Claims (15)
1. Postupak za obradu podloge (102, 402, 404) koji sadrži:
stvaranje plazme visokog napona (HV) izmjenične struje (AC) kod atmosferskog tlaka (AP) u području obrade (124) koji sadrži dvije međusobno razmaknute elektrode (e1/e2; 212/214; 412/414) pri čemu su elektrode predviđene kao prvi i drugi valjci (212/214; 412/414) koji su postavljeni paralelno jedni s drugima, s razmakom između njih, te razmak odgovara debljini podloge, kako bi se omogućilo da se podloga dovodi između valjaka;
naznačen time da postupak sadrži:
usmjeravanje barem jedne laserske zrake (132) u područje obrade, koja je približno paralelna s elektrodama i između je elektroda i malo iznad gornje površine (102a) podloge, radi interakcije s plazmom, što rezultira hibridnom plazmom;
pri čemu je barem jedna laserska zraka usmjerena pod kutom (α) manjim od 1-10 stupnjeva s gornjom površinom podloge koja se obrađuje tako da se izravno ozrači podloga koja se obrađuje dok slučajno reagira s plazmom koja se stvara pomoću dvije elektrode;
i
uzrokovanje da hibridna plazma bude u interakciji sa podlogom u području koje se obrađuje (124).1. Process for treating the substrate (102, 402, 404) which contains:
generating high voltage (HV) alternating current (AC) plasma at atmospheric pressure (AP) in a processing area (124) containing two spaced apart electrodes (e1/e2; 212/214; 412/414) wherein the electrodes are provided as the first and other rollers (212/214; 412/414) which are placed parallel to each other, with a distance between them, and the distance corresponds to the thickness of the substrate, to allow the substrate to be fed between the rollers;
characterized by the fact that the procedure contains:
directing at least one laser beam (132) into the processing area, which is approximately parallel to the electrodes and is between the electrodes and slightly above the upper surface (102a) of the substrate, to interact with the plasma, resulting in a hybrid plasma;
wherein at least one laser beam is directed at an angle (α) of less than 1-10 degrees with the upper surface of the substrate to be processed so as to directly irradiate the substrate to be processed while coincidentally reacting with the plasma generated by the two electrodes;
and
causing the hybrid plasma to interact with the substrate in the area being treated (124).
2. Postupak prema zahtjevu 1, naznačen time da laser ima barem jednu od slijedećih značajki:
laser sadrži excimer laser;
laser radi u ultraljubičastom (UV) opsegu valnih duljina;
laser radi s najmanje 25 W izlazne snage.2. The method according to claim 1, characterized in that the laser has at least one of the following features:
the laser contains an excimer laser;
the laser works in the ultraviolet (UV) range of wavelengths;
the laser operates with at least 25 W of output power.
3. Postupak prema bilo kojem prethodnom zahtjevu, naznačen time da nadalje sadrži:
prije obrade podloge, raspršivanje (122, 322, 422) prekursorskih materijala (323, 437) na podlogu.3. The process according to any preceding claim, characterized in that it further contains:
prior to treating the substrate, spraying (122, 322, 422) precursor materials (323, 437) onto the substrate.
4. Postupak prema bilo kojem prethodnom zahtjevu, naznačen time da nadalje sadrži:
nakon obrade podloge, raspršivanje (126, 326, 426) završnih materijala (327, 439) na podlogu.4. The process according to any preceding claim, characterized in that it further contains:
after processing the substrate, spraying (126, 326, 426) finishing materials (327, 439) on the substrate.
5. Postupak prema bilo kojem prethodnom zahtjevu, naznačen time da je podloga materijal koji je odabran iz skupine koja sadrži sintetski tekstilni materijal, poliester, organski materijal, pamuk i vunu.5. The method according to any preceding claim, characterized in that the substrate is a material selected from the group consisting of synthetic textile material, polyester, organic material, cotton and wool.
6. Postupak prema bilo kojem prethodnom zahtjevu, naznačen time da je barem jedna laserska zraka oblikovana tako da ima pravokutni presjek koji ima konzistentnu gustoću snage na čitavom području koje se obrađuje.6. A method according to any preceding claim, characterized in that at least one laser beam is shaped to have a rectangular cross-section that has a consistent power density over the entire area being treated.
