IT1266647B1 - Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa - Google Patents

Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa

Info

Publication number
IT1266647B1
IT1266647B1 IT93MI002317A ITMI932317A IT1266647B1 IT 1266647 B1 IT1266647 B1 IT 1266647B1 IT 93MI002317 A IT93MI002317 A IT 93MI002317A IT MI932317 A ITMI932317 A IT MI932317A IT 1266647 B1 IT1266647 B1 IT 1266647B1
Authority
IT
Italy
Prior art keywords
fluorinated
aqueous emulsion
monomers
polymerization
olephine
Prior art date
Application number
IT93MI002317A
Other languages
English (en)
Inventor
Julio A Abusleme
Pier Antonio Guarda
Pasquale Ralph J De
Original Assignee
Ausimont Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ausimont Spa filed Critical Ausimont Spa
Publication of ITMI932317A0 publication Critical patent/ITMI932317A0/it
Priority to IT93MI002317A priority Critical patent/IT1266647B1/it
Priority to DE69405680T priority patent/DE69405680T2/de
Priority to AT94116994T priority patent/ATE158311T1/de
Priority to ES94116994T priority patent/ES2107729T3/es
Priority to EP94116994A priority patent/EP0650982B1/en
Priority to RU94039283/04A priority patent/RU2128667C1/ru
Priority to KR1019940027933A priority patent/KR100345912B1/ko
Priority to TW083110027A priority patent/TW277065B/zh
Priority to JP6267088A priority patent/JPH07188337A/ja
Priority to CA002134710A priority patent/CA2134710A1/en
Publication of ITMI932317A1 publication Critical patent/ITMI932317A1/it
Priority to US08/772,865 priority patent/US6096795A/en
Application granted granted Critical
Publication of IT1266647B1 publication Critical patent/IT1266647B1/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
IT93MI002317A 1993-10-29 1993-10-29 Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa IT1266647B1 (it)

Priority Applications (11)

Application Number Priority Date Filing Date Title
IT93MI002317A IT1266647B1 (it) 1993-10-29 1993-10-29 Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa
DE69405680T DE69405680T2 (de) 1993-10-29 1994-10-27 Verfahren zur (Co)polymerisation von fluorenthaltenden olefinischen Monomeren in wässriger Emulsion
AT94116994T ATE158311T1 (de) 1993-10-29 1994-10-27 Verfahren zur (co)polymerisation von fluorenthaltenden olefinischen monomeren in wässriger emulsion
ES94116994T ES2107729T3 (es) 1993-10-29 1994-10-27 Procedimiento de (co)polimerizacion de monomeros olefinicos fluorados en emulsion acuosa.
EP94116994A EP0650982B1 (en) 1993-10-29 1994-10-27 (Co)Polymerization process of fluorinated olefinic monomers in aqueous emulsion
KR1019940027933A KR100345912B1 (ko) 1993-10-29 1994-10-28 수용액성에멀션내의플루오르화올레핀단위체의(공)중합방법
RU94039283/04A RU2128667C1 (ru) 1993-10-29 1994-10-28 Способ (со)полимеризации фторированных олефиновых мономеров
TW083110027A TW277065B (it) 1993-10-29 1994-10-29
JP6267088A JPH07188337A (ja) 1993-10-29 1994-10-31 弗化オレフィンモノマー類の水性エマルション中での（共）重合法
CA002134710A CA2134710A1 (en) 1993-10-29 1994-10-31 (co)polymerization process of fluorinated olefinic monomers in aqueous emulsion
US08/772,865 US6096795A (en) 1993-10-29 1996-12-26 (CO) polymerization process of fluorinated olefinic monomers in aqueous emulsion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI002317A IT1266647B1 (it) 1993-10-29 1993-10-29 Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa

Publications (3)

Publication Number Publication Date
ITMI932317A0 ITMI932317A0 (it) 1993-10-29
ITMI932317A1 ITMI932317A1 (it) 1995-05-02
IT1266647B1 true IT1266647B1 (it) 1997-01-09

Family

ID=11367125

Family Applications (1)

Application Number Title Priority Date Filing Date
IT93MI002317A IT1266647B1 (it) 1993-10-29 1993-10-29 Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa

Country Status (11)

