JP2000160083A - Ink composition for jet printing - Google Patents
Ink composition for jet printingInfo
- Publication number
- JP2000160083A JP2000160083A JP33289298A JP33289298A JP2000160083A JP 2000160083 A JP2000160083 A JP 2000160083A JP 33289298 A JP33289298 A JP 33289298A JP 33289298 A JP33289298 A JP 33289298A JP 2000160083 A JP2000160083 A JP 2000160083A
- Authority
- JP
- Japan
- Prior art keywords
- ink composition
- jet printing
- solvent
- weight
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、ジェット印刷用イ
ンク組成物に関し、詳しくは、紫外線を照射すると赤色
に発光し、インクが浸透し易い紙や繊維等の表面に対し
て吸着力が良好なジェット印刷用インク組成物に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an ink composition for jet printing. The present invention relates to an ink composition for jet printing.
【０００２】[0002]
【従来の技術】従来よりジェット印刷用インクとして
は、酸性染料、直接染料、塩基性染料等の水溶性染料を
グリコール系溶剤と水に溶解したもの、あるいは、油溶
性染料を高沸点溶剤に分散ないし溶解したもの、油溶性
染料を揮発性の溶剤に溶解したものがあった。2. Description of the Related Art Conventionally, jet printing inks have been prepared by dissolving a water-soluble dye such as an acid dye, a direct dye or a basic dye in a glycol solvent and water, or dispersing an oil-soluble dye in a high boiling point solvent. And those in which the oil-soluble dye was dissolved in a volatile solvent.
【０００３】[0003]
【発明が解決しようとする課題】しかし、このようなジ
ェット印刷用インク組成物において、紫外光の照射によ
り印刷物を発光させ可視化できるものを調製すること
は、種々の制約のため困難であった。However, it has been difficult to prepare such a jet printing ink composition that can emit and visualize a printed matter by irradiation with ultraviolet light because of various restrictions.
【０００４】また、従来より種々の特殊用途において
は、通常の光では確認しにくいが、特殊な光によって可
視化したり、センサーでの読み取りを可能にするインキ
が開発され、蛍光増白剤のように紫色に発光するものが
用いられていた。しかし、このような蛍光増白剤は、
紙、繊維等にも広く用いられているため、それらの発光
との区別を付けにくいという欠点もあった。Conventionally, in various special applications, it has been difficult to confirm with ordinary light, but an ink has been developed which can be visualized by special light or read by a sensor. Those that emit purple light were used. However, such optical brighteners are
Since it is widely used for paper, fiber, and the like, it has a drawback that it is difficult to distinguish it from the light emission.
【０００５】また更に、蛍光染料を樹脂で粒子化した蛍
光顔料もあり、これは蛍光染料を樹脂等と混合したもの
であり、有機溶剤を用いると溶解して染料のように使用
できるものであった。しかし、蛍光顔料は可視域にも吸
収を有しており、蛍光を当てないときにも表示した文
字、図形を人が目視で確認できるため、いわゆる目隠し
インキの材料の用途には用いることができなかった。Further, there is a fluorescent pigment in which a fluorescent dye is made into particles with a resin, which is a mixture of the fluorescent dye with a resin or the like, and which can be dissolved and used like a dye by using an organic solvent. Was. However, fluorescent pigments also have an absorption in the visible range, and can be used for so-called blindfold ink materials because humans can visually check the displayed characters and graphics even when fluorescent light is not applied. Did not.
【０００６】従って、本発明の目的は、紫外線（２５４
〜３９０ｎｍ）を照射すると赤色（６００〜６５０ｎ
ｍ）に発光し、吸収され易い紙や繊維等の表面、特に墨
を塗布した表面に吸着し、良好な目視可能な発光強度が
得られ、紫外線照射なしの白昼光下では目視不可能なジ
ェット印刷用インク組成物を提供することである。Accordingly, it is an object of the present invention to provide an ultraviolet (254)
To 390 nm), it is red (600 to 650 n)
m) is a jet that emits light and is easily absorbed, and is adsorbed on the surface of paper or fiber, particularly on the surface coated with black ink, and has a good visible emission intensity, and is invisible under daylight without ultraviolet irradiation. An object of the present invention is to provide a printing ink composition.
