IT1265219B1 - Composizione biodegradabile di polietilene chimicamente legato con amido e procedimento per la sua preparazione - Google Patents
Composizione biodegradabile di polietilene chimicamente legato con amido e procedimento per la sua preparazioneInfo
- Publication number
- IT1265219B1 IT1265219B1 IT93MI002486A ITMI932486A IT1265219B1 IT 1265219 B1 IT1265219 B1 IT 1265219B1 IT 93MI002486 A IT93MI002486 A IT 93MI002486A IT MI932486 A ITMI932486 A IT MI932486A IT 1265219 B1 IT1265219 B1 IT 1265219B1
- Authority
- IT
- Italy
- Prior art keywords
- polyethylene
- starch
- preparation
- acid
- weight
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/02—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
La presente invenzione riguarda un film biodegradabile preparato mediante legame dell'amido e delle catene di polietilene impiegando polietilene, che è una poliolefina avente una applicazione generale la più ampia, un agente di accoppiamento come anidride maleica, anidride metacrilica o maleimmide, che si legano con l'amido ed il polietilene, ed un comanomero catalitico acido come acido acrilico e/o acido metacrilico, ed un procedimento per la loro preparazione.La presente invenzione è stata realizzata variando l'agente di accoppiamento come anidride maleica, anidride metacrilica o maleimmide in una quantità di 0,01-10% in peso, il comanomero catalitico acido come acido acrilico e/o acido metacrilico in una quantità di 0,01-10% in peso, e l'iniziatore radicalico in una quantità di 0,01-1,0% in peso, sulla base della quantità di polietilene, e fu applicata l'estrusione reattiva per abbassare il costo di produzione tramite semplificazione del procedimento.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR920022256 | 1992-11-24 | ||
KR1019930014073A KR960012445B1 (ko) | 1992-11-24 | 1993-07-23 | 전분이 화학결합된 생분해성 폴리에틸렌 조성물 및 그 제조방법 |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI932486A0 ITMI932486A0 (it) | 1993-11-24 |
ITMI932486A1 ITMI932486A1 (it) | 1995-05-24 |
IT1265219B1 true IT1265219B1 (it) | 1996-10-31 |
Family
ID=26629374
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT93MI002486A IT1265219B1 (it) | 1992-11-24 | 1993-11-24 | Composizione biodegradabile di polietilene chimicamente legato con amido e procedimento per la sua preparazione |
Country Status (8)
Country | Link |
---|---|
US (1) | US5461094A (it) |
JP (1) | JPH06316655A (it) |
KR (1) | KR960012445B1 (it) |
CN (1) | CN1037352C (it) |
CA (1) | CA2109657A1 (it) |
GB (1) | GB2272699B (it) |
IT (1) | IT1265219B1 (it) |
TW (1) | TW316274B (it) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2997995B2 (ja) * | 1995-09-13 | 2000-01-11 | 日本コーンスターチ株式会社 | 生分解性樹脂組成物の水系分散液 |
US5667574A (en) * | 1996-11-06 | 1997-09-16 | Chi May Co., Ltd. | Starch-based composition for preparing an environment degradable α-olefinic polymer molding material |
KR100368738B1 (ko) * | 1996-12-12 | 2003-04-21 | 에스케이 주식회사 | 생/광분해성 농업용 멀칭필름 조성물과 이의 제조방법 및 이로 부터 제조된 성형물 |
JP2001098081A (ja) * | 1999-09-30 | 2001-04-10 | Sakae Riken Kogyo Kk | オレフィン系樹脂組成物及びその製造方法 |
AU5064201A (en) * | 2000-03-16 | 2001-09-24 | Sanjiv Satyendra Nevgi | Modified plastic granules for manufacturing flammable type polythene film |
KR20020066258A (ko) * | 2001-02-09 | 2002-08-14 | 김희성 | 환경 친화성 수지 조성물 및 그의 제조방법 |
KR100458042B1 (ko) * | 2001-09-11 | 2004-11-26 | 호남석유화학 주식회사 | 전분함유 폴리에틸렌 생붕괴성 수지 조성물 및 그 제조방법 |
KR20030037530A (ko) * | 2001-11-06 | 2003-05-14 | 박재석 | 일회용 전분제 용기 및 그 제조방법 |
WO2003050153A1 (en) * | 2001-12-12 | 2003-06-19 | North Carolina State University | Methods of co2-assisted reactive extrusion |
US7608649B2 (en) * | 2002-02-28 | 2009-10-27 | Cereplast, Inc. | Biodegradable materials from starch-grafted polymers |
KR100481420B1 (ko) * | 2002-10-22 | 2005-04-08 | 주식회사 이래화학 | 생분해성 소재를 이용한 혈관주사용 주사바늘 |
