HRP20140152T1 - Uporaba ditiin tetrakarboksimida za suzbijanje fitopatogenih gljivica - Google Patents
Uporaba ditiin tetrakarboksimida za suzbijanje fitopatogenih gljivica Download PDFInfo
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- HRP20140152T1 HRP20140152T1 HRP20140152AT HRP20140152T HRP20140152T1 HR P20140152 T1 HRP20140152 T1 HR P20140152T1 HR P20140152A T HRP20140152A T HR P20140152AT HR P20140152 T HRP20140152 T HR P20140152T HR P20140152 T1 HRP20140152 T1 HR P20140152T1
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- dipyrrolo
- dithiino
- tetron
- bis
- species
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- 241000233866 Fungi Species 0.000 title claims 3
- 230000003032 phytopathogenic effect Effects 0.000 title claims 3
- RIYVKHUVXPAOPS-UHFFFAOYSA-N dithiine Chemical compound S1SC=CC=C1 RIYVKHUVXPAOPS-UHFFFAOYSA-N 0.000 title 1
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 claims 56
- 239000002253 acid Substances 0.000 claims 10
- 241000220225 Malus Species 0.000 claims 8
- 235000021016 apples Nutrition 0.000 claims 8
- 229910052736 halogen Inorganic materials 0.000 claims 8
- 150000002367 halogens Chemical group 0.000 claims 8
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 6
- 235000013399 edible fruits Nutrition 0.000 claims 6
- 241000894007 species Species 0.000 claims 6
- 235000012055 fruits and vegetables Nutrition 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- XMIIGOLPHOKFCH-UHFFFAOYSA-N 3-phenylpropionic acid Chemical compound OC(=O)CCC1=CC=CC=C1 XMIIGOLPHOKFCH-UHFFFAOYSA-N 0.000 claims 4
- 244000144725 Amygdalus communis Species 0.000 claims 4
- 235000016068 Berberis vulgaris Nutrition 0.000 claims 4
- 241000335053 Beta vulgaris Species 0.000 claims 4
- 241000167854 Bourreria succulenta Species 0.000 claims 4
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 claims 4
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 claims 4
- 240000003259 Brassica oleracea var. botrytis Species 0.000 claims 4
- 244000178937 Brassica oleracea var. capitata Species 0.000 claims 4
- 244000221633 Brassica rapa subsp chinensis Species 0.000 claims 4
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 claims 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims 4
- 235000005979 Citrus limon Nutrition 0.000 claims 4
- 244000131522 Citrus pyriformis Species 0.000 claims 4
- 240000000560 Citrus x paradisi Species 0.000 claims 4
- 241001529387 Colletotrichum gloeosporioides Species 0.000 claims 4
- 240000009088 Fragaria x ananassa Species 0.000 claims 4
- 235000009827 Prunus armeniaca Nutrition 0.000 claims 4
- 244000018633 Prunus armeniaca Species 0.000 claims 4
- 240000005809 Prunus persica Species 0.000 claims 4
- 235000006040 Prunus persica var persica Nutrition 0.000 claims 4
- 241000220324 Pyrus Species 0.000 claims 4
- 244000062793 Sorghum vulgare Species 0.000 claims 4
- 235000020224 almond Nutrition 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 235000021028 berry Nutrition 0.000 claims 4
- 235000019693 cherries Nutrition 0.000 claims 4
- 201000010099 disease Diseases 0.000 claims 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims 4
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 claims 4
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 235000021017 pears Nutrition 0.000 claims 4
- 239000004575 stone Substances 0.000 claims 4
- 235000021012 strawberries Nutrition 0.000 claims 4
- 235000013311 vegetables Nutrition 0.000 claims 4
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 2
- MLMQPDHYNJCQAO-UHFFFAOYSA-N 3,3-dimethylbutyric acid Chemical compound CC(C)(C)CC(O)=O MLMQPDHYNJCQAO-UHFFFAOYSA-N 0.000 claims 2
