GB836786A - Impregnation of fibrous sheet material with synthetic resins - Google Patents

Impregnation of fibrous sheet material with synthetic resins

Info

Publication number
GB836786A
GB836786A GB2645455A GB2645455A GB836786A GB 836786 A GB836786 A GB 836786A GB 2645455 A GB2645455 A GB 2645455A GB 2645455 A GB2645455 A GB 2645455A GB 836786 A GB836786 A GB 836786A
Authority
GB
United Kingdom
Prior art keywords
acid
monomer
sheet material
temperature
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2645455A
Inventor
Friederich Jakob Hermann
Egide Rossi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
REICHHOLD BECKACITE
Original Assignee
REICHHOLD BECKACITE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by REICHHOLD BECKACITE filed Critical REICHHOLD BECKACITE
Priority to GB2645455A priority Critical patent/GB836786A/en
Publication of GB836786A publication Critical patent/GB836786A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/22Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

A process for the production of impregnated fibrous sheet material, which can be rolled up and stored and can be bonded to like material by the application of heat and pressure, comprises impregnating fibrous sheet material at elevated temperature with a composition which is liquid at the temperature of impregnation but solid at room temperature and which comprises a polyester resin and an unconjugated monomer having a CH2 = C < group and a boiling point of at least 70 DEG C., the monomer being present in a proportion of 4-35% by weight of the total weight of the composition. The polyester resin is derived from at least one alpha-unsaturated alpha-beta-dicarboxylic acid, one or more glycols and at least 10%, preferably at least 15%, by weight, based on the total acid and/or glycol components, of an acid component (a) and/or a glycol component (b) selected from: (a) 1,4,5,6,7,7 - hexachlorobicyclo - (2,2,1) - 5-heptene - 2,3 - dicarboxylic acid, tetrachlorophthalic acid, isophthalic acid and terephthalic acid; (b) <FORM:0836786/IV(c)/1> <FORM:0836786/IV(c)/2> and butane-2,3-diol. The polyester resin may be a mixture of two or more polyesters, but at least one polyester must contain an acid or glycol component selected as above and the other or others may or may not contain such a component, but at least 10%, and preferably at least 15%, by weight of the total acid and/or glycol components must be selected from (a) or (b) above. The preferred unsaturated acids are maleic and fumaric, but halomaleic, halofumaric, itaconic, citraconic and mesaconic acids may be used. Saturated dibasic acids, e.g. succinic, sebacic, phthalic or pimelic, polycarboxylic acids, e.g. citric or aconitic, monocarboxylic acids, e.g. lauric, monohydric alcohols or polyhydric alcohols, e.g. glycerine or pentaerythritol, may be used also. The unconjugated monomer may be styrene, diallyl phthalate or triallyl cyanurate and preferably amounts to 6-25%, advantageously 8-20%, of the composition. The composition may also contain hardening catalysts and/or inhibitors, the catalyst p being one that will cause polymerization only at and above the temperature at which the impregnated fibrous sheet material is to be bonded to like sheet material. The fibrous sheet material may be woven, netted and felted material made from non-metallic or metallic fibres or filaments, e.g. mats or cloths made from glass fibre, cotton, jute, sisal, metal gauze and cloth and wire mesh netting. Fillers may be incorporated. In a modification, impregnation is effected preferably at room temperature with a solution of the resin composition, followed by drying at a temperature of up to 80 DEG C., the solution being in a solvent which is volatile at the drying temperature and which may be another unconjugated monomer having a CH2 = C< group and a boiling point of at least 70 DEG C., or an additional quantity of the same unconjugated monomer in excess of that required in the impregnated sheet, the drying being continued until the solvent or additional monomer has wholly or partly vaporized so that the dried impregnated material contains 3% or less of the solvent or additional monomer. Solvents mentioned in the examples are acetone and vinyl acetate. Specification 746,063 is referred to.ALSO:A process for the production of impregnated fibrous sheet material, which can be