JP2000119004A5 - - Google Patents

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Publication number
JP2000119004A5
JP2000119004A5 JP1998287649A JP28764998A JP2000119004A5 JP 2000119004 A5 JP2000119004 A5 JP 2000119004A5 JP 1998287649 A JP1998287649 A JP 1998287649A JP 28764998 A JP28764998 A JP 28764998A JP 2000119004 A5 JP2000119004 A5 JP 2000119004A5
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JP
Japan
Prior art keywords
reaction chamber
valve provided
shut
reformed gas
upstream side
Prior art date
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Granted
Application number
JP1998287649A
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Japanese (ja)
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JP2000119004A (en
JP4089039B2 (en
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Priority to JP28764998A priority Critical patent/JP4089039B2/en
Priority claimed from JP28764998A external-priority patent/JP4089039B2/en
Priority to DE69924682T priority patent/DE69924682T2/en
Priority to US09/392,691 priority patent/US6562088B2/en
Priority to EP99307162A priority patent/EP0985635B1/en
Publication of JP2000119004A publication Critical patent/JP2000119004A/en
Publication of JP2000119004A5 publication Critical patent/JP2000119004A5/ja
Application granted granted Critical
Publication of JP4089039B2 publication Critical patent/JP4089039B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

従来の方法では、変成部の反応器が大きくなるとともに、運転の停止、作動を繰り返すような用途では、上述の課題があった。本発明は、このような水素精製装置の課題を考慮し、小さな容積の変成部でも高い性能をもつと同時に、装置の運転停止、作動を繰り返した場合の酸素混入による影響を抑制し、長期間にわたって安定に動作する水素精製装置を提供することを目的とする。 In the conventional method, the reactor of the metamorphic part becomes large, and there is the above-mentioned problem in the application where the operation is repeatedly stopped and operated. In consideration of such a problem of the hydrogen purification apparatus, the present invention has high performance even in a metamorphic part having a small volume, and at the same time, suppresses the influence of oxygen mixing when the apparatus is repeatedly stopped and operated for a long period of time. It is an object of the present invention to provide a hydrogen purification apparatus that operates stably over a period of time.

【0006】
【課題を解決するための手段】
上記課題を解決するために本発明の水素精製装置は、水素ガスと一酸化炭素と水蒸気とを少なくとも含有する改質ガスの供給部と、前記改質ガスの供給部の下流側に銅系の変成触媒体を具備した反応室と、前記反応室の上流側および下流側の少なくとも一方に遮断弁
と、前記反応室の上流側に設けられた遮断弁の下流側に、前記反応室の下流側に設けられた遮断弁の上流側に、または前記反応室の上流側に設けられた遮断弁および前記反応室の下流側に設けられた遮断弁の間に存在する前記反応室を含む経路より圧力を加えるための圧力制御手段とを備えたことを特徴とする。
0006
[Means for solving problems]
In order to solve the above problems, the hydrogen purification apparatus of the present invention has a copper-based supply unit for a reformed gas containing at least hydrogen gas, carbon monoxide and water vapor, and a copper-based system downstream of the reformed gas supply unit. A reaction chamber equipped with a reformed catalyst and a shutoff valve on at least one of the upstream side and the downstream side of the reaction chamber.
And the shutoff valve provided on the downstream side of the shutoff valve provided on the upstream side of the reaction chamber, on the upstream side of the shutoff valve provided on the downstream side of the reaction chamber, or on the upstream side of the reaction chamber. It is characterized by being provided with a pressure control means for applying pressure from a path including the reaction chamber existing between shutoff valves provided on the downstream side of the reaction chamber.

また、本発明の水素精製装置は、改質ガスの供給部が、改質ガスを発生する改質部であり、前記反応室の上流側に設けられた遮断弁とは、前記改質部の入口に設けられた遮断弁であることを特徴とする。 Further, in the hydrogen purification apparatus of the present invention, the reforming gas supply unit is a reforming unit that generates the reformed gas, and the shutoff valve provided on the upstream side of the reaction chamber is the reforming unit. It is characterized by being a shutoff valve provided at the inlet.

