JP2000043218A5 - Cosmetic material and transfer sheet - Google Patents
Cosmetic material and transfer sheet Download PDFInfo
- Publication number
- JP2000043218A5 JP2000043218A5 JP1998214997A JP21499798A JP2000043218A5 JP 2000043218 A5 JP2000043218 A5 JP 2000043218A5 JP 1998214997 A JP1998214997 A JP 1998214997A JP 21499798 A JP21499798 A JP 21499798A JP 2000043218 A5 JP2000043218 A5 JP 2000043218A5
- Authority
- JP
- Japan
- Prior art keywords
- transfer
- transfer sheet
- polyurethane
- pattern layer
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims description 34
- 239000002537 cosmetic Substances 0.000 title claims 2
- 239000010410 layer Substances 0.000 claims description 21
- 239000011241 protective layer Substances 0.000 claims description 9
- 229920002803 Thermoplastic polyurethane Polymers 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N [N-]=C=O Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 150000002009 diols Chemical group 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- -1 acrylic acid ester compound Chemical class 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N Isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Description
【０００１】
【発明の属する技術分野】
本発明は、住宅の外装及び内装材等の各種用途に用いる化粧材として、特に密着性、耐熱水性、耐熱性、耐候性等に優れ、建築物内装材、特に浴室、洗面台、キッチンパネル等の水回りに適した化粧材と、転写シートに関する。
[0001]
[Technical field to which the invention belongs]
The present invention is particularly excellent in adhesion, heat resistance, water resistance, heat resistance, weather resistance, etc. as a decorative material used for various purposes such as exterior and interior materials of a house, and is particularly excellent in building interior materials, especially bathrooms, wash basins, kitchen panels, etc. Regarding decorative materials suitable for around water and transfer sheets.
そこで、本発明の課題は、転写で化粧材を製造する場合に、密着性、耐熱水性、耐熱性、耐候性、更に耐擦傷性等の表面物性に優れた化粧材と転写シートを提供する事であり、また該化粧材を製造する際に、模様層等の転写時の剥離性も良好となる化粧材と転写シートを提供する事である。 Therefore, an object of the present invention is to provide a decorative material and a transfer sheet having excellent surface physical properties such as adhesion, heat resistance, heat resistance, weather resistance, and scratch resistance when a decorative material is produced by transfer. Further, it is an object of the present invention to provide a decorative material and a transfer sheet having good peelability at the time of transfer of a pattern layer or the like when the decorative material is manufactured.
【０００６】
【課題を解決するための手段】
そこで、上記課題を解決すべく、本発明では、支持体シート上の転写層として模様層を有する転写シートにおいて、模様層がバインダー樹脂としてウレタン樹脂を有し、該ウレタン樹脂はポリカーボネートジオールとイソシアネートからなるポリウレタン部分とアクリル部分とを有するポリウレタン−アクリルブロック共重合体であり、且つ数平均分子量が３０，０００以上で水酸基を含有しない樹脂である構成とする。この転写シートを、基材表面に、模様層、表面保護層がこの順に積層された化粧材の製造に使用し、表面保護層が（メタ）アクリル酸エステル化合物の架橋硬化物である場合、模様層のウレタン樹脂はアクリル部分を有し、且つ表面保護層もアクリル系樹脂となる為に表面保護層と模様層との密着も良く、耐熱水性、耐熱性、耐候性等の物性に優れる上、耐擦傷性等の表面物性にも優れた化粧材となる。なお、上記ウレタン樹脂を構成するポリウレタン−アクリルブロック共重合体を、そのポリウレタン部分に、ポリオールとしてポリカーボネートジオールを用い、またイソシアネートとして４，４′−メチレンビス（シクロヘキシルイソシアネート）、及びイソホロンジイソシアネートを用いた共重合体とすることによって、耐候性はより良好となる。
0006
[Means for solving problems]
To solve the above problem, the present onset bright, the transfer sheet having a pattern layer as a transfer layer on a support sheet having a urethane resin pattern layer as a binder resin, the urethane resin is a polycarbonate diol It is a polyurethane-acrylic block copolymer having a polyurethane portion made of isocyanate and an acrylic portion, and has a number average molecular weight of 30,000 or more and is a resin containing no hydroxyl group. When this transfer sheet is used for producing a decorative material in which a pattern layer and a surface protective layer are laminated in this order on the surface of a base material, and the surface protective layer is a crosslinked cured product of a (meth) acrylic acid ester compound , a pattern is formed. The urethane resin of the layer has an acrylic part, and since the surface protective layer is also an acrylic resin, the surface protective layer and the pattern layer have good adhesion, and the physical properties such as heat resistance, heat resistance, and weather resistance are excellent. It is a decorative material with excellent surface properties such as scratch resistance. The polyurethane-acrylic block copolymer constituting the urethane resin is co-used with polycarbonate diol as a polyol and 4,4'-methylenebis (cyclohexyl isocyanate) as an isocyanate and isophorone diisocyanate as the polyurethane portion thereof. By using a polymer, the weather resistance becomes better.
