IN2014DN08814A - - Google Patents
Info
- Publication number
- IN2014DN08814A IN2014DN08814A IN8814DEN2014A IN2014DN08814A IN 2014DN08814 A IN2014DN08814 A IN 2014DN08814A IN 8814DEN2014 A IN8814DEN2014 A IN 8814DEN2014A IN 2014DN08814 A IN2014DN08814 A IN 2014DN08814A
- Authority
- IN
- India
- Prior art keywords
- complex
- metal
- catalyst component
- polymerization catalyst
- dispersed phase
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
A process for increasing the catalytic activity of an olefin polymerization catalyst component at higher temperatures, comprising the steps of a) preparing a solution of a complex of a group 2 metal and an electron donor by reacting a compound f said metal with said electron donor or a precursor thereof and an organic liquid reaction medium; b) adding said solution of said complex to at least one titanium compound comprising titanium in the oxidation state of 14, to produce an emulsion the dispersed phase of which contains more than 50 mol% of the group 2 metal in said complex; c) agitating the emulsion in order to maintain the droplets of said dispersed phase within such an average size range of from 5 to 200 pm; d) solidifying said droplets of the dispersed phase; and e) recovering the solidified particles of the olefin polymerization catalyst component; wherein the increase in activity is achieved by decreasing the amount of titanium present in said solidified particles of the olefin polymerization catalyst component being present in the oxidation state of +4 by adding a reducing agent.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06011309.9A EP1862480B1 (en) | 2006-05-31 | 2006-05-31 | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
PCT/EP2007/004838 WO2007137852A1 (en) | 2006-05-31 | 2007-05-31 | Process for preparing an olefin polymerisation catalyst component with improved high temperatur activity |
Publications (1)
Publication Number | Publication Date |
---|---|
IN2014DN08814A true IN2014DN08814A (en) | 2015-07-10 |
Family
ID=37168755
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IN8814DEN2014 IN2014DN08814A (en) | 2006-05-31 | 2007-05-31 |
Country Status (5)
Country | Link |
---|---|
US (3) | US20100056359A1 (en) |
EP (2) | EP2845868A1 (en) |
CN (2) | CN101460528A (en) |
IN (1) | IN2014DN08814A (en) |
WO (1) | WO2007137852A1 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1862481B1 (en) * | 2006-05-31 | 2016-08-31 | Borealis Technology Oy | Catalyst with al-alkoxy component |
EP1939227B1 (en) * | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
EP2138517B1 (en) | 2008-06-26 | 2012-09-12 | Borealis AG | Catalyst preparation using H2 |
EP2216347A1 (en) | 2009-01-30 | 2010-08-11 | Borealis AG | A method of catalyst transitions in olefin polymerizations |
EP2226327A1 (en) | 2009-03-02 | 2010-09-08 | Borealis AG | Preparation of an olefin polymerization catalyst component |
EP2399943A1 (en) | 2010-06-28 | 2011-12-28 | Borealis AG | Process for producing polyethylene |
US9163097B2 (en) | 2010-09-30 | 2015-10-20 | Chemetall Gmbh | Low-viscosity, concentrated solutions of magnesium complexes for producing polymerization catalysts and method for producing the same |
EP2452960B1 (en) | 2010-11-12 | 2015-01-07 | Borealis AG | Process for preparing propylene polymers with an ultra high melt flow rate |
EP2610273B1 (en) | 2011-12-30 | 2018-02-07 | Borealis AG | Catalyst component |
EP2610274A1 (en) | 2011-12-30 | 2013-07-03 | Borealis AG | Propylene random copolymer |
EP2610270B1 (en) | 2011-12-30 | 2015-10-07 | Borealis AG | Catalyst component |
EP2610272B1 (en) | 2011-12-30 | 2017-05-10 | Borealis AG | Catalyst component |
