GB975914A - Sulphonation of organic compounds - Google Patents

Sulphonation of organic compounds

Info

Publication number
GB975914A
GB975914A GB19157/61A GB1915761A GB975914A GB 975914 A GB975914 A GB 975914A GB 19157/61 A GB19157/61 A GB 19157/61A GB 1915761 A GB1915761 A GB 1915761A GB 975914 A GB975914 A GB 975914A
Authority
GB
United Kingdom
Prior art keywords
zone
orifice
mixture
sulphonation
lower pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19157/61A
Inventor
Philip Marshall
John Murray Blakeway
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL278901D priority Critical patent/NL278901A/xx
Priority to BE617968D priority patent/BE617968A/xx
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Priority to GB19157/61A priority patent/GB975914A/en
Priority to ES277408A priority patent/ES277408A1/en
Priority to DEC27021A priority patent/DE1179196B/en
Priority to CH623762A priority patent/CH401031A/en
Priority to US197508A priority patent/US3270038A/en
Priority to FR898594A priority patent/FR1330937A/en
Priority to DK238262AA priority patent/DK117825B/en
Priority to ES280186A priority patent/ES280186A1/en
Publication of GB975914A publication Critical patent/GB975914A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

<PICT:0975914/C1/1> A process for sulphonating or sulphating aliphatic alcohols, saturated fatty acids, aliphatic olefins, aryl or alkaryl hydrocarbons, fatty acid alkanolamides, and condensation products of ethylene or propylene oxide with an alkyl phenol, or a fatty acid, alcohol or alkanolamide comprises passing the organic compound as a liquid solution, suspension or slurry and as a free annular jet from a zone of higher pressure through an orifice into a zone of lower pressure, and introducing a gaseous mixture of sulphur trioxide and an inert gas into the centre of said annular jet through a nozzle extending into said zone of lower pressure. Reaction is preferably effected at 0 to 80 DEG C. and with a pressure drop of 5 to 300 p.s.i. Inert gases specified are air, hydrogen, nitrogen, sulphur dioxide, carbon dioxide, or mixtures thereof. As shown in the Figure, a reactor comprises a passage 11 divided by orifice plate 12 into a zone 13 of higher pressure and a zone 14 of lower pressure. Sulphur trioxide mixture is introduced through tube 15 and nozzle 16, and the organic compound is introduced through pipe 18. The orifice 17 is preferably sharp-edged to increase turbulance, this effect being also increased by flow breaker 20 and by the introduction of inert gas into passage 18; flow breaker 20 serves to break up this gas into small bubbles, which expand on passing through the orifice. These flow breakers may comprise helical coils of wire of a metal inert to sulphur trioxide. Reaction product may be recycled through cooler 31. The process and apparatus may be applied to batch-wise or to continuous sulphation or sulphonation. Specific examples relate to the sulphonation of dodecyl benzene and of a mixture of dodecyl benzene and xylene, and to the sulphation of (a) a mixture of lauryl, cetyl and oleyl alcohols and an adduct of ethylene oxide and cetyl and oleyl alcohols, and (b) of an ethylene oxide adduct of tridecyl alcohol.
GB19157/61A 1961-05-26 1961-05-26 Sulphonation of organic compounds Expired GB975914A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
NL278901D NL278901A (en) 1961-05-26
BE617968D BE617968A (en) 1961-05-26
GB19157/61A GB975914A (en) 1961-05-26 1961-05-26 Sulphonation of organic compounds
ES277408A ES277408A1 (en) 1961-05-26 1962-05-17 A procedure to sulfone an organic compound (Machine-translation by Google Translate, not legally binding)
DEC27021A DE1179196B (en) 1961-05-26 1962-05-18 Method and device for sulfonating and sulfating organic compounds
CH623762A CH401031A (en) 1961-05-26 1962-05-23 Process for sulfonating organic compounds and apparatus for carrying out the process
US197508A US3270038A (en) 1961-05-26 1962-05-24 Sulphonation of organic compounds
FR898594A FR1330937A (en) 1961-05-26 1962-05-24 Method and apparatus for the sulfonation of organic compounds
DK238262AA DK117825B (en) 1961-05-26 1962-05-26 Method and apparatus for sulfonating or sulphating an organic compound.
ES280186A ES280186A1 (en) 1961-05-26 1962-08-22 An apparatus for sulfuring an organic compound (Machine-translation by Google Translate, not legally binding)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB19157/61A GB975914A (en) 1961-05-26 1961-05-26 Sulphonation of organic compounds

Publications (1)

Publication Number Publication Date
GB975914A true GB975914A (en) 1964-11-25

Family

ID=10124710

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19157/61A Expired GB975914A (en) 1961-05-26 1961-05-26 Sulphonation of organic compounds

Country Status (9)

Country Link
US (1) US3270038A (en)
BE (1) BE617968A (en)
CH (1) CH401031A (en)
DE (1) DE1179196B (en)
DK (1) DK117825B (en)
ES (2) ES277408A1 (en)
FR (1) FR1330937A (en)
GB (1) GB975914A (en)
NL (1) NL278901A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155474A (en) * 1984-03-13 1985-09-25 Procter & Gamble Process for the continuous reaction of organic compounds with sulfur trioxide
US5085846A (en) * 1990-04-12 1992-02-04 Albright & Wilson Limited Process for producing phosphorous acid