Country Link
US (1) US6096795A (it)
EP (1) EP0650982B1 (it)
JP (1) JPH07188337A (it)
KR (1) KR100345912B1 (it)
AT (1) ATE158311T1 (it)
CA (1) CA2134710A1 (it)
DE (1) DE69405680T2 (it)
ES (1) ES2107729T3 (it)
IT (1) IT1266647B1 (it)
RU (1) RU2128667C1 (it)
TW (1) TW277065B (it)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1274711B (it) * 1994-08-04 1997-07-24 Ausimont Spa Processo per la preparazione di fluoropolimeri contenenti idrogeno tramite (co)polimerizzazione in sospensione
IT1270703B (it) * 1994-11-17 1997-05-07 Ausimont Spa Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati
IT1273608B (it) * 1995-04-28 1997-07-08 Ausimont Spa Fluoroelastomeri sostanzialmente privi di terminali polari e relativo processo di preparazione
IT1276072B1 (it) * 1995-10-31 1997-10-24 Ausimont Spa Processo di (co)polimerizzazione di monomeri fluorurati per ottenere polimeri contenenti idrogeno
IT1288121B1 (it) * 1996-07-01 1998-09-10 Ausimont Spa Copolimeri termoplastici del vinilidenfluoruro (vdf)
JPH10302800A (ja) * 1997-04-28 1998-11-13 Kureha Chem Ind Co Ltd 電池用バインダー溶液、これを含有する電極合剤、およびそれを用いた電極構造体ならびに電池
AU750308B2 (en) * 1998-02-26 2002-07-18 Atofina Chemicals, Inc. Copolymers of vinylidene fluoride and hexafluoropropylene having reduced extractable content and improved solution clarity
ITMI991516A1 (it) * 1999-07-09 2001-01-09 Ausimont Spa Sintesi dei copolimeri peralogenati termoprocesabili del clorotrifluoroetilene
ITMI991514A1 (it) 1999-07-09 2001-01-09 Ausimont Spa Co polimeri peralogenati termoprocessabili del clorotrifluoroetilene
ITMI991515A1 (it) 1999-07-09 2001-01-09 Ausimont Spa Co polimeri peralogenati termoprocessabili del clorotrifluoroetilene
IT1317834B1 (it) 2000-02-15 2003-07-15 Ausimont Spa Fluoropolimeri termoplastici.
RU2281280C2 (ru) 2000-06-02 2006-08-10 Асахи Гласс Компани Лтд. Способ получения фторированных производных этиленненасыщенных соединений
CA2312194A1 (fr) * 2000-06-13 2001-12-13 Mario Boucher Elastomeres reticulables fluores bromosulfones a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
IT1318596B1 (it) * 2000-06-23 2003-08-27 Ausimont Spa Copolimeri termoprocessbili del tfe.
US6649720B2 (en) * 2001-02-14 2003-11-18 Atofina Chemicals, Inc. Ethane as a chain transfer agent for vinylidene fluoride polymerization
KR100472079B1 (ko) * 2001-05-24 2005-02-21 에스케이케미칼주식회사 불소수지의 제조방법
US6734264B1 (en) * 2002-12-16 2004-05-11 Atofina Chemicals, Inc. Chain transfer agent
US7226957B1 (en) * 2003-11-03 2007-06-05 University Of Iowa Research Foundation Method for producing polymers with controlled molecular weight and end group functionality using photopolymerization in microemulsions
US8920885B2 (en) 2006-11-21 2014-12-30 Dr. Ben Curatolo, Inc. Corrosion-resistant, chromium-free, self-priming coatings curable by ultraviolet light
EP2133370A1 (en) * 2008-06-02 2009-12-16 Solvay Solexis S.p.A. Vinylidene fluoride and trifluoroethylene containing polymers
ES2894902T3 (es) * 2016-03-23 2022-02-16 Agc Inc Método para la producción de ésteres de ácidos alfa-fluoro-acrílicos y composición que contiene un derivado de fluorociclopropano muy puro y composición que contiene un éster de ácido alfa-fluoro-acrílico muy puro
WO2018065396A1 (en) * 2016-10-05 2018-04-12 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride polymer
CN116209684A (zh) * 2020-09-30 2023-06-02 大金工业株式会社 共聚物、压缩成型体、传递成型体和被压缩构件
WO2022071531A1 (ja) * 2020-09-30 2022-04-07 ダイキン工業株式会社 共重合体、射出成形体、被圧縮部材および被覆電線

