JP2000256080A - Alc panel with inorganic coating film layer - Google Patents

Alc panel with inorganic coating film layer

Info

Publication number
JP2000256080A
JP2000256080A JP11063039A JP6303999A JP2000256080A JP 2000256080 A JP2000256080 A JP 2000256080A JP 11063039 A JP11063039 A JP 11063039A JP 6303999 A JP6303999 A JP 6303999A JP 2000256080 A JP2000256080 A JP 2000256080A
Authority
JP
Japan
Prior art keywords
layer
alc
coating film
alkali
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11063039A
Other languages
Japanese (ja)
Inventor
Shinya Saito
信弥 齋藤
Satoru Takahashi
悟 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP11063039A priority Critical patent/JP2000256080A/en
Publication of JP2000256080A publication Critical patent/JP2000256080A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain an ALC panel having high weather resistance and high durability by successively disposing a primer layer, a filler layer and a coating film layer of an alkali-proof inorganic coating material on the surface of an ALC substrate. SOLUTION: A primer layer is formed using an aqueous solution of an acrylic emulsion or the like and exhibits adhesion to the sections of piano wires in the ALC substrate. A filler layer is a coating film layer formed using an emulsion of an acrylic, epoxy or urethane resin and smoothens the sections of the piano wires. A coating film layer of the alkali-proof inorganic coating material is disposed as a top coat layer. When a composite of a metal oxide gel and acrylic urethane is used, a coating film can be formed at ordinary temperature and a special sealer is not used because of no influence of the presence of alkali. A colored layer may be disposed on the filler layer so as to enhance luster. In the formation of the coating films, forced drying at a temperature at which the temperature of the ALC substrate does not exceed 80 deg.C may be carried out besides drying at the ordinary temperature.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、高耐候性、高耐久
性を有する無機塗料塗装ALC(軽量気泡コンクリー
ト)パネルに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inorganic paint-coated ALC (lightweight cellular concrete) panel having high weather resistance and high durability.

【0002】[0002]

【従来の技術】ALCの外壁は、塗装仕上げを施して使
用するが、その塗装は建設現場での吹付け塗装が一般的
である。ALC外壁を構成するパネルを工事現場へ搬入
する事により、工期が短いという特長を有しているにも
かかわらず、工事現場での外壁塗装工程が存在すること
により、その工程が天候に左右され、総合的に工期が遅
れがちになってしまっているのが現状である。
2. Description of the Related Art The outer wall of an ALC is used after applying a paint finish, and the paint is generally sprayed on a construction site. Despite the fact that the construction period of the ALC outer wall is brought into the construction site and the construction period is short, despite the fact that the construction period is short, the process is affected by the weather. However, the current situation is that the construction period is generally delayed.

【0003】近年は、工場で最終塗装仕上げまで行った
ALCも商品化されつつあり、その動向が注目されてい
る。その中で、長期の耐久性を特徴とする無機塗料によ
る塗装(以下、無機塗装と称す)をALCに実施する研
究も進められてきたが、シロキサン結合のみの結合で形
成される無機塗装では、その塗膜形成の為に高温加熱が
必要となり、ALC基材の耐熱以上の雰囲気温度が要求
され、基材自身に亀裂を発生させてしまう。
[0003] In recent years, ALC, which has been completed in a factory until the final coating finish, is also being commercialized, and the trend is attracting attention. Among them, research on applying ALC to inorganic coatings characterized by long-term durability (hereinafter referred to as “inorganic coatings”) has been promoted, but in inorganic coatings formed only by siloxane bonds, High-temperature heating is required to form the coating film, and an ambient temperature higher than the heat resistance of the ALC substrate is required, and the substrate itself cracks.

【0004】また、低温でのシロキサン結合を形成させ
る為に金属アルコキシド系のシリコーン化合物を使用す
ると、基材からのアルカリ溶出が反応を阻害してしまう
為、厳重なアルカリに対するシーリングを必要としてい
た。これらの問題の為に長期耐久性を有するALC素材
に対して、それに見合うだけの耐久性を有する無機塗装
を行う事が適正と思われながら一般的に普及されるに到
ってないのが現状である。
In addition, when a metal alkoxide-based silicone compound is used to form a siloxane bond at a low temperature, the alkali elution from the base material inhibits the reaction, so that strict sealing against the alkali is required. Due to these problems, it is considered that it is appropriate to apply inorganic coatings with the durability corresponding to long-term durability to ALC materials that have long-term durability, but it has not yet come into general use. It is.