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3412143A (en) * 1965-06-21 1968-11-19 Pillsbury Co Process for the production of amine salts of sulfamic acid
US3535339A (en) * 1965-12-17 1970-10-20 Procter & Gamble Process and apparatus for the continuous reaction of organic compounds with undiluted sulfur trioxide
US3482947A (en) * 1966-07-14 1969-12-09 Procter & Gamble Feed device for a film reactor
GB1223255A (en) * 1967-04-25 1971-02-24 Marchon Products Ltd Sulphation process
BE716903A (en) * 1967-06-26 1968-12-02
US3931273A (en) * 1970-02-23 1976-01-06 Costruzioni Meccaniche G. Mazzoni S.P.A. Method for sulphonatizing and sulphatizing organic compounds with sulphur trioxide and apparatus therefor
GB1434020A (en) * 1972-10-30 1976-04-28 Koebner A Sulphonation of aromatic compounds in the presence of solvents
US4144266A (en) * 1973-07-05 1979-03-13 Marathon Oil Company Sulfonation of crude oils to produce petroleum sulfonates
US4614623A (en) * 1974-01-04 1986-09-30 Marathon Oil Company Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates
US4390474A (en) * 1974-10-16 1983-06-28 Stepan Chemical Company Sulfonation petroleum composition
DE2502254C2 (en) * 1975-01-17 1983-08-04 Marathon Oil Co., 45840 Findlay, Ohio Process for the preparation of petroleum sulfonates containing monovalent cations
GB1563994A (en) * 1975-05-15 1980-04-02 Albright & Wilson Sulph(on)ation process and mixer
US4097242A (en) * 1975-07-21 1978-06-27 Kao Soap Co., Ltd. Sulfonation apparatus
US4002431A (en) * 1975-12-19 1977-01-11 United Technologies Corporation Nitrous oxide decomposition reactor
US4113438A (en) * 1976-05-27 1978-09-12 The Chemithon Corporation Sulfonating apparatus
JPS6045185B2 (en) * 1976-11-17 1985-10-08 丸善石油株式会社 Method for sulfonating aromatic compounds
US4560517A (en) * 1979-03-22 1985-12-24 Marathon Oil Company Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates
JPS6033382B2 (en) * 1979-07-06 1985-08-02 ライオン株式会社 Thin film sulfonation method of alkylbenzene
US4879399A (en) * 1986-01-15 1989-11-07 Sandoz Ltd. Ether sulfates of a mixture of branched 1-decanols
US4980087A (en) * 1986-01-15 1990-12-25 Sandoz Ltd. Ether sulfates of a mixture of branched 1-decanols

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL27274C (en) *
US2371284A (en) * 1945-03-13 Preparation of sulphated fatty
US2174760A (en) * 1934-04-19 1939-10-03 Ig Farbenindustrie Ag Condensation products derived from carboxylic acids and method of producing them
US2290167A (en) * 1939-08-14 1942-07-21 Solvay Process Co Preparation of sulphonation derivatives
US2634287A (en) * 1948-04-01 1953-04-07 Monsanto Chemicals Process for sulfation of aliphatic alcohols
DE834245C (en) * 1948-07-17 1952-03-17 Innovations Chimiques Sinnova Process and device for the continuous sulfonation or esterification of organic compounds using chlorosulfonic acid
US2665197A (en) * 1950-08-03 1954-01-05 Rowland Ernest Edward Polymerization control apparatus
US2730433A (en) * 1954-11-02 1956-01-10 Du Pont Spray mixer
US2872297A (en) * 1955-01-11 1959-02-03 Flo Mix Fertilizers Corp Apparatus for converting liquid anhydrous ammonia to aqua ammonia
DE1095817B (en) * 1956-07-17 1960-12-29 Iashellia Res Ltd Continuous process and device for sulfonating organic liquids that can be sulfonated with sulfur trioxide
GB791995A (en) * 1956-07-17 1958-03-19 Shell Res Ltd Sulphonation of organic liquids
US2828331A (en) * 1956-09-26 1958-03-25 Pure Oil Co Sulfonation of petroleum oils
US2923728A (en) * 1957-11-19 1960-02-02 Du Pont Process of reacting organic compounds with sulfur trioxide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155474A (en) * 1984-03-13 1985-09-25 Procter & Gamble Process for the continuous reaction of organic compounds with sulfur trioxide
US5085846A (en) * 1990-04-12 1992-02-04 Albright & Wilson Limited Process for producing phosphorous acid

Also Published As

Publication number Publication date
DE1179196B (en) 1964-10-08
NL278901A (en)
US3270038A (en) 1966-08-30
BE617968A (en)
ES277408A1 (en) 1962-12-01
DK117825B (en) 1970-06-08
FR1330937A (en) 1963-06-28
ES280186A1 (en) 1962-11-16
CH401031A (en) 1965-10-31

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