- 235000005254 Allium ampeloprasum Nutrition 0.000 claims 2
- 240000006108 Allium ampeloprasum Species 0.000 claims 2
- 244000291564 Allium cepa Species 0.000 claims 2
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims 2
- 241000223600 Alternaria Species 0.000 claims 2
- 235000017060 Arachis glabrata Nutrition 0.000 claims 2
- 244000105624 Arachis hypogaea Species 0.000 claims 2
- 235000010777 Arachis hypogaea Nutrition 0.000 claims 2
- 235000018262 Arachis monticola Nutrition 0.000 claims 2
- 241000228212 Aspergillus Species 0.000 claims 2
- 241000228245 Aspergillus niger Species 0.000 claims 2
- 244000075850 Avena orientalis Species 0.000 claims 2
- 235000007319 Avena orientalis Nutrition 0.000 claims 2
- 235000000832 Ayote Nutrition 0.000 claims 2
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims 2
- 241001465180 Botrytis Species 0.000 claims 2
- 241000123650 Botrytis cinerea Species 0.000 claims 2
- 241000219198 Brassica Species 0.000 claims 2
- 235000003351 Brassica cretica Nutrition 0.000 claims 2
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 claims 2
- 235000006008 Brassica napus var napus Nutrition 0.000 claims 2
- 235000004221 Brassica oleracea var gemmifera Nutrition 0.000 claims 2
- 235000017647 Brassica oleracea var italica Nutrition 0.000 claims 2
- 244000308368 Brassica oleracea var. gemmifera Species 0.000 claims 2
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 claims 2
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 claims 2
- 241001301148 Brassica rapa subsp. oleifera Species 0.000 claims 2
- 235000003343 Brassica rupestris Nutrition 0.000 claims 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims 2
- 241000219193 Brassicaceae Species 0.000 claims 2
- -1 C1-C4-alkyl Chemical group 0.000 claims 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims 2
- 244000060011 Cocos nucifera Species 0.000 claims 2
- 240000007154 Coffea arabica Species 0.000 claims 2
- 241000222199 Colletotrichum Species 0.000 claims 2
- 229920000742 Cotton Polymers 0.000 claims 2
- 240000008067 Cucumis sativus Species 0.000 claims 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims 2
- 240000004244 Cucurbita moschata Species 0.000 claims 2
- 235000009854 Cucurbita moschata Nutrition 0.000 claims 2
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 claims 2
- 241000223218 Fusarium Species 0.000 claims 2
- 241001208371 Fusarium incarnatum Species 0.000 claims 2
- 241000223221 Fusarium oxysporum Species 0.000 claims 2
- 241000427940 Fusarium solani Species 0.000 claims 2
- 241000461774 Gloeosporium Species 0.000 claims 2
- 241001620302 Glomerella <beetle> Species 0.000 claims 2
- 235000010469 Glycine max Nutrition 0.000 claims 2
- 244000068988 Glycine max Species 0.000 claims 2
- 244000020551 Helianthus annuus Species 0.000 claims 2
- 235000003222 Helianthus annuus Nutrition 0.000 claims 2
- 240000005979 Hordeum vulgare Species 0.000 claims 2
- 235000007340 Hordeum vulgare Nutrition 0.000 claims 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims 2
- 241001518729 Monilinia Species 0.000 claims 2
- 241000862466 Monilinia laxa Species 0.000 claims 2
- 241001226034 Nectria <echinoderm> Species 0.000 claims 2
- 241000556984 Neonectria galligena Species 0.000 claims 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims 2
- 244000061176 Nicotiana tabacum Species 0.000 claims 2
- 240000007817 Olea europaea Species 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 2
- 235000007164 Oryza sativa Nutrition 0.000 claims 2
- 240000001090 Papaver somniferum Species 0.000 claims 2
- 235000008753 Papaver somniferum Nutrition 0.000 claims 2
- 241000228143 Penicillium Species 0.000 claims 2