【0005】[0005]

【発明が解決しようとする課題】本発明の目的は、高耐
候性、高耐久性を有する(即ち、長期にわたりALC基
材および塗膜に亀裂等の欠陥の生じない)ALCパネル
を提供することである。
SUMMARY OF THE INVENTION It is an object of the present invention to provide an ALC panel having high weather resistance and high durability (that is, no defects such as cracks in the ALC substrate and coating film over a long period of time). It is.

【0006】[0006]

【課題を解決するための手段】即ち本発明は、ALC基
材表面にプライマー層、その上にフィラー層、耐アルカ
リ性無機塗料の塗膜層を設けたことを特徴とするALC
塗装パネル、である。本発明のALCパネルにおいて最
も特徴とする点は、耐アルカリ性能を有する無機塗料の
塗膜層を設けたことである。その耐アルカリ性能を有す
る無機塗料としては、具体的には金属酸化物ゲルとアク
リルウレタンとの複合体である。
That is, the present invention provides an ALC comprising a primer layer on the surface of an ALC substrate, a filler layer and a coating layer of an alkali-resistant inorganic paint on the surface.
Painted panels. The most characteristic feature of the ALC panel of the present invention is that a coating layer of an inorganic paint having alkali resistance is provided. Specifically, the inorganic coating having alkali resistance is a composite of a metal oxide gel and acrylic urethane.

【0007】従来から知られているシラノール基に金属
アルコキシドを反応させる一般の無機塗膜を形成させる
場合には、塗膜形成過程で、高温かつ中性〜酸性の雰囲
気とする必要があった。それに対し、本発明では、金属
酸化物ゲルとアクリルウレタンとの複合体を使用するこ
とにより常温で塗膜を形成することができ、かつ、アル
カリ存在の影響を受けない為、特別なシーラーを使用す
ることなくALCに無機塗装を形成することができる。
In the case of forming a conventional inorganic coating film in which a conventionally known silanol group is reacted with a metal alkoxide, a high-temperature, neutral to acidic atmosphere has to be used during the coating film formation process. On the other hand, in the present invention, a coating film can be formed at room temperature by using a composite of a metal oxide gel and acrylic urethane, and a special sealer is used because it is not affected by the presence of alkali. An inorganic coating can be formed on the ALC without performing the above.

【0008】以下、本発明のALC塗装パネルにおける
無機塗膜層以外の構成について詳細に説明する。本発明
においては、まずALC基材の表面にプライマー層を設
ける。ALC基材のピアノ線切断面に対して密着性を発
現させる為にプライマーを塗布するが、この時、プライ
マーは密着性を高める為のいわば接着剤であり、例えば
アクリルエマルジョン水溶液等が用いられる。
Hereinafter, the structure other than the inorganic coating layer in the ALC coated panel of the present invention will be described in detail. In the present invention, first, a primer layer is provided on the surface of the ALC substrate. A primer is applied to the ALC base material to develop adhesion to the cut surface of the piano wire. At this time, the primer is an adhesive for improving the adhesion, for example, an aqueous acrylic emulsion solution.

【0009】プライマー層の塗膜量は、ALC表面を薄
く覆う程度で充分である為、樹脂エマルションが80w
t%以上の濃度のものであれば50〜200g/m2
適当である。次に、プライマー層の上にフィラー層を設
けるが、フィラー層は、ピアノ線切断面の荒れをならす
為に塗装することから、そのピアノ線切断面の荒れ程度
により、またフィラー中の体質顔料の添加量により、そ
の塗膜量を調整する。
The coating amount of the primer layer is sufficient to cover the ALC surface thinly.
If the concentration is at least t%, 50 to 200 g / m 2 is appropriate. Next, a filler layer is provided on the primer layer. Since the filler layer is applied to smooth the cut surface of the piano wire, the filler pigment is coated depending on the degree of roughness of the cut surface of the piano wire and the filler pigment in the filler. The amount of the coating film is adjusted by the amount added.

【0010】フィラー層における体質顔料の含有量は3
0〜70wt%であり、そのフィラー層の塗膜量は50
0〜2000g/m2 が一般的である。フィラー層は、
アクリル系、エポキシ系またはウレタン系の樹脂をエマ
ルジョンとして塗膜層を形成させたものであるが、それ
には基材からのアルカリ溶出を防ぐ性能をもたせる必要
はない。
[0010] The content of the extender pigment in the filler layer is 3
0 to 70% by weight, and the coating amount of the filler layer is 50%.
0-2000 g / m < 2 > is common. The filler layer is
The coating layer is formed by using an acrylic, epoxy or urethane resin as an emulsion, but it is not necessary to have a function of preventing alkali elution from the base material.

