IE71041B1 - Coupling agent - Google Patents

Coupling agent

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Publication number
IE71041B1
IE71041B1 IE420091A IE420091A IE71041B1 IE 71041 B1 IE71041 B1 IE 71041B1 IE 420091 A IE420091 A IE 420091A IE 420091 A IE420091 A IE 420091A IE 71041 B1 IE71041 B1 IE 71041B1
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IE
Ireland
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formula
compound
radical
die
equal
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IE420091A
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IE914200A1 (en
Inventor
Andreas Muhlebach
Hubert Simon
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Ciba Geigy Ag
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Publication of IE914200A1 publication Critical patent/IE914200A1/en
Publication of IE71041B1 publication Critical patent/IE71041B1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/544Silicon-containing compounds containing nitrogen
    • C08K5/5455Silicon-containing compounds containing nitrogen containing at least one group
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28Non-macromolecular organic substances
    • C08L2666/44Silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Compounds of the general formula I in which R1 denotes C2-C3-alkylene and R2 denotes hydrogen, C1-C6-alkyl or C2-C6-alkenyl, each of which is unsubstituted or substituted by -OH, -CN or -Si(OR3)3-q(R4)q, where R3 is C1-C4-alkyl or two radicals R3 together represent C1-C4-alkylene, R4 is C1-C4-alkyl or phenyl and q can have values from 0 to 2, and E represents a radical of the formula in which R5 and R6 independently of one another are hydrogen, C1-C4-alkyl, aryl-substituted ethenyl, aryl, heteroaryl or radicals of the formulae IIa or IIb with the proviso that at least one of the radicals R5 or R6 denotes aryl-substituted ethenyl, aryl, heteroaryl or a radical of the formulae IIa or IIb, or E, together with R2, denotes a radical of the formula in which R7 is hydrogen, C1-C4-alkyl or -R9-Si(OR3)3-q(R4)q and R3, R4 and q have the above meaning and R9 denotes C1-C8-alkylene, and Y denotes oxygen or sulphur; and also T denotes a radical of the formula -R9-Si(OR3)3-q(R4)q or or, if R7 represents a radical of the formula -R9-Si(OR3)3-q(R4)q and m is greater than or equal to 2, denotes an m-valent radical Z, in which R3, R4, R9, Y and q have the above meanings, X is -S- or -NH- and Z is an organic radical which is derived from a polyisocyanate or a polyisothiocyanate having at least two NCO or NCS groups, and r is 1, 2 or 3 and p is 0 or 1 and m can have values greater than or equal to 1 and n can have values greater than or equal to 1, are suitable, for example, as adhesion promoters, in particular for one and two component polyurethane resin systems.

Description

The present invention relates to nitrogen-containing silane compounds and polyurethane resins containing these silane compounds as adhesion promoters.
The adhesion of cured polyurethanes to various substrates, such as glass, plastic or metal, is in many industrial applications unsatisfactory, which has led to die use of primers. This makes it possible to obtain a good bond between die polyurethane and the substrate. This bond is hardly impaired by high moisture, elevated temperatures and high mechanical stress. Examples of primers which have proven suitable are aminoalkylalkoxysilanes (cf. Plueddemann et al. Silane Coupling Agents, Plenum Press, NY [1982]). However, die most effective aminosilane adhesion promoters cannot be used as built-in adhesion promoters in moisture-curing polyurethanes in unmodified form, since die amino groups will react completely with isocyanate groups. Therefore, DE-A 3414 877 has described ketimines and aldimines of aminoalkylsilanes, which can be added to polyurethane adhesives without impairing their shelf life.
Furthermore, US-A 3,787,416 and 4,289,869 have described cyclic aminals as hardeners for polyurethane resins. Furthermore, reaction products of cyclic aminals with isocyanates to give adducts which are suitable as hardeners for polyurethane resins are disclosed in US-A 4,404,379. However, these aminals or aminal adducts do not contain silane-containing groups.
A group of compounds has now been found which can be added to 1- or 2-component polyurethane resin adhesives, sealing compositions, coating compositions and insulating materials, resulting in significantly improved adhesion to glass, metal, coated steel and plastics while at the same time not impairing or even increasing the curing rate.
The present invention relates to compounds of the general formula I [' E-Rj-N— I(CH2)-0 * 1_ fO-lp-C-HN4—T . Jm (D -271041 in which Rj is C2-C3alkylenc and R2 is hydrogen, Cj-Cgalkyl which is unsubstituted cor substituted by-OH,-CN or -Si(OR3)3^(R4)q or is C^-Cgalkenyl, in which R3 is Cj-C4alkyl or two radicals R3 together are Cj-C4alkylene, R4 is Cj-C4alkyl or phenyl and q can have values from 0 to 2, furthermore E is a radical of the formula in which R5 and Rg, independently of one another, are hydrogen, Cj-C4alkyl, aryl-substituted ethenyl, aryl, heteroaryl or radicals of the formulae Da or Ob O*C^HN- (Ha) (Hb) with the proviso that ar least one of the radicals R5 or Rg is aryl-substituted ethenyl, aryl, heteroaryl or a radical of the formulae Da or Hb or E together with R2 is a radical of die farmnla in which R7 is hydrogen, Cj-Cgalkyl or -R^iCORs^QQq and R3, Rg, Rs, Rg and q -3are as defined above, and R$ is CpCgalkylene, and Y is oxygen or sulfur; furthermore, T is a radical of the formulae -Rg-SiCORs^CIQq or γ II ZH—NH-C — X or, if R7 is a radical of the formula -R^SiCORj^CR^q and m is greater than or equal to 2, is an m-valent radical Z in which R3, Rq, Rg, Y and q are as defined above, X is -S- or -NH- and Z is an organic radical which is derived from a polyisocyanate or a polyisothiocyanate having at least 2 NCO or NCS groups, and r is 1,2 or 3 and p is 0 or 1 and m can have values of greater than or equal to 1 and n can have values oi greater than or equal to 1.