- 241001123663 Penicillium expansum Species 0.000 claims 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims 2
- 244000046052 Phaseolus vulgaris Species 0.000 claims 2
- 241001480007 Phomopsis Species 0.000 claims 2
- 241000233614 Phytophthora Species 0.000 claims 2
- 241001149949 Phytophthora cactorum Species 0.000 claims 2
- 235000010582 Pisum sativum Nutrition 0.000 claims 2
- 240000004713 Pisum sativum Species 0.000 claims 2
- 244000088415 Raphanus sativus Species 0.000 claims 2
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims 2
- 240000000111 Saccharum officinarum Species 0.000 claims 2
- 235000007201 Saccharum officinarum Nutrition 0.000 claims 2
- 241000221662 Sclerotinia Species 0.000 claims 2
- 241000209056 Secale Species 0.000 claims 2
- 235000007238 Secale cereale Nutrition 0.000 claims 2
- 241001533598 Septoria Species 0.000 claims 2
- 240000003768 Solanum lycopersicum Species 0.000 claims 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims 2
- 244000061456 Solanum tuberosum Species 0.000 claims 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 claims 2
- 235000021536 Sugar beet Nutrition 0.000 claims 2
- 235000009470 Theobroma cacao Nutrition 0.000 claims 2
- 244000299461 Theobroma cacao Species 0.000 claims 2
- 241000865903 Thielaviopsis Species 0.000 claims 2
- 235000021307 Triticum Nutrition 0.000 claims 2
- 244000098338 Triticum aestivum Species 0.000 claims 2
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 claims 2
- 241000228452 Venturia inaequalis Species 0.000 claims 2
- 241000082085 Verticillium <Phyllachorales> Species 0.000 claims 2
- 240000008042 Zea mays Species 0.000 claims 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims 2
- 235000013339 cereals Nutrition 0.000 claims 2
- 235000016213 coffee Nutrition 0.000 claims 2
- 235000013353 coffee beverage Nutrition 0.000 claims 2
- 235000005822 corn Nutrition 0.000 claims 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 235000019713 millet Nutrition 0.000 claims 2
- 235000010460 mustard Nutrition 0.000 claims 2
- OVQABVAKPIYHIG-UHFFFAOYSA-N n-(benzenesulfonyl)benzenesulfonamide Chemical compound C=1C=CC=CC=1S(=O)(=O)NS(=O)(=O)C1=CC=CC=C1 OVQABVAKPIYHIG-UHFFFAOYSA-N 0.000 claims 2
- 244000052769 pathogen Species 0.000 claims 2
- 235000020232 peanut Nutrition 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 235000012015 potatoes Nutrition 0.000 claims 2
- 235000015136 pumpkin Nutrition 0.000 claims 2
- 235000009566 rice Nutrition 0.000 claims 2
- 125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 claims 2
- 238000003306 harvesting Methods 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
- C07D495/14—Ortho-condensed systems
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- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Claims (10)
1. Uporaba ditiin-tetrakarboksimida sa općom formulom (I)
[image]
gdje
R1 i R2 su isti ili različiti i predstavljaju vodik, ili predstavljaju C1-C8-alkil koji je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, -OR3 ili -COR4, ili predstavljaju C3-C7-cikloalkil koji je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, C1-C4-alkilom ili C1-C4-haloalkilom, ili predstavljaju aril ili aril-(C1-C4-alkil), svaki od kojih je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, C1-C4-alkilom, C1-C4-haloalkilom, -COR4 ili sulfonilamino,
R3 predstavlja vodik, C1-C4-alkil, C1-C4-alkil-karbonil, ili predstavlja aril koji je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, C1-C4-alkilom ili C1-C4-haloalkilom,
R4 predstavlja hidroksil, C1-C4-alkil ili C1-C4-alkoksi,
n predstavlja 0 ili 1,
za zaštitu ubranog voća ili povrća od fitopatogenih gljivica.