KR100602386B1 (ko) * | 2003-07-11 | 2006-07-20 | 김찬형 | 복합분해성 열가소성 중합체 조성물 및 이로부터 제조되는복합분해성 열가소성 중합체 제품 및 그의 제조 방법 |
WO2005087857A1 (ja) * | 2004-03-10 | 2005-09-22 | Agri Future Joetsu Co., Ltd. | 澱粉配合樹脂組成物、その成形品及びその製造方法 |
US20080249212A1 (en) * | 2007-04-06 | 2008-10-09 | Sigworth William D | Starch-polyolefin composites with improved performance |
AU2008252561A1 (en) * | 2007-04-30 | 2008-11-27 | Peel Away Limited | Paint remover |
US8613834B2 (en) * | 2008-04-03 | 2013-12-24 | Basf Se | Paper coating or binding formulations and methods of making and using same |
US20090275699A1 (en) * | 2008-05-05 | 2009-11-05 | Mingfu Zhang | Starch containing formaldehyde-free thermoset binders for fiber products |
FR2955329B1 (fr) * | 2010-01-15 | 2013-02-01 | Roquette Freres | Procede de preparation de compositions thermoplastiques a base d'amidon plastifie et compositions |
CN102417648A (zh) * | 2011-11-23 | 2012-04-18 | 吴江明峰聚氨酯制品有限公司 | 一种可生物降解的聚乙烯塑料膜 |
US9718258B2 (en) | 2011-12-20 | 2017-08-01 | Kimberly-Clark Worldwide, Inc. | Multi-layered film containing a biopolymer |
US9327438B2 (en) | 2011-12-20 | 2016-05-03 | Kimberly-Clark Worldwide, Inc. | Method for forming a thermoplastic composition that contains a plasticized starch polymer |
US9815949B2 (en) * | 2013-07-31 | 2017-11-14 | Abdul Rasoul Oromiehie | Biodegradable nanocomposites containing nanoclay and titanium dioxide nanoparticles |
US9464188B2 (en) | 2013-08-30 | 2016-10-11 | Kimberly-Clark Worldwide, Inc. | Simultaneous plasticization and compatibilization process and compositions |
EP3227379B1 (en) * | 2014-12-02 | 2020-07-29 | B.G. Negev Technologies and Applications Ltd., at Ben-Gurion University | Quaternized starches for use as anti-microbial agents |
US20170002185A1 (en) | 2015-06-30 | 2017-01-05 | BiologiQ, Inc. | Articles Formed with Biodegradable Materials |
US11674018B2 (en) | 2015-06-30 | 2023-06-13 | BiologiQ, Inc. | Polymer and carbohydrate-based polymeric material blends with particular particle size characteristics |
US11926929B2 (en) | 2015-06-30 | 2024-03-12 | Biologiq, Inc | Melt blown nonwoven materials and fibers including starch-based polymeric materials |
US11149144B2 (en) | 2015-06-30 | 2021-10-19 | BiologiQ, Inc. | Marine biodegradable plastics comprising a blend of polyester and a carbohydrate-based polymeric material |
US11111355B2 (en) | 2015-06-30 | 2021-09-07 | BiologiQ, Inc. | Addition of biodegradability lending additives to plastic materials |
US11111363B2 (en) | 2015-06-30 | 2021-09-07 | BiologiQ, Inc. | Articles formed with renewable and/or sustainable green plastic material and carbohydrate-based polymeric materials lending increased strength and/or biodegradability |
US10920044B2 (en) | 2015-06-30 | 2021-02-16 | BiologiQ, Inc. | Carbohydrate-based plastic materials with reduced odor |
US11046840B2 (en) | 2015-06-30 | 2021-06-29 | BiologiQ, Inc. | Methods for lending biodegradability to non-biodegradable plastic materials |
US11674014B2 (en) | 2015-06-30 | 2023-06-13 | BiologiQ, Inc. | Blending of small particle starch powder with synthetic polymers for increased strength and other properties |
US11926940B2 (en) | 2015-06-30 | 2024-03-12 | BiologiQ, Inc. | Spunbond nonwoven materials and fibers including starch-based polymeric materials |
US10995201B2 (en) | 2015-06-30 | 2021-05-04 | BiologiQ, Inc. | Articles formed with biodegradable materials and strength characteristics of the same |
US11879058B2 (en) | 2015-06-30 | 2024-01-23 | Biologiq, Inc | Yarn materials and fibers including starch-based polymeric materials |
US10919203B2 (en) * | 2015-06-30 | 2021-02-16 | BiologiQ, Inc. | Articles formed with biodegradable materials and biodegradability characteristics thereof |
US11359088B2 (en) | 2015-06-30 | 2022-06-14 | BiologiQ, Inc. | Polymeric articles comprising blends of PBAT, PLA and a carbohydrate-based polymeric material |