【０００７】[0007]
【課題を解決するための手段】本発明は、下記式Means for Solving the Problems The present invention provides the following formula:
【０００８】[0008]
【化２】 で示される蛍光材料の含有量が０．００１〜５．０重量
％であり、溶剤としてアルコール系溶剤を７０重量％以
上含有することを特徴とするジェット印刷用インク組成
物である。Embedded image Wherein the content of the fluorescent material represented by is 0.001 to 5.0% by weight, and the solvent contains an alcohol-based solvent as a solvent in an amount of 70% by weight or more.
【０００９】上記構成により、紫外線を照射した場合の
み印刷部を赤色に発光させることができる。According to the above configuration, the printed portion can emit red light only when irradiated with ultraviolet rays.
【００１０】[0010]
【発明の実施の形態】以下に、本発明を詳細に説明す
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.
【００１１】本発明に用いられる下記式The following formula used in the present invention:
【００１２】[0012]
【化３】 で示される蛍光材料は、２５４〜３９０ｎｍの紫外線を
照射すると６００〜６５０ｎｍの赤色に発光するが、紫
外線を照射しないときは発光しないため目視識別が容易
ではなく、いわゆる目隠しインキの材料として有用であ
る。該蛍光材料は、４，４，４−トリフルオロ−１−
（２−チエニル）−１，３−ブタンジオナート・ユーロ
ピウムキレート化合物であり、可視光のもとでは発光せ
ず紫外光のもとでは赤色に発光する特性を有しており、
発光強度が大きく、また、耐光性等にも優れている。該
蛍光材料は、水に対する溶解性はほとんどなく、インク
化することは難しく、また、アルコール系溶剤以外の揮
発性を有するケトン系溶剤等には可溶で、印刷物中に浸
透して印刷表面に蛍光材料が付着しにくいが、アルコー
ル系溶剤中では極めて微分散（１〜１００ｎｍの粒径）
するため、印刷されたインクは印刷物中に浸透しにく
く、印刷物表面に蛍光材料が付着し、印刷物表面、特に
墨面上での発光強度が大きい。Embedded image The fluorescent material represented by the formula (1) emits red light of 600 to 650 nm when irradiated with ultraviolet light of 254 to 390 nm, but does not emit light when not irradiated with ultraviolet light, so that it is not easy to visually discriminate and is useful as a material of so-called blinding ink. . The fluorescent material is 4,4,4-trifluoro-1-
(2-thienyl) -1,3-butanedionate europium chelate compound, which does not emit light under visible light but emits red light under ultraviolet light,
The emission intensity is high and the light resistance is excellent. The fluorescent material has almost no solubility in water, is difficult to form an ink, and is soluble in a volatile ketone-based solvent other than the alcohol-based solvent, and penetrates into the printed material to penetrate the printed surface. Fluorescent material does not easily adhere, but is extremely finely dispersed in alcoholic solvents (particle size of 1 to 100 nm)
Therefore, the printed ink hardly penetrates into the printed matter, the fluorescent material adheres to the printed matter surface, and the emission intensity on the printed matter surface, especially on the black surface, is large.
【００１３】本発明では、該蛍光材料を記録液中に０．
００１〜５．０重量％、好ましくは０．０１〜３．０重
量％用いることにより隠し印字物としての所望の検知が
良好にできる。０．００１重量％よりも少ないと発光量
が少なくなり、発光の読み取りが難しくなり、また、
５．０重量％よりも多いと自己吸収が生じて発光強度が
低くなる。According to the present invention, the fluorescent material is added to a recording liquid in an amount of 0.1%.
By using 001 to 5.0% by weight, preferably 0.01 to 3.0% by weight, desired detection as a hidden printed matter can be favorably performed. If the amount is less than 0.001% by weight, the amount of light emission decreases, making it difficult to read light emission.
If the content is more than 5.0% by weight, self-absorption occurs and the emission intensity decreases.
【００１４】溶剤としては、該蛍光材料の分散性に優れ
るメタノール、エタノール、プロパノール等のアルコー
ル系溶剤が用いられる。溶剤は７０重量％以上、好まし
くは８０重量％以上含有させる。溶剤が７０重量％未満
であると、染料が分散または溶解しない。As the solvent, an alcoholic solvent such as methanol, ethanol and propanol which is excellent in dispersibility of the fluorescent material is used. The solvent is contained in an amount of 70% by weight or more, preferably 80% by weight or more. If the solvent is less than 70% by weight, the dye will not be dispersed or dissolved.
