GB974038A - Process for the removal of alkynes from hydrocarbon mixtures containing alkadienes - Google Patents
Process for the removal of alkynes from hydrocarbon mixtures containing alkadienesInfo
- Publication number
- GB974038A GB974038A GB3205862A GB3205862A GB974038A GB 974038 A GB974038 A GB 974038A GB 3205862 A GB3205862 A GB 3205862A GB 3205862 A GB3205862 A GB 3205862A GB 974038 A GB974038 A GB 974038A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkynes
- mixtures containing
- removal
- hydrogen
- hydrocarbon mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
- C07C7/167—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The selective hydrogenation of alkynes in a hydrocarbon mixture also containing alkadienes is effected by passing a solution of hydrogen in the mixture in an upflow stream through a fixed bed of palladium catalyst. Ambient temperature up to 60 DEG C. is preferred with a pressure below 25 kg./cm.2 abs. The solution is formed by condensing the hydrocarbons in the presence of hydrogen. Gaseous hydrogen may also be present by addition or by reducing the pressure. The catalyst may contain up to 5% wt. palladium on a macroporous support and may also contain Pt, Ni, Co, Cu, Fe, Al, Zn, Cd, Pb, Bi, Hg, Tl or compounds thereof. Mixtures containing butadiene or isoprene in particular may be treated. Specification 866,395 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3205862A GB974038A (en) | 1962-08-21 | 1962-08-21 | Process for the removal of alkynes from hydrocarbon mixtures containing alkadienes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3205862A GB974038A (en) | 1962-08-21 | 1962-08-21 | Process for the removal of alkynes from hydrocarbon mixtures containing alkadienes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB974038A true GB974038A (en) | 1964-11-04 |
Family
ID=10332526
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3205862A Expired GB974038A (en) | 1962-08-21 | 1962-08-21 | Process for the removal of alkynes from hydrocarbon mixtures containing alkadienes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB974038A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3373219A (en) * | 1965-11-30 | 1968-03-12 | Bayer Ag | Process for the selective hydrogenation of c4-fractions |
-
1962
- 1962-08-21 GB GB3205862A patent/GB974038A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3373219A (en) * | 1965-11-30 | 1968-03-12 | Bayer Ag | Process for the selective hydrogenation of c4-fractions |
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