HUP0203042A2 - Peszticid hatású tetrahidro-piridin vegyületek - Google Patents
Peszticid hatású tetrahidro-piridin vegyületekInfo
- Publication number
- HUP0203042A2 HUP0203042A2 HU0203042A HUP0203042A HUP0203042A2 HU P0203042 A2 HUP0203042 A2 HU P0203042A2 HU 0203042 A HU0203042 A HU 0203042A HU P0203042 A HUP0203042 A HU P0203042A HU P0203042 A2 HUP0203042 A2 HU P0203042A2
- Authority
- HU
- Hungary
- Prior art keywords
- alkyl
- alkenyl
- halogen
- halo
- alkynyl
- Prior art date
Links
- 239000000575 pesticide Substances 0.000 title abstract 2
- 125000004853 tetrahydropyridinyl group Chemical class N1(CCCC=C1)* 0.000 title 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 8
- 125000005843 halogen group Chemical group 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 150000003839 salts Chemical group 0.000 abstract 2
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- 125000006701 (C1-C7) alkyl group Chemical group 0.000 abstract 1
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 1
- 125000006766 (C2-C6) alkynyloxy group Chemical group 0.000 abstract 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- -1 benzyl ,phenoxy, benzyloxy Chemical group 0.000 abstract 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000005844 heterocyclyloxy group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 230000001902 propagating effect Effects 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/20—N-Aryl derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/70—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Hydrogenated Pyridines (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
A találmány tárgya (I) általános képletű vegyületek R1 és R2 jelentéseegymástól függetlenül például halogénatom, C1-C6-alkil, C3-C6-cikloalkil, halogén-(C1-C6-alkil), halogén-(C3-C6-cikloalkil), C2-C4-alkenil, C2-C4-alkinil, halogén-(C2-C4-alkenil), vagy halogén-(C2-C4-alkinil)- csoport; R3 jelentése hidrogénatom, OH csoport, halogénatom,C1-C6-alkoxi- vagy -OC(=O)-C1-C6-alkil-csoport; R4 jelentése példáulvagy fenil, benzil, fenoxi- vagy benzil-oxi-csoport, amely egymástólfüggetlenül a következő szubsztituensekkel mono - pentaszubsztituált:halogénatom, ciano, NO2, C1-C6-alkil, C3- C8-cikloalkil, C3-C8-cikloalkil-C1-C6-alkil, halogén- (C1-C6-alkil), C1-C6-alkoxi, C3-C8-cikloalkoxi, C3-C8-cikloalkoxi-C1-C6-alkil, C3-C8- cikloalkil-C1-C6-alkoxi, halogén-(C1-C6-alkoxi), C2-C4-alkenil, C2-C4-alkinil,halogén(C2-C4-alkenil), halogén-(C2-C4-alkinil), C2-C4-alkenil-<->oxi, C2-C6-alkinil-oxi, halogén(C2-C6-alkenil)- oxi, halogén-(C2-C6-alkinil)-oxi, -NR6-C(=O)-O- C1-C6-alkil, -NR6C(=O)-O-C2-C6-alkenil, -NR6-C(=O)-O- halogén-(C1-C6-alkil), -C(R7)=N-W-R8, fenil, benzil,fenoxi, benzil-oxi, heterociklil- vagy heterociklil-oxi-csoport; a kétR5 jelentése egymástól függetlenül hidrogénatom vagy C1-C6-alkilcsoport; R6 jelentése hidrogénatom, C1-C6- alkil- vagybenzilcsoport; R7 jelentése például halogénatom, vagy C1-C7-alkil-csoport; R8 jelentése például hidrogénatom, vagy C1-C6-alkil-csoport,m jelentése egész szám, melynek értéke 0, 1, 2, 3, 4 vagy 5; njelentése egész szám, melynek értéke 0, 1, 2, 3, 4 vagy 5; p jelentéseegész szám, melynek értéke 0, 1 vagy 2; q jelentése egész szám,melynek értéke 0 vagy 1; W jelentése O vagy NH vagy N-C1-C6-alkil-csoport; - és, ha léteznek, azok E/Z izomerjei, E/Z izomer keverékeiés/vagy tautomerjei szabad vegyület formában vagy só formájában. Atalálmány tárgya még ezeknek a vegyületeknek az előállítása ésalkalmazása, a peszticidek, amelyeknek a hatóanyagát ezek a vegyületekvagy agrokémiailag alkalmazható sóik képezik, ezeknek a kompozícióknakaz előállítási eljárása és alkalmazása, a kompozíciókkal védettnövényi szaporítóanyagok és eljárás kártevők irtására. Ó