【００１５】本発明のジェット印刷用インク組成物は、
溶剤の種類、バインダーの使用の有無、種類、量等を選
択し、粘度、表面張力、電導度、乾燥性等を調節するこ
とによって、種々のプリンターや種々の被印刷体に適用
させることができる。ジェット印刷用インク組成物の特
性としては、プリンターによって適性が異なるが、一般
に粘度０．８〜１５ｍＰａ・ｓ、表面張力２０〜６０ｄ
ｙｎ／ｃｍが好ましい。紙等の浸透性の被印刷体を対象
とするときは、下記のようなインク組成物を用いること
が好ましい。即ち、本発明の蛍光材料、溶剤、必要に応
じ、バインダー成分、添加剤等を溶解してインク組成物
を調製する。The ink composition for jet printing of the present invention comprises:
It can be applied to various printers and various printing media by selecting the type of solvent, the use or non-use of binder, the type, the amount, etc., and adjusting the viscosity, surface tension, conductivity, drying property, etc. . As the properties of the ink composition for jet printing, suitability varies depending on the printer, but in general, the viscosity is 0.8 to 15 mPa · s, and the surface tension is 20 to 60 d.
yn / cm is preferred. When a permeable printing material such as paper is targeted, it is preferable to use the following ink composition. That is, an ink composition is prepared by dissolving the fluorescent material of the present invention, a solvent, and, if necessary, a binder component and an additive.
【００１６】バインダー成分は蛍光材料を良好に定着さ
せるためのものであり、上記溶剤に対する溶解性が良好
であり、インク組成物の粘度を適度に調整できるものと
して、以下のような樹脂を挙げることができる。即ち、
塩化ビニル−酢酸ビニル共重合体、ポリ塩化ビニリデ
ン、ポリビニルピロリドン系、セルロース系、石油樹脂
系、フェノール樹脂系、エポキシ系、エポキシフェノー
ル系、アクリル系、スチレン−アクリル系、ポリエステ
ル系、ポリアミド系、ポリウレタン系、ブチラール系、
シリコン系、ロジン、ロジン変性樹脂（フェノール、マ
レイン酸、フマル酸樹脂等）、ゴム系、アクリルアミド
系、アルキッド系、シェラック系等の上記溶剤に溶解す
る溶解性の樹脂が用いられる。これらの樹脂は、非浸透
性の被印刷体に対して印刷を行う時に必要となるもので
あり、インク組成物中に好ましくは０．５〜１０重量
％、より好ましくは１〜５重量％用いる。０．５重量％
よりも少ないと非浸透性の被印刷体に対して蛍光材料を
十分に定着することが難しくなる。また、１０重量％よ
りも多くなると、インク組成物の吐出安定性を低下させ
ることがある。また、蛍光材料の周囲を樹脂層が厚く覆
うことになり、蛍光材料の発光の低下を招く恐れがあ
る。The binder component is for fixing the fluorescent material well, has good solubility in the above-mentioned solvent, and can appropriately adjust the viscosity of the ink composition. Can be. That is,
Vinyl chloride-vinyl acetate copolymer, polyvinylidene chloride, polyvinylpyrrolidone, cellulose, petroleum resin, phenol resin, epoxy, epoxy phenol, acrylic, styrene-acryl, polyester, polyamide, polyurethane System, butyral system,
Soluble resins that dissolve in the above solvents, such as silicon-based, rosin, rosin-modified resins (phenol, maleic acid, fumaric acid resins, etc.), rubber-based, acrylamide-based, alkyd-based, and shellac-based resins are used. These resins are required when printing on a non-permeable print medium, and are preferably used in the ink composition in an amount of 0.5 to 10% by weight, more preferably 1 to 5% by weight. . 0.5% by weight
If the amount is smaller than this, it becomes difficult to sufficiently fix the fluorescent material to the impermeable printing medium. If the content is more than 10% by weight, the ejection stability of the ink composition may be reduced. In addition, since the resin layer thickly covers the periphery of the fluorescent material, the light emission of the fluorescent material may be reduced.