R3, R4, R5, R<5 and R7 as Cj-^alkyl or R2 as CrCgalkyl are, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl and tert-butyl and in the case of R2 additionally n-pentyl or n-hexyl.
The preferred meaning of R3 and R4 as alkyl is methyl and ethyl, in particular methyl.
Examples of R5 and Re as aryl are phenyl or naphthyl, which can be unsubstituted or substituted by Ci-C4alkyl, Cj-Qalkenyl, in particular -ΟΗ=€Η2, Cj-Qalkoxy, -NOj and halogen, in particular chlorine or bromine. Examples are methylphenyl, ethylphenyl, propylphenyl, isopropylphenyl, butylphenyl, isobutylphenyl and tert-butylphenyl; methoxyphenyl, ethoxyphenyl and butoxyphenyl; nitrophenyl, fluorophenyl, chlorophenyl, bromophenyl, dichlorophenyl and dibromophenyl and styryl.
Rs and R$ as heteroaryl are in particular heteroaromadcs having 5 or 6 ring members and one or two N, O or S atoms, which, if desired, can be benzo-fused, such as pyridyl, thienyl, benzothienyl, furyl, pyrrolyl, imidazolyl, pyrazolyl, pyrazinyl, pyrimidinyl and -4quinolyl.
Ri as CrQalkylene, two radicals R3 together as Ci-Qalkylene andRj as CpCgalkylene are straight-chain or branched alkylene, the straight-chain alkylene being preferred. Examples are methylene, ethylene, propylene, trimethylene, tetramethylene, 2-methyl-l,3-trimethylene for R3 and R9 and in the case of R$ additionally pentamethytene, 2-methyl- 1,4-tetramethytene, 3-propyl-l,3-triinethylene, 1,6-hexameihylene, 1,7-heptamethylene, l,8-octamethyleneor2-ethyl-l,2-hexamethylene, the meaning of Rj being limited to ethylene, propylene and trimethylene.
Preferably, R9 is CpCgalkylene, in particular trimethylene or ethylene.
R2 as Q-Cgalkenyl is straight-chain or branched alkenyl, preferably straight-chain alkenyl containing one or mate, but preferably one, double bond, such as ethenyl (vinyl), 2-propenyl (allyl), n-butenyl, 13-butadienyl, i-pentenyl, n-pentenyl or n-hexenyL R2 as CpQalkyl substituted by OH, CN or -Si(OR3)3^(R4)q groups can be mono- or poly substituted, monosubstitution being preferred. The substitution can be present in any possible position, although the terminal position is preferred.
Preferably, R2 is CpQalkyl, in particular methyl.
Preferably, die parameter p in formula I has the value 0.
Also preferably, the parameter q has the value 0.
The radical Z is derived from a polyisocyanate or polyisothiocyanate having at least 2 NCO or NCS groups. This NCO or NSC functionality of greater than or equal to 2 of the polyisocyanate or polyisothiocyanate which is possible according to the invention is achieved by converting, for example, polyamines, such as amino-tenninal pdyetber polyols, to polyisocyanates or polyisothiocyanates having a functionality of greater than or equal to 2 by phosgenation or tiuophosgenation. The polyisocyanates or polyisothiocyanates thus obtainable can either be used directly or first convened with diols, polyols, dithiols, diamines or polyamines to NCO- or NCS-terminal prepolymers. The polyisocyanates obtainable in the manner described below can also be reacted in this way. -5A further possibility to prepare polyisocyanates having an NCO functionality of greater than/equal to 2 consists in oligomerisation of diisocyanates. Thus, for example, diisocyanates, such as hexamethylene diisocyanate, can be converted by partial hydrolysis to products containing biuret groups (for example Desmodur® N100 from Bayer).
Furthermore, diisocyanates, such as hexamethylene diisocyanate, can be partially trimerised, leading to die formation of higher functional polyisocyanates containing isocyanurate rings (for example Desmodur® N3200 from Bayer).
Chain-lengthening by reaction of diisocyanates with polyfunctional compounds having acidic hydrogen and a functionality of greater than or equal to 2, such as triols, tetrols, pentols, triamines, pdyamines or polythiols, also leads to polyisocyanates having an NCO functionality of greater than/equal to 2. There, the NCO/OH ratio is greater than 1, but preferably greater than 3:1, in particular greater than 10:1.
Suitable diisocyanates are not only aromatic but also aliphatic, heterocyclic or monocyclic and polycyclic bifunctional isocyanate compounds. Examples of compounds of this type are toluylene diisocyanate, diphenylmethane diisocyanate, napthylene diisocyanate, xylylene diisocyanate, hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, isophorone diisocyanate or dicydohexylmethane diisocyanate.
The parameters m and n have, advantageously independently of one another, values from 1 to 49, preferably 1 to 9, particularly preferably 1 ro 5 and very particularly preferably 1, 2 and 3. The sum of n + m is advantageously 2 to 50, preferably 2 to 10, in particular 2 ro 6.
