IL54540A - Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cells - Google Patents

Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cells

Info

Publication number
IL54540A
IL54540A IL54540A IL5454078A IL54540A IL 54540 A IL54540 A IL 54540A IL 54540 A IL54540 A IL 54540A IL 5454078 A IL5454078 A IL 5454078A IL 54540 A IL54540 A IL 54540A
Authority
IL
Israel
Prior art keywords
ion exchange
separators
base layer
polymer containing
fluorinated ion
Prior art date
Application number
IL54540A
Other versions
IL54540A0 (en
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of IL54540A0 publication Critical patent/IL54540A0/en
Publication of IL54540A publication Critical patent/IL54540A/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14Monomers containing only one unsaturated aliphatic radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18Homopolymers or copolymers of tetrafluoroethylene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)

Abstract

Fluorinated ion exchange polymers which have pendant side chains which contain groups wherein W is F or CF3, and R is an inonizable group, or which have such pendant side chains and also pendant side chains which contain sulfonyl groups, when used in the form of membranes to separate the anode and cathode compartments of an electrolysis cell, permit operation at high current efficiency. They can be made by copolymerization of a mixture of monomers, one of which is a vinyl monomer which contains the indicated carboxylic funtional group.
IL54540A 1977-04-20 1978-04-19 Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cells IL54540A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US78972577A 1977-04-20 1977-04-20

Publications (2)

Publication Number Publication Date
IL54540A0 IL54540A0 (en) 1978-07-31
IL54540A true IL54540A (en) 1981-09-13

Family

ID=25148505

Family Applications (1)

Application Number Title Priority Date Filing Date
IL54540A IL54540A (en) 1977-04-20 1978-04-19 Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cells

Country Status (15)

Country Link
JP (2) JPS53132089A (en)
AU (2) AU525335B2 (en)
BE (1) BE866121A (en)
BR (1) BR7802433A (en)
CA (1) CA1133425A (en)
DE (1) DE2817344A1 (en)
FR (1) FR2388012A1 (en)
GB (1) GB1604102A (en)
IL (1) IL54540A (en)
IT (1) IT1094102B (en)
MX (1) MX151031A (en)
NL (1) NL7804221A (en)
NZ (1) NZ187023A (en)
SU (1) SU1165239A3 (en)
ZA (1) ZA782225B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3050931C2 (en) * 1979-05-31 1994-06-09 Asahi Chemical Ind Fluorinated carboxylic acid derivatives and process for their preparation
US4329435A (en) 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated copolymer with tridihydro fluorosulfonyl fluoride pendant groups and preparation thereof
US4329434A (en) 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated cation exchange membrane and process for producing the same
DE3036066A1 (en) * 1980-09-25 1982-05-06 Hoechst Ag, 6000 Frankfurt Bonding electrode to fluorine contg. copolymer electrolysis membrane - by applying electrode powder to membrane and pressing opt. with heating
JPS5792028A (en) * 1980-11-29 1982-06-08 Asahi Chem Ind Co Ltd Fluorocarbon cation exchange membrane
JPS58189210A (en) * 1982-04-30 1983-11-04 Daikin Ind Ltd Production of tetrafluoroethylene/fluorinated alkyl vinyl ether copolymer
US4954256A (en) * 1989-05-15 1990-09-04 Pall Corporation Hydrophobic membranes
WO1994003503A2 (en) * 1992-07-30 1994-02-17 Imperial Chemical Industries Plc Fluorinated polymers
JP2003246906A (en) * 2002-02-25 2003-09-05 Asahi Kasei Corp Fluorine-containing copolymer composition
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
JP5409803B2 (en) * 2008-12-11 2014-02-05 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア Purification of fluoroionomer compositions
JP5799926B2 (en) * 2012-09-27 2015-10-28 旭硝子株式会社 Method for producing fluorine-containing copolymer

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
FR1527816A (en) * 1966-02-16 1968-06-07 Du Pont Perfluorinated alkyl-vinyl ethers bearing substituents, preparation of these ethers by pyrolysis of the corresponding salts, and their use as components of copolymers
US3784399A (en) * 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US3849243A (en) * 1971-11-08 1974-11-19 Du Pont Laminates of support material and fluorinated polymer containing pendant side chains containing sulfonyl groups
AU464313B2 (en) * 1971-12-27 1975-08-21 Hooker Chemicals And Plastics Coup Electrolysis method and apparatus
JPS551351B2 (en) * 1974-03-07 1980-01-12
JPS5224176A (en) * 1975-07-09 1977-02-23 Asahi Chem Ind Co Ltd Cathion exchange membrane
JPS5223192A (en) * 1975-08-15 1977-02-21 Asahi Glass Co Ltd Preparation of improved fluoropolymer bearing cation exchange groups
JPS5228587A (en) * 1975-08-29 1977-03-03 Asahi Glass Co Ltd Method for manufacturing an improved fluoropolymer having cation excha nge groups
GB1518387A (en) * 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5228586A (en) * 1975-08-29 1977-03-03 Asahi Glass Co Ltd Method for manufacturing an improved fluoropolymer having cation excha nge groups
JPS52120999A (en) * 1976-04-05 1977-10-11 Asahi Chem Ind Co Ltd Electrolysis of alkali metal halides

Also Published As

Publication number Publication date
AU1304888A (en) 1988-06-16
AU525335B2 (en) 1982-11-04
GB1604102A (en) 1981-12-02
FR2388012A1 (en) 1978-11-17
ZA782225B (en) 1979-04-25
BE866121A (en) 1978-10-19
DE2817344C2 (en) 1990-11-15
SU1165239A3 (en) 1985-06-30
JPS6356257B2 (en) 1988-11-07
MX151031A (en) 1984-09-12
IL54540A0 (en) 1978-07-31
IT1094102B (en) 1985-07-26
AU3516478A (en) 1979-10-25
NZ187023A (en) 1980-11-28
JPS53132089A (en) 1978-11-17
CA1133425A (en) 1982-10-12
BR7802433A (en) 1979-01-16
IT7822494A0 (en) 1978-04-19
NL7804221A (en) 1978-10-24
JPS59211583A (en) 1984-11-30
DE2817344A1 (en) 1978-10-26

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