IT1094102B - FLUORINATED EXCHANGE POLYMER CONTAINING CARBOXYL GROUPS AND FILM AND MEMBRANE WITH ITS PRODUCTS - Google Patents

FLUORINATED EXCHANGE POLYMER CONTAINING CARBOXYL GROUPS AND FILM AND MEMBRANE WITH ITS PRODUCTS

Info

Publication number
IT1094102B
IT1094102B IT22494/78A IT2249478A IT1094102B IT 1094102 B IT1094102 B IT 1094102B IT 22494/78 A IT22494/78 A IT 22494/78A IT 2249478 A IT2249478 A IT 2249478A IT 1094102 B IT1094102 B IT 1094102B
Authority
IT
Italy
Prior art keywords
membrane
products
film
carboxyl groups
polymer containing
Prior art date
Application number
IT22494/78A
Other languages
Italian (it)
Other versions
IT7822494A0 (en
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of IT7822494A0 publication Critical patent/IT7822494A0/en
Application granted granted Critical
Publication of IT1094102B publication Critical patent/IT1094102B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14—Monomers containing only one unsaturated aliphatic radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)

Abstract

Fluorinated ion exchange polymers which have pendant side chains which contain groups wherein W is F or CF3, and R is an inonizable group, or which have such pendant side chains and also pendant side chains which contain sulfonyl groups, when used in the form of membranes to separate the anode and cathode compartments of an electrolysis cell, permit operation at high current efficiency. They can be made by copolymerization of a mixture of monomers, one of which is a vinyl monomer which contains the indicated carboxylic funtional group.
IT22494/78A 1977-04-20 1978-04-19 FLUORINATED EXCHANGE POLYMER CONTAINING CARBOXYL GROUPS AND FILM AND MEMBRANE WITH ITS PRODUCTS IT1094102B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US78972577A 1977-04-20 1977-04-20

Publications (2)

Publication Number Publication Date
IT7822494A0 IT7822494A0 (en) 1978-04-19
IT1094102B true IT1094102B (en) 1985-07-26

Family

ID=25148505

Family Applications (1)

Application Number Title Priority Date Filing Date
IT22494/78A IT1094102B (en) 1977-04-20 1978-04-19 FLUORINATED EXCHANGE POLYMER CONTAINING CARBOXYL GROUPS AND FILM AND MEMBRANE WITH ITS PRODUCTS

Country Status (15)

Country Link
JP (2) JPS53132089A (en)
AU (2) AU525335B2 (en)
BE (1) BE866121A (en)
BR (1) BR7802433A (en)
CA (1) CA1133425A (en)
DE (1) DE2817344A1 (en)
FR (1) FR2388012A1 (en)
GB (1) GB1604102A (en)
IL (1) IL54540A (en)
IT (1) IT1094102B (en)
MX (1) MX151031A (en)
NL (1) NL7804221A (en)
NZ (1) NZ187023A (en)
SU (1) SU1165239A3 (en)
ZA (1) ZA782225B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4329434A (en) * 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated cation exchange membrane and process for producing the same
US4329435A (en) 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated copolymer with tridihydro fluorosulfonyl fluoride pendant groups and preparation thereof
DE3050931C2 (en) * 1979-05-31 1994-06-09 Asahi Chemical Ind Fluorinated carboxylic acid derivatives and process for their preparation
DE3036066A1 (en) * 1980-09-25 1982-05-06 Hoechst Ag, 6000 Frankfurt Bonding electrode to fluorine contg. copolymer electrolysis membrane - by applying electrode powder to membrane and pressing opt. with heating
JPS5792028A (en) * 1980-11-29 1982-06-08 Asahi Chem Ind Co Ltd Fluorocarbon cation exchange membrane
JPS58189210A (en) * 1982-04-30 1983-11-04 Daikin Ind Ltd Production of tetrafluoroethylene/fluorinated alkyl vinyl ether copolymer
US4954256A (en) * 1989-05-15 1990-09-04 Pall Corporation Hydrophobic membranes
AU4576893A (en) * 1992-07-30 1994-03-03 Imperial Chemical Industries Plc Fluorinated polymers
JP2003246906A (en) * 2002-02-25 2003-09-05 Asahi Kasei Corp Fluorine-containing copolymer composition
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
DK2376541T3 (en) * 2008-12-11 2013-01-28 Solvay Specialty Polymers It Purification of fluorine ionomer compositions
JP5799926B2 (en) * 2012-09-27 2015-10-28 旭硝子株式会社 Method for producing fluorine-containing copolymer