rolled up and stored and can be bonded to like material by the application of heat and pressure, comprises impregnating fibrous sheet material at elevated temperature with a composition which is liquid at the temperature of impregnation but solid at room temperature and which comprises a polyester resin and an unconjugated monomer having a CH2=C< group and a boiling-point of at least 70 DEG C., the monomer being present in a proportion of 4-35% by weight of the total weight of the composition. The polyester resin is derived from at least one alpha - unsaturated alpha - beta - dicarboxylic acid, one or more glycols and at least 10%, preferably at least 15%, by weight based on the total acid and/or glycol components of an acid component (a) and/or glycol component (b) selected from: (a) 1,4,5,6,7,7-hexachlorobicyclo - (2,2,1) - 5 - heptene - 2,3 - dicarboxylic acid, tetrachlorophthalic acid, isophthalic acid and terephthalic acid: (b) <FORM:0836786/IV (a)/1> and butan-2,3-diol. The polyester resin may be a mixture of two or more polyesters. but at least one polyester must contain an acid or glycol component selected as above and the other or others may or may not contain such a component, but at least 10% and preferably at least 15% by weight of the total acid and/or glycol components must be selected from (a) or (b) above. The preferred unsaturated acids are maleic and fumaric, but halomaleic, halofumaric, itaconic, citraconic and mesaconic acids may be used. Saturated dibasic acids, e.g. succinic, sebacic, phthalic or pimelic, polycarboxylic acids, e.g. citric or aconitic, monocarboxylic acids, e.g. lauric, monohydric alcohols or polyhydric alcohols, e.g. glycerine or pentacrythritol may be used also. The unconjugated monomer may be styrene, diallyl phthalate or triallyl cyanurate and preferably amounts to 6-25%, advantageously 8-20% of the composition. The composition may also contain hardening catalysts and/or inhibitors, the catalyst being one that will cause polymerization only at and above the temperature at which the impregnated fibrous sheet material is to be bonded to like sheet material. Fillers may be incorporated. In a modification, impregnation is effected preferably at room temperature with a solution of the resin composition, followed by drying at a temperature of up to 80 DEG C., the solution being in a solvent which is volatile at the drying temperature and which may be another unconjugated monomer having a CH2=C< group and a boiling point of at least 70 DEG C., or an additional quantity of the same unconjugated monomer in excess of that required in the impregnated sheet, the drying being continued until the solvent or additional monomer has wholly or partly vaporized so that the dried impregnated material contains 3% or less of the solvent or additional monomer. Solvents mentioned in the examples are acetone and vinyl acetate. Specification 746,063 is referred to.
GB2645455A 1955-09-15 1955-09-15 Impregnation of fibrous sheet material with synthetic resins Expired GB836786A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2645455A GB836786A (en) 1955-09-15 1955-09-15 Impregnation of fibrous sheet material with synthetic resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2645455A GB836786A (en) 1955-09-15 1955-09-15 Impregnation of fibrous sheet material with synthetic resins

Publications (1)

Publication Number Publication Date
GB836786A true GB836786A (en) 1960-06-09

Family

ID=10243875

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2645455A Expired GB836786A (en) 1955-09-15 1955-09-15 Impregnation of fibrous sheet material with synthetic resins

Country Status (1)

Country Link
GB (1) GB836786A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2215746A (en) * 1988-02-05 1989-09-27 Hardman D Covering sheet material
CN115958841A (en) * 2022-12-28 2023-04-14 宜兴威尼特集装袋有限公司 Preparation process of laminating valve port bag

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2215746A (en) * 1988-02-05 1989-09-27 Hardman D Covering sheet material
GB2215746B (en) * 1988-02-05 1992-06-10 Hardman D Covering sheet material
CN115958841A (en) * 2022-12-28 2023-04-14 宜兴威尼特集装袋有限公司 Preparation process of laminating valve port bag
CN115958841B (en) * 2022-12-28 2023-10-20 宜兴威尼特集装袋有限公司 Preparation process of laminated valve pocket

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