【0011】さらに、フィラー層の上にトップコート層
として前記した無機塗料の塗膜層を設ける。本発明にお
いては、必要に応じてフィラー層の上に着色層を設ける
ことにより光沢を強調することができてより好ましい。
またトップコートとしてクリアの無機塗料を用いて仕上
げることによっても光沢を強調することができてより好
ましい。
Further, a coating layer of the above-mentioned inorganic paint is provided as a top coat layer on the filler layer. In the present invention, it is more preferable to provide a colored layer on the filler layer if necessary, so that the gloss can be enhanced.
It is more preferable that the gloss can be enhanced by finishing with a clear inorganic paint as the top coat.

【0012】さらには、経済性の面からエナメルの無機
塗料を用い、着色層とクリア層を兼ねた1層塗装とする
ことも可能であるが、光沢低下等の外観の低下が起こっ
てしまう場合がある。前記のそれぞれの塗膜を形成させ
る方法としては、一般的に行われている方法でよいが、
常温乾燥だけでなく、ALC基材温度が80℃を越えな
い範囲での加熱であれば、遠赤外線、熱風循環、高周波
加熱等の手段を用いて強制乾燥を行っても良い。
Further, from the viewpoint of economy, it is possible to use an enamel inorganic paint to form a one-layer coating which serves both as a coloring layer and a clear layer. There is. As a method of forming each of the above-mentioned coating films, generally used methods may be used,
As long as the heating is performed not only at room temperature but also in a range where the ALC substrate temperature does not exceed 80 ° C., forced drying may be performed using means such as far infrared rays, hot air circulation, and high frequency heating.

【0013】[0013]

【発明実施の形態】次に、実施例および参考例によって
本発明をさらに詳細に説明する。ここで無機塗料として
使用するものはアクリル酸エステル、ポリイソシアネー
ト化合物、金属酸化物ゲルと反応触媒からなる塗料組性
物である(国際公開WO96/34063)。
Now, the present invention will be described in further detail with reference to Examples and Reference Examples. Here, what is used as the inorganic paint is a paint composition comprising an acrylate, a polyisocyanate compound, a metal oxide gel and a reaction catalyst (WO 96/34063).

【0014】[0014]

【実施例1】以下、図面を参照しながら本発明の具体的
実施例を説明する。図2に本実施例の塗膜層構成を示し
ている。通常の方法により作製されたALCパネルの表
面にプライマー層としてアクリルエマルションプライマ
ーを100g/m2 、その上にフィラー層として体質顔
料60wt%のアクリルエマルジョン系フィラーを12
00g/m2 、その上に着色塗料としてアクリルウレタ
ン系塗料を100g/m2 、さらにクリアの無機塗料1
00g/m2 を各々塗布し、24時間の常温乾燥にて塗
膜を形成させ試験体とした。
Embodiment 1 Hereinafter, a specific embodiment of the present invention will be described with reference to the drawings. FIG. 2 shows the coating layer structure of the present embodiment. 100 g / m 2 of an acrylic emulsion primer as a primer layer on the surface of an ALC panel produced by an ordinary method, and an acrylic emulsion-based filler of extender 60 wt% of 12 wt.
00g / m 2, 100g / m 2 of acrylic urethane paint as colored coating thereon, further clear of inorganic coating 1
00 g / m 2 was applied, and dried at room temperature for 24 hours to form a coating film, which was used as a test specimen.

【0015】[0015]

【実施例2】前記実施例1における着色層を省略し、無
機塗料として着色されたエナメル無機塗料を100g/
2 塗布し、24時間の常温乾燥にて塗膜を形成させ試
験体とした。
Example 2 The colored layer in Example 1 was omitted, and 100 g / color of the colored enamel inorganic paint was used as the inorganic paint.
m 2 was applied and dried at room temperature for 24 hours to form a coating film, which was used as a test specimen.

【0016】[0016]

【比較例1】前記の実施例2と同様にフィラー塗布まで
行い、トップコートとして焼き付け型の無機塗料を使用
し、雰囲気温度120℃、風速1m/秒の熱風循環乾燥
機で1時間静置して試験体を得た。
COMPARATIVE EXAMPLE 1 Filler application was performed in the same manner as in Example 2 above, and a baking type inorganic paint was used as a top coat, and was left standing for 1 hour in a hot air circulating dryer at an atmospheric temperature of 120 ° C. and a wind speed of 1 m / sec. To obtain a test body.

【0017】[0017]

【比較例2】前記の実施例2と同様にフィラー塗布まで
行い、トップコートのみを低温焼き付け型の金属アルコ
キシド系無機塗料を使用し、雰囲気温度100℃、風速
1m/秒の熱風循環乾燥機で30時間静置して試験体を
得た。これらの試験体(前記の実施例および比較例)の
評価結果を表1に示す。
COMPARATIVE EXAMPLE 2 Filler coating was performed in the same manner as in Example 2 described above, and only the top coat was formed using a low-temperature baking type metal alkoxide-based inorganic coating material. The specimen was left standing for 30 hours. Table 1 shows the evaluation results of these test pieces (Examples and Comparative Examples).