2. Uporaba prema zahtjevu 1, naznačena time da je bolest uzrokovana sa jednim od slijedećih patogena: vrstama Colletotrichum, na primjer Colletotrichum gloeosporioides; vrstama Fusarium, na primjer Fusarium semitectum, Fusarium solani, Fusarium oxysporum; vrstama Verticillium; vrstama Botrytis, na primjer Botrytis cinerea; vrstama Phomopsis; vrstama Alternaria; vrstama Phytophthora, na primjer Phytophthora cactorum; vrstama Septoria; vrstama Monilinia, na primjer Monilinia laxa; vrstama Venturia, na primjer Venturia inaequalis; vrstama Glomerella, na primjer Glomerella cingulata; vrstama Sclerotinia; vrstama Penicillium, na primjer Penicillium expansum; vrstama Gloeosporium; vrstama Stemphillium; vrstama Thielaviopsis; vrstama Aspergillus, na primjer Aspergillus niger; vrstama Nectria, na primjer Nectria galligena.
3. Uporaba prema zahtjevu 1 ili 2, naznačena time da je voće i povrće odabrano između žitarica, kao na primjer pšenica, ječam, raž, riža, proso/sirak i zob; repa, na primjer šećerna repa i stočna repa; jabučastog voća, koštuničavog voća i jagodastog voća, na primjer jabuke, kruške, marelice, trešnje, badem i breskve, kao i jagode; grah, grašak, soja; uljarica, na primjer uljana repica, gorušica, mak, maslina, suncokret, kokos, kakao, kikiriki; porodice bundeva, na primjer krastavac; pamuka, limuna, naranča i grejpa; Brassicaceae, na primjer bijeli kupus, crveni kupus, brokula, cvjetača, Prokulice, kineski kupus (pak choi), koraba, rotkvica; povrća, na primjer poriluk, rajčica, luk, krumpir; ili kukuruza, duhana, kave, šećerne trske, vinove loze.
4. Uporaba prema zahtjevu 1, 2 ili 3, naznačena time da su ditiin-tetrakarboksimidi sa općom formulom (I) odabrani iz skupine koja sadrži:
(1) 2,6-dimetil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(2) 2,6-dietil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(3) 2,6-dipropil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(4) 2,6-di(propan-2-il)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(5) 2,6-diciklopropil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(6) 2,6-bis(2,2,2-trifluoroetil)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(7) 2,6-bis[1-(trifluorometil)ciklopropil]-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(8) 1H, 5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(9) 2,6-bis(3,5-dichlorofenil)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(10) 2,6-difenil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron
(11) 2,6-dibenzil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron
(12) 2,6-bis(2-metoksietil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(13) 2,6-bis(2-hidroksibutil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(14) 2,6-bis(2-hidroksipropil)-2H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(15) 2,6-bis(2-fenoksietil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(16) 2,6-bis(2-etoksietil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(17) 2,6-bis(2-fenilpropan-2-il)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(18) 2,6-bis(1-feniletil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(19) 2,6-bis(2-metoksi-2-metilpropil)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(20) 2,6-di-tert-butil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(21) (1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)diethane-2,1-diil diacetat
(22) 4,4'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dibenzenesulfonamid
(23) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dioctena kiselina
(24) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dipropionska kiselina
(25) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dimaslačna kiselina
(26) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)diheksanska kiselina
(27) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)bis(3,3-dimetilmaslačna kiselina)
(28) 3,3'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dimaslačna kiselina
(29) 5,5'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dipentanska kiselina
(30) 2,6-bis[3-(trifluorometil)cikloheksil]-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H, 6H)tetron
(31) 2,6-bis[3-(trifluorometil)fenil]-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(32) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino(2,3-c:5,6-c']dipirolo-2,6-diil)bis(3-fenilpropionska kiselina)
(33) 2,6-bis(2-hidroksietil)-1H,5H-[1,4]-ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)-tetron
(34) 2,6-bis(2-hidroksi-2-metilpropil)-1H,5H-[1,4]-ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)-tetron
(35) (1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dibutan-1,2-diil diacetat
(36) (1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dipropan-1,2-diil diacetat
(37) 2,6-bis(hidroksimetil)-1H,5H-[1,4]-ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(38) 2,6-dimetil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron 4-oksid
(39) 2-etil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron
(40) Dietil 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)diheksanoat
(41) 2-[2-(1-etoksi-1-oksobutan-2-il)-1,3,5,7-tetraokso-2,3,5,7-tetrahidro-1H,6H-[1,4]ditiino-[2,3-c:5,6-c']dipirol-6-il]maslačna kiselina.
