GB870060A - Improvements in or relating to the plating of metallic surfaces - Google Patents

Improvements in or relating to the plating of metallic surfaces

Info

Publication number
GB870060A
GB870060A GB24920/57A GB2492057A GB870060A GB 870060 A GB870060 A GB 870060A GB 24920/57 A GB24920/57 A GB 24920/57A GB 2492057 A GB2492057 A GB 2492057A GB 870060 A GB870060 A GB 870060A
Authority
GB
United Kingdom
Prior art keywords
gms
bath
plating
nickel
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24920/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pechiney SA
Original Assignee
Pechiney SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pechiney SA filed Critical Pechiney SA
Publication of GB870060A publication Critical patent/GB870060A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1803Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • C23C18/1824Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
    • C23C18/1837Multistep pretreatment
    • C23C18/1844Multistep pretreatment with use of organic or inorganic compounds other than metals, first
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1803Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • C23C18/1848Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by electrochemical pretreatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/32Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C23C18/34Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
    • C23C18/36Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1803Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • C23C18/1806Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by mechanical pretreatment, e.g. grinding, sanding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S205/00Electrolysis: processes, compositions used therein, and methods of preparing the compositions
    • Y10S205/916Sequential electrolytic and nonelectrolytic, or nonelectrolytic and electrolytic coating from the same bath

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemically Coating (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

Prior to plating a metallic surface is electrolytically oxidized in an aqueous bath containing at least one compound of one or more plating metals to be deposited and a reducing agent, whereafter the surface is chemically or electrolytically plated. Preferably the metallic surface is connected in the electrical circuit before immersion in the bath and oxidation is effected with A.C., D.C., or pulsating D.C. to provide a coating of less than 20m thickness. The oxidation treatment may be employed prior to plating with copper, silver, gold, zinc, cadmium, chromium or nickel, especially on readily oxidizable metals such as aluminium, beryllium, iron, magnesium, titanium, uranium, zirconium or their alloys. The bath may contain simple or complex salts of the metal to be deposited and as reducing agent one or more sulphites, thiosulphites, hyposulphites, arsenites or hypophosphites or lower valency salts of a multivalent metal, e.g. ferrous, titanous, cuprous, or stannous salts, or alcohols, aldehydes, hydrazine or hydroxylamine may be used. The electrolytic oxidation may be effected in the same bath as the subsequent plating or in a similar bath of lower pH. Typically an aluminium base alloy was polished, degreased in trichlorethylene, cathodically degreased in an aqueous solution of sodium phosphate and sodium silicate, neutralized with nitric acid, rinsed, and immersed as anode in an aqueous bath containing per litre 23 gms crystalline nickel sluphate, 24 gms sodium hypophosphite, 27 gms lactic acid, and 20 gms sodium succinate, the pH being adjusted to 4.7 with sulphuric acid or sodium hydroxide, to produce an oxide coating of thickness 0.8m . After switching off, the article remained in the bath at 96-98 DEG C. for 1 hour whereby a nickel layer 22m thick was deposited. An aluminium article after degreasing with trichlorethylene, and chemical brightening in a bath containing phosphoric acid, nitric acid, and copper nitrate at 95 DEG C. followed by rinsing, was anodically oxidized in a nickel hypophosphite bath composed as above at 95 DEG C. but of pH 1. Other pure aluminium articles, after trichlorethylene degreasing, etching in hot caustic soda followed by a neutralizing nitric acid dip and rinsing, were anodically oxidized in aqueous baths containing per litre 23 gms crystallized nickel sulphate, 27 gms lactic acid, 20 gms sodium succinate, and 9 gms formaldehyde or 10 gms pure ethyl alcohol or 56 gms neutral sodium sulphate crystals. Chemical plating of nickel to a thickness of 22m was in each case effected as set out above for the aluminium alloy.
GB24920/57A 1956-08-08 1957-08-07 Improvements in or relating to the plating of metallic surfaces Expired GB870060A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR720113 1956-08-08

Publications (1)

Publication Number Publication Date
GB870060A true GB870060A (en) 1961-06-07

Family

ID=8703533

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24920/57A Expired GB870060A (en) 1956-08-08 1957-08-07 Improvements in or relating to the plating of metallic surfaces

Country Status (6)

Country Link
US (1) US2965551A (en)
BE (1) BE559886A (en)
CH (1) CH363871A (en)
DE (1) DE1125254B (en)
FR (1) FR1157194A (en)
GB (1) GB870060A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5095139A (en) * 1973-12-27 1975-07-29
JPS63140091A (en) * 1986-12-02 1988-06-11 Kobe Steel Ltd Improvement of corrosion resistance in electroless ni-p plating substrate for magnetic disk