US10752759B2 (en) | 2015-06-30 | 2020-08-25 | BiologiQ, Inc. | Methods for forming blended films including renewable carbohydrate-based polymeric materials with high blow up ratios and/or narrow die gaps for increased strength |
TR201808556T4 (tr) | 2015-10-27 | 2018-07-23 | Pep Licensing Ltd | Bir biyobozunur, biyogübrelenebilir, biyoçürütülebilir plastik. |
US9925707B2 (en) | 2015-12-22 | 2018-03-27 | Pep Licensing Limited | Process for preparation of biodegradable biocompostable biodigestible polyolefins |
PE20191321A1 (es) * | 2016-11-22 | 2019-09-24 | Polymateria Ltd | Polimero degradable y metodo de produccion |
US11505687B2 (en) | 2020-08-05 | 2022-11-22 | Nano And Advanced Materials Institute Limited | Environmentally degradable foamed master batch composition and using thereof |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1485833A (en) * | 1973-11-28 | 1977-09-14 | Coloroll Ltd | Synthetic-resin-based compositions |
US3867324A (en) * | 1972-07-28 | 1975-02-18 | Union Carbide Corp | Environmentally degradable-biodegradable blend of an oxyalkanoyl polymer and an environmentally degradable ethylene polymer |
DE2436555C3 (de) * | 1974-07-30 | 1979-12-13 | Maizena Gmbh, 2000 Hamburg | Verfahren zur Herstellung von Pfropfpolymeren durch Umsetzen von Stärke mit wasserlöslichen oder in Wasser dispergierbaren Vinyl- und/ oder Acrylpolymeren |
GB1600496A (en) * | 1977-09-16 | 1981-10-14 | Coloroll Ltd | Plasticsbased composition |
US4337181A (en) * | 1980-01-17 | 1982-06-29 | The United States Of America As Represented By The Secretary Of Agriculture | Biodegradable starch-based blown films |
US4375535A (en) * | 1980-04-28 | 1983-03-01 | Standard Brands Incorporated | Stable liquid, amylopectin starch graft copolymer compositions |
JPH075688B2 (ja) * | 1983-02-14 | 1995-01-25 | キュノ、インコーポレーテッド | 変性多糖支持体 |
CH671961A5 (it) * | 1987-02-27 | 1989-10-13 | Amrotex Ag | |
US5162392A (en) * | 1989-05-19 | 1992-11-10 | Agri-Tech Industries, Inc. | Injection moldable biodegradable starch polymer composite |
US5026745A (en) * | 1989-06-12 | 1991-06-25 | Aristech Chemical Corporation | Biodeteriable plastics and blends |
IT1240503B (it) * | 1990-07-25 | 1993-12-17 | Butterfly Srl | Miscela polimerica amidacea particolarmente per la produzione di film e simili e procedimento per la sua produzione. |
BE1005694A3 (fr) * | 1992-02-07 | 1993-12-21 | Solvay | Composition a base d'amidon. |
US5321064A (en) * | 1992-05-12 | 1994-06-14 | Regents Of The University Of Minnesota | Compositions of biodegradable natural and synthetic polymers |
-
1993
- 1993-07-23 KR KR1019930014073A patent/KR960012445B1/ko not_active IP Right Cessation
- 1993-11-20 TW TW082109789A patent/TW316274B/zh active
- 1993-11-22 CA CA002109657A patent/CA2109657A1/en not_active Abandoned
- 1993-11-23 US US08/156,371 patent/US5461094A/en not_active Expired - Lifetime
- 1993-11-23 GB GB9324058A patent/GB2272699B/en not_active Expired - Fee Related
- 1993-11-24 JP JP5317408A patent/JPH06316655A/ja active Pending
- 1993-11-24 IT IT93MI002486A patent/IT1265219B1/it active IP Right Grant
- 1993-11-24 CN CN93121455A patent/CN1037352C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR940011556A (ko) | 1994-06-21 |
GB2272699B (en) | 1997-04-02 |
GB2272699A (en) | 1994-05-25 |
JPH06316655A (ja) | 1994-11-15 |
GB9324058D0 (en) | 1994-01-12 |
CA2109657A1 (en) | 1994-05-25 |
CN1037352C (zh) | 1998-02-11 |
CN1092083A (zh) | 1994-09-14 |
US5461094A (en) | 1995-10-24 |
ITMI932486A0 (it) | 1993-11-24 |
TW316274B (it) | 1997-09-21 |
ITMI932486A1 (it) | 1995-05-24 |
KR960012445B1 (ko) | 1996-09-20 |
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Legal Events
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0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970829 |