JP2001118611A - Regeneration method of lead accumulator battery by electric treatment - Google Patents

Regeneration method of lead accumulator battery by electric treatment

Info

Publication number
JP2001118611A
JP2001118611A JP29308599A JP29308599A JP2001118611A JP 2001118611 A JP2001118611 A JP 2001118611A JP 29308599 A JP29308599 A JP 29308599A JP 29308599 A JP29308599 A JP 29308599A JP 2001118611 A JP2001118611 A JP 2001118611A
Authority
JP
Japan
Prior art keywords
lead
accumulator battery
lead accumulator
performance
deteriorated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29308599A
Other languages
Japanese (ja)
Inventor
Takeji Nishida
西田武次
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
New & S Kk
Original Assignee
New & S Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by New & S Kk filed Critical New & S Kk
Priority to JP29308599A priority Critical patent/JP2001118611A/en
Publication of JP2001118611A publication Critical patent/JP2001118611A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Secondary Cells (AREA)

Abstract

PROBLEM TO BE SOLVED: To recover the performance of a deteriorated lead accumulator battery by the electric treatment, and regenerate it back to normal use again. SOLUTION: A regeneration method of lead accumulator battery where against a lead accumulator battery of which performance is deteriorated, an appropriate pulse current of direct current is passed according to the specifications of a lead accumulator battery, the internal resistance value, CCA value, the terminal voltage and the temperature at the treatment, and the charge/discharge treatment which has an appropriate interval is carried out automatically.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【０００１】[0001]

【発明の属する技術分野】本発明は、性能が劣化して使
用済みとされた鉛蓄電池あるいは廃棄された鉛蓄電池を
再生利用するための方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for reusing a used or discarded lead storage battery whose performance has deteriorated.

【０００２】[0002]

【従来の技術】使用継続され、または使用されずに長期
間自然放電した結果、性能の著しく劣化した鉛蓄電池
は、一般的な充電を施しても一時的な性能回復しかでき
ないか、全く能力回復が見られず、いわゆる'寿命'とさ
れ廃棄されていた。劣化した鉛蓄電池の能力を向上させ
る手段としては、電解液に炭素コロイドを添加する例な
どがあるが、電気的な処理を施すことによって通常使用
に耐える程度にまで鉛蓄電池の性能を向上させ、または
回復させる方法はこれまで存在していない。2. Description of the Related Art A lead-acid battery whose performance has been significantly deteriorated as a result of natural discharge for a long period of time without use or continuous use can only temporarily recover its performance after general charging, or can completely recover its performance. Was not seen, and it was called 'life' and was discarded. Means for improving the performance of a deteriorated lead storage battery include, for example, adding a carbon colloid to the electrolytic solution.However, by performing an electrical treatment, the performance of the lead storage battery is improved to a level that can withstand normal use, Or there is no way to recover.

【０００３】[0003]

【発明が解決しようとする課題】この発明は、性能が劣
化した鉛蓄電池を電気的処理によってその性能を回復さ
せ、再び通常使用できるようにする方法を確立すること
を目的とする。SUMMARY OF THE INVENTION An object of the present invention is to establish a method for recovering the performance of a lead-acid battery whose performance has deteriorated by electrical treatment and making it usable again normally.

【０００４】[0004]

【課題を解決するための手段】鉛蓄電池劣化の主要因
は、電極表面に析出するサルフェーション(硫酸鉛PbS
O4)結晶であることは既知の事実である。鉛蓄電池は、
負極(Pb)と正極(PbO2)が電解液(2H2SO4)中にあり、充放
電を繰り返すが、その過程でサルフェーション(硫酸鉛P
bSO4)の発生は避けられない。サルフェーション(硫酸鉛
PbSO4)は電極表面に析出するイオン性結晶固体であり、
電子伝導性及びイオン伝導性を有しないため、電極表面
の不導体被膜となり、鉛蓄電池は容量低下となって性能
を劣化させてゆく。そして、通常３年程度の使用で鉛蓄
電池は'寿命'とされ、廃棄されてきた。The main cause of the deterioration of the lead-acid battery is the sulfation (lead sulfate PbS
O 4 ) is a known fact. Lead acid batteries are
The negative electrode (Pb) and the positive electrode (PbO 2 ) are in the electrolyte solution (2H 2 SO 4 ), and charge and discharge are repeated.Sulfation (lead sulfate P
The occurrence of bSO 4 ) is inevitable. Sulfation (lead sulfate
PbSO 4 ) is an ionic crystalline solid deposited on the electrode surface,
Since it does not have electron conductivity and ionic conductivity, it becomes a non-conductive film on the electrode surface, and the capacity of the lead storage battery is reduced, and the performance is degraded. The lead-acid battery has been used for about three years, and its life has been expired.

