JP2000025188A - Decorative material - Google Patents

Decorative material

Info

Publication number
JP2000025188A
JP2000025188A JP10195208A JP19520898A JP2000025188A JP 2000025188 A JP2000025188 A JP 2000025188A JP 10195208 A JP10195208 A JP 10195208A JP 19520898 A JP19520898 A JP 19520898A JP 2000025188 A JP2000025188 A JP 2000025188A
Authority
JP
Japan
Prior art keywords
layer
pattern layer
pattern
variable pattern
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP10195208A
Other languages
Japanese (ja)
Inventor
Kazuo Suzuki
和生 鈴木
Kenji Yamamoto
謙司 山本
Tomoo Hirooka
智生 廣岡
Michiko Nezu
美智子 根津
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP10195208A priority Critical patent/JP2000025188A/en
Publication of JP2000025188A publication Critical patent/JP2000025188A/en
Withdrawn legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To change a looking way of a pattern by a looking angle. SOLUTION: A bright pattern layer 1 comprising a binder resin containing a silver type or iridescent color type titanium coated mica powder is patternwise formed on a colored opaque base material B. The patterns shown by the bright pattern layer 1 change in a looking way by a looking angle, for example, look bright from a certain angle but look dark from a separate angle. When the bright pattern layer 1 is formed by silk screen printing, a change of a looking way can be made large.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、絵柄の見え方が、
見る角度によって変化する化粧板等の化粧材に関する。
BACKGROUND OF THE INVENTION The present invention relates to an image
The present invention relates to a decorative material such as a decorative board that changes depending on a viewing angle.

【0002】[0002]

【従来の技術】従来から、樹脂板、木質板、金属板等の
各種板材、或いは樹脂シート等の基材に、絵柄を印刷し
て装飾した化粧板や化粧シート等の化粧材が、種々の用
途で使用されている。例えば、冷蔵庫等に使用される化
粧板では、表面をメッキ処理した鉄板に、グラビアオフ
セット印刷等で絵柄を印刷した化粧鋼板等が使用されて
いる。
2. Description of the Related Art Conventionally, decorative materials such as decorative plates and decorative sheets obtained by printing a pattern on a substrate such as a resin plate, a wooden plate, a metal plate or the like, or a base material such as a resin sheet have been used. Used in applications. For example, as a decorative plate used for a refrigerator or the like, a decorative steel plate or the like in which a pattern is printed by gravure offset printing or the like on an iron plate whose surface is plated is used.

【0003】[0003]

【発明が解決しようとする課題】しかし、従来の化粧材
では、いずれも、印刷形成された絵柄層の絵柄は、どの
角度から見ても、一様に同じ様に見える物でしかなかっ
た。そこで、本発明の課題は、見る角度によって絵柄の
見え方が異なると言う、斬新な意匠表現も可能な化粧材
を提供する事である。
However, in any of the conventional decorative materials, the pattern of the pattern layer formed by printing is always the same even when viewed from any angle. Therefore, an object of the present invention is to provide a decorative material that can express a novel design that the appearance of a pattern differs depending on the viewing angle.

【0004】[0004]

【課題を解決するための手段】そこで、上記課題を解決
すべく、本発明の化粧材では、着色不透明基材に、バイ
ンダー樹脂中にシルバータイプ又は虹彩色タイプの二酸
化チタン被覆雲母粉を含有する可変絵柄層がパターン状
に形成された構成とした。その結果、可変絵柄層中に含
有される上記二酸化チタン被覆雲母粉の作用効果によっ
て、可変絵柄層が表す絵柄が、見る角度によって輝いて
見えたり暗く見えたりと変化する化粧材にできる。な
お、可変絵柄層は透明としておけば、下側の着色不透明
基材が透けて見えるので、可変絵柄層が暗く見える角度
でも、下側の着色不透明基材が見える為に、あたかも可
変絵柄層の柄が消失した様に見えさせる事も可能であ
る。なお、可変絵柄層は、シルクスクリーン印刷で形成
されてなる層とすれば、厚みを厚く出来、上記二酸化チ
タン被覆雲母粉による作用効果を大きくする事が出来
る。
Therefore, in order to solve the above problems, in the cosmetic material of the present invention, the colored opaque base material contains silver type or iris type titanium dioxide-coated mica powder in a binder resin. The variable pattern layer was formed in a pattern. As a result, due to the action and effect of the titanium dioxide-coated mica powder contained in the variable pattern layer, a decorative material in which the pattern represented by the variable pattern layer changes to appear bright or dark depending on the viewing angle can be obtained. In addition, if the variable pattern layer is transparent, the lower colored opaque substrate can be seen through, so that even at an angle at which the variable pattern layer appears dark, the lower colored opaque substrate is visible, It is also possible to make the pattern appear to have disappeared. If the variable pattern layer is a layer formed by silk screen printing, the thickness can be increased, and the effect of the titanium dioxide-coated mica powder can be increased.

【0005】[0005]

【発明の実施の形態】以下、本発明の化粧材を、図面を
参照しながら実施の形態を説明する。図1は本発明の化
粧材の各種形態例の断面図と、絵柄の見え方の変わり具
合を示す概念図、図2及び図3は本発明の化粧材の他の
形態例を示す断面図である。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of the decorative material of the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view of various embodiments of the cosmetic material of the present invention, and a conceptual diagram showing how the appearance of the pattern changes, and FIGS. 2 and 3 are cross-sectional views showing other embodiments of the cosmetic material of the present invention. is there.