The radical Z has preferably an average molecular weight of less than 10 000, in particular an Mb of less than 4000.
Preference is given ro compounds of the formula I in which Y is oxygen.
Preferred compounds have the formula I in which Z is derived from an aliphatic, cycloaliphatic, aliphatic/aromatic, aromatic or heterocyclic polyisocyanate or polyisothiocyanate in which fee number of NCO ot NCS groups is greater than or equal 2, it being possible for this radical Z ro contain, if desired, one or more ester, ether, urethane, -6thiourethane, isocyanurate, uvea ot biuret functions.
Particularly preferred compounds have the formula I in which Z is derived from an aliphatic or mixed aliphatic/aramatic polyisocyanate in which the number of NCO groups is 2 2, it being possible for this radical Z to contain, if desired, a total of one or two ester, ether, urethane, thiomethane, isocyanurate, urea or biuret functions.
In the compounds of foe formula I in which Z has ether oxygen atoms, Z can be a monoether or oligoether, for example a group of foe formula -(CHfCHJ-CHj-O)^ or -(CH2-CH2-CH2-CH2-O)y-, in which y is a number from 1 to 80, preferably from 1 to 20.
In foe compounds of foe formula I in which foe radical Z comprises urethane or thiourcthane groups, Z is a derivative which is obtainable by reaction of polyols with compounds containing isocyanate or isothiocyanate groups. This is also understood to include radicals which contain not only one or mote urethane groups but also one or more thiourethane groups, for example those containing a bridging member of foe formula o o o o II II or H II or -O-C-HN—D—NH-C-O- -S-C-HN—-D—NH-C — SO II S-C-HNO II -D—NH-C—O, in which D is the radical of foe polyol.
Examples of polyols which can also be used are OH-terminal polyethers or polyesters.
The radical Z in preferred compounds of foe formula I contains two ester, urethane, isocyanurate, urea or biuret functions, but in particularly preferred compounds only one. The ether functions represent a certain exception, since, as shown above, they are capable of forming oligoether bridging members. Compounds of this type can therefore contain up to 80, preferably up to 20, ether functions.
Preference is given to compounds of the formula I in which Rx is propylene.
Particular preference is given to compounds of die formula 1 in which at least one of the radicals R5 orR$ is a group of the formulae -7A further preferred embodiment relates to compounds of the formula I in which T is a radical of the formulae ^-SifOR^^CR^q or in particular those in which at least one radical X is -S-.
Special preference is given to compounds of the formula I in which p and q are 0, mis 1 and n is 2, Y is oxygen, X is-S-, R} and R$ are propylene, R2 and R3 are methyl, R5 is phenyl and R5 is hydrogen.
The compounds of the formula I are prepared by processes known per se, which can be most simply illustrated by means of the following reaction schemes.
I. Amine portion of die aminal or imine HN—Rj— NH2 O Ry-N -RSh + This preparation is carried out, for example, in the manner described in US-A4,404379. Starting materials (A) and (B) are known compounds, some of them being commercially available, or can be prepared in a simple, known manner. Suitable starting materials (A) are in particular 3-methylaminopropylamine and 3-(2-aminoethylamino)propyltiimethoxysilane. Examples of suitable starting materials (B) are the carbonyl compounds benzaldehyde, 4-pyridinecaiboxaldehyde, benzophenone, cinnamaldehyde, furfural, p-anisaldehyde or also terephthaldehyde.
Aminals of the formula (E) (E) can be prepared by reaction of (C) with suitable compounds containing reactive double bonds, for example acrylonitrile, using die process described in EP-A 70 536.
Aminals (C) and (E) thus prepared can be reacted in a further step with a polyisocyanate Z-(NCO)n or a polyisothiocyanate Z-(NCS)„, in which n is greater than or equal to 2. Π. Silane portion The amino- or mercaptoalkoxysilanes used according to the invention are compounds which are known per se. Some are commercially available, or they can be prepared by methods known per se. Compounds of this type are described in detail, for example, in Silane Coupling Agents by EJ*. Plueddemann, Plenum Press, New York (1982).
HL Polyisocyanate Z-(NCO)& 2 or polyisothiocyanate Z-(NCS) 2 These isocyanates are prepared by methods known from the literature, such as are described in US-A 3,492,330, 3,394,164 and 3,567,763; in DE-A 19 29 034 and 20 04 048; in German patents 10 22 789; 12 22 067; 1101394; 10 27 394 and 12 31 688; in British patents 994,890,889,050,956,474 and 1,072,956 or in Belgian patent 723,640.
The polyisothiocyanates can be prepared analogously. Instead of the diisocyanates, die corresponding diisothiocyanates are used as starting materials. Aliphatic starting materials can be prepared by the methods described in US-A 3,787,472 and aromatic starting materials by die methods described in Org. Syntheses; Collective Volume 1, p. 447 John Wiley, New York (1948). -9IV. Conversion of the pol yisoc yanates obtained bv the above process ΙΠ with the aminals (C) and/or (E) and with the silanes obtained by process Π to the compounds of thefonnula L The reaction of the polyisocyanates or polyisothiocyanates with the other two components 5 can be carried out in succession or together. In the stepwise reaction, first the aminal compound can be reacted with die polyisocyanate or polyisothiocyanate and then the adduct can be reacted with the alkoxysilane or vice versa. In this reaction, it is also possible to ftxm polyisocyanate or -thiocyanate adducts with different aminal or «lme components, it being possible to react die various components alternately with one another, i.e., far example, first adduct formation with a silane, then adduct formation with the aminal and finally adduct formation with the second silane.