また、本発明の化粧材は、上記転写シートで基材に模様層を転写法で形成し、さらに、（メタ）アクリル酸エステル化合物である表面保護層を塗装法で形成した。その結果、表面が粗面な厚板等の直接印刷が困難な基材表面に対しても、特定材料の模様層及び特定材料の表面保護層によって、転写時の剥離性も良好で、化粧材を容易に製造できる。 Further, in the decorative material of the present invention, a pattern layer was formed on the base material of the transfer sheet by a transfer method, and a surface protective layer which was a (meth) acrylic acid ester compound was further formed by a coating method. As a result, even on the surface of a base material such as a thick plate having a rough surface, which is difficult to print directly, the pattern layer of the specific material and the surface protection layer of the specific material have good peelability at the time of transfer, and the decorative material. Can be easily manufactured.
なお、本発明に於いて、転写圧として、固体粒子の衝突圧を利用できる。固体粒子衝突圧を転写圧に利用する事により、被転写面がゴムローラを用いる従来の転写法では不可能な様な凹凸表面でも転写でき、より高意匠の化粧材を容易に製造できる。 Incidentally, in the present onset bright, as the transfer pressure, available impact pressure of the solid particles. By using the solid particle collision pressure as the transfer pressure, it is possible to transfer even an uneven surface on which the surface to be transferred cannot be obtained by the conventional transfer method using a rubber roller, and a decorative material having a higher design can be easily manufactured.
【０００９】
【発明の実施の形態】
以下、図面を参照しながら本発明の化粧材及び転写シートについて、実施の形態を説明する。
0009
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the decorative material and transfer sheet of the present invention will be described with reference to the drawings.
以下、さらに本発明について詳述する。 It will be described in detail further with this onset Akira.
〔転写シート〕
本発明の化粧材を製造する場合に、模様層を転写法で形成する際に用いる本発明の転写シートとしては、図２にその一形態を例示する転写シートＳの如く、支持体シート４と転写移行する転写層５とからなり、その転写層５として前記した如きバインダー樹脂からなる模様層１を有する構成のものを用いる。
[Transfer sheet]
The transfer sheet of the present invention used when forming the pattern layer by the transfer method in the case of producing the decorative material of the present invention includes the support sheet 4 as in the transfer sheet S exemplifying one form thereof in FIG. A transfer layer 5 is used, which is composed of a transfer layer 5 to be transferred, and has a pattern layer 1 made of a binder resin as described above as the transfer layer 5.
〔表面保護層〕
表面保護層２は、前述した如く、基材に塗装法で形成しても良く、転写法で形成しても良いが、本発明による化粧材では塗装法で形成する。また、転写法で形成する場合に用いる転写シートとして、その支持体シート上に形成するには、転写法を含むグラビア印刷等の印刷法でも良く、或いは塗装法でも良い。但し、化粧材に於いて表面保護層は架橋硬化物であるので、基材にはスプレーコート、ロールコート等の塗装法で形成した方が、転写シートの取扱いが容易になる点では好ましい。
[Surface protective layer]
As described above, the surface protective layer 2 may be formed on the base material by a coating method or a transfer method, but the decorative material according to the present invention is formed by a coating method . Further, as the transfer sheet used when forming by the transfer method, in order to form the transfer sheet on the support sheet, a printing method such as gravure printing including the transfer method may be used, or a painting method may be used. However, since the surface protective layer is a crosslinked cured product in the decorative material, it is preferable to form the base material by a coating method such as spray coating or roll coating in terms of easy handling of the transfer sheet.
【００７０】
【発明の効果】
（１）本発明によれば、耐熱水性、耐熱性、耐候性等の物性に優れ、且つ耐擦傷性等の表面物性にも優れる。従って、浴室等の水回り用途に適する化粧材となる。
（２）本発明によれば、上記の如き化粧材を模様層等の転写時の支持体シートの剥離性も良好に出来、容易に製造できる。
（３）なお、特に、転写圧に固体粒子衝突圧を用いる転写法を模様層形成等に採用すれば、大きな三次元的凹凸表面が装飾された化粧材が容易に得られる。もちろん、二次元的凹凸も可能で、平板状の板材以外にも瓦の様に全体として（包絡面形状が）波うち形状のもの、或いは凸又は凹に湾曲した形状のものでも容易に得られる。また、大柄な凹凸表面の凸部上、凹部内（底部や凸部と底部の連結部分である側面）も転写できる。また、大柄な凹凸の凸部上に、更に微細な凹凸（例えば梨地等）が有る場合でも、その微細凹凸の凹部内にまで、転写できる。また、従来のゴムローラ押圧方式の様に、基材の凹凸部によるローラ等部品の損耗も無い。従って、従来に無く極めて意匠性に優れた化粧材が得られる。
[0070]
【Effect of the invention】
(1) According to the onset bright, hot water resistance, heat resistance, excellent physical properties such as weather resistance, and also excellent in surface properties such as scratch resistance. Therefore, it is a decorative material suitable for use around water such as a bathroom.