【0006】〔概要〕先ず、図1の断面図に、本発明の
化粧材の各種形態のうちの幾つかを例示する。図1
(A)は、着色不透明基材Bに可変絵柄層1がパターン
状に形成された化粧材Dを示し、図1(B)は図1
(A)の構成に対して、着色不透明基材Bが、基材素材
2と着色層3とからなる構成の化粧材Dを示し、図1
(C)は、図1(A)の構成に対して、可変絵柄層1側
の面の全面の可変絵柄層の上に、透明樹脂層4が形成さ
れた構成の化粧材Dを示す。そして、これら本発明の化
粧材Dでは、図1(D)の図面左右で例示する如く、見
る角度を変えると、可変絵柄層1が、明確に光輝性を持
って輪郭が明確に見えたり(図面左側)、暗く光輝性が
無く従って輪郭が不明朗で、あたかも可変絵柄層がそこ
に存在し無いかの如く見えたりして(図面右側)、可変
絵柄層の見え方が変化する。この様な見え方の変化は、
可変絵柄層を、シルバータイプ又は虹彩色タイプの二酸
化チタン被覆雲母粉を含有するインキで形成して、バイ
ンダー樹脂中に該二酸化チタン被覆雲母粉を分散含有さ
せた層とする事によって達成される。また、この様な、
可変絵柄層はシルクスクリーン印刷で形成すると、比較
的厚く形成できるので、見え方の変化をより大きくでき
る。以上の結果、化粧材Dは、従来では不可能であった
斬新な意匠表現も可能となる。例えば、隠し模様等を入
れる事が出来る。
[Outline] First, some of various forms of the decorative material of the present invention are illustrated in the cross-sectional view of FIG. FIG.
1A shows a decorative material D in which a variable pattern layer 1 is formed in a pattern on a colored opaque base material B, and FIG.
1A shows a decorative material D in which a colored opaque substrate B is composed of a substrate material 2 and a colored layer 3, and FIG.
FIG. 1C shows a decorative material D having a configuration in which a transparent resin layer 4 is formed on the variable pattern layer on the entire surface of the variable pattern layer 1 side with respect to the configuration of FIG. Then, in these decorative materials D of the present invention, when the viewing angle is changed, as illustrated in the left and right drawings of FIG. 1 (D), the variable pattern layer 1 has a distinctly bright appearance and a clear contour ( The left side of the drawing) is dark and has no glitter, so the outline is unclear, and it looks as if the variable pattern layer does not exist there (right side of the drawing), and the appearance of the variable pattern layer changes. Such a change in appearance is
This is achieved by forming the variable pattern layer with an ink containing silver dioxide or iris type titanium dioxide-coated mica powder and dispersing and containing the titanium dioxide-coated mica powder in a binder resin. Also, like this,
If the variable pattern layer is formed by silk screen printing, it can be formed relatively thick, so that the change in appearance can be increased. As a result, the decorative material D can also realize a novel design expression that has been impossible in the past. For example, a hidden pattern or the like can be inserted.

【0007】可変絵柄層の見え方が見る角度によって変
化し、可変絵柄層自体が輝いて見えたり、暗く見えあた
かも該層が存在し無いかの如く見えたりする理由は、定
かではないが、次の様に推察される。それは、可変絵柄
層中の二酸化チタン被覆雲母粉の粒子形状は通常板状で
あり、その板面が可変絵柄層面(すなわち、化粧材面)
に略水平に並ぶ様に、可変絵柄層のバインダー樹脂中に
分散している。従って、微小な鏡をその面を揃えて多数
設けた様になる。そこで、見る角度(水平方向及び垂直
方向)を、丁度、化粧材を照明する照明光(太陽や室内
照明等)が可変絵柄層に入射しそこの鏡で正反射して、
その反射光の進行方向から逆に見る様な角度にすれば、
照明光の反射光が直接目に入り明るく見える。しかも、
可変絵柄層に於ける反射面は、実際には一枚の平面の反
射面では無く、面が向く方向に多少バラツキの或る多数
の微小面であり、それぞれからの反射光の進行方向が微
妙にずれる為に、(微小な見る角度の変化によって)輝
いて見える事になる。ところが、見る角度が、正反射光
の進行方向からずれると、照明光からの反射光は全く見
る事が出来なくなる。従って、照明光が全く無いのと同
じ状態となり、暗く見えると言うものである。しかし、
可変絵柄層が無い面部分では、この様な場合でも、照明
光は光の拡散作用によってその拡散光を見る事ができ
る。拡散光は、その部分の物体色を見る事になる。すな
わち、拡散光は、通常に物体を目視で認識する場合に利
用している物体色としての光である。なお、上記正反射
光には物体色は含まれず、基本的には照明光の色をその
まま見る事になる。従って、可変絵柄層が輝いて見えな
い角度から化粧材を見れば、化粧材全体としては、着色
不透明基材の(物体)色を見ている事になる。従って、
着色不透明基材が呈する色の化粧材面の中に、可変絵柄
層部分は該可変絵柄層からの光が無い暗黒のパターンと
して見える事になる。
The reason why the appearance of the variable pattern layer changes depending on the viewing angle, and the reason why the variable pattern layer itself looks shining or looks dark as if the layer does not exist is not clear, but the following is not clear. It is inferred as follows. That is, the particle shape of the titanium dioxide-coated mica powder in the variable pattern layer is usually plate-like, and the plate surface is the variable pattern layer surface (that is, the decorative material surface).
Are dispersed in the binder resin of the variable pattern layer so as to be arranged substantially horizontally. Therefore, it is as if a large number of minute mirrors are provided with their surfaces aligned. Therefore, the viewing angle (horizontal direction and vertical direction), just the illumination light (sun or indoor lighting, etc.) that illuminates the cosmetic material is incident on the variable pattern layer and specularly reflected by the mirror there,
If you make an angle that looks backward from the direction of travel of the reflected light,
The reflected light of the illumination light comes directly into the eyes and looks bright. Moreover,
The reflecting surface in the variable pattern layer is actually not a single flat reflecting surface, but rather a number of minute surfaces that vary somewhat in the direction in which the surface faces, and the traveling direction of reflected light from each is delicate. Because of the deviation, it will appear shining (due to a slight change in the viewing angle). However, if the viewing angle deviates from the traveling direction of the specularly reflected light, the reflected light from the illumination light cannot be seen at all. Therefore, the state is the same as when there is no illumination light, and the image looks dark. But,
In such a case, the diffused light can be seen on the surface portion without the variable pattern layer due to the light diffusing action. The diffused light will see the object color in that part. That is, the diffused light is light as an object color that is normally used when an object is visually recognized. Note that the specular reflection light does not include the object color, and basically sees the color of the illumination light as it is. Therefore, when the decorative material is viewed from an angle at which the variable pattern layer does not shine, the overall decorative material is viewed as the (object) color of the colored opaque substrate. Therefore,
In the decorative material surface of the color exhibited by the colored opaque substrate, the variable pattern layer portion appears as a dark pattern without light from the variable pattern layer.