【０００５】サルフェーション(硫酸鉛PbSO4)は硫酸イ
オン(SO4 2-)を結晶内に保有するため、この鉛蓄電池を
充電してもその硫酸イオン(SO4 2-)は電解液(H2SO4)に還
元されない。そのため電解液中のH2OがSO4 2-に対して相
対的に増加した状態となり、電解液の比重は低下する。
鉛蓄電池の性能状態を間接的に把握する為に電解液の比
重測定が行われるのはこのためである。劣化した鉛蓄電
池の性能を回復させるためには、この電極表面に析出し
たサルフェーション(硫酸鉛PbSO4)を分子分解して、SO4
2-の形で電解液(H2SO4)に還元させ、電極の充放電能力
を回復させることが必要である。[0005] Since sulfation (lead sulfate PbSO 4 ) has sulfate ions (SO 4 2- ) in the crystal, even if the lead storage battery is charged, the sulfate ions (SO 4 2- ) are converted into the electrolyte solution (H 2 Not reduced to SO 4 ). Therefore, H 2 O in the electrolytic solution is relatively increased with respect to SO 4 2− , and the specific gravity of the electrolytic solution is reduced.
This is why the specific gravity of the electrolyte is measured in order to indirectly grasp the performance state of the lead storage battery. In order to restore the degraded lead-acid battery performance, sulfation deposited on the electrode surface (lead sulphate PbSO 4) and molecular decomposition, SO 4
It is necessary to reduce the electrolyte (H 2 SO 4 ) in the form of 2- to restore the charge / discharge capability of the electrode.

【０００６】鉛蓄電池電極に直流パルスを流すことでサ
ルフェーション(硫酸鉛PbSO4)が分子分解されることは
公知の事実である。しかし、この直流パルスによるサル
フェーションの分解速度は、処理対象とする鉛蓄電池の
規格、劣化度(サルフェーションの量や結晶化の程度)そ
して処理時の温度によって変動する。したがって、効率
よくサルフェーションを分解するためには、それらの変
動要因に応じてパルスの波形、波高、duty比(最大振幅
時の電流継続時間比)及び充電電流値を最適に設定する
必要がある。It is a known fact that sulfation (lead sulfate PbSO 4 ) is molecularly decomposed by applying a DC pulse to a lead-acid battery electrode. However, the decomposition rate of sulfation by the DC pulse varies depending on the specification of the lead storage battery to be processed, the degree of deterioration (the amount of sulfation and the degree of crystallization), and the temperature during processing. Therefore, in order to efficiently decompose the sulfation, it is necessary to optimally set the pulse waveform, the wave height, the duty ratio (current duration ratio at the maximum amplitude) and the charging current value in accordance with the fluctuation factors.

【０００７】サルフェーション(硫酸鉛PbSO4)が除去さ
れた鉛蓄電池が、その性能を回復するためには、更に適
切な充電を施す必要がある。ここに言う適切な充電と
は、処理対象とする鉛蓄電池の規格、劣化度そして処理
時の温度に応じて最適な電流値と最適なインターバルを
有する充放電の繰り返しによる。[0007] In order to recover the performance of the lead storage battery from which the sulfation (lead sulfate PbSO 4 ) has been removed, it is necessary to perform more appropriate charging. The term “appropriate charging” as used herein refers to repetition of charge / discharge having an optimal current value and an optimal interval in accordance with the standard, the degree of deterioration, and the temperature during processing of a lead storage battery to be processed.

【０００８】この発明は、上記目的を達するため、再生
対象とする劣化した鉛蓄電池に対し、まず内部抵抗、Ｃ
ＣＡ値(Cold Cranking Ampere)及び端子電圧を測定して
劣化度を測り、その劣化度、鉛蓄電池の規格、そして処
理時の温度に応じた最適な直流パルスと最適なインター
バル充電を一連の作用として行える方法を確立するもの
である。According to the present invention, in order to achieve the above-mentioned object, first, an internal resistance, C
Measure the CA value (Cold Cranking Ampere) and terminal voltage to measure the degree of deterioration, and as a series of actions, the optimal DC pulse and the optimal interval charge according to the degree of deterioration, the standard of the lead storage battery, and the temperature during processing. Establish a way to do it.

