GB912893A - Improvements in and relating to the crystallization of sodium bicarbonate and sodiumsesquicarbonate - Google Patents

Improvements in and relating to the crystallization of sodium bicarbonate and sodiumsesquicarbonate

Info

Publication number
GB912893A
GB912893A GB2438460A GB2438460A GB912893A GB 912893 A GB912893 A GB 912893A GB 2438460 A GB2438460 A GB 2438460A GB 2438460 A GB2438460 A GB 2438460A GB 912893 A GB912893 A GB 912893A
Authority
GB
United Kingdom
Prior art keywords
sodium
ppm
carbon atoms
taurate
sulphonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2438460A
Inventor
William Charles Bauer
Allen Porter Mccue
Kenneth Calder Rule
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Priority to GB2438460A priority Critical patent/GB912893A/en
Publication of GB912893A publication Critical patent/GB912893A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D7/00Carbonates of sodium, potassium or alkali metals in general
    • C01D7/22Purification
    • C01D7/24Crystallisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Investigating Or Analysing Biological Materials (AREA)

Abstract

Sodium bicarbonate or sodium sesquicarbonate is crystallized from an aqueous solution in the presence of 5 to 800 ppm. of an anionic active surface active agent (surfactant), the surfactant being an alkyl benzene or alkyl naphthalene sulphonate in which the alkyl carbon atoms total at least four, an N-organic substituted taurate of formula R1R11NCH2CH2SO3M where R1 is a hydrocarbon radical, M is an alkali metal, and R11 is a fatty acid group of at least 8 carbon atoms, or a primary alcohol sulphate containing at least 8 carbon atoms. For the crystallization of the sesquicarbonate the preferred surfactant concentration is 5-20 ppm., while for the bicarbonate 40-400 ppm. is preferred. A large number of surfactants are exemplified, those in the specific examples being dodecyl benzene sodium sulphonate, butyl naphthalene sodium sulphonate, sodium lauryl sulphate, sodium-N-methyl-N-oleyl taurate, and sodium-N-cyclohexyl-N-palmityl taurate. Specification 30170/48 open to inspection under Section 91.
GB2438460A 1960-07-13 1960-07-13 Improvements in and relating to the crystallization of sodium bicarbonate and sodiumsesquicarbonate Expired GB912893A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2438460A GB912893A (en) 1960-07-13 1960-07-13 Improvements in and relating to the crystallization of sodium bicarbonate and sodiumsesquicarbonate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2438460A GB912893A (en) 1960-07-13 1960-07-13 Improvements in and relating to the crystallization of sodium bicarbonate and sodiumsesquicarbonate

Publications (1)

Publication Number Publication Date
GB912893A true GB912893A (en) 1962-12-12

Family

ID=10210902

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2438460A Expired GB912893A (en) 1960-07-13 1960-07-13 Improvements in and relating to the crystallization of sodium bicarbonate and sodiumsesquicarbonate

Country Status (1)

Country Link
GB (1) GB912893A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10398652B2 (en) 2012-12-21 2019-09-03 Solvay Sa Sodium bicarbonate particles manufactured by atomization
CN113292084A (en) * 2021-05-17 2021-08-24 昆明理工大学 Nano sodium bicarbonate powder and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10398652B2 (en) 2012-12-21 2019-09-03 Solvay Sa Sodium bicarbonate particles manufactured by atomization
CN113292084A (en) * 2021-05-17 2021-08-24 昆明理工大学 Nano sodium bicarbonate powder and preparation method thereof

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