【００１７】本発明に使用する溶剤としては、インク組
成物のノズル部分での乾燥、インク組成物の固化を防止
し、安定なインク組成物の噴射及びノズルの経時での乾
燥を防止するものとして下記のような溶剤を加えて用い
ることもできる。このような溶剤としては、エチレング
リコール、ジエチレングリコール、プロピレングリコー
ル、トリエチレングリコール、ポリエチレングリコー
ル、グリセリン、テトラエチレングリコール、ジプロピ
レングリコール、ケトンアルコール類、ジエチレングリ
コールモノブチルエーテル、エチレングリコールモノブ
チルエーテル、エチレングリコールモノエチルエーテ
ル、１，２−ヘキサンジオール、置換ピロリドン、２，
４，６−ヘキサントリオール、テトラフルフリルアルコ
ール、４−メトキシ−４−メチルペンタノン等を例示で
きる。これらの溶剤は、単独ないし混合してインク組成
物の０〜５０重量％の範囲で用いることが好ましい。The solvent used in the present invention is one that prevents drying of the ink composition at the nozzle portion, solidification of the ink composition, stable ejection of the ink composition, and drying of the nozzle over time. The following solvents can be added for use. Examples of such a solvent include ethylene glycol, diethylene glycol, propylene glycol, triethylene glycol, polyethylene glycol, glycerin, tetraethylene glycol, dipropylene glycol, ketone alcohols, diethylene glycol monobutyl ether, ethylene glycol monobutyl ether, and ethylene glycol monoethyl ether. , 1,2-hexanediol, substituted pyrrolidone, 2,
Examples thereof include 4,6-hexanetriol, tetrafurfuryl alcohol, 4-methoxy-4-methylpentanone and the like. These solvents are preferably used alone or as a mixture in the range of 0 to 50% by weight of the ink composition.
【００１８】また、インク組成物の循環、あるいは、移
動、また、インク組成物の製造時の泡の発生を防止する
ため消泡剤を添加することもできる。インク組成物の吐
出安定性、記録画像の向上のため、以下のような界面活
性剤を加えて用いることもできる。このような界面活性
剤としては、アニオン性、非イオン性、カチオン性、両
イオン性活性剤を用いることができる。In addition, an antifoaming agent may be added to prevent circulation or movement of the ink composition, and to prevent foaming during the production of the ink composition. In order to improve the ejection stability of the ink composition and the recorded image, the following surfactants can be added for use. As such a surfactant, an anionic, nonionic, cationic, or amphoteric surfactant can be used.
【００１９】インク組成物の製造については、蛍光材
料、溶剤、必要に応じ樹脂、添加剤等を混合し、攪拌し
て溶解し、必要に応じて希釈、他の添加剤を混合してイ
ンク組成物を調製する。混合攪拌は、通常の攪拌羽根を
用いた攪拌機による攪拌の他、高速の分散機、乳化機等
により行うこともできる。混合されたインク組成物は、
希釈の前あるいは後で孔径３μｍ以下のフィルターによ
り十分濾過する。好ましくは、１．０μｍ以下のフルタ
ーで濾過する。フィルターの濾過に先立って、遠心分離
による濾過を用いることもでき、これによりフィルター
による濾過における目詰まりを少なくし、フィルター使
用可能期間を長くできる。For the production of the ink composition, a fluorescent material, a solvent, a resin, an additive and the like are mixed as needed, dissolved by stirring, and diluted if necessary, and other additives are mixed with the ink composition. Prepare the product. Mixing and stirring can be performed by a high-speed disperser, emulsifier, or the like, in addition to stirring by a stirrer using ordinary stirring blades. The mixed ink composition is
Before or after dilution, the mixture is sufficiently filtered with a filter having a pore size of 3 μm or less. Preferably, it is filtered with a filter having a size of 1.0 μm or less. Prior to filtration of the filter, filtration by centrifugation can be used, whereby clogging in filtration by the filter can be reduced, and the filter life can be extended.
【００２０】本発明により製造されるインク組成物は、
紙や繊維に対する吸着性が著しく良好であるのでジェッ
ト印刷用インク組成物として好適に用いられ、オフィス
における書類、各種容器のマーキング、ナンバリング、
バーコード等の目隠し印刷、セキュリティー機能を有す
る印刷物の分野にて利用することができる。The ink composition produced according to the present invention comprises:
It is used as an ink composition for jet printing because it has extremely good adsorptivity to paper and fibers.Documents in offices, marking of various containers, numbering,
It can be used in the field of blind printing of barcodes and the like and printed matter having a security function.
