GB861418A - Organic acids and a method of producing same - Google Patents
Organic acids and a method of producing sameInfo
- Publication number
- GB861418A GB861418A GB5763/59A GB576359A GB861418A GB 861418 A GB861418 A GB 861418A GB 5763/59 A GB5763/59 A GB 5763/59A GB 576359 A GB576359 A GB 576359A GB 861418 A GB861418 A GB 861418A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ester
- styrene
- dimethyl
- formula
- organic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of the formula <FORM:0861418/IV (b)/1> and a process for their preparation by condensing b ,b -dimethyl-styrene of the formula <FORM:0861418/IV (b)/2> with a diazo-acetic acid ester N2CHCOOR, where R represents an alkyl group, at an elevated temperature and saponifying the ester so produced. In an example b ,b -dimethyl-styrene is condensed with ethyl diazo-acetate at 125 DEG C. in the presence of anhydrous copper sulphate and the resulting ester saponified in the cold using aqueous alcoholic sodium hydroxide followed by hydrochloric acid. The acid product is a mixture of cis and trans isomers.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5763/59A GB861418A (en) | 1959-02-19 | 1959-02-19 | Organic acids and a method of producing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5763/59A GB861418A (en) | 1959-02-19 | 1959-02-19 | Organic acids and a method of producing same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB861418A true GB861418A (en) | 1961-02-22 |
Family
ID=9802192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5763/59A Expired GB861418A (en) | 1959-02-19 | 1959-02-19 | Organic acids and a method of producing same |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB861418A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3857880A (en) * | 1971-07-20 | 1974-12-31 | Schering Corp | Cyclopropane carboxylic acid derivatives |
-
1959
- 1959-02-19 GB GB5763/59A patent/GB861418A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3857880A (en) * | 1971-07-20 | 1974-12-31 | Schering Corp | Cyclopropane carboxylic acid derivatives |
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