【0008】そして、更に、可変絵柄層を通して下側の
着色不透明基材に別の絵柄(全面ベタでも良い)があっ
たり、可変絵柄層の上側に可変絵柄層を透かして見える
様な別の絵柄(上絵柄層)が有ると、可変絵柄層自体か
らの反射光が無く該層が暗黒になっても(光を吸収する
事による黒ではなく、そこからの反射光が見る方向に到
達しない為の黒である)、これら別の絵柄による拡散光
は見る事ができるので、可変絵柄層がそこに存在し無い
かの如く見える事になる。
Further, there is another pattern (which may be entirely solid) on the lower colored opaque base material through the variable pattern layer, or another pattern which can be seen through the variable pattern layer above the variable pattern layer. If there is (upper pattern layer), even if there is no reflected light from the variable pattern layer itself and the layer becomes dark (it is not black due to light absorption, reflected light from there does not reach the viewing direction) The diffused light due to these other patterns can be seen, so that it looks as if the variable pattern layer does not exist there.

【0009】以下、更に本発明を詳述する。Hereinafter, the present invention will be described in more detail.

【0010】〔着色不透明基材〕着色不透明基材Bは、
不透明で着色された基材であれば特に制限はない。な
お、着色とは、基材自体が元々有している色調であっも
良いし、図1(B)で例示の如く、基材素材3自体に着
色層3を形成する事で、着色しても良い。また、着色層
を設ける場合は、基材素材と着色層との少なくともどち
らか一方を不透明とすれば良い。すなわち、どちらか一
方は透明でも良い。また、基材の不透明性にて、裏側か
らの光で可変絵柄層の反射光が薄まり、その効果の低下
を防ぐ。
[Colored opaque substrate] The colored opaque substrate B is
There is no particular limitation as long as the substrate is opaque and colored. The coloring may be a color tone originally possessed by the base material itself, or may be colored by forming the coloring layer 3 on the base material 3 itself as illustrated in FIG. Is also good. When a colored layer is provided, at least one of the base material and the colored layer may be opaque. That is, either one may be transparent. In addition, due to the opacity of the base material, the light reflected from the variable pattern layer is weakened by light from the back side, thereby preventing the effect from being reduced.

【0011】着色不透明基材の材料は、例えば、鉄、ア
ルミニウム、銅等の金属材料、陶器、磁器、硝子、琺瑯
等の無機質材料、杉、檜、樫等の各種樹種からなる単板
や合板、パーティクルボード等の木質材料、ポリメチル
メタクリレート等のアクリル樹脂、ポリプロピレン等の
ポリオレフィン系樹脂、ABS樹脂、フェノール樹脂、
ポリエステル樹脂等の樹脂材料、或いは、紙、不織布等
の繊維質材料等である。そして、着色不透明基材の形態
は、板材の他にシートの形態でも良い。着色不透明基材
の厚みは用途により10μm〜1cm程度だがこの範囲
外でも良い。また、金属材料の場合は、軟鋼板、電鋳鉄
箔、アルミニウム板、銅板等の板材、或いはこれらに亜
鉛、錫、鉛、アルミニウム、銅、クロム、ニッケル等の
一種又は二種以上をメッキしたもの等を使用できる。二
種以上のメッキとしては、鉄と亜鉛の合金メッキ、アル
ミニウムと亜鉛の合金メッキ等がある。
The material of the colored opaque substrate is, for example, a metal material such as iron, aluminum, or copper; an inorganic material such as pottery, porcelain, glass, or enamel; or a veneer or plywood made of various tree species such as cedar, cypress, and oak. Wood material such as particle board, acrylic resin such as polymethyl methacrylate, polyolefin resin such as polypropylene, ABS resin, phenol resin,
It is a resin material such as polyester resin, or a fibrous material such as paper or nonwoven fabric. The form of the colored opaque substrate may be a sheet in addition to the plate. The thickness of the colored opaque substrate is about 10 μm to 1 cm depending on the application, but may be outside this range. In the case of a metal material, a sheet material such as a mild steel plate, an electroformed iron foil, an aluminum plate, a copper plate or the like, or a material obtained by plating one or more of zinc, tin, lead, aluminum, copper, chromium, nickel, etc. Etc. can be used. Examples of the two or more types of plating include alloy plating of iron and zinc, alloy plating of aluminum and zinc, and the like.