【0018】[0018]

【表1】 [Table 1]

【0019】[0019]

【発明の効果】本発明のALC無機塗装パネルにおいて
は、耐アルカリ性を有する無機塗料を使用するためにア
ルカリに対するシーラー処理が不要であり、方法的には
常温で塗膜形成ができるという効果を有し、得られたパ
ネルは高耐候性・高耐久性を有するものである。
The ALC inorganic coating panel of the present invention does not require a sealer treatment against alkali since an inorganic coating having alkali resistance is used, and has an effect that a coating film can be formed at room temperature. The obtained panel has high weather resistance and high durability.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明のALC塗装パネルのピアノ線切断面模
式図。
FIG. 1 is a schematic diagram of a piano wire cut surface of an ALC painted panel of the present invention.

【図2】本発明のALC塗装パネルの塗膜構成を表した
図。
FIG. 2 is a diagram showing a coating film configuration of an ALC coated panel of the present invention.

【符号の説明】[Explanation of symbols]

1 ピアノ線切断面 2 ALC気泡面 3 無機塗装(クリア) 4 着色層 5 フィラー層 6 プライマー 7 ALC基材 DESCRIPTION OF SYMBOLS 1 Piano wire cut surface 2 ALC bubble surface 3 Inorganic paint (clear) 4 Colored layer 5 Filler layer 6 Primer 7 ALC base material

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 ALC基材表面にプライマー層、その上
にフィラー層、耐アルカリ性無機塗料の塗膜層を設けた
ことを特徴とするALC塗装パネル。
1. An ALC coated panel comprising a primer layer on the surface of an ALC substrate, a filler layer thereon, and a coating layer of an alkali-resistant inorganic paint.
【請求項2】 耐アルカリ性無機塗料が金属酸化物ゲル
とアクリルウレタンとの複合体であることを特徴とする
請求項1記載のALC塗装パネル。
2. The ALC coated panel according to claim 1, wherein the alkali-resistant inorganic coating is a composite of a metal oxide gel and acrylic urethane.
【請求項3】 フィラー層と耐アルカリ性無機塗料の塗
膜層との間に着色層を設けたことを特徴とする請求項1
または2記載のALC塗装パネル。
3. A color layer is provided between the filler layer and the coating layer of the alkali-resistant inorganic paint.
Or the ALC coated panel according to 2.
JP11063039A 1999-03-10 1999-03-10 Alc panel with inorganic coating film layer Pending JP2000256080A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11063039A JP2000256080A (en) 1999-03-10 1999-03-10 Alc panel with inorganic coating film layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11063039A JP2000256080A (en) 1999-03-10 1999-03-10 Alc panel with inorganic coating film layer

Publications (1)

Publication Number Publication Date
JP2000256080A true JP2000256080A (en) 2000-09-19

Family

ID=13217806

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11063039A Pending JP2000256080A (en) 1999-03-10 1999-03-10 Alc panel with inorganic coating film layer

Country Status (1)

Country Link
JP (1) JP2000256080A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007331974A (en) * 2006-06-14 2007-12-27 Asahi Kasei Construction Materials Co Ltd Surface-treating method of autoclaved lightweight cellular concrete panel

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996034063A1 (en) * 1995-04-28 1996-10-31 Nof Corporation Coating composition, process for preparing the composition, and process for preparing dispersion of inorganic oxide sol
JPH101377A (en) * 1996-06-13 1998-01-06 Onoda Autoclaved Light Weight Concrete Co Ltd Surface treatment of lightweight cellular concrete panel
JPH1121185A (en) * 1997-06-30 1999-01-26 Sk Kaken Co Ltd Production of alc mirror finished and coated panel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996034063A1 (en) * 1995-04-28 1996-10-31 Nof Corporation Coating composition, process for preparing the composition, and process for preparing dispersion of inorganic oxide sol
JPH101377A (en) * 1996-06-13 1998-01-06 Onoda Autoclaved Light Weight Concrete Co Ltd Surface treatment of lightweight cellular concrete panel
JPH1121185A (en) * 1997-06-30 1999-01-26 Sk Kaken Co Ltd Production of alc mirror finished and coated panel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007331974A (en) * 2006-06-14 2007-12-27 Asahi Kasei Construction Materials Co Ltd Surface-treating method of autoclaved lightweight cellular concrete panel

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