Claims (2)

水素ガスと一酸化炭素と水蒸気とを少なくとも含有する改質ガスの供給部と、前記改質ガスの供給部の下流側に銅系の変成触媒体を具備した反応室と、前記反応室の上流側および下流側の少なくとも一方に遮断弁と、前記反応室の上流側に設けられた遮断弁の下流側に、前記反応室の下流側に設けられた遮断弁の上流側に、または前記反応室の上流側に設けられた遮断弁および前記反応室の下流側に設けられた遮断弁の間に存在する前記反応室を含む経路より圧力を加えるための圧力制御手段とを備えたことを特徴とする水素精製装置。A reformed gas supply unit containing at least hydrogen gas, carbon monoxide, and water vapor; a reaction chamber having a copper-based shift catalyst body downstream of the reformed gas supply unit; and an upstream of the reaction chamber A shut-off valve on at least one of the side and the downstream side, on the downstream side of the shut-off valve provided on the upstream side of the reaction chamber, on the upstream side of the shut-off valve provided on the downstream side of the reaction chamber, or on the reaction chamber And a pressure control means for applying pressure from a path including the reaction chamber existing between a shut-off valve provided on the upstream side of the reaction chamber and a shut-off valve provided on the downstream side of the reaction chamber. Hydrogen purification equipment to do. 前記改質ガスの供給部が、改質ガスを発生する改質部であり、前記反応室の上流側に設けられた遮断弁とは、前記改質部の入口に設けられた遮断弁であることを特徴とする請求項記載の水素精製装置。 The reformed gas supply unit is a reforming unit that generates reformed gas, and the shutoff valve provided on the upstream side of the reaction chamber is a shutoff valve provided at the inlet of the reforming unit. The hydrogen purifier according to claim 1 .
JP28764998A 1998-09-09 1998-10-09 Hydrogen purification equipment Expired - Lifetime JP4089039B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP28764998A JP4089039B2 (en) 1998-10-09 1998-10-09 Hydrogen purification equipment
DE69924682T DE69924682T2 (en) 1998-09-09 1999-09-09 Apparatus for producing hydrogen
US09/392,691 US6562088B2 (en) 1998-09-09 1999-09-09 Method for operating a hydrogen generating apparatus
EP99307162A EP0985635B1 (en) 1998-09-09 1999-09-09 Hydrogen generating apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28764998A JP4089039B2 (en) 1998-10-09 1998-10-09 Hydrogen purification equipment

Publications (3)

Publication Number Publication Date
JP2000119004A JP2000119004A (en) 2000-04-25
JP2000119004A5 true JP2000119004A5 (en) 2005-09-15
JP4089039B2 JP4089039B2 (en) 2008-05-21

Family

ID=17719950

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28764998A Expired - Lifetime JP4089039B2 (en) 1998-09-09 1998-10-09 Hydrogen purification equipment

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JP (1) JP4089039B2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2336847C (en) * 1999-03-18 2005-08-02 Matsushita Electric Works, Ltd. Catalyst for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell
WO2001047802A1 (en) 1999-12-28 2001-07-05 Matsushita Electric Industrial Co., Ltd. Apparatus for forming hydrogen
JP4810749B2 (en) * 2000-06-08 2011-11-09 トヨタ自動車株式会社 Fuel reformer
CN1209279C (en) 2000-08-18 2005-07-06 松下电器产业株式会社 Hydrogen purification apparatus
JP4663095B2 (en) * 2000-10-23 2011-03-30 パナソニック株式会社 Hydrogen purification equipment
JP2002226204A (en) * 2001-01-26 2002-08-14 Matsushita Electric Ind Co Ltd Hydrogen purification unit
US20030086852A1 (en) * 2001-10-15 2003-05-08 Ballard Generation Systems Inc. Apparatus for the selective oxidation of carbon monoxide in a hydrogen-containing gas mixture
JP2005067990A (en) * 2003-08-28 2005-03-17 Mitsubishi Heavy Ind Ltd Evaporator for reforming raw material
CN101111961B (en) 2005-01-31 2010-07-21 松下电器产业株式会社 Fuel cell power generation system, and method for operating fuel cell power generation system
KR100857703B1 (en) * 2007-03-29 2008-09-08 삼성에스디아이 주식회사 Reaction vessel and reaction device
US8221511B2 (en) 2007-05-31 2012-07-17 Panasonic Corporation Hydrogen producing apparatus
DE102007026712A1 (en) 2007-06-06 2008-12-11 Uhde Gmbh Apparatus and method for catalytic gas phase reactions and their use

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