GB975914A - Sulphonation of organic compounds - Google Patents
Sulphonation of organic compoundsInfo
- Publication number
- GB975914A GB975914A GB19157/61A GB1915761A GB975914A GB 975914 A GB975914 A GB 975914A GB 19157/61 A GB19157/61 A GB 19157/61A GB 1915761 A GB1915761 A GB 1915761A GB 975914 A GB975914 A GB 975914A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zone
- orifice
- mixture
- sulphonation
- lower pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B45/00—Formation or introduction of functional groups containing sulfur
- C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
<PICT:0975914/C1/1> A process for sulphonating or sulphating aliphatic alcohols, saturated fatty acids, aliphatic olefins, aryl or alkaryl hydrocarbons, fatty acid alkanolamides, and condensation products of ethylene or propylene oxide with an alkyl phenol, or a fatty acid, alcohol or alkanolamide comprises passing the organic compound as a liquid solution, suspension or slurry and as a free annular jet from a zone of higher pressure through an orifice into a zone of lower pressure, and introducing a gaseous mixture of sulphur trioxide and an inert gas into the centre of said annular jet through a nozzle extending into said zone of lower pressure. Reaction is preferably effected at 0 to 80 DEG C. and with a pressure drop of 5 to 300 p.s.i. Inert gases specified are air, hydrogen, nitrogen, sulphur dioxide, carbon dioxide, or mixtures thereof. As shown in the Figure, a reactor comprises a passage 11 divided by orifice plate 12 into a zone 13 of higher pressure and a zone 14 of lower pressure. Sulphur trioxide mixture is introduced through tube 15 and nozzle 16, and the organic compound is introduced through pipe 18. The orifice 17 is preferably sharp-edged to increase turbulance, this effect being also increased by flow breaker 20 and by the introduction of inert gas into passage 18; flow breaker 20 serves to break up this gas into small bubbles, which expand on passing through the orifice. These flow breakers may comprise helical coils of wire of a metal inert to sulphur trioxide. Reaction product may be recycled through cooler 31. The process and apparatus may be applied to batch-wise or to continuous sulphation or sulphonation. Specific examples relate to the sulphonation of dodecyl benzene and of a mixture of dodecyl benzene and xylene, and to the sulphation of (a) a mixture of lauryl, cetyl and oleyl alcohols and an adduct of ethylene oxide and cetyl and oleyl alcohols, and (b) of an ethylene oxide adduct of tridecyl alcohol.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL278901D NL278901A (en) | 1961-05-26 | ||
BE617968D BE617968A (en) | 1961-05-26 | ||
GB19157/61A GB975914A (en) | 1961-05-26 | 1961-05-26 | Sulphonation of organic compounds |
ES277408A ES277408A1 (en) | 1961-05-26 | 1962-05-17 | A procedure to sulfone an organic compound (Machine-translation by Google Translate, not legally binding) |
DEC27021A DE1179196B (en) | 1961-05-26 | 1962-05-18 | Method and device for sulfonating and sulfating organic compounds |
CH623762A CH401031A (en) | 1961-05-26 | 1962-05-23 | Process for sulfonating organic compounds and apparatus for carrying out the process |
US197508A US3270038A (en) | 1961-05-26 | 1962-05-24 | Sulphonation of organic compounds |
FR898594A FR1330937A (en) | 1961-05-26 | 1962-05-24 | Method and apparatus for the sulfonation of organic compounds |
DK238262AA DK117825B (en) | 1961-05-26 | 1962-05-26 | Method and apparatus for sulfonating or sulphating an organic compound. |
ES280186A ES280186A1 (en) | 1961-05-26 | 1962-08-22 | An apparatus for sulfuring an organic compound (Machine-translation by Google Translate, not legally binding) |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB19157/61A GB975914A (en) | 1961-05-26 | 1961-05-26 | Sulphonation of organic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB975914A true GB975914A (en) | 1964-11-25 |
Family
ID=10124710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19157/61A Expired GB975914A (en) | 1961-05-26 | 1961-05-26 | Sulphonation of organic compounds |
Country Status (9)
Country | Link |
---|---|
US (1) | US3270038A (en) |
BE (1) | BE617968A (en) |
CH (1) | CH401031A (en) |
DE (1) | DE1179196B (en) |
DK (1) | DK117825B (en) |
ES (2) | ES277408A1 (en) |
FR (1) | FR1330937A (en) |
GB (1) | GB975914A (en) |
NL (1) | NL278901A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2155474A (en) * | 1984-03-13 | 1985-09-25 | Procter & Gamble | Process for the continuous reaction of organic compounds with sulfur trioxide |
US5085846A (en) * | 1990-04-12 | 1992-02-04 | Albright & Wilson Limited | Process for producing phosphorous acid |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3412143A (en) * | 1965-06-21 | 1968-11-19 | Pillsbury Co | Process for the production of amine salts of sulfamic acid |