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
FR1527816A (en) * 1966-02-16 1968-06-07 Du Pont Perfluorinated alkyl-vinyl ethers bearing substituents, preparation of these ethers by pyrolysis of the corresponding salts, and their use as components of copolymers
US3784399A (en) * 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US3849243A (en) * 1971-11-08 1974-11-19 Du Pont Laminates of support material and fluorinated polymer containing pendant side chains containing sulfonyl groups
AU464313B2 (en) * 1971-12-27 1975-08-21 Hooker Chemicals And Plastics Coup Electrolysis method and apparatus
JPS551351B2 (en) * 1974-03-07 1980-01-12
JPS5224176A (en) * 1975-07-09 1977-02-23 Asahi Chem Ind Co Ltd Cathion exchange membrane
JPS5223192A (en) * 1975-08-15 1977-02-21 Asahi Glass Co Ltd Preparation of improved fluoropolymer bearing cation exchange groups
JPS5228587A (en) * 1975-08-29 1977-03-03 Asahi Glass Co Ltd Method for manufacturing an improved fluoropolymer having cation excha nge groups
JPS5228586A (en) * 1975-08-29 1977-03-03 Asahi Glass Co Ltd Method for manufacturing an improved fluoropolymer having cation excha nge groups
GB1518387A (en) * 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS52120999A (en) * 1976-04-05 1977-10-11 Asahi Chem Ind Co Ltd Electrolysis of alkali metal halides

Also Published As

Publication number Publication date
AU1304888A (en) 1988-06-16
SU1165239A3 (en) 1985-06-30
IT7822494A0 (en) 1978-04-19
AU525335B2 (en) 1982-11-04
BE866121A (en) 1978-10-19
MX151031A (en) 1984-09-12
DE2817344A1 (en) 1978-10-26
JPS59211583A (en) 1984-11-30
GB1604102A (en) 1981-12-02
CA1133425A (en) 1982-10-12
JPS6356257B2 (en) 1988-11-07
JPS53132089A (en) 1978-11-17
BR7802433A (en) 1979-01-16
AU3516478A (en) 1979-10-25
IL54540A0 (en) 1978-07-31
FR2388012A1 (en) 1978-11-17
IL54540A (en) 1981-09-13
NZ187023A (en) 1980-11-28
DE2817344C2 (en) 1990-11-15
ZA782225B (en) 1979-04-25
NL7804221A (en) 1978-10-24

Similar Documents

Publication Publication Date Title
KR830006474A (en) Improved Hybrid Ion Exchange Membrane
ATE11153T1 (en) IMPROVED SULFONIC ACID MEMBRANES FOR AN ELECTROLYTIC CELL.
IT1094102B (en) FLUORINATED EXCHANGE POLYMER CONTAINING CARBOXYL GROUPS AND FILM AND MEMBRANE WITH ITS PRODUCTS
JPS5439833A (en) Diaphragm for galvanic cell
FR2295982A1 (en) MEMBRANES BASED ON TRIFLUOROSTYRENE SULPHONIC ACID AND THEIR APPLICATION TO ELECTROCHEMICAL CELLS
IT1094088B (en) FLUORINATED EXCHANGE POLYMER CONTAINING CARBOXYL GROUPS AND PROCESS FOR ITS PREPARATION
GB1522877A (en) Process for producing alkali metal hydroxide by electrolysis
FR2275298A1 (en) COMPOSITE CATION EXCHANGER MEMBRANE AND ITS USE IN THE ELECTROLYSIS OF AN ALKALINE METAL HALOGENIDE
GB1184321A (en) Electrochemical Cells
IT1088860B (en) PROCEDURE FOR THE PRODUCTION OF A FLUORINATED COPOLYMER WITH ION EXCHANGE GROUPS
MX159745A (en) PERMSELECTIVE MEMBRANE FLUORO POLYMERIC AND PROCEDURE FOR ITS OBTAINING
IL31719A (en) Ion-exchange copolymers and their use
BR7604438A (en) MEMBER OF PERMUTA CATIONICA PROCESS OF ITS PREPARATION CELL THAT USES THE SAME AND IMPROVEMENT IN THE ELECTROLYSIS PROCESS THAT USES THE CELL
Tsuchida et al. Lithium ion conducting polymeric hybrids
ES478573A1 (en) their preparation and their use in the electrolysis of sodium chloride.
GB872218A (en) Improvements in or relating to ion exchange membranes
GB1516048A (en) Electrolysis of aqueous solution of sodium chloride
GB1179812A (en) Improvements in or relating to Copolymers and Adhesives containing such Copolymers
JPS55122361A (en) Separator for cell and its manufacture
JPS5736110A (en) Preparation of hydrophilic membrane
FR2334768A2 (en) Electrolytic cell contg cation exchanger diaphragm - of graft copolymer contg polyolefine and hydroxy-styrene
JPS5371692A (en) Cation exchange membrane and production thereof
JPS52142792A (en) Suspension polymerization of vinyl chloride
JPS53101084A (en) Aqueous resin dispersion composition
GB1140133A (en) Carbon bisulphide copolymers and processes for the preparation thereof