The reaction can be carried out in the absence of solvents, although, as a rule, one or all components are diluted with a suitable inert solvent, for example xylene, in order, fir example, to adjust the viscosity to the requirements.
The addition reaction itself is advantageously carried out at temperatures of between 15°C and 200°C, but preferably at temperatures of between 30°C and 140°G The course of die reaction can be monitored by infrared spectroscopy or titration.
It is also possible to use catalysts of die type known per se in die addition reactions, fir example tertiary amines such as triethylamine, N-methylmorpholine, NJiJi* Ji’-tetra20 methylethylenediamine or l,4-diazabicyclo[2J.2]octane. Organometallic compounds, in particular organic tin compounds, can also be used as catalysts. f Examples of organic tin compounds are tin(II) salts of carboxylic acids, fir example tinQI) acetate, tin(II) octanoate and txn The stoichiometric ratios during the addition reaction of the aminal and silane components with die polyisocyanates or -thiocyanates are maintained at such a value that die ratio of the NH groups of the aminals and die NH2 or SH groups of the silanes is approximately equimolar with respect to die NCO or NCS groups of the polyisocyanates or -thiocyanates. The adduct can still contain free NCO or NCS groups. Preferably, however, no free NCO -10or NCS group is present The ratio of aminal or urea imine radicals to silane radicals in die compounds according to the invention of the formula I can be controlled by the stoichiometric ratio of the starting materials during the addition reaction. For this purpose, the aminal or silane conpound is reacted with the polyisocyanate or -thiocyanate in separate steps. As anile, the first step takes place at a ratio of NH or SH groups to NCO or NCS groups of less than 1. The preferred aminal-NH/NCO or NCS ratio is between 1:2 and 1:6, in particular between 1:3 and 1:5. The preferred ratio of sUane-NH^/NCO or silane-SHZNCO or NCS groups is between 2:3 and 1:5, in particular between 2:3 and 1:2.
As a rule, the remaining free NCO or NCS groups are reacted completely in the second step with the aminal-NH or stiane-NH2 or -SH groups. To tins end, die stoichiometric ratio of die groups containing acidic hydrogen to die NCO or NCS groups is greater than or equal to 1, preferably 4:1 to 1:1, in particular 2:1 to 1:1.
However, it is also possible to react only a portion of the remaining free NCO or NCS groups in the second step. In this case, the same stoichiometric ratios as in the first addition step apply. Such a procedure is preferably used when two or more different aminal or silane compounds are added.
The compounds according to die invention can be used as adhesion promoters in substrates such as polyurethane resins. Their use is particularly effective in moisture-curing polyurethane resins which are used as adhesives, sealing compositions, coating compositions or insulating materials. If used in adhesives, die compounds according ro the invention have properties which enable diem to be used in two-component and very particularly in one-component systems. By using die compounds according to the invention as adhesion promoters in the substrates mentioned, a pretreatment of the surfaces to be braided with a primer is made superfluous. Suitable use examples are the braiding of windscreens and headlights in automobile construction. Compounds of the formula I in which m is greater dun or equal to 2 can furthermore be used as moisture-activated curing agents for the substrates mentioned. Moreover, compounds of the formula I can be used as primers for the pretreatment of the substrate.
A moisture-curing polyurethane as the substrate contains, as the main component, polyfunctional isocyanates andfar polyurethane prepolymers. Suitable compounds are both -11aromatic as well as aliphatic, monocyclic as well as polycyclic, polyfunctional isocyanate compounds. Thus, according to a first embodiment, the aromatic isocyanate compound used is toluylene diisocyanate or diphenylmethanc diisocyanate. Technical grade diphenylmethane diisocyanate containing higher functional diisocyanates and having an isocyanate group functionality of greater than 2 is paiticulariy suitable. A further suitable aromatic diisocyanate is xylylene diisocyanate. In addition to these, a large number of aliphatic isocyanates having a functionality of 2 and higher can be used. Examples of these in die farm of cyclic aliphatic diisocyanates are isophorone diisocyanate and dicyclohexylmethane diisocyanate. Further examples are aliphatic, straight-chain diisocyanates, such as are obtained by phosgenation of diamines, for example tetramethylene diisocyanate or hexamethylene diisocyanate.
According to a preferred embodiment Oi the invention, polyurethane prepolymers are used instead of the polyfunctional isocyanate compounds. Prepolymers are understood in this context to mean adducts of an excess of palyfunctional isocyanates with polyfunctional alcohols, for example the reaction products of one of the abovementioned aromatic or aliphatic diisocyanates with ethylene glycol, propylene glycol, glycerol, trimethylolpropane or pentaerythritol. Reaction products of diisocyanates with polyether polyols, for example polyether polyols based on polyethylene oxide or based on polypropylene oxide, can also be used asprepolymers. Preference is given to polyurethane prepolymers based on polyether polyols having molecular weights of between 200 and 10000, in particular 500 and 3000. A person skilled in polyurethane chemistry is familiar with a large number of polyether polyols of this type; they are offered by many manufacturers and are characterised by their molecular weight (number-average), which can he calculated from end group determinations. Further suitable poiyether polyols are polyether polyols based (m polytetrahydrofuran.
