CN102851960A - Production method of fireproof mould-proof fabric - Google Patents
Production method of fireproof mould-proof fabric Download PDFInfo
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- CN102851960A CN102851960A CN2012103500306A CN201210350030A CN102851960A CN 102851960 A CN102851960 A CN 102851960A CN 2012103500306 A CN2012103500306 A CN 2012103500306A CN 201210350030 A CN201210350030 A CN 201210350030A CN 102851960 A CN102851960 A CN 102851960A
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Abstract
The invention discloses a production method of a fireproof mould-proof fabric. The production method comprises steps as follows: dipping and rolling the fabric in a dipping liquid with a fireproof and mould-proof agent, and then parching at 65 to 80 DEG C; and keeping the temperature for 0.5 to 2 hours at 175 to 190 DEG C, wherein the fireproof and the mould-proof agent includes the following components in parts by weight: 50 to 65 parts of organic phosphorus compound, 20 to 30 parts of hexamethylol melamine, 2 to 8 parts of penetrant, and 2 to 5 parts of silane coupling agent. According to the production method provided by the invention, the compound fireproof mould-proof agent is adopted, which can be firmly combined with the weaving material, and obvious flame retarding performance and mould-proof performance are brought to the fiber or textile; and high wearable performance can be achieved, such as water resistance, dry cleaning resistance, and weather resistance and the like; the color, the appearance, the hand feeling and other physical mechanical performances of the fiber and the textile cannot be influenced or influenced less.
Description
Technical field
The present invention relates to a kind of production method of the mildew-resistant fabric of preventing fires.
Background technology
According to statistics, the Fire in China death toll reaches thousands of people every year, and accounts for half by the fire that textiles causes, 500,000,000 yuan of direct economic losses.Wherein bedding, furniture decoration are main causes on fire with cloth and drapery, particularly build home fire, and it is larger that textiles the shared ratio of fire spread.Textile garment directly contact with human, in case burn, gently then partial skin is burnt, and suffers misery, and is heavy then the skin large tracts of land is burnt burn, threat to life.In addition, the pernicious gas that textile combustion produces also endangers people's life, such as carbon monoxide, carbon dioxide, hydrogen cyanide, nitrogen oxide, Ammonia and gaseous aldehyde etc., all can cause suffocating or poisoning and death of people.
Existing mildew-resistant fabric adopts usually at fabric surface spraying mould inhibitor, and its short-term has certain effect, but durability is very poor, through losing very soon the mildew-resistant effect after the washing.And there be limited evidence currently of had not only been prevented fires but also the multifunctional fabric of mildew-resistant emerges.
Summary of the invention
The object of the present invention is to provide a kind of production method of the mildew-resistant fabric of preventing fires, the defects that exists to overcome prior art.
For solving the problems of the technologies described above, the prevent fires production method of mildew-resistant fabric of the present invention, comprise the steps: with fabric in the maceration extract that contains the mould inhibitor of preventing fires through after padding operation 65-80 ℃ of lower oven dry, then between 175-190 ℃ constant temperature 0.5-2 hour;
Described fire prevention mould inhibitor is comprised of the component of following weight portion:
Organic phosphorus compound 50-65 part,
Hexamethylolmelamine 20-30 part,
Bleeding agent 2-8 part,
Silane coupler 2-5 part.
Adding water after each component of fire prevention mould inhibitor is mixed is made into mass content and is not less than 10% maceration extract; Preferably be made into the maceration extract of mass content 30~40%.
As a kind of preferred version, described organic phosphorus compound is the phosphorus compound that contains at least one aryl; The preferential oxidation triphenylphosphine.
Bleeding agent is fatty alcohol-polyoxyethylene ether (JFC).
For the not strict restriction of facing fabric itself, be applicable to various natural fabrics, artificial fibre fabric.