7. Uređaj (100, 400A, 400B, 400C, 400D, 400E, 400F) za obradu materijala koji sadrži:
dvije međusobno razmaknute elektrode (e1/e2; 212/214; 412/414) za stvaranje plazme u području koje se obrađuje (124);
pri čemu dvije elektrode su prvi i drugi valjci koji su smješteni paralelno jedni su drugima s razmakom između njih, te razmak odgovara debljini podloge, kako bi se omogućilo da se materijal uvodi između valjaka;
naznačen time da uređaj obuhvaća:
jedan ili više lasera (130) koji usmjeravaju odgovarajuću jednu ili više zraka (132) u područje koje se obrađuje radi interakcije s plazmom i materijalom koji se obrađuje; te
sredstva za usmjeravanje barem jedne laserske zrake pod kutom (α) manjim od 1-10 stupnjeva s gornjom površinom materijala koji se obrađuje kako bi izravno zračio materijal dok slučajno reagira s plazmom koja se stvara pomoću dvije elektrode.7. Device (100, 400A, 400B, 400C, 400D, 400E, 400F) for processing material containing:
two mutually spaced electrodes (e1/e2; 212/214; 412/414) for generating plasma in the area to be processed (124);
wherein the two electrodes are the first and second rollers which are placed parallel to each other with a distance between them, and the distance corresponds to the thickness of the substrate, to allow the material to be introduced between the rollers;
indicated that the device includes:
one or more lasers (130) directing respective one or more beams (132) into the area being processed to interact with the plasma and the material being processed; you
means for directing at least one laser beam at an angle (α) of less than 1-10 degrees with the upper surface of the material being processed to directly irradiate the material as it coincidentally reacts with the plasma generated by the two electrodes.
8. Uređaj prema zahtjevu 7, naznačen time da nadalje sadrži:
treće i četvrte valjke (416/418) koji su smješteni pored prvih i drugih valjaka i oblikuju polu-zrako nepropusnu šupljinu (440) između vanjskih površina prvih, drugih, trećih i četvrtih valjaka (412, 414, 416, 418) radi definiranja područja koje se obrađuje (124) i za plazmu.8. Device according to claim 7, characterized in that it further contains:
third and fourth rollers (416/418) which are located next to the first and second rollers and form a semi-airtight cavity (440) between the outer surfaces of the first, second, third and fourth rollers (412, 414, 416, 418) to define the area which is processed (124) and for plasma.
9. Uređaj prema zahtjevu 8, naznačen time da:
barem jedan od trećih i četvrtih valjaka (436, 438) sadrži metalni vanjski sloj (437, 439).9. Device according to claim 8, characterized in that:
at least one of the third and fourth rollers (436, 438) comprises a metal outer layer (437, 439).
10. Uređaj prema zahtjevu 7, naznačen time da nadalje sadrži:
štit (420) postavljen oko prvih i drugih valjaka (412, 414) da bi se definirala polu-zrako nepropusna šupljina (440).10. Device according to claim 7, characterized in that it further contains:
a shield (420) positioned around the first and second rollers (412, 414) to define a semi-airtight cavity (440).
11. Uređaj u skladu s bilo kojim od zahtjeva 7 do 10, naznačen time da nadalje sadrži najmanje jedan od:
mlaznice (322, 422) za isporuku prekursorskog materijala, u tekućem, čvrstom ili atomiziranom obliku; i
mlaznice (326) za izdavanje završnog materijala (327) na materijal koji se obrađuje.11. The device according to any one of claims 7 to 10, characterized in that it further contains at least one of:
nozzles (322, 422) for delivering precursor material, in liquid, solid or atomized form; and
nozzles (326) for dispensing the finishing material (327) onto the material being processed.
12. Uređaj prema zahtjevu 7, naznačen time da su elektrode (e1/e2; 212/214; 412/414) obložene keramikom.12. Device according to claim 7, characterized in that the electrodes (e1/e2; 212/214; 412/414) are coated with ceramics.
13. Uređaj u skladu s bilo kojim od zahtjeva 7 do 12 naznačen time da je najmanje jedna laserska zraka oblikovana tako da ima pravokutni presjek koji pokazuje dosljednu gustoću snage na čitavom području koje se obrađuje.13. A device according to any one of claims 7 to 12, characterized in that at least one laser beam is shaped to have a rectangular cross-section that exhibits a consistent power density over the entire area being treated.
14. Uporaba uređaja prema bilo kojem od zahtjeva 7 do 13 naznačena time da služi za obradu tekstilne podloge pri čemu je tekstilna podloga odabrana iz skupine koja se sastoji od sintetskog tekstilnog materijala, poliestera, organskog materijala, pamuka i vune.14. The use of the device according to any one of claims 7 to 13, characterized in that it is used for processing a textile substrate, wherein the textile substrate is selected from the group consisting of synthetic textile material, polyester, organic material, cotton and wool.
15. Tekstilni materijal naznačen time da se dobiva postupkom prema bilo kojem od zahtjeva 1 do 6.15. Textile material characterized by the fact that it is obtained by a process according to any of claims 1 to 6.