EP2610271B1 (en) | 2011-12-30 | 2019-03-20 | Borealis AG | Preparation of phthalate free ZN PP catalysts |
EP2746306B1 (en) | 2012-12-21 | 2017-10-04 | Borealis AG | Supported Ziegler Natta procatalyst for ethylene polymerisation |
EP2746300B1 (en) | 2012-12-21 | 2016-12-07 | Borealis AG | Process for producing a ziegler natta procatalyst for ethylene polymerisation |
US9944734B2 (en) | 2013-12-20 | 2018-04-17 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
WO2015091982A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
EP3083717B1 (en) | 2013-12-20 | 2019-08-28 | Saudi Basic Industries Corporation | Catalyst system for polymerization of an olefin |
BR112016014027B1 (en) | 2013-12-20 | 2021-03-23 | Sabic Global Technologies B.V. | CATALYST SYSTEM FOR THE POLYMERIZATION OF AN OLEFINE, ITS PREPARATION PROCESS, POLYOLEFINE AND THE SAME PREPARATION PROCESS |
BR112016013609B1 (en) | 2013-12-20 | 2021-11-09 | Saudi Basic Industries Corporation | CATALYST COMPOSITION, ITS PREPARATION PROCESS AND POLYMERIZATION CATALYST SYSTEM |
MX2016008035A (en) | 2013-12-20 | 2017-03-03 | Saudi Basic Ind Corp | Catalyst system for polymerization of an olefin. |
MX2016008029A (en) * | 2013-12-20 | 2017-03-03 | Saudi Basic Ind Corp | Procatalyst for polymerization of olefins. |
US9714302B2 (en) | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
CN105541877B (en) * | 2014-10-28 | 2019-03-22 | 中国石油化工股份有限公司 | Adduct of magnesium halides and application and the catalytic component for olefinic polymerization and catalyst system and application and olefine polymerizing process |
CN105622793B (en) * | 2014-10-28 | 2019-05-31 | 中国石油化工股份有限公司 | For the catalytic component and catalyst system of olefinic polymerization and its application and olefine polymerizing process |
CN105622794B (en) * | 2014-10-28 | 2018-07-20 | 中国石油化工股份有限公司 | For the catalytic component and catalyst system of olefinic polymerization and its application and olefine polymerizing process |
CN105622644B (en) * | 2014-10-28 | 2018-12-28 | 中国石油化工股份有限公司 | A kind of adduct of magnesium halides and its application |
CN107840910B (en) * | 2016-09-18 | 2020-06-09 | 中国石油化工股份有限公司 | Catalyst component for ethylene polymerization reaction, preparation method thereof, catalyst and application thereof |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2951045A (en) * | 1956-12-20 | 1960-08-30 | Exxon Research Engineering Co | Preparation of titanium chloride polymerization catalyst |
NL271985A (en) * | 1961-11-30 | |||
JPS591407B2 (en) * | 1977-03-04 | 1984-01-12 | 三井化学株式会社 | Method for producing titanium catalyst component |
DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
IT1169291B (en) | 1981-12-24 | 1987-05-27 | Montedison Spa | CATALYST COMPONENTS FOR THE POLYMERIZATION OF ETHYLENE AND ITS MIXTURES WITH OLEFINS AND ITS CATALYSTS OBTAINED FROM THEM |
IT1169292B (en) | 1981-12-24 | 1987-05-27 | Montedison Spa | COMPONENTS OF CATALYSTS FOR THE POLYMERIZATION OF ALPHA OLEFINS AND THE CATALYSTS OBTAINED FROM THEM |
DE3634915A1 (en) * | 1986-10-14 | 1988-04-28 | Basf Ag | METHOD FOR PRODUCING HOMO- AND COPOLYMERISATES OF ETHYLENE BY MEANS OF A ZIEGLER CATALYST SYSTEM |
IT1236510B (en) * | 1989-10-06 | 1993-03-11 | Renzo Invernizzi | PROCEDURE FOR THE PREPARATION OF ETHYLENE-PROPYLENE COPOLYMERS. |
FI89066C (en) * | 1989-11-20 | 1993-08-10 | Neste Oy | FOERFARANDE FOER FRAMSTAELLNING AV EN POLYMERISERINGSKATALYTKONPONENT FOER OLEFINER, EN POLYMERISERINGSKATALYTKONPONENT FRAMSTAELLD MED FOERFARANDET OCH DESS BRUK |
US5409875A (en) * | 1993-03-08 | 1995-04-25 | Queen's University | Polymer-supported catalyst for polymerization and copolymerization of olefins |