【００２１】本発明で使用することのできる上記の電導
度調整剤としては、硝酸リチウム、亜硝酸リチウム、亜
硝酸アンモニウム、蟻酸アンモニウム、酢酸アンモニウ
ム、ハロゲン化リチウム、チオシアン酸ソーダ等を挙げ
ることができる。更に、本発明で使用することのできる
上記の界面活性剤、紫外線吸収剤、消泡剤、分散剤、防
腐剤は、ジェット印刷用インク組成物に通常に用いられ
ているものである。本発明のジェット印刷用インク組成
物はそれらの添加剤をインク組成物の０．１〜５重量％
の量で含有することができる。Examples of the above-mentioned conductivity adjusting agent that can be used in the present invention include lithium nitrate, lithium nitrite, ammonium nitrite, ammonium formate, ammonium acetate, lithium halide, sodium thiocyanate and the like. Furthermore, the above-mentioned surfactants, ultraviolet absorbers, defoamers, dispersants, and preservatives that can be used in the present invention are those commonly used in ink compositions for jet printing. The ink composition for jet printing according to the present invention may contain these additives in an amount of 0.1 to 5% by weight of the ink composition.
In an amount of
【００２２】[0022]
【実施例】以下、実施例に基づき、本発明を更に詳細に
説明する。実施例中、部及び％は、重量部及び重量％を
それぞれ表す。The present invention will be described in more detail with reference to the following examples. In the examples, parts and% represent parts by weight and% by weight, respectively.
【００２３】〔実施例１〜３及び比較例１〜３〕以下の
表１に記載の原料を混合し、ジェット印刷用インク組成
物を作製し、墨の上での発光強度試験を行った。結果を
表１に示す。なお、表中の数値は、重量％である。[Examples 1 to 3 and Comparative Examples 1 to 3] The raw materials described in Table 1 below were mixed to prepare an ink composition for jet printing, and a luminescence intensity test was performed on black ink. Table 1 shows the results. The numerical values in the table are% by weight.
【００２４】[0024]
【表１】 [Table 1]
【００２５】蛍光染料Ａ：トリ−４，４，４−トリフル
オロ−１−（２−チオニル）−１，３−ブタンジオナー
ト・ユーロピウムキレート化合物 蛍光染料Ｂ：テトラ−ｎ−ブチルアンモニウム塩を対イ
オンに有するテトラ−４，４，４−トリフルオロ−１−
（２−チエニル）−１，３−ブタンジオナート・ユーロ
ピウム錯体 アクリル樹脂Ｃ：ＮｅｏＣｒｙｌＢ−８１７（カネカ社
製商品名；分子量約２０，０００、酸化５９９） ポリアミド樹脂Ｄ：ＧＡＸ１１−９６６（ヘンケル白水
社製商品名；分子量約９，０００） ポリビニルピロリドンＥ：ＰＶＰＫ−１５（ＩＳＰ社製
商品名；分子量約８，０００）Fluorescent dye A: tri-4,4,4-trifluoro-1- (2-thionyl) -1,3-butanedionate europium chelate compound Fluorescent dye B: tetra-n-butylammonium salt Tetra-4,4,4-trifluoro-1- having ion
(2-thienyl) -1,3-butanedionate europium complex Acrylic resin C: NeoCrylB-817 (trade name, manufactured by Kaneka Corporation; molecular weight: about 20,000, oxidation: 599) Polyamide resin D: GAX11-966 (Henkel Hakusuisha) Polyvinylpyrrolidone E: PVPK-15 (trade name, manufactured by ISP; molecular weight: about 8,000)
【００２６】＜墨の上での発光強度試験＞印刷物に紫外
線を照射し、紙に塗った墨の上の発光状態を目視で比較
確認した。<Luminescence intensity test on black ink> The printed matter was irradiated with ultraviolet rays, and the luminous state on the black ink applied to the paper was visually compared and confirmed.