Instead of polyeiher polyols, polyester polyols can also be used. Suitable polyester polyols are react»» products of polyfunctional acids with polyfunctional alcohols, for example polyesters based on aliphatic and/or aromatic dicarboxylic acids and polyfunctional alcohols having a functionality of 2-4. Thus, polymers obtained from adipic acid, sebacic acid, phthalic acid, hydrophthalic acid and/or trimellitic acid on the one hand and ethylene glycol, propylene glycol, neopentyl glycol, hexane glycol, glycerol and/or trimethylolpropane on the other hand can be used. In particular polyester polyols having a molecular weight (number-average) of between 500 and 5000, in particular between 600 and 2000, are suitable. Further suitable polyester polyols are die reaction products of caprolactone -12with alcohols having a functionality of 2-4, for example fee adduct of 1-5 moles of caprolactone with 1 mole of ethylene glycol, propylene glycol, glycerol and/or frimefeylolpropane.
A further suitable group of polyfunctional alcohols are polybutadienols. These are oligomers based on butadiene and containing OH groups as end groups. Of these, suitable products are those in the molecular weight range 200-4000, in particular 500-3000. Furthermore, siloxane prepolymers, preferably in combination with other prepolymers, are suitable.
When the polyurethane prepolymers are prepared, the ratio of the OH groups of fee alcohol component to fee isocyanate groups is important. It is in general between 1:2 and 1:10. A high excess of isocyanate tends to give low-viscosity polyurethane prepolymers, while a small excess of isocyanate gives highly viscous preparations, which in most cases can only be applied by trowelling.
It is known to a person skilled in polyurethane chemistry that the crosslinking density and thus the hardness of the polyurethanes increases wife the functionality of fee isocyanate component or else of fee polyol. Reference may be made here to the general technical literature, for example to fee monograph by Saunders and Frisch Polyurethanes, Chemistry and Technology, Volume XVI of the series High Polymers Interscience Publishers, New York-London, Part I (1962) and Part Π (1964).
The polyurethane preparations according to fee invention can furthermore contain various auxiliaries. Examples of auxiliaries which can be used are fillers. Suitable fiflera are inorganic compounds which are unreactive towards isocyanates, for example chalk or ground chalk, precipitated and/or pyrogenic silicas, zeolites, bentonites, ground minerals and other inorganic fillers known to a person skilled in this technical field, in particular chopped fibres, and others. Far some applications, fillers are preferred which give fee preparations thixotropic properties, for example swellable plastics, in particular PVC.
Apart from fee compounds mentioned, fee polyurethane preparations according to fee invention can contain further auxiliaries, for example solvents. Suitable solvents are those which themselves do not react wife isocyanate groups, for example halogenated hydro30 carbons, esters, ketones and aromatic hydrocarbons. Plasticisers, retardants, dyes and anti-ageing agents, such as are known in polyurethane adhesives and sealing -13compositions, can also be incorporated.
For some applications, it is desirable to add foam stabilisers to the polyurethane preparations according to the invention. So-called silicosurfactants can be used as foam stabilisers. These are understood to mean block copolymers which are composed of a polysiloxane block and one or mare polyoxyethylene and/or polyoxypropylene blocks.
The polyurethane preparations according to die invention can furthermore contain flameretardant and plasticising additives. Compounds containing phosphorus and/or halogen atoms, such as tricresyl phosphate, diphenyl cresyl phosphate, tris(2-chloroethyl) phosphate, tris(2-chloropropyl) phosphate and tris(2,3-dibromopropyl) phosphate are common. In addition, flame retardants can be used, for example chloroparaffins, phosphinic acid halides, ammonium phosphate and halogen- and phosphorus-containing resins. Far some applications, plasticisers are important as further additives.
Examples of these which axe suitable axe esters of phthalic acid or esters of long-chain dicarboxylic acids, for example sebacic or azelaic esters. So-called epoxide plasticisers, for example epoxidised fatty acid derivatives, can also be used.
Further possible additives arc basic accelerators. Examples of basic accelerators are tertiary bases, such as bis(N,N’-dimethylamino)diethyl ether, dimethylaminocyclohexane, NJQ-dimethylbenzylamine, N-methylmorpholine and die reaction products of dialkyl(B-hydroxyethyl)amines with monoisocyanates and esterification products of dialkyl20 (B-hydroxyethyl)amines with dicarboxylic acids. A further important accelerator is 1,4-diaminobicyclo[2.2J2]octane. Furthermore, non-basic substances can be used as accelerators. Of these, suitable substances are metal compounds, for example in» acetylacetonate and tm(H) 2-ethylhexanoate, dibutyltin dilaurate or molybdenum glycolate.
The compounds of the formula I axe added to the polyurethane resins in amounts of 0.1-20 % by weight, preferably 05-15 % by weight, in particular 2.5-10 % by weight, relative to the prepolymer.
Furthermore, the compounds of the formula I can also be used as hardeners. When used as hardeners, die molar ratio of released secondary NH groups to free isocyanate groups in the resin should be 0.5 to 1.5:1, preferably 0.9 to 1.1:1. -14The examples below illustrate the invention.
I. Preparation of the starting materials Example A: l,4-Bis(l-methylhexahydropyrimidin-2-yl)benzene ch3 1 mol of terephthalaldehyde in 500 ml of toluene is initially introduced into all sulfonating flask equipped with sriner, reflux condenser, thermometer and water separator. An equimolar amount of 3-methylaminopropylamine is then slowly added dropwise under nitrogen, followed by 0.1 % by weight of toluenesulfonic add as die catalyst The mixture is then refluxed for some time, during which die extent of the reaction can be monitored by the amount of water separated. The reaction mixture is then concentrated in a rotary evaporator, and the product is then worked up under a high vacuum.
