table 1 and a water repellent Panaguard RE301 (manufactured by Daiwa Chemical Co., Ltd., urethane fluorine-based water repellent, solid content : 20%), and dried at a temperature of 100 ° C for 10 minutes, and then heat-treated at a temperature of 180 ° C for 1 minute. Table 1 also shows the amounts of the flameproofing agent, the fungicide, and the water repellent attached to the obtained work cloth and the performance of the work cloth.
【００２９】［比較例１］実施例１において、染色時、
ＹＭ８８を用いなかった以外は実施例１と同様にして処
理を行なった。得られた加工布の防炎剤、防黴剤、撥水
剤の付着量、及び加工布の性能を表１に併せて示す。[Comparative Example 1]
Processing was performed in the same manner as in Example 1 except that YM88 was not used. Table 1 also shows the amounts of the flameproofing agent, the fungicide, and the water repellent attached to the obtained work cloth and the performance of the work cloth.
【００３０】［比較例２］実施例３で使用した防黴剤の
代わりにＢＣＭ（ベンズイミダゾールカルバミン酸メチ
ルの１０％乳化分散体）の４％ｓｏｌ及びバインダーと
してＧＳ０１Ｃ（伸葉（株）製、エチレン酢酸ビニール
共重合エマルジョン、固形分：４３％）を２％ｓｏｌし
たものを用いる以外は実施例３と同様にして処理をし
た。得られた加工布の防炎剤、防黴剤、撥水剤の付着
量、及び加工布の性能を表１に併せて示す。[Comparative Example 2] Instead of the fungicide used in Example 3, 4% sol of BCM (10% emulsified dispersion of methyl benzimidazole carbamate) and GS01C (manufactured by Shinba Corp.) as a binder were used. The treatment was carried out in the same manner as in Example 3 except that 2% sol of an ethylene-vinyl acetate copolymer emulsion (solid content: 43%) was used. Table 1 also shows the amounts of the flameproofing agent, the fungicide, and the water repellent attached to the obtained work cloth and the performance of the work cloth.
【００３１】[0031]
【表１】 [Table 1]
【００３２】なお、表中Ｌ0は洗濯を行わない試料につ
いて、防黴性及び撥水性を評価した結果を、また、Ｌ10
は、ＪＩＳ Ｌ−０２１７ １０３法による洗濯を繰り
返し１０回行った試料について、防黴性及び撥水性をそ
れぞれ評価した結果を示す。[0032] Incidentally, in the table L 0 is the sample that does not perform washing, the results were evaluated antifungal and water repellency, also, L 10
Shows the results of evaluating the antifungal property and the water repellency of a sample obtained by repeatedly performing washing according to JIS L-0217103 method 10 times.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０９Ｋ 21/14 Ｃ０９Ｋ 21/14 Ｄ０６Ｍ 13/08 Ｄ０６Ｍ 13/08 13/355 13/355 Ｆターム(参考） 4H011 AA02 AA03 BA01 BB16 BC19 DA07 DA10 DG16 DH04 DH19 4H020 BA12 4H028 AA25 AA26 AA34 AA35 BA04 BA06 4L033 AA07 AB01 AC03 AC05 AC10 BA05 BA36 CA53 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C09K 21/14 C09K 21/14 D06M 13/08 D06M 13/08 13/355 13/355 F-term (reference) 4H011 AA02 AA03 BA01 BB16 BC19 DA07 DA10 DG16 DH04 DH19 4H020 BA12 4H028 AA25 AA26 AA34 AA35 BA04 BA06 4L033 AA07 AB01 AC03 AC05 AC10 BA05 BA36 CA53
Claims (1)
燐元素として対ポリマー重量で０．３〜１．５重量％共
重合した難燃性ポリエステル繊維をハロゲン化シクロア
ルカン系防炎剤及び有機窒素・硫黄含有化合物で処理し
た後、有機フッ素化ポリマー系撥水剤で処理することを
特徴とするポリエステル繊維からなる難燃・防黴性布帛
の製造方法。 【化１】 （但し、Ｒは飽和、開鎖状又は環状アルキレン、アリレ
ーン又はアルアルキレン残基を、Ｒ1は６個までの炭素
原子を有するアルキル基、アリール又はアルアルキル基
を意味する。また、残基Ｒ及び／又はＲ1は１個又は多
数個のヘテロ原子、特にＦ，Ｃｌ，Ｂｒ，Ｏ及びＳを含
有しても良い。Ｒ2、Ｒ3は炭素数が１〜１８のアルキル
基、アリール基、又は水素原子を表す）1. A halogenated cycloalkane-based flame retardant comprising a flame-retardant polyester fiber obtained by copolymerizing a phosphorus compound represented by the following general formula (1) as a phosphorus element in an amount of 0.3 to 1.5% by weight based on a polymer weight And a method of producing a flame-retardant / mold-resistant fabric comprising polyester fibers, wherein the fabric is treated with an organic fluorinated polymer-based water repellent after being treated with an organic nitrogen / sulfur-containing compound. Embedded image (Where R represents a saturated, open-chain or cyclic alkylene, arylene or aralkylene residue, and R 1 represents an alkyl group, aryl or aralkyl group having up to 6 carbon atoms. And / or R 1 may contain one or more heteroatoms, especially F, Cl, Br, O and S. R 2 and R 3 each represent an alkyl group having 1 to 18 carbon atoms, an aryl group, Or represents a hydrogen atom)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31085799A JP2001131874A (en) | 1999-11-01 | 1999-11-01 | Method for producing flame-retardant mildewproof fabric comprising polyester fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31085799A JP2001131874A (en) | 1999-11-01 | 1999-11-01 | Method for producing flame-retardant mildewproof fabric comprising polyester fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001131874A true JP2001131874A (en) | 2001-05-15 |
Family
ID=18010233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31085799A Pending JP2001131874A (en) | 1999-11-01 | 1999-11-01 | Method for producing flame-retardant mildewproof fabric comprising polyester fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001131874A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102851960A (en) * | 2012-09-20 | 2013-01-02 | 昆山市周市斐煌服饰厂 | Production method of fireproof mould-proof fabric |
| WO2013117188A3 (en) * | 2012-02-09 | 2013-11-21 | Wenko-Wenselaar Gmbh & Co. Kg | Shower curtain with anti-fouling facility and method for the production thereof |
-
1999
- 1999-11-01 JP JP31085799A patent/JP2001131874A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013117188A3 (en) * | 2012-02-09 | 2013-11-21 | Wenko-Wenselaar Gmbh & Co. Kg | Shower curtain with anti-fouling facility and method for the production thereof |
| CN102851960A (en) * | 2012-09-20 | 2013-01-02 | 昆山市周市斐煌服饰厂 | Production method of fireproof mould-proof fabric |
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