IT1270070B (en) * | 1994-07-08 | 1997-04-28 | Spherilene Srl | COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINE |
JP3471099B2 (en) | 1994-11-25 | 2003-11-25 | 昭和電工株式会社 | Method for producing catalyst support for olefin polymerization |
US5955396A (en) | 1995-10-17 | 1999-09-21 | Bp Amoco Corporation | Morphology-controlled olefin polymerization catalyst formed from an emulsion |
FI111848B (en) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Process and equipment for the preparation of homopolymers and copolymers of propylene |
JP2001527136A (en) | 1997-12-23 | 2001-12-25 | ボレアリス テクノロジー オイ | Catalyst component containing magnesium, titanium, halogen and electron donor, method of making and using the same |
CA2234188C (en) * | 1998-04-07 | 2006-07-11 | Nova Chemicals Ltd. | Heat treatment of ziegler-natta catalysts to increase activity in solution polymerization process |
FI981717A (en) | 1998-08-07 | 2000-02-08 | Borealis As | Catalyst component comprising magnesium, titanium, halogen and an electron donor, its preparation and use |
FI981718A (en) | 1998-08-07 | 2000-02-08 | Borealis As | Catalyst component comprising magnesium, titanium, halogen and an electron donor, its preparation and use |
BR9917539B1 (en) * | 1999-10-23 | 2008-11-18 | solid titanium catalyst for homo- and co-polymerization of alpha olefin. | |
GB0001914D0 (en) | 2000-01-27 | 2000-03-22 | Borealis Polymers Oy | Catalyst |
USH2060H1 (en) * | 2000-08-22 | 2003-03-04 | Engelhard Corporation | Cyclobutyl silanes for catalysts useful for making highly isotactic olefin polymers |
ES2266053T3 (en) * | 2001-06-20 | 2007-03-01 | Borealis Technology Oy | PREPARATION OF A CATALYST COMPONENT FOR OLEFINE POLYMERIZATION. |
US6723677B1 (en) * | 2001-06-25 | 2004-04-20 | Nova Chemicals (International) S.A. | High activity ziegler-natta catalyst for high molecular weight polyolefins |
EP1403292B1 (en) * | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
EP1484345A1 (en) * | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
EP1489110B1 (en) | 2003-06-20 | 2012-01-18 | Borealis Polymers Oy | Method for preparing an olefin polymerisation catalyst composition |
CN1229400C (en) * | 2003-09-18 | 2005-11-30 | 中国石油化工股份有限公司 | Catalyst compoment used for olefinic polymerization and its catalyst |
EP1862481B1 (en) * | 2006-05-31 | 2016-08-31 | Borealis Technology Oy | Catalyst with al-alkoxy component |
EP1939227B1 (en) * | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
-
2006
- 2006-05-31 EP EP14004083.3A patent/EP2845868A1/en not_active Withdrawn
- 2006-05-31 EP EP06011309.9A patent/EP1862480B1/en not_active Not-in-force
-
2007
- 2007-05-31 CN CNA2007800202105A patent/CN101460528A/en active Pending
- 2007-05-31 US US12/302,566 patent/US20100056359A1/en not_active Abandoned
- 2007-05-31 WO PCT/EP2007/004838 patent/WO2007137852A1/en active Application Filing
- 2007-05-31 CN CN201310364378.5A patent/CN103601824A/en active Pending
- 2007-05-31 IN IN8814DEN2014 patent/IN2014DN08814A/en unknown
-
2015
- 2015-04-16 US US14/688,838 patent/US20150291709A1/en not_active Abandoned
- 2015-04-16 US US14/688,813 patent/US20150291712A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CN101460528A (en) | 2009-06-17 |
EP2845868A1 (en) | 2015-03-11 |
US20150291709A1 (en) | 2015-10-15 |
CN103601824A (en) | 2014-02-26 |
US20100056359A1 (en) | 2010-03-04 |
US20150291712A1 (en) | 2015-10-15 |
EP1862480A1 (en) | 2007-12-05 |
WO2007137852A1 (en) | 2007-12-06 |
EP1862480B1 (en) | 2016-07-27 |
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