【0012】(着色層)着色層としては、全面が一様な
色調の層(全面ベタ層)でも良いが、パターン状に色調
が異なる層(着色絵柄層)でも良い。この様な着色層と
しては、基本的には特に制限は無く、柄パターンを有す
る場合は、グラビア印刷、シルクスクリーン印刷、オフ
セット印刷、グラビアオフセット印刷等の印刷手段、全
ベタの場合はこれら印刷手段の他にロールコート、カー
テンフローコート等の塗工手段で形成する等、従来公知
の方法及び材料で形成すればよい。また、着色層形成に
用いるインキ又は塗液のビヒクルを構成するバインダー
樹脂としては、アクリル樹脂等の熱可塑性樹脂、或いは
ポリウレタン樹脂等の硬化性樹脂でも良いが、耐久性等
の点で、ポリエステル系樹脂、アミノアルキド系樹脂、
熱硬化性アクリル系樹脂等の熱硬化性樹脂は好ましい。
また、上記ビヒクルには従来公知の顔料や染料等の着色
剤、その他、必要に応じて適宜、体質顔料等の各種添加
剤が添加される。なお、着色絵柄層はもちろんの事、多
色刷りの複層構成でも良く、全面ベタ層と組み合わせる
事もある。この様に全面ベタ層を絵柄(着色絵柄層の絵
柄、或いは後述の上絵柄層の絵柄)と組み合わせる場合
には、基調色で全面ベタ層を形成したりするのも好まし
い。ちなみに、図2に例示する形態の本発明の化粧材D
は、基材素材2上にプライマー層5、ベースコート層
6、パターン状の着色絵柄層3が形成された着色不透明
基材Bの上に、可変絵柄層4が形成され、さらに全面に
透明樹脂層4が形成された構成である。また、着色絵柄
層による柄ではなく、基材素材自体が柄を有しておれば
(例えば木目柄)、その柄を活かしても良い。
(Coloring Layer) The coloring layer may be a layer having a uniform color tone on the entire surface (solid layer on the entire surface) or a layer having a different color tone in a pattern (colored picture layer). Such a colored layer is basically not particularly limited, and has a pattern pattern, such as gravure printing, silk-screen printing, offset printing, gravure offset printing, and the like. In addition, it may be formed by a conventionally known method and material such as forming by a coating means such as a roll coat and a curtain flow coat. The binder resin constituting the vehicle of the ink or the coating liquid used for forming the colored layer may be a thermoplastic resin such as an acrylic resin, or a curable resin such as a polyurethane resin. However, in terms of durability and the like, a polyester resin is used. Resin, amino alkyd resin,
Thermosetting resins such as thermosetting acrylic resins are preferred.
In addition, conventionally known coloring agents such as pigments and dyes, and other various additives such as extender pigments are appropriately added to the vehicle as needed. It is to be noted that, not only the colored pattern layer, but also a multi-layered multi-layer structure may be used, and the entire surface may be combined with a solid layer. When the entire solid layer is combined with a pattern (a pattern of a colored pattern layer or a pattern of an upper pattern layer to be described later), it is also preferable to form the entire solid layer with a base color. Incidentally, the decorative material D of the present invention in the form illustrated in FIG.
A variable pattern layer 4 is formed on a colored opaque base material B in which a primer layer 5, a base coat layer 6, and a patterned colored pattern layer 3 are formed on a base material 2, and a transparent resin layer is formed on the entire surface. This is the configuration in which No. 4 is formed. If the base material itself has a pattern (for example, a wood pattern) instead of the pattern formed by the colored pattern layer, the pattern may be used.

【0013】また、着色不透明基材には、上記着色層や
可変絵柄層の接着性向上の為のプライマー層や、色調調
整等の為のベースコート層等を、必要に応じて、適宜、
上記着色層で列記した様な印刷法、塗工法等の公知の形
成方法と、公知の材料で設けも良い(図3の符号6参
照)。なお、ベースコート層を有色(白を含む)とする
場合は、上記した着色絵柄層の全面ベタ層でもある。な
お、プライマー層には、例えば、ポリエステル系樹脂、
アクリル系樹脂、エポキシ系樹脂等の熱硬化性樹脂を用
いれば耐久性も良い。また、ベースコート層も、プライ
マー層同様の樹脂を用いれば良い。
The colored opaque substrate may be provided with a primer layer for improving the adhesion of the colored layer and the variable picture layer, a base coat layer for adjusting the color tone and the like, if necessary.
A known forming method such as a printing method or a coating method as listed in the above colored layer, or a known material may be used (see reference numeral 6 in FIG. 3). When the base coat layer is colored (including white), it is also a solid layer on the entire surface of the above-mentioned colored pattern layer. In addition, in the primer layer, for example, polyester resin,
If a thermosetting resin such as an acrylic resin or an epoxy resin is used, the durability is good. The base coat layer may be made of the same resin as the primer layer.

【0014】〔可変絵柄層〕可変絵柄層1は、シルバー
タイプ又は虹彩色タイプの二酸化チタン被覆雲母粉をバ
インダー樹脂中に含有する、パターン状に形成された層
である。二酸化チタン被覆雲母粉は、雲母粉末を被覆す
る二酸化チタンの厚み等を変えて光の干渉作用で各種色
調の光輝性を出す顔料である。シルバータイプでは銀色
の光輝感が得られる。また、虹彩色タイプでは、二酸化
チタンの被覆層の厚み設定を変える事で、金、赤、赤
紫、紫、青、緑等の虹色を構成する各色で光輝感が得ら
れる。なお、二酸化チタン被覆雲母粉の粒径は、その主
たる粒径を5〜15μmの範囲にすると良い。粒径が小
さすぎると、光輝感が得られず、また逆に大きすぎても
光輝感がギラギラしたドギツサが出て来て、光輝感が見
え難い角度でも見え易い様になり、可変絵柄層の見え方
の変化が小さくなる。
[Variable Pattern Layer] The variable pattern layer 1 is a layer formed in a pattern containing silver type or iris type titanium dioxide-coated mica powder in a binder resin. Titanium dioxide-coated mica powder is a pigment that provides various colors of brilliancy by the interference of light by changing the thickness of titanium dioxide coating the mica powder. The silver type gives a silver glitter. In the case of the iris type, by changing the thickness setting of the coating layer of titanium dioxide, a glittering feeling can be obtained in each color constituting the rainbow colors such as gold, red, magenta, purple, blue and green. The main particle size of the titanium dioxide-coated mica powder is preferably in the range of 5 to 15 μm. If the particle size is too small, glitter cannot be obtained, and conversely, if it is too large, a glittering glitter appears, making it easier to see even at angles where glitter is difficult to see, and the variable pattern layer The change in appearance is small.

【0015】そして、可変絵柄層は、適宜樹脂をバイン
ダーの樹脂とするビヒクルに、該二酸化チタン被覆雲母
粉を添加し、更に必要に応じ適宜、体質顔料等の各種添
加剤を添加したインキで印刷形成すれば良い。インキの
バインダーの樹脂としては、アクリル樹脂等の熱可塑性
樹脂、或いはポリウレタン樹脂等の硬化性樹脂でも良い
が、耐久性等の点で、ポリエステル系樹脂、アミノアル
キド系樹脂、熱硬化性アクリル系樹脂等の熱硬化性樹脂
は好ましい。なお、可変絵柄層は、着色剤として、例え
ばカーボンブラック等の着色顔料、或いは染料等を併用
しても良い。
The variable pattern layer is printed with an ink obtained by adding the titanium dioxide-coated mica powder to a vehicle using a resin as a binder resin and further adding various additives such as extender pigments as needed. It may be formed. As the resin of the ink binder, a thermoplastic resin such as an acrylic resin or a curable resin such as a polyurethane resin may be used. However, in terms of durability and the like, a polyester resin, an aminoalkyd resin, and a thermosetting acrylic resin are used. And the like are preferred. In the variable pattern layer, a coloring pigment such as carbon black or a dye may be used in combination as a coloring agent.

