GB952525A - Thermoplastic compositions and method for their production - Google Patents
Thermoplastic compositions and method for their productionInfo
- Publication number
- GB952525A GB952525A GB3967261A GB3967261A GB952525A GB 952525 A GB952525 A GB 952525A GB 3967261 A GB3967261 A GB 3967261A GB 3967261 A GB3967261 A GB 3967261A GB 952525 A GB952525 A GB 952525A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- components
- copolymer
- prepared
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
A thermoplastic composition of high impact strength is made by blending a copolymer of from 90 to 60% by weight of styrene and from 10 to 40% by weight of acrylonitrile with a substantially inelastic copolymer of from 80 to 55% by weight of butadiene and from 20 to 45% by weight of acrylonitrile in such an amount that the composition contains from 5 to 45% by weight of said inelastic copolymer. The mixing of the two components can be effected by conventional methods, for instance by masticating the separately produced dry components on a calendar or in a Banburry mixer at a suitable temperature e.g. 150 DEG C.; other ingredients such as fillers, dyestuffs and stabilizers may be incorporated. The components may also be prepared in the form of emulsions and blended as latices, the mixture being dried according to conventional methods. The styrene copolymer may be prepared by suspension or bulk polymerisation. Mixtures of the two components may also be prepared by dissolving one of the copolymers in the monomer of the other component and polymerising the mixture. One of the two components may be first emulsion-polymerised, said emulsion may then be added to an emulsion of the monomer of the other component, and the polymerization may then be continued to completion. The butadiene-acrylonitrile copolymer may be prepared in the presence of a mercaptan polymerization modifier and also, if desired, in the presence of a small amount of cross-linking agent e.g. divinyl benzene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DET19257A DE1175432B (en) | 1960-11-11 | 1960-11-11 | Polystyrene molding compounds with improved impact resistance |
Publications (1)
Publication Number | Publication Date |
---|---|
GB952525A true GB952525A (en) | 1964-03-18 |
Family
ID=7549250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3967261A Expired GB952525A (en) | 1960-11-11 | 1961-11-06 | Thermoplastic compositions and method for their production |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1175432B (en) |
GB (1) | GB952525A (en) |
NL (1) | NL271214A (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE840152C (en) * | 1946-10-19 | 1952-05-29 | Us Rubber Co | Compound thermoplastic homogeneous mixture |
US2652384A (en) * | 1949-04-12 | 1953-09-15 | Standard Oil Dev Co | Composition of a premilled butadiene-acrylonitrile copolymer and a nonrubbery thermoplastic synthetic resin |
-
0
- NL NL271214D patent/NL271214A/xx unknown
-
1960
- 1960-11-11 DE DET19257A patent/DE1175432B/en active Pending
-
1961
- 1961-11-06 GB GB3967261A patent/GB952525A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1175432B (en) | 1964-08-06 |
NL271214A (en) |
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