【００２７】表１の結果より明らかなように、本発明の
ジェット印刷用インク組成物を用いた実施例１〜３は、
墨の上での発光強度が大であった。これに対して、本発
明の蛍光材料を用いずにテトラ−ｎ−ブチルアンモニウ
ム塩を対イオンに有するテトラ−４，４，４−トリフル
オロ−１−（２−チエニル）−１，３−ブタンジオナー
ト・ユーロピウム錯体を用いた比較例１及び３、アルコ
ール系以外の溶剤を用いた比較例２は、墨の上での発光
強度が小であった。As is clear from the results shown in Table 1, Examples 1 to 3 using the ink composition for jet printing of the present invention were:
The light emission intensity on the ink was large. In contrast, tetra-4,4,4-trifluoro-1- (2-thienyl) -1,3-butane having a tetra-n-butylammonium salt as a counter ion without using the fluorescent material of the present invention. In Comparative Examples 1 and 3 using the dionate europium complex and Comparative Example 2 using a solvent other than the alcohol-based solvent, the emission intensity on black was small.
【００２８】[0028]
【発明の効果】本発明によれば、微分散性に優れた吐出
安定性の良いジェット印刷用インク組成物を得ることが
できる。According to the present invention, it is possible to obtain an ink composition for jet printing which has excellent fine dispersion and good ejection stability.
【００２９】この印刷物は、紙等の下地と識別しにくい
印刷を行うことが可能であり、また、紫外光により赤色
の発光を生じるので特殊な印刷物としてセンサーでの読
み取り、隠し文字、セキュリティーに関する印刷等に適
用できる。This printed material can be printed so that it is difficult to discriminate it from a base such as paper. In addition, since red light is emitted by ultraviolet light, reading with a sensor, hidden characters, and printing related to security are performed as a special printed material. And so on.
フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） // Ｃ０９Ｄ 5/22 Ｂ４１Ｊ 3/04 １０１Ｙ (72)発明者 城田 常雄 神奈川県横浜市南区中里１−18−３ ベル シェ31 102号 Ｆターム(参考） 2C056 FC01 FD07 2H086 BA01 BA52 BA54 BA56 BA62 4J038 BA021 BA231 CA001 CC051 CD061 CD081 CE071 CG141 CG171 CK031 CR011 DA031 DB001 DB461 DD001 DD231 DG001 DH001 DL031 JA20 JA21 JA27 JA33 JB27 JC38 KA06 KA12 NA19 PB11 PC10 4J039 AB02 AB08 AD03 AD04 AD05 AD07 AD08 AD09 AD11 AD18 AD20 AE02 AE04 AE05 AE06 AE08 AE11 AF01 BC07 BC09 BC10 BC11 BC14 BC15 BC16 BC31 BC50 BE02 BE12 CA02 EA15 EA28 EA43 GA24 Continuation of the front page (51) Int.Cl. 7 Identification symbol FI Theme coat II (reference) // C09D 5/22 B41J 3/04 101Y (72) Inventor Tsuneo Shirota 1-18-3 Nakazato, Minami-ku, Yokohama-shi, Kanagawa Belcher 31 102 No.F term (reference) 2C056 FC01 FD07 2H086 BA01 BA52 BA54 BA56 BA62 4J038 BA021 BA231 CA001 CC051 CD061 CD081 CE071 CG141 CG171 CK031 CR011 DA031 DB001 DB461 DD001 DD231 DG001 DH001 DL27 JA10 JA20 JA27 4J039 AB02 AB08 AD03 AD04 AD05 AD07 AD08 AD09 AD11 AD18 AD20 AE02 AE04 AE05 AE06 AE08 AE11 AF01 BC07 BC09 BC10 BC11 BC14 BC15 BC16 BC31 BC50 BE02 BE12 CA02 EA15 EA28 EA43 GA24
Claims (1)
％であり、溶剤としてアルコール系溶剤を７０重量％以
上含有することを特徴とするジェット印刷用インク組成
物。[Claim 1] The following formula: The ink composition for jet printing, wherein the content of the fluorescent material represented by the formula (1) is 0.001 to 5.0% by weight, and the solvent contains an alcohol-based solvent in an amount of 70% by weight or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33289298A JP2000160083A (en) | 1998-11-24 | 1998-11-24 | Ink composition for jet printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33289298A JP2000160083A (en) | 1998-11-24 | 1998-11-24 | Ink composition for jet printing |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007334334A Division JP5008546B2 (en) | 2007-12-26 | 2007-12-26 | Ink composition for jet printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000160083A true JP2000160083A (en) | 2000-06-13 |
Family
ID=18259977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33289298A Pending JP2000160083A (en) | 1998-11-24 | 1998-11-24 | Ink composition for jet printing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000160083A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1288268A1 (en) * | 2001-08-31 | 2003-03-05 | Orient Chemical Industries, Ltd. | Blue luminous ink composition |