【0016】バインダー樹脂に対する二酸化チタン被覆
雲母粉の含有量は、目的とする効果により増減すれば良
い。例えば、バインダー樹脂100重量部当たり5〜4
0重量部の範囲で使用すると良い。二酸化チタン被覆雲
母粉がこの範囲よりも少ないとその効果が十分に得られ
ず、また逆にこの範囲を超えると、可変絵柄層が常に輝
いて見えてしまい、やはり見る角度による変化が少なく
なり効果が減少する。また、可変絵柄層の下側となる着
色不透明基材の色調や柄を透けて見える様にするには、
バインダー樹脂中に分散含有している二酸化チタン被覆
雲母粉同士間の間隙から見える様にする事が必要であ
り、この為にも、二酸化チタン被覆雲母粉の上記含有量
は、40重量部未満が好ましい。
The content of the titanium dioxide-coated mica powder in the binder resin may be increased or decreased depending on the desired effect. For example, 5 to 4 per 100 parts by weight of the binder resin
It is good to use in the range of 0 parts by weight. If the amount of titanium dioxide-coated mica powder is less than this range, the effect will not be sufficiently obtained. Conversely, if it exceeds this range, the variable pattern layer will always look shining, and the change due to the viewing angle will also be reduced. Decrease. Also, in order to see through the color tone and pattern of the colored opaque base material below the variable pattern layer,
It is necessary to make it visible from the gap between the titanium dioxide-coated mica powders dispersed and contained in the binder resin. For this reason, the content of the titanium dioxide-coated mica powder is less than 40 parts by weight. preferable.

【0017】この様な可変絵柄層の印刷形成方法は、グ
ラビア印刷、シルクスクリーン印刷、オフセット印刷、
グラビアオフセット印刷等の公知の印刷手段で良い。中
でも、二酸化チタン被覆雲母粉による可変絵柄層を厚く
形成でき、その見え方の変化を大きくできる点でシルク
スクリーン印刷は好ましい。なお、可変絵柄層の厚みは
特に制限は無いが、その効果をどの程度とするかによっ
て適宜厚みに設定する。例えば、5〜20μm程度であ
るが、通常は7〜10μm程度で良い。また、厚みは同
程度の効果を得る場合でも、二酸化チタン被覆雲母粉の
含有量によっても異なる。また、シルクスクリーン印刷
は可変絵柄層をスポット的に形成する事も容易である。
しかも、グラビア印刷やグラビアオフセット印刷等に比
べて、版製造が容易で多品種少量印刷に向いている為
に、着色絵柄層や上絵柄層の側はグラビア印刷やグラビ
アオフセット印刷等で共通に印刷して、可変絵柄層のみ
を各種絵柄に代えた化粧材を容易に製造する事ができ、
低コストな化粧材にできる利点が有る。
Such a variable pattern layer print forming method includes gravure printing, silk screen printing, offset printing,
Known printing means such as gravure offset printing may be used. Among them, silk-screen printing is preferable because a variable pattern layer made of mica powder coated with titanium dioxide can be formed thickly and the change in appearance can be increased. The thickness of the variable pattern layer is not particularly limited, but is appropriately set depending on the effect. For example, it is about 5 to 20 μm, but usually about 7 to 10 μm. Further, the thickness varies depending on the content of the titanium dioxide-coated mica powder even when the same effect is obtained. In addition, silk screen printing makes it easy to form a variable pattern layer in a spot-like manner.
In addition, compared to gravure printing or gravure offset printing, plate production is easier and suitable for high-mix low-volume printing, so the side of the colored picture layer and upper picture layer is commonly printed by gravure printing or gravure offset printing. Then, it is possible to easily manufacture a decorative material in which only the variable pattern layer is replaced with various patterns,
There is an advantage that a low-cost cosmetic material can be obtained.

【0018】なお、着色不透明基材が着色絵柄層を有す
る場合で、着色絵柄層に重なる部分ができる様に可変絵
柄層を形成する場合は、着色絵柄層はパターン状の可変
絵柄層で一部が隠れる事になる。従って、この場合は、
可変絵柄層は下側の着色絵柄層の柄が見える程度の透明
な層としておく事が好ましい。さもないと、可変絵柄層
が輝いて見えない角度から見た時に、可変絵柄層の部分
は下の着色絵柄層の柄が見えない部分として、可変絵柄
層がパターン状に見え易いからである。可変絵柄層を透
明にするには、上述の様に、二酸化チタン被覆雲母粉の
含有量を少なめに調整したり、可変絵柄層の厚みを薄く
したりすれば良い。
In the case where the colored opaque substrate has a colored pattern layer and the variable pattern layer is formed so as to form a portion overlapping the colored pattern layer, the colored pattern layer is partially formed of a patterned variable pattern layer. Will be hidden. Therefore, in this case,
It is preferable that the variable picture layer is a transparent layer that allows the pattern of the lower colored picture layer to be seen. Otherwise, when viewed from an angle at which the variable picture layer shines and cannot be seen, the variable picture layer is likely to look like a pattern because the pattern of the lower colored picture layer is not visible. In order to make the variable pattern layer transparent, as described above, the content of the titanium dioxide-coated mica powder may be adjusted to be small, or the thickness of the variable pattern layer may be reduced.

【0019】〔上絵柄層〕なお、着色不透明基材上の可
変絵柄層の上に、上絵柄層を更に形成しても良い。もち
ろん、この上絵柄層は、可変絵柄層の効果が失われない
様に、下側の可変絵柄層が見える程度の透明性を有する
層とする。上絵柄層を透明にするには、該層を形成する
インキの着色剤に染料や透明顔料を使用したり、或い
は、上絵柄層を散在して(例えば網点状に)形成すれば
良い(図4の参照)。上絵柄層の形成は、前述した着色
(絵柄)層で列記した様な、従来公知の材料及び印刷方
法で形成すれば良い。
[Upper Pattern Layer] An upper pattern layer may be further formed on the variable pattern layer on the colored opaque substrate. Of course, this upper pattern layer is a layer having such transparency that the lower variable pattern layer can be seen so that the effect of the variable pattern layer is not lost. In order to make the upper pattern layer transparent, a dye or a transparent pigment may be used as a coloring agent of the ink forming the layer, or the upper pattern layer may be formed in a scattered manner (for example, in a dot shape) ( See FIG. 4). The upper picture layer may be formed by a conventionally known material and printing method as listed in the above-mentioned colored (picture) layer.