5. Uporaba prema zahtjevu 1, 2, 3 ili 4, naznačena time da je voće i povrće odabrano između jabučastog voća, koštuničavog voća i jagodastog voća, na primjer jabuke, kruške, marelice, trešnje, badem i breskve, kao i jagode; limuna, naranča i grejpa; vinove loze.
6. Postupak za kontrolu bolesti nakon berbe i/ili bolesti tijekom skladištenja naznačen time da je za obradu voća i povrća sa barem jednim ditiin-tetrakarboksimidom sa općom formulom (I)
[image]
gdje
R1 i R2 su isti ili različiti i predstavljaju vodik, ili predstavljaju C1-C8-alkil koji je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, -OR3 ili -COR4, ili predstavljaju C3-C7-cikloalkil koji je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, C1-C4-alkil ili C1-C4-haloalkil, ili predstavljaju aril ili aril-(C1-C4-alkil), svaki od kojih je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, C1-C4-alkil, C1-C4-haloalkil, -COR4 ili sulfonilamino,
R3 predstavlja vodik, C1-C4-alkil, C1-C4-alkil-karbonil, ili predstavlja aril koji je proizvoljno monosupstituiran ili polisupstituiran sa halogenom, C1-C4-alkil ili C1-C4-haloalkil,
R4 predstavlja hidroksil, C1-C4-alkil ili C1-C4-alkoksi,
n predstavlja 0 ili 1,
za zaštitu ubranog voća ili povrća od fitopatogenih gljivica.
7. Postupak prema zahtjevu 6, naznačen time da je bolest uzrokovana sa jednim od slijedećih patogena: vrstama Colletotrichum, na primjer Colletotrichum gloeosporioides; vrstama Fusarium, na primjer Fusarium semitectum, Fusarium solani, Fusarium oxysporum; vrstama Verticillium; vrstama Botrytis, na primjer Botrytis cinerea; vrstama Phomopsis; vrstama Alternaria; vrstama Phytophthora, na primjer Phytophthora cactorum; vrstama Septoria; vrstama Monilinia, na primjer Monilinia laxa; vrstama Venturia, na primjer Venturia inaequalis; vrstama Glomerella, na primjer Glomerella cingulata; vrstama Sclerotinia; vrstama Penicillium, na primjer Penicillium expansum; vrstama Gloeosporium; vrstama Stemphillium; vrstama Thielaviopsis; vrstama Aspergillus, na primjer Aspergillus niger; vrstama Nectria, na primjer Nectria galligena.
8. Postupak prema zahtjevu 6 ili 7, naznačen time da je voće i povrće odabrano između žitarica, na primjer pšenica, ječam, raž, riža, proso/sirak i zob; repa, na primjer šećerna repa i stočna repa; jabučastog voća, koštuničavog voća i jagodastog voća, na primjer jabuke, kruške, marelice, trešnje, badem i breskve, te jagoda; grah, grašak, soja; uljarica, na primjer uljana repica, gorušica, mak, maslina, suncokret, kokos, kakao, kikiriki; porodice bundeva, na primjer krastavac; pamuka, limuna, naranča i grejpa; Brassicaceae, na primjer bijeli kupus, crveni kupus, brokula, cvjetača, Prokulice, kineski kupus (pak choi), koraba, rotkvica; povrća, na primjer poriluk, rajčica, luk, krumpir; ili kukuruza, duhana, kave, šećerne trske, vinove loze.