Yield: 87% Melting point: 135°C Elemental analysis: calculated: C 70.03 %; H 9.55 %; N 20.42 % found: C 69.95 %; H 9.74 %; N 20.62 % Example B: l-Methyl-2-phenylhexahydropyrimidine The procedure of Example A is repeated, using 1 mol of benzaldehyde instead of the 20 terephthalaldehyde.
Yield :91% Boiling point: 75°C/0.1 mbar Elemental analysis: calculated: C 74.96 %; H 9.15 %; N 15.89 % found: C 74.94 %; H 9.10 %; N 15.99 % -15Example C: l-Methyl-2£-diphenylhexahydropyrimidine The procedure of Example A is repeated, using 1 mol of benzophenone instead of die terephthalaldehyde.
Yield: 39 % Boiling point: 130°C/0.1 mbar Elemental analysis: calculated: C 80.91 %; H 7.99 %; N 11.10 % found: C 81.76 %; H 7.68 %; N 8.85 % Example D: l-Methyl-2-pyridin-4-ylhexahydropyrimidine The procedure of Example A is repeated, using 1 mol of 4-pyridinecarboxaldehyde instead of the terephthalaldehyde.
Yield :46% Boiling point: 70°CZ0.05 mbar Elemental analysis: calculated: C 67.76 %; H 8 J3 %; N 23.71 % found: C 67.69 %; H 8.73 %; N 23.81 % Example E: l-Methvl-2-(2-phenvlethenvl)hexahvdropvrimidine The procedure of Example A is repeated, using 1 mol of cinnamaldehyde instead of the -16terephthalaldehyde.
Yield: 28 % Boiling point: 85°CA).17 mbar Elemental analysis: calculated: C 77.18 %; H 8.97 %; N 13.85 % found: C 7327 %;H 9.80 %;N 17.00% Example F: l-Methyl-2-furan-2-ylhexahydropyrimidine h3c' The procedure of Example A is repeated, using 1 mol of furfural instead of the terephthalaldehyde.
Yield :75% Boiling point: 110°C/0.12 mbar Elemental analysis: calculated: C 65.03 %; H 8.49 %; N 16.85 % found: C 64.88 %; H 831 %;N 16.84 % Example G: l-Methyl-2-(4-methoxyphenyl)hexahydropyrimidine h3c The procedure of Example A is repeated, using 1 mol of p-anisaldehyde instead of the terephthalaldehyde.
Yield :78% Boiling point: 97°C/0.04 mbar Elemental analysis: calculated: C 69.87 %; H 8.80 %; N 13.58 % found: C 69.55 %; H 8.81 %; N 13.59 % -17Π. Synthesis of the adhesion promoters Example 1: In a 100 ml sulfonating flask, 20 g (0.1032 mol of -NCO) of partially trimerised hexamethylene diisocyanate having an isocyanate content of 21.6 % (Desmodur® N 3200 from Bayer AG) are dissolved in 20 g of xylene, and the solution is heated to 80°C 13.51 g (0.0688 mol) of 3-mercaptqnppyltrimedxnysilane are then added dropwise under o nitrogen using a dropping funnel, and stirring of the mixture is then continued at 80°C fir 1.5 hours and then at 130°C fir 2.5 hours. After cooling to room temperature, 0.03441 mol of die aminal according to Example B is added dropwise at such a rate that die temperature always remains below 30°C. Stirring at roam temperature is then continued for another 4 hours, and the free NCO content is then checked by titration.
Viscosity (according to Epprecht): η = 76 800 mPa-s Average molecular weight (GPC, polystyrene-calibrated): 1^=1680 g/mol Mw = 2640g/mol Elemental analysis: found: C 56.40 %; H 8.34 %; N 10.26 % 2o Imine/aminal ratio (%, JH NMR analysis [N-CH-J): 61/39 Isocyanate group content: < 0.1 % -18Example 2: and The procedure of Example 1 is repeated, using the aminal from Example A instead of the aminal from Example B.
Viscosity (according to Epprecht): η > 100 000 mPa-s Average molecular weight (GPC, polystyrene-calibrated): -19M„= 1780 g/mol M, = 4 640 g/mol Elemental analysis: found: C 53.33 %; H7.93%; N 7.42% Imine/aminal ratio (%, τΗ NMR analysis [N-CHj]): 69/31 Isocyanate group content: < 0.1 % The procedure of Example 1 is repeated, using the aminal from Example E instead of the aminal from Example B.
Viscosity (according to Epprecht): η = 12 000 mPa s Average molecular weight (GPC, polystyrene-calibrated): M,,» 1480 g/mol 15 Mw = 2 320 g/mol Elemental analysis: found: C 61.80 %; H8.44%; N 8.62% Imine/aminal ratio (%, NMR analysis [N-CHJ): 61/39 Isocyanate group content: <0.1% -20Example4: The procedure of Example 1 is repeated, using the aminal from Example F instead of fee aminal from Example B.