The present invention adopts composite fire prevention mould inhibitor, can with the textile material strong bonded, durability is strong, and has following beneficial effect: 1, fiber or textiles are had significantly fire-retardant, mildew-proof function; 2, have good durability, comprise water-fastness, anti-dry-cleaning, weather fastness etc.; 3, do not affect or color and luster, outward appearance, feel and other physical and mechanical propertiess of little effect fiber and fabric.
The specific embodiment
Embodiment 1
The preparation of fire prevention mould inhibitor:
Raw material is prepared:
50 parts of triphenylphosphine oxides,
30 parts of hexamethylolmelamines,
2 parts of penetrating agent JFCs,
5 parts of silane couplers.
Be added to the water after said components mixed in proportion that to be hybridly prepared into the quality solid content be 15% maceration extract.
The production of fire prevention mildew-resistant fabric:
With fabric in the maceration extract that contains the mould inhibitor of preventing fires through after padding operation 65 ℃ of lower oven dry, constant temperature 2 hours between 175 ℃ then.
Embodiment 2
The preparation of fire prevention mould inhibitor:
Raw material is prepared:
65 parts of triphenylphosphine oxides,
20 parts of hexamethylolmelamines,
8 parts of penetrating agent JFCs,
2 parts of silane couplers.
Be added to the water after said components mixed in proportion that to be hybridly prepared into the quality solid content be 40% maceration extract.
The production of fire prevention mildew-resistant fabric:
With fabric in the maceration extract that contains the mould inhibitor of preventing fires through after padding operation 80 ℃ of lower oven dry, constant temperature 0.5 hour between 190 ℃ then.
Application Example
1, durability
With containing the neutral detergent of 1 grams per liter with the ratio of 1: 50 fabric and detergent solution, washing is 30 minutes about 60 ℃ with fabric, and is dry about 60 ℃ behind the centrifuge dewatering.Wash respectively as stated above 5 times, 30 times.
2, fire protecting performance
Method according to national standard GB/T 17591-2006 " flame-retardant textile " is measured fire protecting performance (product category is according to FURNISHING FABRIC), and the result is as follows:
Fire resistance behind the different washing times of table 1
A represents that b represents to wash 5 times without the fabric of washing in the table, and c represents to wash 30 times.
As seen, the present invention has good wash durability, through repeatedly still having good flame retardant effect after the washing.
3, fungicidal properties
The present invention's mildew-resistant fabric of preventing fires is placed on humidity greater than 90, after indoor 3 months of temperature 20-30 degree centigrade, does not find mildew.
Claims (5)
1. production method of mildew-resistant fabric of preventing fires, comprise the steps: with fabric in the maceration extract that contains the mould inhibitor of preventing fires through after padding operation 65-80 ℃ of lower oven dry, then under the temperature between 175-190 ℃, kept 0.5-2 hour;
Described fire prevention mould inhibitor is comprised of the component of following weight portion:
Organic phosphorus compound 50-65 part,
Hexamethylolmelamine 20-30 part,
Bleeding agent 2-8 part,
Silane coupler 2-5 part.
2. the production method of fire prevention mildew-resistant fabric according to claim 1 is characterized in that, adds water after each component is mixed in the fire prevention mould inhibitor and is made into mass content and is not less than 10% maceration extract.
3. the production method of fire prevention mildew-resistant fabric according to claim 1 is characterized in that, adds water after each component is mixed in the fire prevention mould inhibitor and is made into the maceration extract that mass content is 30-40%.
4. the production method of fire prevention mildew-resistant fabric according to claim 1 is characterized in that, described organic phosphorus compound is the phosphorus compound that contains at least one aryl.
5. the production method of fire prevention mildew-resistant fabric according to claim 4 is characterized in that, described organic phosphorus compound is triphenylphosphine oxide.