9. Postupak prema zahtjevu 6, 7 ili 8, naznačen time da su ditiin-tetrakarboksimidi sa općom formulom (I) odabrani iz skupine koja sadrži:
(1) 2,6-dimetil-1H,5H-[1,4]ditiino[2,3-c:5,6-c'] dipirolo-1,3,5,7(2H,6H)tetron
(2) 2,6-dietil-1H,5H-[1,4]ditiino[2,3-c:5,6-c'] dipirolo-1,3,5,7(2H,6H)tetron
(3) 2,6-dipropil-1H,5H-[1,4]ditiino[2,3-c:5,6-c'] dipirolo-1,3,5,7(2H,6H)tetron
(4) 2,6-di(propan-2-il)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(5) 2,6-diciklopropil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(6) 2,6-bis(2,2,2-trifluoroetil)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(7) 2,6-bis[1-(trifluorometil)ciklopropil]-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(8) 1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(9) 2,6-bis(3,5-dichlorofenil)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(10) 2,6-difenil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron
(11) 2,6-dibenzil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron
(12) 2,6-bis(2-metoksietil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(13) 2,6-bis(2-hidroksibutil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(14) 2,6-bis(2-hidroksipropil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(15) 2,6-bis(2-fenoksietil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(16) 2,6-bis(2-etoksietil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(17) 2,6-bis(2-fenilpropan-2-il)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(18) 2,6-bis(1-feniletil)-1H,5H-[1,4]ditiino-[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(19) 2,6-bis(2-metoksi-2-metilpropil)-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(20) 2,6-di-tert-butil-1H,5H-[1,4]dithino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(21) (1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)diethane-2,1-diil diacetat
(22) 4,4'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dibenzenesulfonamid
(23) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dioctena kiselina
(24) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dipropionska kiselina
(25) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dimaslačna kiselina
(26) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)diheksanska kiselina
(27) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)bis(3,3-dimetilmaslačna kiselina)
(28) 3,3'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dimaslačna kiselina
(29) 5,5'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dipentanska kiselina
(30) 2,6-bis[3-(trifluorometil)cikloheksil]-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(31) 2,6-bis[3-(trifluorometil)fenil]-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(32) 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino(2,3-c:5,6-c']dipirolo-2,6-diil)bis(3-fenilpropionska kiselina)
(33) 2,6-bis(2-hidroksietil)-1H,5H-[1,4]-ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)-tetron
(34) 2,6-bis(2-hidroksi-2-metilpropil)-1H,5H-[1,4]-ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)-tetron
(35) (1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dibutan-1,2-diil diacetat
(36) (1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)dipropan-1,2-diil diacetat
(37) 2,6-bis(hidroksimetil)-1H,5H-[1,4]-ditiino[2,3-c:5,6-c']dipirolo-1,3,5,7(2H,6H)tetron
(38) 2,6-dimetil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron 4-oksid
(39) 2-etil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']-dipirolo-1,3,5,7(2H,6H)tetron
(40) Dietil 2,2'-(1,3,5,7-tetraokso-1,3,5,7-tetrahidro-2H,6H-[1,4]ditiino[2,3-c:5,6-c']dipirolo-2,6-diil)diheksanoat
(41) 2-[2-(1-etoksi-1-oksobutan-2-il)-1,3,5,7-tetraokso-2,3,5,7-tetrahidro-1H,6H-[1,4]ditiino-[2,3-c:5,6-c']dipirol-6-il]maslačna kiselina.
10. Postupak prema zahtjevu 6, 7, 8 ili 9, naznačen time da je voće i povrće odabrano između jabučastog voća, koštuničavog voća i jagodastog voća, na primjer jabuke, kruške, marelice, trešnje, badem i breskve, kao i jagode; limuna, naranča i grejpa; vinove loze.
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