| JP2003081983A (en) * | 2001-09-13 | 2003-03-19 | Orient Chem Ind Ltd | Light-generating organic compound |
| WO2003067679A1 (en) * | 2002-02-08 | 2003-08-14 | Elam-T Limited | Method for forming electroluminescent devices |
| EP2087051A1 (en) * | 2006-11-28 | 2009-08-12 | Imaje S.A. | Fluorescent liquid ink composition for inkjet printing |
| US7618555B2 (en) | 2006-04-06 | 2009-11-17 | Orient Chemical Industries, Ltd. | Ink composition containing red luminous material |
| JP2013203801A (en) * | 2012-03-27 | 2013-10-07 | Toyo Seikan Co Ltd | Ink composition for inkjet printing viewable by ultraviolet irradiation, and container with hidden mark |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53140105A (en) * | 1977-05-12 | 1978-12-06 | Dainippon Toryo Kk | Jet printing aqueous ink visually recognized by ultraviolet ray radiation |
| JPS6426583A (en) * | 1987-07-21 | 1989-01-27 | Mitsui Toatsu Chemicals | Luminescent compound and ink composition and polymer composition containing said compound |
| JPH04220395A (en) * | 1990-03-13 | 1992-08-11 | Eastman Kodak Co | Thermally transferable fluorescent europium complex |
| JPH08239609A (en) * | 1995-03-03 | 1996-09-17 | Toyo Ink Mfg Co Ltd | Recording fluid |
| JPH09188835A (en) * | 1996-01-11 | 1997-07-22 | The Inctec Inc | Fluorescent ink and preparation of fluorescent print |
| JPH10287043A (en) * | 1997-04-16 | 1998-10-27 | Dainippon Toryo Co Ltd | Ink for jet printing and method for visual confirmation of hidden symbol, etc. |
-
1998
- 1998-11-24 JP JP33289298A patent/JP2000160083A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53140105A (en) * | 1977-05-12 | 1978-12-06 | Dainippon Toryo Kk | Jet printing aqueous ink visually recognized by ultraviolet ray radiation |
| JPS6426583A (en) * | 1987-07-21 | 1989-01-27 | Mitsui Toatsu Chemicals | Luminescent compound and ink composition and polymer composition containing said compound |
| JPH04220395A (en) * | 1990-03-13 | 1992-08-11 | Eastman Kodak Co | Thermally transferable fluorescent europium complex |
| JPH08239609A (en) * | 1995-03-03 | 1996-09-17 | Toyo Ink Mfg Co Ltd | Recording fluid |
| JPH09188835A (en) * | 1996-01-11 | 1997-07-22 | The Inctec Inc | Fluorescent ink and preparation of fluorescent print |
| JPH10287043A (en) * | 1997-04-16 | 1998-10-27 | Dainippon Toryo Co Ltd | Ink for jet printing and method for visual confirmation of hidden symbol, etc. |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1288268A1 (en) * | 2001-08-31 | 2003-03-05 | Orient Chemical Industries, Ltd. | Blue luminous ink composition |
| US6743283B2 (en) | 2001-08-31 | 2004-06-01 | Orient Chemical Industries, Ltd. | Blue luminous ink composition |
| JP2003081983A (en) * | 2001-09-13 | 2003-03-19 | Orient Chem Ind Ltd | Light-generating organic compound |
| WO2003067679A1 (en) * | 2002-02-08 | 2003-08-14 | Elam-T Limited | Method for forming electroluminescent devices |
| US7618555B2 (en) | 2006-04-06 | 2009-11-17 | Orient Chemical Industries, Ltd. | Ink composition containing red luminous material |
| EP2087051A1 (en) * | 2006-11-28 | 2009-08-12 | Imaje S.A. | Fluorescent liquid ink composition for inkjet printing |
| JP2010511069A (en) * | 2006-11-28 | 2010-04-08 | マーケム−イマージュ | Fluorescent liquid ink composition for inkjet printing |
| JP2013203801A (en) * | 2012-03-27 | 2013-10-07 | Toyo Seikan Co Ltd | Ink composition for inkjet printing viewable by ultraviolet irradiation, and container with hidden mark |
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