IT1256801B - Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. - Google Patents
Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli.Info
- Publication number
- IT1256801B IT1256801B ITTO920080A ITTO920080A IT1256801B IT 1256801 B IT1256801 B IT 1256801B IT TO920080 A ITTO920080 A IT TO920080A IT TO920080 A ITTO920080 A IT TO920080A IT 1256801 B IT1256801 B IT 1256801B
- Authority
- IT
- Italy
- Prior art keywords
- polyols
- hydrogenation
- hydrogenolysis
- catalyst
- carbohydrates
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Composizione di catalizzatore metallico, su supporto inerte, particolarmente adatto per reazioni di idrogenolisi di polioli superiori, caratterizzato dal fatto che comprende, con riferimento a 100 parti del catalizzatore:a) da 0,5 a 5% in peso di rutenio,b) da 1 a 10% in peso di un metallo scelto dal gruppo che consiste di palladio, platino e rodio, e c) da 0,5 a 2,5% in peso di rame,in cui i1 tenore di rame è inferiore al tenore del metallo b).Il catalizzatore è impiegato particolarmente per la produzione di polioli inferiori quali etandiolo, propandiolo, butandioli e glicerina, mediante reazione di idrogenolisi di polioli superiori.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO920080A IT1256801B (it) | 1992-01-31 | 1992-01-31 | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. |
AU34520/93A AU3452093A (en) | 1992-01-31 | 1993-01-28 | A hydrogentation catalyst, and a method for its preparation and use, in particular for hydrogenation and/or hydrogenolysis of carbohydrates and polyhydric alcohols |
EP93914535A EP0625072A1 (en) | 1992-01-31 | 1993-01-28 | A hydrogentation catalyst, and a method for its preparation and use, in particular for hydrogenation and/or hydrogenolysis of carbohydrates and polyhydric alcohols |
IL93104546A IL104546A0 (en) | 1992-01-31 | 1993-01-28 | Hydrogenation catalyst,and method for its preparation and use,in particular for hydrogenation and/or hydrogenolysis of carbohydrates and polyhydric alcohols |
PCT/EP1993/000194 WO1993014867A1 (en) | 1992-01-31 | 1993-01-28 | A hydrogentation catalyst, and a method for its preparation and use, in particular for hydrogenation and/or hydrogenolysis of carbohydrates and polyhydric alcohols |
US08/011,189 US5326912A (en) | 1992-01-31 | 1993-01-29 | Hydrogenation catalyst, and a method for its preparation and use, in particular for hydrogenation and/or hydrogenolysis of carbohydrates and polyhydric alcohols |
TW082100591A TW227528B (it) | 1992-01-31 | 1993-01-30 | |
CN93102397A CN1078173A (zh) | 1992-01-31 | 1993-01-31 | 一种氢化,特别是碳水化合物和多元醇的氢化和/或氢解的催化剂及其制备和应用的方法 |
US08/221,810 US5543379A (en) | 1992-01-31 | 1994-04-01 | Hydrogenation catalyst, and a method for its preparation and use, in particular for hydrogenation and/or hydrogenolysis of carbohydrates and polyhydric alcohols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO920080A IT1256801B (it) | 1992-01-31 | 1992-01-31 | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. |
Publications (3)
Publication Number | Publication Date |
---|---|
ITTO920080A0 ITTO920080A0 (it) | 1992-01-31 |
ITTO920080A1 ITTO920080A1 (it) | 1993-07-31 |
IT1256801B true IT1256801B (it) | 1995-12-15 |
Family
ID=11409988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITTO920080A IT1256801B (it) | 1992-01-31 | 1992-01-31 | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. |
Country Status (8)
Country | Link |
---|---|
US (2) | US5326912A (it) |
EP (1) | EP0625072A1 (it) |
CN (1) | CN1078173A (it) |
AU (1) | AU3452093A (it) |
IL (1) | IL104546A0 (it) |
IT (1) | IT1256801B (it) |
TW (1) | TW227528B (it) |
WO (1) | WO1993014867A1 (it) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1256801B (it) * | 1992-01-31 | 1995-12-15 | Novamont Spa | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. |
DE19758788B4 (de) * | 1997-01-17 | 2007-12-13 | Südzucker Aktiengesellschaft Mannheim/Ochsenfurt | Verfahren zur Hydrierung von Glucose oder Glucosegemischen mittels eines Schalenkatalysators |
US6383979B1 (en) * | 1997-08-12 | 2002-05-07 | Tricat Industries, Inc. | Catalyst and process for preparing and using same |