【0020】〔可変絵柄層の柄と組み合わせる柄〕本発
明の化粧材は、可変絵柄層による柄のみでも良いが、そ
れ以外の柄も設ける事によって、可変絵柄層の柄と共に
より複雑で高意匠の化粧材とできる。可変絵柄層以外の
柄は、着色絵柄層の柄(として与えられる着色不透明基
材の柄)、上絵柄層の柄、或いは(着色絵柄層無しで
の)基材素材自体が元々有する柄等である。これら可変
絵柄層以外の柄は、適宜1以上を可変絵柄層の柄と共に
使用する。なお、これら可変絵柄層以外の柄は、可変絵
柄層の柄と位置的同調をさせても良いし、させなくても
良い。また、これら可変絵柄層以外の柄は、可変絵柄層
の柄と関係の有る柄で組み合わせて或る柄を成す様にし
ても良いし、無関係の柄同士を組み合わせても良い。以
上に於いて可変絵柄層以外の柄には、全面ベタ柄も含
む。例えば、着色絵柄層は全面ベタ柄(全面ベタ層)で
下地色を与え、可変絵柄層の柄で大柄な柄を与え、上絵
柄層の小柄な柄を前記着色絵柄層の下地色と組み合わせ
て或る一つの意匠柄を与える等の組み合わせである。も
ちろん、各絵柄層乃至は基材素材同士の柄の組み合わせ
は、これに限定されず、用途、意匠に応じて適宜組み合
わせとすれば良い。
[Pattern to be Combined with Pattern of Variable Pattern Layer] The decorative material of the present invention may be composed of only the pattern of the variable pattern layer. Can be used as a cosmetic material. The pattern other than the variable pattern layer is the pattern of the colored pattern layer (the pattern of the colored opaque substrate given as), the pattern of the upper pattern layer, or the pattern originally possessed by the base material itself (without the colored pattern layer). is there. One or more patterns other than the variable pattern layer are appropriately used together with the pattern of the variable pattern layer. In addition, the pattern other than these variable pattern layers may or may not be tuned in position with the pattern of the variable pattern layer. The patterns other than the variable pattern layer may be combined with patterns having a relationship with the pattern of the variable pattern layer to form a certain pattern, or unrelated patterns may be combined. In the above, patterns other than the variable pattern layer include solid patterns on the entire surface. For example, the colored pattern layer gives a base color with a solid pattern (a solid layer), a large pattern with a pattern of a variable pattern layer, and a small pattern of the upper pattern layer in combination with the base color of the colored pattern layer. It is a combination such as giving a certain design pattern. Of course, the combination of the patterns of the respective pattern layers or the base materials is not limited to this, and may be appropriately selected according to the use and the design.

【0021】また、可変絵柄層の柄と、着色絵柄層、上
絵柄層或いは基材素材自体等の他の柄との組み合わせ方
は任意ではあるが、例えば、次の様な組み合わせは、可
変絵柄層の見る角度による見え方の変化を大きく出来る
点で、好ましい組み合わせである。先ず、他の柄と可変
絵柄層とは、同色相の柄が好ましい。例えば、他の柄が
白、ベージュ等の淡色の場合には、可変絵柄層はシルバ
ー、ゴールド、緑、青、赤等が良く、中でもシルバーが
見え方の変化の効果が大きい点で好ましい。また、他の
柄が黒、褐色、紺等の濃色の場合は、可変絵柄層は青、
緑等が好ましい。他の柄と可変絵柄層の柄の具体的な柄
の例としては、他の柄をベタ柄、雲柄や砂目柄等とし
て、可変絵柄層の絵柄は、花、鳥、風月、水玉等と、可
変絵柄層の柄の方が他の柄よりも大きい様にする。
The combination of the pattern of the variable pattern layer and another pattern such as the colored pattern layer, the upper pattern layer or the base material itself is optional. This is a preferable combination because the change in appearance depending on the viewing angle of the layer can be increased. First, the other pattern and the variable picture layer preferably have the same hue. For example, when the other pattern is a light color such as white or beige, the variable pattern layer is preferably silver, gold, green, blue, red and the like, and silver is particularly preferable in that the effect of changing the appearance of silver is large. Also, if the other patterns are dark colors such as black, brown, navy blue, etc., the variable pattern layer is blue,
Green and the like are preferred. Examples of specific patterns of the other patterns and the variable pattern layer include solid patterns, cloud patterns, and grain patterns, etc., and patterns of the variable pattern layer include flowers, birds, fugetsu, polka dots, etc. The pattern of the variable pattern layer is larger than the other patterns.