Priority Applications (1)
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CN2012103500306A CN102851960A (en) | 2012-09-20 | 2012-09-20 | Production method of fireproof mould-proof fabric |
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CN2012103500306A CN102851960A (en) | 2012-09-20 | 2012-09-20 | Production method of fireproof mould-proof fabric |
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CN102851960A true CN102851960A (en) | 2013-01-02 |
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CN2012103500306A Pending CN102851960A (en) | 2012-09-20 | 2012-09-20 | Production method of fireproof mould-proof fabric |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103710773A (en) * | 2013-12-04 | 2014-04-09 | 江苏博士邦尼时装有限公司 | Production technology for mildew-proof fabric |
CN103710774A (en) * | 2013-11-26 | 2014-04-09 | 常熟常圣服饰有限公司 | Production method for mildew-resistant fabric |
CN103790005A (en) * | 2013-11-30 | 2014-05-14 | 常熟市亚欧进出口贸易有限公司 | Method for producing fireproof mildew-proof shell fabric |
CN107618225A (en) * | 2017-08-23 | 2018-01-23 | 海宁市泰达针织有限公司 | A kind of high-temperature operation fireproof facing material and preparation method thereof |
CN110936691A (en) * | 2019-11-25 | 2020-03-31 | 绍兴柯桥区归零纺织品有限公司 | Fireproof laser embroidery fabric and manufacturing method thereof |
Citations (6)
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CN1037556A (en) * | 1988-05-13 | 1989-11-29 | 陈生才 | Fire prevention, waterproof and mildew-resistant fabric |
JPH06184907A (en) * | 1992-12-09 | 1994-07-05 | Toyobo Co Ltd | Flame-retardant, antifungal filamentous nonwoven fabric for wall facing material |
JP2001131874A (en) * | 1999-11-01 | 2001-05-15 | Teijin Ltd | Method for producing flame-retardant mildewproof fabric comprising polyester fiber |
CN1556274A (en) * | 2003-12-30 | 2004-12-22 | 浙江恒逸集团有限公司 | Cotton viscose fabric phosphorus silicon synergistic effect fire retarding treating liquid |
WO2008081809A1 (en) * | 2006-12-29 | 2008-07-10 | Nippon Kayaku Kabushiki Kaisha | Polyphosphate salt-containing aqueous dispersion, antiflaming agent using the same, and antiflaming process for fiber |
CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
-
2012
- 2012-09-20 CN CN2012103500306A patent/CN102851960A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1037556A (en) * | 1988-05-13 | 1989-11-29 | 陈生才 | Fire prevention, waterproof and mildew-resistant fabric |
JPH06184907A (en) * | 1992-12-09 | 1994-07-05 | Toyobo Co Ltd | Flame-retardant, antifungal filamentous nonwoven fabric for wall facing material |
JP2001131874A (en) * | 1999-11-01 | 2001-05-15 | Teijin Ltd | Method for producing flame-retardant mildewproof fabric comprising polyester fiber |
CN1556274A (en) * | 2003-12-30 | 2004-12-22 | 浙江恒逸集团有限公司 | Cotton viscose fabric phosphorus silicon synergistic effect fire retarding treating liquid |
WO2008081809A1 (en) * | 2006-12-29 | 2008-07-10 | Nippon Kayaku Kabushiki Kaisha | Polyphosphate salt-containing aqueous dispersion, antiflaming agent using the same, and antiflaming process for fiber |
CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103710774A (en) * | 2013-11-26 | 2014-04-09 | 常熟常圣服饰有限公司 | Production method for mildew-resistant fabric |
CN103790005A (en) * | 2013-11-30 | 2014-05-14 | 常熟市亚欧进出口贸易有限公司 | Method for producing fireproof mildew-proof shell fabric |
CN103710773A (en) * | 2013-12-04 | 2014-04-09 | 江苏博士邦尼时装有限公司 | Production technology for mildew-proof fabric |
CN107618225A (en) * | 2017-08-23 | 2018-01-23 | 海宁市泰达针织有限公司 | A kind of high-temperature operation fireproof facing material and preparation method thereof |
CN110936691A (en) * | 2019-11-25 | 2020-03-31 | 绍兴柯桥区归零纺织品有限公司 | Fireproof laser embroidery fabric and manufacturing method thereof |
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Application publication date: 20130102 |