【０００９】[0009]

【実施例】図１において、再生処理対象である鉛蓄電池
８は、回路７を通じて制御部４によって内部抵抗値、Ｃ
ＣＡ値及び端子電圧が測定され、演算部３を通じて表示
部１に表示される。操作者は、その表示された値、鉛蓄
電池の規格そして温度を入力部２によって入力する。演
算部３は、その入力値に応じて制御部４を通じて、最適
なdutyを有する直流パルスを流すとともに、最適なイン
ターバルを有する充放電を行い、鉛蓄電池の内部抵抗
値、ＣＣＡ値及び端子電圧が最適値を示すと自動的に処
理が終了する。In FIG. 1, a lead storage battery 8 to be subjected to a regeneration process has an internal resistance value C
The CA value and the terminal voltage are measured and displayed on the display unit 1 through the calculation unit 3. The operator inputs the displayed value, the standard of the lead storage battery, and the temperature through the input unit 2. The operation unit 3 supplies a DC pulse having an optimum duty and performs charging and discharging at an optimum interval through the control unit 4 in accordance with the input value, so that the internal resistance value, the CCA value, and the terminal voltage of the lead storage battery are changed. When the optimum value is indicated, the process automatically ends.

【００１０】[0010]

【発明の効果】以上のように、この発明によれば、従来
は廃棄されていた使用済み鉛蓄電池を効率よく再生して
再利用することができる。As described above, according to the present invention, a used lead storage battery which has been conventionally discarded can be efficiently regenerated and reused.

【図面の簡単な説明】[Brief description of the drawings]

【図１】 本発明に係るシステムのブロック構成図であ
る。FIG. 1 is a block diagram of a system according to the present invention.

【符号の説明】[Explanation of symbols]

１・・・表示部ＬＣＤ ２・・・入力部テンキースイッチ ３・・・演算部ＣＰＵ ４・・・制御部 DESCRIPTION OF SYMBOLS 1 ... Display part LCD 2 ... Input part ten key switch 3 ... Calculation part CPU 4 ... Control part

Claims (1)

【特許請求の範囲】[Claims] 【請求項１】 性能が劣化した鉛蓄電池に対し、鉛蓄電
池の規格、内部抵抗値、ＣＣＡ値、端子電圧及び処理時
の温度に応じた適切な直流パルス電流を流し、かつ適切
なインターバルを有する充放電処理を自動的に行うこと
を特徴とする鉛蓄電池再生方法1. An appropriate DC pulse current is supplied to a lead-acid battery whose performance has deteriorated in accordance with the standard, internal resistance value, CCA value, terminal voltage and temperature during processing of the lead-acid battery, and has an appropriate interval. A method for regenerating a lead-acid battery, characterized by automatically performing charge / discharge processing
JP29308599A 1999-10-15 1999-10-15 Regeneration method of lead accumulator battery by electric treatment Pending JP2001118611A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29308599A JP2001118611A (en) 1999-10-15 1999-10-15 Regeneration method of lead accumulator battery by electric treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29308599A JP2001118611A (en) 1999-10-15 1999-10-15 Regeneration method of lead accumulator battery by electric treatment

Publications (1)

Publication Number Publication Date
JP2001118611A true JP2001118611A (en) 2001-04-27

Family

ID=17790255

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29308599A Pending JP2001118611A (en) 1999-10-15 1999-10-15 Regeneration method of lead accumulator battery by electric treatment

Country Status (1)

Country Link
JP (1) JP2001118611A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004030137A1 (en) * 2002-09-24 2004-04-08 Eruma Co., Ltd. Device for removing lead sulfate film formed in lead-acid battery
WO2006057083A1 (en) * 2004-11-26 2006-06-01 Pulsetech Japan Corporation Used lead battery regenerating/new lead battery capacity increasing method
JP2007080552A (en) * 2005-09-12 2007-03-29 Nishida Tomoe Regeneration method of storage battery
WO2008033054A2 (en) * 2006-08-08 2008-03-20 Konstantin Ivanovich Tyukhtin Method and device for a storage battery recovery
DE102010024101A1 (en) 2009-08-07 2011-03-24 Gennady Dmitrevic Platonov Method for reducing an accumulator battery and device for carrying it out
ES2529602A1 (en) * 2013-08-22 2015-02-23 Soretsel Lab Consulting, S.L. Battery repair method (Machine-translation by Google Translate, not legally binding)
CN106025400A (en) * 2016-06-14 2016-10-12 深圳美能动力科技有限公司 Charging-discharging instrument for repairing lead storage battery and repairing charging method for lead storage battery
WO2016189630A1 (en) * 2015-05-25 2016-12-01 株式会社トーア紡コーポレーション Lead storage battery regeneration device
US9755218B2 (en) 2013-03-12 2017-09-05 K-Tec Engineering, Inc. Stationary lead battery performance improvement method
JPWO2022018876A1 (en) * 2020-07-22 2022-01-27