(2) According to the onset bright, can also good releasability of the support sheet at the time of transfer of the pattern layer, such as the above-mentioned decorative material can be easily produced.
(3) In particular, if a transfer method using a solid particle collision pressure as the transfer pressure is adopted for pattern layer formation or the like, a decorative material having a large three-dimensional uneven surface can be easily obtained. Of course, two-dimensional unevenness is also possible, and in addition to flat plate materials, those with a wavy shape (envelope surface shape) as a whole, such as roof tiles, or those with a convex or concave curve can be easily obtained. .. In addition, it is possible to transfer on the convex portion of the large uneven surface and in the concave portion (the bottom portion or the side surface which is the connecting portion between the convex portion and the bottom portion). Further, even if there are finer unevenness (for example, satin finish) on the convex portion of the large unevenness, the transfer can be performed even in the concave portion of the fine unevenness. Further, unlike the conventional rubber roller pressing method, there is no wear of parts such as rollers due to the uneven portion of the base material. Therefore, it is possible to obtain a decorative material having an extremely excellent design, which has never been seen before.
【図２】本発明の化粧材の製造方法で使用する本発明の転写シートの一例を示す
断面図。
FIG. 2 is a cross-sectional view showing an example of a transfer sheet of the present invention used in the method for producing a decorative material of the present invention.
Claims (3)
模様層がバインダー樹脂としてウレタン樹脂を有し、該ウレタン樹脂はポリカーボネートジオールとイソシアネートからなるポリウレタン部分とアクリル部分とを有するポリウレタン-アクリルブロック共重合体であり、且つ数平均分子量が３０，０００以上で水酸基を含有しない樹脂である、転写シート。 In a transfer sheet having a pattern layer as a transfer layer on a support sheet ,
The pattern layer has a urethane resin as a binder resin, and the urethane resin is a polyurethane-acrylic block copolymer having a polyurethane part made of polycarbonate diol and isocyanate and an acrylic part, and has a number average molecular weight of 30,000 or more. Ru resin der not containing a hydroxyl group, the transfer sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21499798A JP4074008B2 (en) | 1998-07-30 | 1998-07-30 | Cosmetic material and transfer sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21499798A JP4074008B2 (en) | 1998-07-30 | 1998-07-30 | Cosmetic material and transfer sheet |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000043218A JP2000043218A (en) | 2000-02-15 |
| JP2000043218A5 true JP2000043218A5 (en) | 2005-10-27 |
| JP4074008B2 JP4074008B2 (en) | 2008-04-09 |
Family
ID=16665000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21499798A Expired - Fee Related JP4074008B2 (en) | 1998-07-30 | 1998-07-30 | Cosmetic material and transfer sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4074008B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4603125B2 (en) * | 2000-04-21 | 2010-12-22 | 株式会社たからセルロイド | Decorative board for gaming machines |
| JP4895850B2 (en) * | 2006-02-13 | 2012-03-14 | エスケー化研株式会社 | Manufacturing method of decorative sheet |
| JP5476903B2 (en) * | 2009-09-30 | 2014-04-23 | 大日本印刷株式会社 | Decorative sheet and decorative resin molded product using the same |
| US10265895B2 (en) * | 2011-03-25 | 2019-04-23 | Dai Nippon Printing Co., Ltd. | Decorative sheet for three-dimensional molding and method for producing same, and decorative molded article using decorative sheet and method for producing same |
| CN103395251B (en) * | 2013-07-02 | 2016-03-09 | 金赛博阳(北京)科技有限公司 | A kind of manufacturing process of synthetic resin face artificial board |
| CN103640289B (en) * | 2013-12-04 | 2016-01-20 | 东莞市纳利光学材料有限公司 | A kind of anti-electromagnetic wave anti-scratch diaphragm and preparation method thereof |
| EP3216602B1 (en) | 2014-11-05 | 2022-01-12 | Dai Nippon Printing Co., Ltd. | Transfer sheet and hard coat body using same |
-
1998
- 1998-07-30 JP JP21499798A patent/JP4074008B2/en not_active Expired - Fee Related
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