US3535339A (en) * | 1965-12-17 | 1970-10-20 | Procter & Gamble | Process and apparatus for the continuous reaction of organic compounds with undiluted sulfur trioxide |
US3482947A (en) * | 1966-07-14 | 1969-12-09 | Procter & Gamble | Feed device for a film reactor |
GB1223255A (en) * | 1967-04-25 | 1971-02-24 | Marchon Products Ltd | Sulphation process |
BE716903A (en) * | 1967-06-26 | 1968-12-02 | ||
US3931273A (en) * | 1970-02-23 | 1976-01-06 | Costruzioni Meccaniche G. Mazzoni S.P.A. | Method for sulphonatizing and sulphatizing organic compounds with sulphur trioxide and apparatus therefor |
GB1434020A (en) * | 1972-10-30 | 1976-04-28 | Koebner A | Sulphonation of aromatic compounds in the presence of solvents |
US4144266A (en) * | 1973-07-05 | 1979-03-13 | Marathon Oil Company | Sulfonation of crude oils to produce petroleum sulfonates |
US4614623A (en) * | 1974-01-04 | 1986-09-30 | Marathon Oil Company | Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates |
US4390474A (en) * | 1974-10-16 | 1983-06-28 | Stepan Chemical Company | Sulfonation petroleum composition |
DE2502254C2 (en) * | 1975-01-17 | 1983-08-04 | Marathon Oil Co., 45840 Findlay, Ohio | Process for the preparation of petroleum sulfonates containing monovalent cations |
GB1563994A (en) * | 1975-05-15 | 1980-04-02 | Albright & Wilson | Sulph(on)ation process and mixer |
US4097242A (en) * | 1975-07-21 | 1978-06-27 | Kao Soap Co., Ltd. | Sulfonation apparatus |
US4002431A (en) * | 1975-12-19 | 1977-01-11 | United Technologies Corporation | Nitrous oxide decomposition reactor |
US4113438A (en) * | 1976-05-27 | 1978-09-12 | The Chemithon Corporation | Sulfonating apparatus |
JPS6045185B2 (en) * | 1976-11-17 | 1985-10-08 | 丸善石油株式会社 | Method for sulfonating aromatic compounds |
US4560517A (en) * | 1979-03-22 | 1985-12-24 | Marathon Oil Company | Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates |
JPS6033382B2 (en) * | 1979-07-06 | 1985-08-02 | ライオン株式会社 | Thin film sulfonation method of alkylbenzene |
US4879399A (en) * | 1986-01-15 | 1989-11-07 | Sandoz Ltd. | Ether sulfates of a mixture of branched 1-decanols |
US4980087A (en) * | 1986-01-15 | 1990-12-25 | Sandoz Ltd. | Ether sulfates of a mixture of branched 1-decanols |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL27274C (en) * | ||||
US2371284A (en) * | 1945-03-13 | Preparation of sulphated fatty | ||
US2174760A (en) * | 1934-04-19 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from carboxylic acids and method of producing them |
US2290167A (en) * | 1939-08-14 | 1942-07-21 | Solvay Process Co | Preparation of sulphonation derivatives |
US2634287A (en) * | 1948-04-01 | 1953-04-07 | Monsanto Chemicals | Process for sulfation of aliphatic alcohols |
DE834245C (en) * | 1948-07-17 | 1952-03-17 | Innovations Chimiques Sinnova | Process and device for the continuous sulfonation or esterification of organic compounds using chlorosulfonic acid |
US2665197A (en) * | 1950-08-03 | 1954-01-05 | Rowland Ernest Edward | Polymerization control apparatus |
US2730433A (en) * | 1954-11-02 | 1956-01-10 | Du Pont | Spray mixer |
US2872297A (en) * | 1955-01-11 | 1959-02-03 | Flo Mix Fertilizers Corp | Apparatus for converting liquid anhydrous ammonia to aqua ammonia |
DE1095817B (en) * | 1956-07-17 | 1960-12-29 | Iashellia Res Ltd | Continuous process and device for sulfonating organic liquids that can be sulfonated with sulfur trioxide |
GB791995A (en) * | 1956-07-17 | 1958-03-19 | Shell Res Ltd | Sulphonation of organic liquids |
US2828331A (en) * | 1956-09-26 | 1958-03-25 | Pure Oil Co | Sulfonation of petroleum oils |
US2923728A (en) * | 1957-11-19 | 1960-02-02 | Du Pont | Process of reacting organic compounds with sulfur trioxide |
-
0
- BE BE617968D patent/BE617968A/xx unknown
- NL NL278901D patent/NL278901A/xx unknown
-
1961
- 1961-05-26 GB GB19157/61A patent/GB975914A/en not_active Expired
-
1962
- 1962-05-17 ES ES277408A patent/ES277408A1/en not_active Expired
- 1962-05-18 DE DEC27021A patent/DE1179196B/en active Pending
- 1962-05-23 CH CH623762A patent/CH401031A/en unknown
- 1962-05-24 FR FR898594A patent/FR1330937A/en not_active Expired
- 1962-05-24 US US197508A patent/US3270038A/en not_active Expired - Lifetime
- 1962-05-26 DK DK238262AA patent/DK117825B/en unknown
- 1962-08-22 ES ES280186A patent/ES280186A1/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2155474A (en) * | 1984-03-13 | 1985-09-25 | Procter & Gamble | Process for the continuous reaction of organic compounds with sulfur trioxide |
US5085846A (en) * | 1990-04-12 | 1992-02-04 | Albright & Wilson Limited | Process for producing phosphorous acid |
Also Published As
Publication number | Publication date |
---|---|
DE1179196B (en) | 1964-10-08 |
NL278901A (en) | |
US3270038A (en) | 1966-08-30 |
BE617968A (en) | |
ES277408A1 (en) | 1962-12-01 |
DK117825B (en) | 1970-06-08 |
FR1330937A (en) | 1963-06-28 |
ES280186A1 (en) | 1962-11-16 |
CH401031A (en) | 1965-10-31 |
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