Viscosity (according to Epprecht): η = 9 600 mPa s Average molecular weight (GPC, polystyrene-calibrated): M„ = 1650 g/mol Mw = 2 970 g/mol Elemental analysts: found: C 59.25 %; H8.27%; N 850% Imine/aminal ratio (%, Ή NMR analysis [N-CH3]): 68/32 Isocyanate group content: <0.1 % The procedure of Example 1 is repeated, using the aminal from Example G instead of the aminal from Example B.
Viscosity (according to Epprecht): η = 4 800 mPa-s Average molecular weight (GPC, polystyrene-calibrated): Mn = 2120gZmol Mw = 4970g/inol Elemental analysis: found: C 59.60 %; H7.92%; N 6.59% Imine/aminal ratio (%, XH NMR analysis [N-CH3]): 68/32 Isocyanate group content: < 0.1 % -22Example6: The procedure of Example 1 is repeated, using the aminal from Example D instead of the aminal from Example B.
Viscosity (according to Epprecht): η = 38 400 mPa-s Average molecular weight (GPC, polystyrene-calibrated): M„ = 1140 g/mol Mw = 1 660 g/mol Elemental analysis: found: C 55.92 %; H 8.43 %; N 10.97 % hnine/aminal ratio (%, JH NMR analysis (N-CHJ): 57/43 Isocyanate group content: <0.1% and The procedure of Example 1 is repeated, using the aminal from Example C instead of die aminal from Example B.
Viscosity (according to Epprecht): η = 1960 mPa-s Average molecular weight (GPC, polystyrene-calibrated): Mn=l 080 g/mol 10 Mw = 2 460 g/mol Elemental analysis: found: C 63.90 %; H8.21%; N7.47% Imine/aminal ratio (%, Ή NMR analysis [N-CH3]): 61/39 Isocyanate group content: < 0.1 % -24ΙΠ. Adhesive formulations Example 8: One-component system (moisture-curing) 8A) Synthesis of the prepolymer An isocyanate-tenninated prepolymer is prepared by adding a mixture of240 g of dry bishydroxy-terminated polypropylene glycol of molecular weight2000 (Desmophen® 1900 U from Bayer AG) and 0.3 ml of dibutyltin dilaurate at 80°C to 50 g of methylenediphenyl diisocyanate (Isonate® M125 from Upjohn) over a period of 1 hour. 1.0 g of trimethylolpropane is then added to the mixture obtained, which is stined at 80°C for another 2 hours until an isocyanate-tenninated prepolymer having an isocyanate content of 2.0 % has been formed. 8B) Formulation: The adhesive formulation has the following composition: 55.1 % by weight of die prepolymer according to Example 8A 20 % by weight of ground lamp black 14.9 % by weight of dioctyl phthalate 5 % by weight of silica aerogel (thixotropic agent) % by weight of the adhesion promoter according to Example 1 8C) Adhesion to various substrates: The adhesive formulation obtained in 8B) is poured onto a substrate (according to die table below) such that a 5 mm thick polyurethane layer is formed. After storage in air for 2 weeks, these samples are stored for 2 weeks in water at room temperature. The results are summarised in Table 1, in which (-) means that die layer can te peeled off with ease and die substrate surface remains dean; (-) means that the layer cante peeled off with difficulty and the substrate surface remains clean; (+/-) means that die majority of the layer cm the substrate surface can te removed by scratching using a knife; (+) means that die majority of the layer remains attached to die substrate surface despite scratching using a knife; (++) means drat the entire layer remains attached to die substrate surface despite scratching using a knife. -25Table 1 Substrate without adhesion promoter with adhesion promoter according to Example 1 Glass - + + SMC - + PC + - RIM-PUR - + PA • · + - SMC * Sheet Moulding Compound PC = Polycmbonate RIM-PUR = Reaction Injection Moulding - Polyurethane PA = Polyamide Example 9: Two-component system (heat-curing) 9A) Formulation: The adhesive formulation has die following composition: 100 parts by weight of polyol mainly comprising branched polyether polyols and mineral fillers parts by weight of isocyanate based on diphenylmethane diisocyanate 5 parts by weight of the adhesion promoter according to Example 1 9B) Mechanical properties The tensile shear strengths of various samples were determined.
Test specimens: Substrate thickness 3.0 mm Width 25.0mm Overlapping 12.5 mm Thickness of die adhesive joint 0.2 mm The specimens were cured at 80°C over a period of 1 hour. The results are summarised in Table 2. -26Table2 Substrate without adhesion promoter with adhesion promoter according to Example 1 PA 2.3 C(40%) 3.2 cno%) PC 3.5 Ad 5.0 C(50%) PP 1.6 Ad 45 MB PA Polyamide PC>* Polycarbonate PP « Polypropylene (Qame-pKDeatod) Ad» Adhesion break C* Cohesion break MB=Material break, substrate break The values obtained show that die use of die compounds according to die present invention as adhesion promoters substantially improves the tensile shear strength of these specimens.