US6339038B1 (en) * | 1998-06-16 | 2002-01-15 | Tanaka Kikinzoku Kogyo K. K. | Catalyst for a fuel cell containing polymer solid electrolyte and method for producing catalyst thereof |
US6291725B1 (en) | 2000-03-03 | 2001-09-18 | Board Of Trustees Operating Michigan State University | Catalysts and process for hydrogenolysis of sugar alcohols to polyols |
US6551960B1 (en) * | 2000-06-19 | 2003-04-22 | Canon Kabushiki Kaisha | Preparation of supported nano-sized catalyst particles via a polyol process |
DE60101743T2 (de) | 2000-06-20 | 2004-12-09 | E.I. Du Pont De Nemours And Co., Wilmington | Katalytische dehydroxylation von diolen und polyolen |
US6841085B2 (en) * | 2001-10-23 | 2005-01-11 | Battelle Memorial Institute | Hydrogenolysis of 6-carbon sugars and other organic compounds |
US6479713B1 (en) * | 2001-10-23 | 2002-11-12 | Battelle Memorial Institute | Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen |
US7033419B1 (en) * | 2003-09-16 | 2006-04-25 | The United States Of America As Represented By The United States Department Of Energy | Method for high temperature mercury capture from gas streams |
GB0325386D0 (en) * | 2003-10-30 | 2003-12-03 | Davy Process Techn Ltd | Process |
US20070172417A1 (en) * | 2005-06-28 | 2007-07-26 | Qinglin Zhang | Hydrogen generation catalysts and systems for hydrogen generation |
MY148259A (en) * | 2005-12-21 | 2013-03-29 | Virent Inc | Catalysts and methods for reforming oxygenated compounds |
ES2547913T3 (es) * | 2006-05-08 | 2015-10-09 | Virent, Inc. | Métodos para generar polioles |
US20080103340A1 (en) * | 2006-10-27 | 2008-05-01 | Archer-Daniels-Midland Company | Applications of biobased glycol compositions |
CN101583583A (zh) * | 2006-12-15 | 2009-11-18 | 巴斯夫欧洲公司 | 通过非均相催化氢解多元醇生产1,2-乙二醇和1,2-丙二醇的方法 |
WO2008071641A1 (de) * | 2006-12-15 | 2008-06-19 | Basf Se | Verfahren zur herstellung von 1,2-ethylenglycol und 1,2-propylenglycol durch heterogen katalysierte hydrogenolyse eines polyols |
BRPI0719504A2 (pt) * | 2006-12-20 | 2017-10-24 | Virent Energy Systems Inc | "reator de fluxo descendente concorrente concorrente para converter um material de partida líquido em um produto gasoso não condensável mediante a utilização de um catalisador heterogêneo, sistema de geração de energia e método para a manufatura de gás não condensável" |
US8017818B2 (en) | 2007-03-08 | 2011-09-13 | Virent Energy Systems, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
US20090088317A1 (en) * | 2007-09-28 | 2009-04-02 | Frye Jr John G | Multi-metal reduction catalysts and methods of producing reduction catalysts |
AR072446A1 (es) * | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | Proceso de hidrogenacion mejorado |
US20090246430A1 (en) | 2008-03-28 | 2009-10-01 | The Coca-Cola Company | Bio-based polyethylene terephthalate polymer and method of making same |
US20100028512A1 (en) * | 2008-03-28 | 2010-02-04 | The Coca-Cola Company | Bio-based polyethylene terephthalate packaging and method of making thereof |
US20090264686A1 (en) * | 2008-04-16 | 2009-10-22 | Holladay Johnathan E | Hydrogenolysis processes and hydrogenolysis catalyst preparation methods |
US20090264687A1 (en) | 2008-04-16 | 2009-10-22 | Battelle Memorial Institute | Chemical Production Processes and Systems |
CN100528347C (zh) * | 2008-07-07 | 2009-08-19 | 上虞市众昌化工有限公司 | 一种以α-氨基酸为原料制备α-氨基醇的方法及所用催化剂和催化剂的制备方法 |
AU2009285699B2 (en) * | 2008-08-27 | 2014-04-10 | Virent, Inc. | Synthesis of liquid fuels from biomass |
JP5197308B2 (ja) * | 2008-11-06 | 2013-05-15 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
US8071820B2 (en) * | 2008-12-23 | 2011-12-06 | Uop Llc | Method for converting glycerol to propanol |
EP3130623A1 (en) | 2009-03-03 | 2017-02-15 | The Coca-Cola Company | Bio-based polyethylene terephthalate packaging and method of making thereof |
WO2010144448A2 (en) * | 2009-06-08 | 2010-12-16 | University Of Kansas | Polyol hydrogenolysis by in-situ generated hydrogen |
CN101921174B (zh) * | 2009-06-10 | 2013-06-12 | 华东理工大学 | 一种氢解山梨醇制备乙二醇和1,2-丙二醇的方法 |
BRPI1010126A2 (pt) * | 2009-06-30 | 2016-03-15 | Virent Inc | método de regeneração de um catalizador de hidrogenação e método para a hidrogenação de uma açucar e a regeneração em linha de um catalizador de hidrogenação que contém depósitos carbonáceos |