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH160799 | 1999-09-03 | ||
PCT/EP2000/008566 WO2001017964A1 (en) | 1999-09-03 | 2000-09-01 | Tetrahydropyridines as pesticides |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP0203042A2 true HUP0203042A2 (hu) | 2003-01-28 |
HUP0203042A3 HUP0203042A3 (en) | 2003-02-28 |
Family
ID=4214391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU0203042A HUP0203042A3 (en) | 1999-09-03 | 2000-09-01 | Tetrahydropyridines as pesticides |
Country Status (23)
Country | Link |
---|---|
US (1) | US6638940B1 (hu) |
EP (1) | EP1208084B1 (hu) |
JP (1) | JP4763195B2 (hu) |
KR (1) | KR20020029121A (hu) |
CN (1) | CN1138758C (hu) |
AT (1) | ATE254103T1 (hu) |
AU (1) | AU767535B2 (hu) |
BR (1) | BR0013757A (hu) |
CA (1) | CA2381003A1 (hu) |
CZ (1) | CZ2002764A3 (hu) |
DE (1) | DE60006544T2 (hu) |
DK (1) | DK1208084T3 (hu) |
ES (1) | ES2211611T3 (hu) |
HU (1) | HUP0203042A3 (hu) |
IL (2) | IL147831A0 (hu) |
MX (1) | MXPA02001705A (hu) |
PL (1) | PL353397A1 (hu) |
PT (1) | PT1208084E (hu) |
RU (1) | RU2002107432A (hu) |
TR (1) | TR200200566T2 (hu) |
UA (1) | UA75051C2 (hu) |
WO (1) | WO2001017964A1 (hu) |
ZA (1) | ZA200201648B (hu) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002068392A1 (en) * | 2001-02-05 | 2002-09-06 | Syngenta Participations Ag | N-substituted tetrahydropyridines and their use as pesticides |
TW200400005A (en) * | 2002-02-11 | 2004-01-01 | Syngenta Participations Ag | Derivatives of (1-benzyl-piperidine-4-yl)-diphenyl-methanol |
BR0316747A (pt) * | 2002-12-18 | 2005-10-18 | Fmc Corp | Piperidinas n-(arilmetil substituìdas)-4-(metil dissubstituìdas) e piperazinas |
JP4585818B2 (ja) * | 2004-09-10 | 2010-11-24 | 日本エンバイロケミカルズ株式会社 | シロアリ防除剤 |
DK2114885T3 (en) * | 2007-02-09 | 2016-05-09 | Dow Agrosciences Llc | A process for the oxidation of certain substituted sulfiliminer for insecticidal sulfoximines |
US8597688B2 (en) | 2008-07-09 | 2013-12-03 | Basf Se | Pesticidal mixtures comprising isoxazoline compounds II |
KR101680912B1 (ko) | 2008-07-09 | 2016-11-29 | 바스프 에스이 | 이속사졸린 화합물 ⅰ을 포함하는 살충 활성 혼합물 |
TW201029997A (en) | 2008-12-23 | 2010-08-16 | Basf Se | Imine compounds for combating invertebrate pests |
EA201100980A1 (ru) | 2008-12-23 | 2012-01-30 | Басф Се | Замещенные амидиновые соединения для подавления животных-вредителей |
CN102762543B (zh) | 2010-02-01 | 2016-03-09 | 巴斯夫欧洲公司 | 用于防除动物害虫的取代的酮型异*唑啉化合物和衍生物 |
WO2013092943A1 (en) | 2011-12-23 | 2013-06-27 | Basf Se | Isothiazoline compounds for combating invertebrate pests |
CN107459515A (zh) * | 2016-06-06 | 2017-12-12 | 南开大学 | 一类手性四氢吡啶衍生物及其制备方法和用途 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS517127A (ja) * | 1974-07-04 | 1976-01-21 | Fujisawa Pharmaceutical Co | Rikuseigaichuyosatsuchuzai |
JPS5283567A (en) * | 1976-01-01 | 1977-07-12 | Fujisawa Pharmaceut Co Ltd | N-containing, 6-membered quaternary compounds |
US4485107A (en) * | 1982-11-01 | 1984-11-27 | Janssen Pharmaceutica N.V. | [[Bis(aryl)methylene]-1-piperidinyl]alkyl-pyrimidinones |
JPH0253773A (ja) * | 1988-08-18 | 1990-02-22 | Sumitomo Chem Co Ltd | 複素環化合物およびそれを有効成分とする殺菌剤 |
JPH06172306A (ja) | 1992-10-05 | 1994-06-21 | Nissan Chem Ind Ltd | 環状アミド化合物および除草剤 |
US5569664A (en) | 1995-02-16 | 1996-10-29 | Fmc Corporation | Insecticidal n-(substituted arylmethyl)-4-[bis(substituted phenyl) methyl]pi |
