IN2014DN05910A - - Google Patents

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Publication number
IN2014DN05910A
IN2014DN05910A IN5910DEN2014A IN2014DN05910A IN 2014DN05910 A IN2014DN05910 A IN 2014DN05910A IN 5910DEN2014 A IN5910DEN2014 A IN 5910DEN2014A IN 2014DN05910 A IN2014DN05910 A IN 2014DN05910A
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IN
India
Prior art keywords
polymer
less
dbi
vinyl
itaconate
Prior art date
Application number
Inventor
Tijs Nabuurs
Gerardus Cornelis Overbeek
Jeffrey Stubbs
Matthew Stewart Gebhard
Original Assignee
Dsm Ip Assets Bv
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Application filed by Dsm Ip Assets Bv filed Critical Dsm Ip Assets Bv
Publication of IN2014DN05910A publication Critical patent/IN2014DN05910A/en

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    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
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    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
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    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
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    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
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    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
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    • Y10T428/31855—Of addition polymer from unsaturated monomers
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    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Abstract

There are described vinyl sequential copolymers (and processes for making them) comprising (a) at least 8. 5 wt % preferably >=20 wt % of a higher itaconate diester (preferably dibutyl itaconate DBI); (b) less than 23 wt % acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer (c) optionally with less than 50 wt % of other itaconate monomers and (d) optionally less than 77 wt %of other monomers not (a) to (c). The DBI may be biorenewable. One embodiment is an aqueous dispersion of the vinyl sequential polymer of two phases: A) 40 to 90 wt % of a vinyl polymer A with Tg from 50 to 30°C; and B) 10 to 60 wt % of a vinyl polymer B with Tg from 50 to 130°C; where DBI is used to prepare A and/or B and polymer A has from 0.1 to 10 wt % of at least one acid functional olefinically unsaturated monomer.
IN5910DEN2014 2012-02-03 2013-02-04 IN2014DN05910A (en)

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