BR122019001300B1 (pt) * | 2009-12-23 | 2020-03-03 | Evonik Degussa Gmbh | Processo para produção de adoçantes |
WO2011115781A1 (en) * | 2010-03-17 | 2011-09-22 | The Regents Of The University Of California | Conversion of oxygenates to hydrocarbon fuels by deoxygenation |
CN103357427B (zh) * | 2013-07-31 | 2015-03-25 | 合肥工业大学 | 一种纳米金属/固体碱复合催化剂、其制备方法及其用途 |
WO2017011615A1 (en) | 2015-07-15 | 2017-01-19 | Archer Daniels Midland Company | Improved copper-containing multimetallic catalysts, and method for using the same to make biobased 1,2-propanediol |
WO2019156854A1 (en) * | 2018-02-09 | 2019-08-15 | Archer Daniels Midland Company | Sugar hydrogenolysis with molybdenum co-catalyst selective for producing glycols |
Family Cites Families (20)
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US2965679A (en) * | 1960-12-20 | Process for the production of glycerol | ||
US2852570A (en) * | 1958-09-16 | Process for preparing polyhydric | ||
US2004135A (en) * | 1932-12-23 | 1935-06-11 | Du Pont | Production of polyhydric alcohols |
CH342554A (de) * | 1956-04-28 | 1959-11-30 | Inventa Ag | Verfahren zur Herstellung von mehrwertigen Alkoholen, vorzugsweise 1,3-Propylenglykol, aus Hexiten |
US2868847A (en) * | 1956-10-05 | 1959-01-13 | Engelhard Ind Inc | Hydrogenation of mono-and disaccharides to polyols |
US3901827A (en) * | 1972-09-27 | 1975-08-26 | Exxon Research Engineering Co | Multimetallic catalysts |
FR2223337B1 (it) * | 1973-03-26 | 1977-04-29 | Inst Francais Du Petrole | |
US4111842A (en) * | 1977-06-01 | 1978-09-05 | Stamicarbon, B.V. | Process for the preparation of supported catalysts |
US4366332A (en) * | 1981-01-21 | 1982-12-28 | Hydrocarbon Research, Inc. | Catalytic hydrogenolysis of alditols to product glycerol and polyols |
US4380678A (en) * | 1981-01-21 | 1983-04-19 | Hydrocarbon Research, Inc. | Multi-stage aldoses to polyols process |
US4401823A (en) * | 1981-05-18 | 1983-08-30 | Uop Inc. | Hydrogenolysis of polyhydroxylated compounds |
BR8204165A (pt) * | 1981-07-22 | 1983-07-12 | Du Pont | Processo para hidrogenolise de pentitois e misturas de pentitois com outros glicois hexitois e misturas de hexitois com outros poliois e poliois para etileno glicol |
US4476331A (en) * | 1982-02-11 | 1984-10-09 | Ethyl Corporation | Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage |
US4430253A (en) * | 1982-02-11 | 1984-02-07 | Ethyl Corporation | Sulfide-modified ruthenium catalyst |
US4496780A (en) * | 1983-06-22 | 1985-01-29 | Uop Inc. | Hydrocracking of polyols |
US4591578A (en) * | 1985-02-04 | 1986-05-27 | American Cyanamid Company | Catalyst of molybdenum on wide-pore carbon support |
US4743577A (en) * | 1986-10-14 | 1988-05-10 | Amoco Corporation | Catalyst composition |
US4787969A (en) * | 1986-11-21 | 1988-11-29 | Exxon Research And Engineering Company | Reforming with polymetallic catalysts |
US5149680A (en) * | 1987-03-31 | 1992-09-22 | The British Petroleum Company P.L.C. | Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters |
IT1256801B (it) * | 1992-01-31 | 1995-12-15 | Novamont Spa | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'idrogenazione e/o idrogenolisi di carboidrati e polioli. |
-
1992
- 1992-01-31 IT ITTO920080A patent/IT1256801B/it active IP Right Grant
-
1993
- 1993-01-28 EP EP93914535A patent/EP0625072A1/en not_active Ceased
- 1993-01-28 AU AU34520/93A patent/AU3452093A/en not_active Abandoned
- 1993-01-28 IL IL93104546A patent/IL104546A0/xx unknown
- 1993-01-28 WO PCT/EP1993/000194 patent/WO1993014867A1/en not_active Application Discontinuation
- 1993-01-29 US US08/011,189 patent/US5326912A/en not_active Expired - Fee Related
- 1993-01-30 TW TW082100591A patent/TW227528B/zh active
- 1993-01-31 CN CN93102397A patent/CN1078173A/zh active Pending
-
1994
- 1994-04-01 US US08/221,810 patent/US5543379A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1078173A (zh) | 1993-11-10 |
AU3452093A (en) | 1993-09-01 |
EP0625072A1 (en) | 1994-11-23 |
WO1993014867A1 (en) | 1993-08-05 |
US5326912A (en) | 1994-07-05 |
ITTO920080A0 (it) | 1992-01-31 |
IL104546A0 (en) | 1993-05-13 |
US5543379A (en) | 1996-08-06 |
ITTO920080A1 (it) | 1993-07-31 |
TW227528B (it) | 1994-08-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19960131 |