【0022】〔透明樹脂層〕透明樹脂層(トップコート
層)4を、化粧材の表面保護、塗装感、高光沢等の意匠
感付与、帯電防止、耐汚染性等の機能付与等の為に、必
要に応じて、適宜、最外層として設けても良い。もろろ
ん、透明樹脂層は透明なクリアー層である。なお、透明
は着色透明でも良い。透明樹脂層としては特に限定は無
く、要求物性、用途等に応じて、従来公知の材料及び形
成方法で設ければ良い。透明樹脂層は、樹脂液の塗工又
は印刷で形成する。透明樹脂層に用いる樹脂としては、
アクリル樹脂等の熱可塑性樹脂、或いはポリウレタン樹
脂等の硬化性樹脂でも良いが、表面物性、耐久性等の点
で、ポリエステル系樹脂、アミノアルキド系樹脂、熱硬
化性アクリル系樹脂、シリコーン樹脂等の熱硬化性樹脂
は好ましい。樹脂液(インキ又は塗液)は無溶剤又は溶
剤希釈溶液として、例えば、グラビアオフセット印刷等
の印刷法、ロールコート、カーテンフローコート等の塗
工法等の公知の形成方法で形成すれば良い。なお、上記
樹脂液中には、必要に応じ適宜、充填剤、体質顔料、着
色剤、減摩剤、滑剤、紫外線吸収剤、光安定剤等の各種
の添加剤を添加する。
[Transparent Resin Layer] The transparent resin layer (top coat layer) 4 is used for protecting the surface of the decorative material, imparting a design feeling such as a painted feeling and a high gloss, and imparting functions such as antistatic and stain resistance. It may be provided as an outermost layer as needed. Of course, the transparent resin layer is a transparent clear layer. The transparency may be colored and transparent. The transparent resin layer is not particularly limited, and may be provided by a conventionally known material and a forming method according to required physical properties, applications, and the like. The transparent resin layer is formed by applying or printing a resin liquid. As the resin used for the transparent resin layer,
A thermoplastic resin such as an acrylic resin, or a curable resin such as a polyurethane resin may be used, but in terms of surface physical properties, durability, and the like, polyester resins, aminoalkyd resins, thermosetting acrylic resins, silicone resins, and the like. Thermosetting resins are preferred. The resin liquid (ink or coating liquid) may be formed as a solvent-free or solvent-diluted solution by a known forming method such as a printing method such as gravure offset printing and a coating method such as roll coating and curtain flow coating. Various additives such as a filler, an extender, a coloring agent, a lubricant, a lubricant, an ultraviolet absorber, and a light stabilizer are appropriately added to the resin liquid as needed.

【0023】〔化粧材の用途〕化粧材の用途は特に制限
は無い。例えば、壁面、天井、床等の建築物内装材、冷
蔵庫、空調器、暖房機等の家電製品表面材、ユニットバ
ス、厨房等の住設機器表面材、エレベータ内装材、間仕
切り表面材、自動車、電車、航空機、船舶等の乗物内装
材等である。
[Use of Cosmetic Material] The use of the cosmetic material is not particularly limited. For example, building interior materials such as walls, ceilings, floors, etc., surface materials for home appliances such as refrigerators, air conditioners, and heaters, unit baths, surface materials for housing equipment such as kitchens, interior materials for elevators, partition surface materials, automobiles, Vehicle interior materials such as trains, aircraft, and ships.

【0024】[0024]

【実施例】以下、本発明を実施例によって、更に具体的
に説明する。
EXAMPLES The present invention will be described more specifically with reference to the following examples.

【0025】図3の如き構成の化粧材Dを次の様にして
製造した。着色不透明基材Bの基材素材2として、鉄と
亜鉛とによる合金メッキを鉄板に施したメッキ鋼板(厚
み0.45mm)を用意した。そして、この片面全面に
熱硬化性ポリエステル系樹脂からなるプライマー塗料を
ロールコートして後、加熱硬化させてプライマー層5を
形成した。次いで、プライマー層の上に、熱硬化性ポリ
エステル系樹脂からなる灰色の着色インキを、カーテン
フローコートした後、加熱硬化して、灰色のにベースコ
ート層6(全面ベタ層の着色層でもある)を形成して、
着色不透明基材Bとした。
A decorative material D having the structure shown in FIG. 3 was manufactured as follows. As a base material 2 of the colored opaque base material B, a plated steel plate (0.45 mm thick) in which an alloy plate of iron and zinc was applied to an iron plate was prepared. Then, a primer coating composed of a thermosetting polyester resin was roll-coated on the entire surface of one side, and then heated and cured to form a primer layer 5. Then, a gray colored ink composed of a thermosetting polyester resin is coated on the primer layer by curtain flow coating, and then cured by heating to form a gray base coat layer 6 (which is also a solid color layer on the entire surface). Forming
This was a colored opaque substrate B.

【0026】次いで、上記着色不透明基材Bのベースコ
ート層6を形成した側の面に、ビヒクルのバインダーの
樹脂には熱硬化性ポリエステル系樹脂を使用し、該樹脂
100重量部に対して、シルバータイプの二酸化チタン
被覆雲母粉(主たる粒径6μm)10重量部含有させた
インキを調整し、このインキをシルクスクリーン印刷し
た後、加熱硬化して、一部分にワンポイントの鳥の絵柄
を表すパターン形状に透明な可変絵柄層1を形成した。
Next, on the surface of the colored opaque base material B on which the base coat layer 6 is formed, a thermosetting polyester resin is used as a vehicle binder resin. An ink containing 10 parts by weight of titanium dioxide-coated mica powder (main particle size 6 μm) was prepared, silk-screen-printed this ink, and then heat-cured to partially form a pattern representing a one-point bird pattern To form a transparent variable pattern layer 1.

【0027】更に次に、可変絵柄層1上を含む全面柄と
して、可変絵柄層の柄パターンよりも小柄な雲柄(御影
石の劈開面の様な柄)を有する透明で全体的色調がピン
ク色の上絵柄層7を、ビヒクルのバインダーの樹脂が熱
硬化性ポリエステル系樹脂で、これに着色顔料を添加し
てなるインキを用いて、グラビアオフセット印刷した
後、加熱硬化して形成した。そして、最後にトップコー
ト層として、熱硬化性ポリエステル系樹脂からなる透明
インキをカーテンフローコートして、加熱硬化させ、厚
さ15μmの透明樹脂層4を形成して、化粧鋼板として
本発明の化粧材Dを得た。
Next, as the whole pattern including the upper part of the variable pattern layer 1, a transparent and overall color tone having a cloud pattern smaller than the pattern pattern of the variable pattern layer (a pattern like a cleavage plane of granite) is pink. The upper pattern layer 7 was formed by gravure offset printing using an ink obtained by adding a coloring pigment to a resin of a vehicle binder which is a thermosetting polyester resin, and then heating and curing. Finally, as a top coat layer, a transparent ink made of a thermosetting polyester resin is curtain flow coated and cured by heating to form a transparent resin layer 4 having a thickness of 15 μm. Material D was obtained.

【0028】得られた化粧材は、可変絵柄層の柄が、或
る角度から見ると上絵柄層とベースコート層とによる雲
柄の中で輝いて見え、また別の或る角度から見ると見え
ず、見えるのは雲柄のみであった。化粧材は、従来に無
く、斬新な意匠表現のものとなった。
In the obtained decorative material, the pattern of the variable pattern layer appears to shine in the cloud pattern formed by the upper pattern layer and the base coat layer when viewed from a certain angle, and also when viewed from another certain angle. But only the cloud pattern was visible. Cosmetic materials have never before existed, and have become novel design expressions.