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL122179C (en) * 1959-02-06 1966-12-15
US3041259A (en) * 1959-07-31 1962-06-26 Hanson Van Winkle Munning Co Cleaning aluminum surfaces
US3207679A (en) * 1960-05-03 1965-09-21 American Potash & Chem Corp Method for electroplating on titanium
NL280474A (en) * 1961-07-07
US3178311A (en) * 1961-09-25 1965-04-13 Bunker Ramo Electroless plating process
US3380151A (en) * 1962-02-09 1968-04-30 Oakite Prod Inc Fusion-joining coarse-surfaced high carbon ferrous metals to metals
US3219557A (en) * 1962-04-12 1965-11-23 Pacific Scientific Co Method of producing a rotary coupling
US3282809A (en) * 1962-11-07 1966-11-01 Clevite Corp Iron coating for refractory metal
US3350285A (en) * 1963-07-20 1967-10-31 Ngk Insulators Ltd Method of forming rust-proofing and corrosion-resisting coating on metal surfaces
US3454473A (en) * 1963-12-07 1969-07-08 Matsushita Electric Ind Co Ltd Method for the manufacture of titanium anodic oxidation film capacitors having non-electrolytically plated cathode
US3340164A (en) * 1963-12-26 1967-09-05 Sperry Rand Corp Method of copper plating anodized aluminum
US3386896A (en) * 1964-11-05 1968-06-04 Bell Telephone Labor Inc Electroplasting onto molybdenum surfaces
US3393134A (en) * 1965-03-23 1968-07-16 Benno A. Schwartz Jr. Method of chromium plating
US3310430A (en) * 1965-06-30 1967-03-21 Day Company Electroless copper plating
US3493474A (en) * 1966-04-29 1970-02-03 Gen Motors Corp Aluminum plating process
US3515650A (en) * 1966-06-02 1970-06-02 Toyoda Chuo Kenkyusho Kk Method of electroplating nickel on an aluminum article
US3533918A (en) * 1967-04-18 1970-10-13 John C Smith Method of making electrodes for fuel cells
US3620777A (en) * 1968-07-24 1971-11-16 Hooker Chemical Corp Chromate chemical coating solution for zinc alloy
US3489657A (en) * 1968-09-30 1970-01-13 Sylvania Electric Prod Process for producing solderable aluminum materials
US3640854A (en) * 1969-12-10 1972-02-08 Mallory & Co Inc P R Continuous forming of metal oxides
FR2091934A1 (en) * 1970-05-15 1971-01-21 Delarue Ets Treatment of magnesium articles - prior to chrome plating
US3685582A (en) * 1971-01-14 1972-08-22 Shell Oil Co Electroless metal plating techniques for consolidation of incompetent formations
JPS5742715B2 (en) * 1975-03-20 1982-09-10
JPS5278719A (en) * 1975-12-26 1977-07-02 Nippon Kagaku Sangyo Kk Plating method of aluminum and aluminum alloy
US4293617A (en) * 1979-12-26 1981-10-06 Gould Inc. Process for producing strippable copper on an aluminum carrier and the article so obtained
US4325791A (en) * 1981-01-07 1982-04-20 The United States Of America As Represented By The United States Department Of Energy Method for providing uranium articles with a corrosion resistant anodized coating
DE3124522C2 (en) * 1981-06-23 1983-11-24 Dornier System Gmbh, 7990 Friedrichshafen Process for electroless coloring of porous materials
JPS6057519B2 (en) * 1981-08-20 1985-12-16 住友金属工業株式会社 Oil country tubular joint with excellent seizure resistance and its manufacturing method
JPS5838637A (en) * 1981-09-01 1983-03-07 Nippon Steel Corp Repairing method for mold for continuous casting
FR2567913B1 (en) * 1984-07-18 1989-11-10 Commissariat Energie Atomique PROCESS FOR PREPARING THE SURFACE OF URANIUM OR ALLOY URANIUM-BASED PARTS
JPH07116612B2 (en) * 1991-04-18 1995-12-13 株式会社コサク Electroless plating bath composition
JP3052515B2 (en) * 1991-11-28 2000-06-12 上村工業株式会社 Electroless copper plating bath and plating method
IT1319225B1 (en) * 2000-10-19 2003-09-26 Pietro Pedeferri METHOD OF COLORING OF TITANIUM OR ITS ALLOYS BY ANODIC OXIDATION.
CN103898582A (en) * 2013-06-03 2014-07-02 无锡市锡山区鹅湖镇荡口青荡金属制品厂 Pretreatment solution for electroplating chromium on surface of magnesium alloy die casting

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE606850C (en) * 1930-11-07 1934-12-12 Siemens Ag Process for generating firmly adhering galvanic deposits on aluminum and its alloys
US2231086A (en) * 1936-04-23 1941-02-11 Sherka Chemical Co Inc Method of producing oxide coated aluminum and aluminum base alloys and electrolyte therefor
DE656663C (en) * 1936-06-19 1938-02-10 Ver Aluminium Werke Akt Ges Process for the electrolytic coating of aluminum and aluminum alloys with metals
DE671978C (en) * 1937-10-01 1939-02-17 I G Farbenindustrie Akt Ges Process for the electrolytic production of protective coatings on workpieces made of magnesium and its alloys
US2473163A (en) * 1945-06-25 1949-06-14 Ewald H Mccoy Plating nickel on aluminum
US2495941A (en) * 1946-12-18 1950-01-31 Reynolds Metals Co Electroplating copper on aluminum
US2532283A (en) * 1947-05-05 1950-12-05 Brenner Abner Nickel plating by chemical reduction
LU30231A1 (en) * 1949-08-08
FR1016580A (en) * 1950-04-21 1952-11-17 Process of chrome plating aluminum or its alloys
US2658839A (en) * 1951-04-21 1953-11-10 Gen Am Transport Process of chemical nickel plating
FR1078895A (en) * 1952-06-24 1954-11-24 Thomson Houston Comp Francaise Process for electroplating aluminum

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5095139A (en) * 1973-12-27 1975-07-29
JPS63140091A (en) * 1986-12-02 1988-06-11 Kobe Steel Ltd Improvement of corrosion resistance in electroless ni-p plating substrate for magnetic disk
JPH0159359B2 (en) * 1986-12-02 1989-12-15 Kobe Steel Ltd

Also Published As

Publication number Publication date
DE1125254B (en) 1962-03-08
FR1157194A (en) 1958-05-27
US2965551A (en) 1960-12-20
CH363871A (en) 1962-08-15
BE559886A (en)

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