GB903132A - Process for the manufacture of epoxy resins - Google Patents

Process for the manufacture of epoxy resins

Info

Publication number
GB903132A
GB903132A GB3445760A GB3445760A GB903132A GB 903132 A GB903132 A GB 903132A GB 3445760 A GB3445760 A GB 3445760A GB 3445760 A GB3445760 A GB 3445760A GB 903132 A GB903132 A GB 903132A
Authority
GB
United Kingdom
Prior art keywords
glycidol
monoglycidyl ether
reacting
reaction
epoxy resins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3445760A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Licentia Patent Verwaltungs GmbH
Original Assignee
Licentia Patent Verwaltungs GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Licentia Patent Verwaltungs GmbH filed Critical Licentia Patent Verwaltungs GmbH
Publication of GB903132A publication Critical patent/GB903132A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3254Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/30Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)

Abstract

Epoxy resins are made by reacting an orthotitanic acid ester with a monoglycidyl compound containing at least one hydroxyl group, selected from glycidol and its monoethers with di- or polyalcohols, to produce a resin <FORM:0903132/IV(a)/1> in which x is zero or a whole number and R is alkylene, alkyleneoxy, arylene, aryleneoxy or substituted forms of these groups, the resin then being hardened by reacting with an organic amine or an acid anhydride. The examples describe the reaction of tetrabutyl titanate with:-(1) glycidol; (2) glycol monoglycidyl ether and (3) resorcinol monoglycidyl ether, the products being cured by reaction with:- (1) diethylamine and (2) and (3) phthalic anhydride.ALSO:Epoxy containing compounds of the formula <FORM:0903132/IV (b)/1> where x is zero or a whole number and R is alkyleneoxy, or aryleneoxy or substituted forms of these groups, are made by reacting an ortho-titanic acid ester with glycidol or a monoether thereof with a di- or polyalcohol. The examples describe the reaction of tetrabutyl titanate with:-(1) glycidol; (2) glycol monoglycidyl ether and (3) resorcinol monoglycidyl ether.
GB3445760A 1959-10-08 1960-10-07 Process for the manufacture of epoxy resins Expired GB903132A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEL34435A DE1105612B (en) 1959-10-08 1959-10-08 Process for the production of plastics based on polyepoxides

Publications (1)

Publication Number Publication Date
GB903132A true GB903132A (en) 1962-08-09

Family

ID=7266670

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3445760A Expired GB903132A (en) 1959-10-08 1960-10-07 Process for the manufacture of epoxy resins

Country Status (2)

Country Link
DE (1) DE1105612B (en)
GB (1) GB903132A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2353998A (en) * 1999-09-08 2001-03-14 Goodyear Tire & Rubber Titanium and zirconium compounds
CN100375757C (en) * 2005-09-28 2008-03-19 中国航空工业第一集团公司北京航空材料研究院 Organic titanium epoxy resin catalytic ester cyanate system

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE910335C (en) * 1951-05-31 1954-04-29 Albert Ag Chem Werke Method of hardening AEthoxylin resins

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2353998A (en) * 1999-09-08 2001-03-14 Goodyear Tire & Rubber Titanium and zirconium compounds
US6417286B1 (en) * 1999-09-08 2002-07-09 The Goodyear Tire & Rubber Company Titanium and zirconium compounds
GB2353998B (en) * 1999-09-08 2004-03-17 Goodyear Tire & Rubber Titanium and zirconium compounds
US6870064B2 (en) 1999-09-08 2005-03-22 The Goodyear Tire & Rubber Company Titanium and zirconium compounds
CN100375757C (en) * 2005-09-28 2008-03-19 中国航空工业第一集团公司北京航空材料研究院 Organic titanium epoxy resin catalytic ester cyanate system

Also Published As

Publication number Publication date
DE1105612B (en) 1961-04-27

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