【0029】[0029]

【発明の効果】本発明の化粧材によれば、絵柄層を特
定材料からなる可変絵柄層とし、且つその下の基材を着
色不透明基材とする事で、該基材が白色等の淡色の場合
には、或る角度から見ると、可変絵柄層の柄が輝いて浮
き上がって見え、また別の角度から見ると、可変絵柄層
の柄が暗色の影状に見える様にする事ができる。また、
着色不透明基材が濃色の場合には、或る角度から見る
と、可変絵柄層の柄が輝いて浮き上がって見え、また別
の角度から見ると、可変絵柄層の柄は輝きを失うが、僅
かに輝いて見える様にする事ができる。この様な結果、
化粧材は、従来に無い斬新な意匠表現が可能となる。 可変絵柄層をシルクスクリーン印刷で形成した層とす
れば、厚みを厚く出来、上記可変絵柄層の見え方の変化
を大きく出来る。
According to the decorative material of the present invention, the pattern layer is a variable pattern layer made of a specific material, and the base material below the base material is a colored opaque base material. In the case of, when viewed from a certain angle, the pattern of the variable pattern layer can be seen to shine and rise, and when viewed from another angle, the pattern of the variable pattern layer can be made to look like a dark shadow. . Also,
When the colored opaque substrate is dark, when viewed from a certain angle, the pattern of the variable pattern layer shines and appears to rise, and when viewed from another angle, the pattern of the variable pattern layer loses shine, You can make it look slightly shiny. As a result,
The cosmetic material enables a novel and innovative design expression that has never been seen before. If the variable pattern layer is a layer formed by silk screen printing, the thickness can be increased, and the change in the appearance of the variable pattern layer can be increased.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の化粧材の形態例の幾つかを例示する断
面図。
FIG. 1 is a cross-sectional view illustrating some embodiments of a cosmetic material of the present invention.

【図2】本発明の化粧材の他の形態例を示す断面図。FIG. 2 is a sectional view showing another embodiment of the decorative material of the present invention.

【図3】本発明の化粧材の他の形態例を示す断面図。FIG. 3 is a sectional view showing another embodiment of the decorative material of the present invention.

【符号の説明】[Explanation of symbols]

1 可変絵柄層 2 基材素材 3 着色層 4 透明樹脂層 5 プライマー層 6 ベースコート層 7 上絵柄層 B 着色不透明基材 D 化粧材 DESCRIPTION OF SYMBOLS 1 Variable pattern layer 2 Base material 3 Color layer 4 Transparent resin layer 5 Primer layer 6 Base coat layer 7 Upper pattern layer B Color opaque substrate D Cosmetic material

───────────────────────────────────────────────────── フロントページの続き (72)発明者 廣岡 智生 神奈川県愛甲郡愛川町中津4013番地 大日 本エリオ株式会社内 (72)発明者 根津 美智子 東京都新宿区市谷加賀町一丁目1番1号 大日本印刷株式会社内 Fターム(参考) 4F100 AA21B AA21H AB03 AB18 AC05B AC05H AK01B AK41 AR00A BA02 BA05 CA13B EH71 EJ65 GB08 GB31 GB33 GB48 HB00A HB06B HB31B JL10A JN02A JN24B JN24H ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Tomio Hirooka 4013 Nakatsu, Aikawa-cho, Aiko-gun, Kanagawa Pref. Dainichi Erio Co., Ltd. F-term (reference) in Dai Nippon Printing Co., Ltd. 4F100 AA21B AA21H AB03 AB18 AC05B AC05H AK01B AK41 AR00A BA02 BA05 CA13B EH71 EJ65 GB08 GB31 GB33 GB48 HB00A HB06B HB31B JL10A JN02A JN24B JN24H

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 着色不透明基材に、バインダー樹脂中に
シルバータイプ又は虹彩色タイプの二酸化チタン被覆雲
母粉を含有する可変絵柄層がパターン状に形成され、該
可変絵柄層で表される絵柄の見え方が見る角度によって
変化する、化粧材。
1. A colored opaque base material, wherein a variable pattern layer containing silver type or iris type titanium dioxide-coated mica powder in a binder resin is formed in a pattern, and a pattern represented by the variable pattern layer is formed. A cosmetic material whose appearance changes depending on the viewing angle.
【請求項2】 可変絵柄層が、シルクスクリーン印刷で
形成されてなる、請求項1記載の化粧材。
2. The decorative material according to claim 1, wherein the variable pattern layer is formed by silk screen printing.
JP10195208A 1998-07-10 1998-07-10 Decorative material Withdrawn JP2000025188A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10195208A JP2000025188A (en) 1998-07-10 1998-07-10 Decorative material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10195208A JP2000025188A (en) 1998-07-10 1998-07-10 Decorative material

Publications (1)

Publication Number Publication Date
JP2000025188A true JP2000025188A (en) 2000-01-25

Family

ID=16337264

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10195208A Withdrawn JP2000025188A (en) 1998-07-10 1998-07-10 Decorative material

Country Status (1)

Country Link
JP (1) JP2000025188A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004050461A (en) * 2002-07-17 2004-02-19 Nisshin Steel Co Ltd Clear coated metal plate showing sharp hue
JP2010243814A (en) * 2009-04-07 2010-10-28 Toppan Printing Co Ltd Display plate
JP2014200977A (en) * 2013-04-03 2014-10-27 日本カーバイド工業株式会社 Decorative sheet
CN104972543A (en) * 2014-04-03 2015-10-14 广东盈然木业有限公司 Wood floor surface treatment method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004050461A (en) * 2002-07-17 2004-02-19 Nisshin Steel Co Ltd Clear coated metal plate showing sharp hue
JP2010243814A (en) * 2009-04-07 2010-10-28 Toppan Printing Co Ltd Display plate
JP2014200977A (en) * 2013-04-03 2014-10-27 日本カーバイド工業株式会社 Decorative sheet
CN104972543A (en) * 2014-04-03 2015-10-14 广东盈然木业有限公司 Wood floor surface treatment method

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