US5639763A (en) * | 1994-03-01 | 1997-06-17 | Fmc Corporation | Insecticidal N-(substituted arylmethyl)-4-[bis(substituted phenyl)methyl]piperidines |
DE69625069T2 (de) | 1995-05-19 | 2003-09-11 | Fmc Corp | Insektizide von n-(substituiertes arylmethyl)-4-(bis (substituiertes phenyl oder pyridyl)methyl)-piperidin. |
CA2255727A1 (en) * | 1996-05-31 | 1997-12-04 | Trophix Pharmaceuticals, Inc. | Pharmaceutical for treating of neurological and neuropsychiatric disorders |
AU3505197A (en) | 1996-07-02 | 1998-01-21 | Fmc Corporation | Insecticidal n-(substituted arylmethyl)-4-{bis(substituted aryl) hydroxymethyl}piperidinium salts |
GB2319524A (en) | 1996-11-25 | 1998-05-27 | Zeneca Ltd | Nortropane derivatives for use as insecticides |
-
2000
- 2000-01-09 UA UA2002042576A patent/UA75051C2/uk unknown
- 2000-09-01 HU HU0203042A patent/HUP0203042A3/hu unknown
- 2000-09-01 CZ CZ2002764A patent/CZ2002764A3/cs unknown
- 2000-09-01 TR TR2002/00566T patent/TR200200566T2/xx unknown
- 2000-09-01 CA CA002381003A patent/CA2381003A1/en not_active Abandoned
- 2000-09-01 PL PL00353397A patent/PL353397A1/xx not_active Application Discontinuation
- 2000-09-01 DE DE60006544T patent/DE60006544T2/de not_active Expired - Lifetime
- 2000-09-01 IL IL14783100A patent/IL147831A0/xx not_active IP Right Cessation
- 2000-09-01 AT AT00964091T patent/ATE254103T1/de not_active IP Right Cessation
- 2000-09-01 MX MXPA02001705A patent/MXPA02001705A/es active IP Right Grant
- 2000-09-01 AU AU75132/00A patent/AU767535B2/en not_active Ceased
- 2000-09-01 BR BR0013757-0A patent/BR0013757A/pt not_active IP Right Cessation
- 2000-09-01 ES ES00964091T patent/ES2211611T3/es not_active Expired - Lifetime
- 2000-09-01 JP JP2001521711A patent/JP4763195B2/ja not_active Expired - Fee Related
- 2000-09-01 PT PT00964091T patent/PT1208084E/pt unknown
- 2000-09-01 DK DK00964091T patent/DK1208084T3/da active
- 2000-09-01 RU RU2002107432/04A patent/RU2002107432A/ru not_active Application Discontinuation
- 2000-09-01 KR KR1020027002812A patent/KR20020029121A/ko not_active Application Discontinuation
- 2000-09-01 EP EP00964091A patent/EP1208084B1/en not_active Expired - Lifetime
- 2000-09-01 US US10/069,807 patent/US6638940B1/en not_active Expired - Fee Related
- 2000-09-01 WO PCT/EP2000/008566 patent/WO2001017964A1/en not_active Application Discontinuation
- 2000-09-01 CN CNB008121354A patent/CN1138758C/zh not_active Expired - Fee Related
-
2002
- 2002-01-24 IL IL147831A patent/IL147831A/en unknown
- 2002-02-27 ZA ZA200201648A patent/ZA200201648B/en unknown
Also Published As
Publication number | Publication date |
---|---|
RU2002107432A (ru) | 2003-10-10 |
KR20020029121A (ko) | 2002-04-17 |
BR0013757A (pt) | 2002-05-14 |
UA75051C2 (en) | 2006-03-15 |
DE60006544D1 (de) | 2003-12-18 |
IL147831A (en) | 2006-12-31 |
TR200200566T2 (tr) | 2002-06-21 |
MXPA02001705A (es) | 2002-08-06 |
PL353397A1 (en) | 2003-11-17 |
ATE254103T1 (de) | 2003-11-15 |
PT1208084E (pt) | 2004-03-31 |
IL147831A0 (en) | 2002-08-14 |
US6638940B1 (en) | 2003-10-28 |
CN1138758C (zh) | 2004-02-18 |
JP2003508519A (ja) | 2003-03-04 |
CN1371364A (zh) | 2002-09-25 |
EP1208084A1 (en) | 2002-05-29 |
CA2381003A1 (en) | 2001-03-15 |
WO2001017964A1 (en) | 2001-03-15 |
ES2211611T3 (es) | 2004-07-16 |
EP1208084B1 (en) | 2003-11-12 |
CZ2002764A3 (cs) | 2002-05-15 |
HUP0203042A3 (en) | 2003-02-28 |
AU767535B2 (en) | 2003-11-13 |
DE60006544T2 (de) | 2004-09-16 |
AU7513200A (en) | 2001-04-10 |
DK1208084T3 (da) | 2004-03-22 |
JP4763195B2 (ja) | 2011-08-31 |
ZA200201648B (en) | 2002-11-27 |
WO2001017964A8 (en) | 2001-04-12 |
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