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2600202A (en) * 1950-06-28 1952-06-10 Gen Electric Method for polymerizing chlorotrifluoroethylene
US2559752A (en) * 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2978396A (en) * 1956-12-18 1961-04-04 Exxon Research Engineering Co Radiation induced ethylene polymerization
US2912373A (en) * 1957-11-08 1959-11-10 Minnesota Mining & Mfg Polymerization of fluoroethylene monomers
US3467635A (en) * 1964-10-30 1969-09-16 Du Pont Copolymers of tetrafluoroethylene and olefins curable to elastomers
GB1146188A (en) * 1965-07-30 1969-03-19 Montedison Spa Polymerization of halogen containing olefins
US3624250A (en) * 1970-01-20 1971-11-30 Du Pont Copolymers of ethylene/tetrafluoroethylene and of ethylene/chlorotrifluoroethylene
US3892641A (en) * 1970-05-26 1975-07-01 Japan Atomic Energy Res Inst Process for producing a copolymer of tetrafluoroethylene and propylene
US3865845A (en) * 1971-02-24 1975-02-11 Paul Raphael Resnick Fluorinated dioxoles
US3933773A (en) * 1972-06-08 1976-01-20 Thiokol Corporation Thermoplastic elastomeric copolymers and terpolymers of tetrafluoroethylene and propylene and method of making the same
JPS5125274B2 (it) * 1973-02-23 1976-07-29
US3978030A (en) * 1973-08-01 1976-08-31 E. I. Du Pont De Nemours And Company Polymers of fluorinated dioxoles
JPS5396088A (en) * 1977-02-01 1978-08-22 Asahi Glass Co Ltd Preparation of fluorine-containing copolymer
JPS53125491A (en) * 1977-04-08 1978-11-01 Daikin Ind Ltd Fluorine-containing polymer easily curable and its curable composition
JPS5950162B2 (ja) * 1977-05-20 1984-12-06 旭硝子株式会社 改良されたエチレン−四弗化エチレン系共重合体及びその製法
JPS5838707A (ja) * 1981-08-20 1983-03-07 イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− パ−フルオロ−２，２−ジメチル−１，３−ジオキソ−ルの無定形共重合体
US4429143A (en) * 1981-09-28 1984-01-31 E. I. Du Pont De Nemours & Co. Cyclic monomers derived from trifluoropyruvate esters
US4399264A (en) * 1981-11-19 1983-08-16 E. I. Du Pont De Nemours & Co. Perfluorodioxole and its polymers
FR2519007B1 (fr) * 1981-12-24 1985-12-27 Charbonnages Ste Chimique Copolymeres modifies de l'ethylene et d'au moins une a-olefine et procede pour leur preparation
JPS59197411A (ja) * 1983-04-25 1984-11-09 Daikin Ind Ltd エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体
US4694045A (en) * 1985-12-11 1987-09-15 E. I. Du Pont De Nemours And Company Base resistant fluoroelastomers
US4675380A (en) * 1985-10-25 1987-06-23 E. I. Du Pont De Nemours And Company Melt-processible tetrafluoroethylene/perfluoroolefin copolymer granules and processes for preparing them
IT1189092B (it) * 1986-04-29 1988-01-28 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
JP2773215B2 (ja) * 1989-04-07 1998-07-09 ダイキン工業株式会社 高分子誘電体材料
US4973633A (en) * 1989-05-15 1990-11-27 E. I. Du Pont De Nemours And Company Peroxide-curable fluoroelastomers having bromine an iodine curesites and the preparation thereof
IT1235545B (it) * 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
IT1247934B (it) * 1991-05-15 1995-01-05 Ausimont Spa Fluoroelastomeri a base di vinilidenfluoruro, dotati di superiore resistenza alle basi
IT1271136B (it) * 1993-03-23 1997-05-27 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
IT1265067B1 (it) * 1993-05-18 1996-10-30 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
IT1264662B1 (it) * 1993-07-05 1996-10-04 Ausimont Spa Perflurodiossoli loro omopolimeri e copolimeri e loro impiego per il rivestimento di cavi elettrici
IT1264661B1 (it) * 1993-07-05 1996-10-04 Ausimont Spa Copolimeri termoprocessabilin del tetrafluoroetilene

Also Published As

Publication number Publication date
ES2107729T3 (es) 1997-12-01
US6096795A (en) 2000-08-01
KR100345912B1 (ko) 2002-11-23
TW277065B (it) 1996-06-01
KR950014150A (ko) 1995-06-15
JPH07188337A (ja) 1995-07-25
ITMI932317A1 (it) 1995-05-02
ITMI932317A0 (it) 1993-10-29
ATE158311T1 (de) 1997-10-15
CA2134710A1 (en) 1995-05-03
RU2128667C1 (ru) 1999-04-10
RU94039283A (ru) 1996-08-20
DE69405680D1 (de) 1997-10-23
EP0650982A1 (en) 1995-05-03
DE69405680T2 (de) 1998-04-09
EP0650982B1 (en) 1997-09-17

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TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19961127