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004030137A1 (en) * 2002-09-24 2004-04-08 Eruma Co., Ltd. Device for removing lead sulfate film formed in lead-acid battery
WO2004030138A1 (en) * 2002-09-24 2004-04-08 Eruma Co., Ltd. Method for removing lead sulfate film formed in lead-acid battery
WO2006057083A1 (en) * 2004-11-26 2006-06-01 Pulsetech Japan Corporation Used lead battery regenerating/new lead battery capacity increasing method
JP2007080552A (en) * 2005-09-12 2007-03-29 Nishida Tomoe Regeneration method of storage battery
WO2008033054A2 (en) * 2006-08-08 2008-03-20 Konstantin Ivanovich Tyukhtin Method and device for a storage battery recovery
WO2008033054A3 (en) * 2006-08-08 2008-07-24 Konstantin Ivanovich Tyukhtin Method and device for a storage battery recovery
DE102010024101A1 (en) 2009-08-07 2011-03-24 Gennady Dmitrevic Platonov Method for reducing an accumulator battery and device for carrying it out
US9755218B2 (en) 2013-03-12 2017-09-05 K-Tec Engineering, Inc. Stationary lead battery performance improvement method
ES2529602A1 (en) * 2013-08-22 2015-02-23 Soretsel Lab Consulting, S.L. Battery repair method (Machine-translation by Google Translate, not legally binding)
WO2016189630A1 (en) * 2015-05-25 2016-12-01 株式会社トーア紡コーポレーション Lead storage battery regeneration device
JPWO2016189630A1 (en) * 2015-05-25 2017-06-15 株式会社トーア紡コーポレーション Lead-acid battery regeneration device
CN106025400A (en) * 2016-06-14 2016-10-12 深圳美能动力科技有限公司 Charging-discharging instrument for repairing lead storage battery and repairing charging method for lead storage battery
JPWO2022018876A1 (en) * 2020-07-22 2022-01-27
JP7246115B2 (en) 2020-07-22 2023-03-27 株式会社Ｋｋｂテクノロジー Battery activation device and maintenance system for secondary battery

Similar Documents

Publication Publication Date Title
JP3510795B2 (en) How to recycle lead-acid batteries
JP4565362B1 (en) Prevention and regeneration device for storage capacity deterioration due to electrical treatment of lead acid battery
JP2001118611A (en) Regeneration method of lead accumulator battery by electric treatment
WO2006057083A1 (en) Used lead battery regenerating/new lead battery capacity increasing method
JP3723795B2 (en) Recycling method for lead acid battery
JP6298895B2 (en) Lead-acid battery regeneration device
JP2009016324A (en) Regenerating method for lead storage battery and its device
JP4083579B2 (en) Method and apparatus for resisting sulfation in electrical storage batteries
US20190165426A1 (en) Nanoparticle compositions and methods for enhancing lead-acid batteries
JP3386801B1 (en) Lead-acid battery electrolyte composition
JP3746135B2 (en) Charging method for sealed lead-acid batteries
KR101499816B1 (en) Multi-pulse power charge device to lead storage battery enhancement
JPH0636803A (en) Charging of lithium secondary battery
JP2018113131A (en) Activation charging method for lead acid storage battery
EP1184928A1 (en) Method of regenerating lead storage batteries
RU59337U1 (en) DEVICE FOR RESTORING THE BATTERY
RU2309509C1 (en) Method and device for restoring accumulator battery
JP4293587B2 (en) Lead-acid battery regeneration method and apparatus used therefor
WO2000065681A1 (en) Method for curing electrodes
JP2762889B2 (en) Method of forming negative electrode plate for lead-acid battery using copper grid
JP2009048870A (en) Secondary battery regeneration method
JP2010062007A (en) Method of regenerating lead-acid battery
JP3010691B2 (en) Battery forming method for sealed lead-acid batteries
Kozawa et al. Basic understanding of the low current charge and high current charge for lead-acid batteries
JPH1064530A (en) Manufacture of electrode plate for lead-acid battery

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050331

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20060310

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20060310

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070515

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20070925