Claims (21)

1. Claims / ——————
1. A compound of the general formula I ϊ ί τ_ E-Rj-N— I(CH 2 ^O- 1 —C-HN-J—T _Jm in which 5 Ri is CrQalkylene and R 2 is hydrogen, CpCgalkyl which is unsubstituted or substituted by -OH, -CN or -Si(OR 3 )3^(R4)q or is C
2. *C6aUcenyl, in which R 3 is Ci-Qalkyl or two radicals R 3 together are C r C4alkylene, R4 is CpQalkyl or phenyl and 10 q can have values from 0 to 2, furthermore E is a radical of the formula or E together with R 2 is a radical of the formula »5 A V in which R 5 and Re, independently of one another, are hydrogen, Ci-C 4 alkyl, aryl-substituted ethenyl, aryl, heteroaryl or radicals of the formulae Ha or lib (Ha) -28:=Ν Ζ 1 ’ k n z Sin > I r 2 (Hb) with tiie proviso that at least one of the radicals R5 or Re is aryl-substituted ethenyl, aryl, heteroaryl or a radical of the formulae Ila or Db and in which R 7 is hydrogen, CpC 4 alkyl or -R9-Si(OR 3 )3^(R4) q and R 3 , R4 andq are 5 as defined above, and R9 is CpCgalkylene, and Y is oxygen or sulfur; furthermore, T is a radical of the formulae -R 9 -Si(OR 3 ) 3q (R 4 ) q or or, if R 7 is a radical of the formula -Rp-SKORj^fRJq and m is greater than or equal to 2, is an m-valent radical Z in which R 3 , R4, R$, Y and q are as defined above, X is -S- or -NH- and Z is an organic radical which is derived from a polyisocyanate or a polyisothiocyanate 15 having at least 2 NCO or NCS groups, and r is 1,2 or 3 and p isOorland m can have values of greater than or equal to 1 and n can have values of greater than or equal to 1. 20 2. A compound of the formula I according to claim 1, in which Y is oxygen.
3. A compound of die formula I according to claim 1, in which Z is derived from an aliphatic, cycloaliphatic, aliphatic/aromatic, aromatic or heterocyclic polyisocyanate or polyisothiocyanate in which the number of NCO or NCS groups is greater than or equal to 2, it being possible for the radical Z to contain, if desired, one or mote ester, ether, -29urethane, thiourethane, isocyanurate, urea or biuret functions.
4. A compound of the formula I according to claim 3, in which Z is derived from an aliphatic or mixed aliphatic/aromatic polyisocyanate in which die number of NCO groups is greater than or equal to 2, it being possible for this radical Z to contain, if desired, a 5. Total of one or two ester, ether, urethane, thiourethane, isocyanurate, urea or biuret functions.
5. A compound of the formula I according to claim 1, in which the radical Z has an average molecular weight M„ of less than 10 000.
6. A compound of the formula I according to claim 1, in which m and n, independently of 10 one another, have values from 1 to 49.
7. A compound of the formula I according to claim 1, in which the sum of m + n is 2 to 50.
8. A compound of the formula I according to claim 1, in which n is 1,2 or 3 and mis 3,2 or 1.
9. A compound of the formula I according to claim 1, in which R } is propylene. 15
10. A compound of the formula I according to claim 1, in which p has the value 0.
11. A compound of the formula I according to claim 1, in which q has die value 0.
12. A compound of die formula I according to claim 1, in which at least one of the radicals R5 or Rg is a group of the formulae O - · · O'· 20
13. A compound of the formula I according to claim l,in which T is a radical of the formulae -R9-Si(OR 3 )3^(R4)q or -30in which X, Y, Z, R 3 , R4, Rg, q and n are as defined in claim 1. i
14. A compound of the formula I according to claim 13, in which at least one radical X is , -S-. *
15. A compound of the formula I according to claim 1, in which p and q are 0, m is 1 and 5 n is 2, Y is oxygen, X is -S-, R t and R9 are propylene, R 2 and R 3 are methyl, R 5 is phenyl and Rg is hydrogen.
16. A polyurethane resin containing at least one compound of the formula I according to claim 1.
17. A polyurethane resin according to claim 16, containing 0.1 to 20 % by weight of a 10 compound of the formula I.
18. A conpound aooording to claim 1, substantially as hereinbefore described and exenplified.
19. A process for preparing a compound according to claim 1, substantially as hereinbefore described and exenplified. 15
20. A compound according to claim 1, whenever prepared by a process claimed in claim 19.
21. A polyurethane resin according to claim 16, substantially as hereinbefore described and exenplified.
IE420091A 1990-12-04 1991-12-03 Coupling agent IE71041B1 (en)

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DE10103027A1 (en) 2001-01-24 2002-07-25 Bayer Ag Adhesion promoter, e.g. for improving adhesion of silicon-based protective coatings to polymeric substrates, comprising two-component polyurethane binder based on alkoxysilane-modified polyisocyanate
JP4298750B2 (en) * 2004-06-15 2009-07-22 エルジー・ケム・リミテッド Novel silane coupling agent and method for producing the same
EP3034527B1 (en) * 2014-12-19 2017-05-31 Evonik Degussa GmbH Cover net systems for encapsulation films comprising bis-(alkenylamide) compounds
ES2743790T3 (en) * 2016-08-24 2020-02-20 Henkel Ag & Co Kgaa Promotion of plastic adhesion for 2K polyurethane adhesives

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JPS6131461A (en) * 1984-07-24 1986-02-13 Shin Etsu Chem Co Ltd Room temperature curing organosiloxane composition
JPS62249992A (en) * 1986-04-24 1987-10-30 Nippon Kayaku Co Ltd Novel silicon urethane (meth)acrylate, resin composition and coating agent using said compound
DE59004478D1 (en) * 1989-06-13 1994-03-17 Ciba Geigy Adhesion promoter.

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CA2056751C (en) 2002-06-04
EP0489688A1 (en) 1992-06-10
IE914200A1 (en) 1992-06-17
EP0489688B1 (en) 1996-03-06

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