GB828791A - Method of selectively polymerising alpha-olefins - Google Patents
Method of selectively polymerising alpha-olefinsInfo
- Publication number
- GB828791A GB828791A GB34154/55A GB3415455A GB828791A GB 828791 A GB828791 A GB 828791A GB 34154/55 A GB34154/55 A GB 34154/55A GB 3415455 A GB3415455 A GB 3415455A GB 828791 A GB828791 A GB 828791A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solid
- catalyst
- metal
- alet3
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A catalyst used in the polymerization of olefins and consisting of a compound of a Group IVa, Va or VIa metal "in contact with" (defined in the Specification) metal alkyl groups containing Al or a Group II metal, is obtained in the solid or non-solid form either by the choice of components or by the separation (filtration, decantation, &c.) of a catalyst containing solid and non-solid forms. The solid form is meant to be the materials which are not capable of micellar dispersion in the medium used, whereas by non-solid is meant a material which dissolves or disperses. The Specification describes the production of catalysts from halides, oxyhalides, hydroxides, alkoxyhalides and alkoxides of Ti, Zr, V, Cr and W in conjunction with organo aluminium compounds and it is said that complexes are formed, although in the case of solids this may be on the surface only. Reference has been directed by the Comptroller to Specification 810,023.ALSO:a -Olefins of at least 3 carbon atoms are polymerized to linear, head-to-tail polymers by the use as catalyst of a compound of a Group IVa, Va or VIa metal "in contact with" (defined in the Specification) metal alkyl groups containing Al or a Group II metal, and characterized in that the polymerization is selectively regulated towards an increased crystallizable (isotactic) or non-crystalline (atactic) content by the use of catalyst in either the substantially solid or substantially non-solid form, the appropriate form resulting from the choice of components and conditions of formation, or from an intermediate step of preparing catalyst having solid and non-solid forms, wherein separation may then be effected by filtration, decantation, sedimentation, centrifuging or flotation. The non-solid form of catalyst includes materials in the state where they are dissolved or dispersed in the reaction medium used, while the solid form includes materials not capable of micellar dispersion. The Specification describes the production of catalysts from halides, oxyhalides, hydroxides, alkoxyhalides and alkoxides of the metals Ti, Zr, V, Cr and W in conjunction with organo aluminium compounds and it is suggested that complexes are formed although in the case of solid catalysts this may be only at the surface of the heavy metal compound. The monomers, solvents, reactions and fractionation of products may be as disclosed in Specification 810,023. When the alkyl groups of the metal alkyl contain up to 4 C atoms the production of crystallizable polymers may be favoured, whereas the use of lyophilic groups (e.g. alkoxy, hydroxy, C5 to C16 alkyl) in the catalyst components favours the non-crystalline polymer. In examples polymers of high crystallinity are obtained from propylene, butene and styrene by the use of catalysts derived from TiCl2 + AlEt3, and TiCl3 with AlEt3, AlPr3, AlBu3 or AlEt2Cl. Products of low crystallinity are obtained from TiCl4 with Al(C4H9)3, Al(C6H13)3, Al(C16H33)3 or Al(C12H25)2Cl; AlEt3 with Ti butylates or propylates; AlEt3 with Ti(OH)4, TiI3, CrOCl2, WCl6 or VCl4; VOCl3 + Al (C6H33)3; and Al(C10H21)3 with CrCl3, ZrCl4 or VCl4. The use as catalysts of filtered products and filtrates from AlEt3 + TiCl4 or VCl4 is also described. The examples also disclose the addition of catalyst components during polymerization, and the use of materials such as methanol, ether, benzene, toluene, and hydrochloric acid in the purification of the products. Reference has been directed by the Comptroller to Specification 810,023.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT52610154 | 1954-12-03 | ||
IT1647954 | 1954-12-16 | ||
IT1057155 | 1955-07-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB828791A true GB828791A (en) | 1960-02-24 |
Family
ID=27272769
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB34154/55A Expired GB828791A (en) | 1954-12-03 | 1955-11-29 | Method of selectively polymerising alpha-olefins |
GB21373/56A Expired GB836814A (en) | 1954-12-03 | 1956-07-10 | Process for the preparation of linear, high polymers of ª‡-olefins |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21373/56A Expired GB836814A (en) | 1954-12-03 | 1956-07-10 | Process for the preparation of linear, high polymers of ª‡-olefins |
Country Status (10)
Country | Link |
---|---|
BE (2) | BE549638A (en) |
CH (2) | CH365879A (en) |
CY (1) | CY219A (en) |
DE (1) | DE1520237A1 (en) |
FR (2) | FR1139806A (en) |
GB (2) | GB828791A (en) |
IT (1) | IT526101A (en) |
LU (1) | LU33991A1 (en) |
MY (1) | MY6100061A (en) |
NL (2) | NL111136C (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0032734A1 (en) * | 1980-01-18 | 1981-07-29 | Montedison S.p.A. | Components of catalysts for polymerizing alpha-olefins and catalysts prepared therefrom |
US4309522A (en) | 1979-07-25 | 1982-01-05 | Chemische Werke Huels, Aktiengesellschaft | Process for the production of extensively amorphous butene-1-propene-ethene terpolymers having a high softening point |
US6743869B2 (en) | 1997-07-15 | 2004-06-01 | Phillips Petroleum Company | High polymer solids slurry polymerization employing 1-olefin comonomer |
WO2008077204A2 (en) * | 2006-12-22 | 2008-07-03 | Dominique Bosteels | Catalytic combustion process with rejuvenation step |
US7482303B2 (en) | 2001-10-10 | 2009-01-27 | Dominique Bosteels | Catalytic burning reaction |
US7723257B2 (en) | 2001-10-10 | 2010-05-25 | Dominique Bosteels | Process for the catalytic control of radial reaction |
US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3141872A (en) * | 1954-12-03 | 1964-07-21 | Montedison Spa | Polymerization catalyst and stereospecific polymerization of propylene therewith |
US4076698A (en) * | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
US2893984A (en) * | 1956-04-02 | 1959-07-07 | Exxon Research Engineering Co | Polymerization of alpha olefins |
US3009905A (en) * | 1956-06-11 | 1961-11-21 | Ici Ltd | Production of polymers |
DE1209296B (en) * | 1956-10-17 | 1966-01-20 | Ethyl Corp | Process for the polymerisation or mixed polymerisation of olefinically unsaturated hydrocarbons with at least three carbon atoms |
NL220937A (en) * | 1956-10-29 | |||
US2948711A (en) * | 1956-11-27 | 1960-08-09 | Sun Oil Co | Preparation of polyolefins |
US2935495A (en) * | 1956-11-27 | 1960-05-03 | Sun Oil Co | Manufacture of polyolefins |
US3107236A (en) * | 1956-12-17 | 1963-10-15 | Sun Oil Co | Preparation of polypropylene |
GB877050A (en) * | 1958-06-16 | 1961-09-13 | Ici Ltd | Improvements in and relating to the polymerisation of olefines, catalysts for such polymerisation, crystalline materials suitable as components of the catalysts and processes for their preparation |
BE554685A (en) * | 1957-02-02 | |||
GB860647A (en) * | 1957-03-04 | 1961-02-08 | Exxon Research Engineering Co | Method for preparing titanium trichloride containing polymerization catalyst and polymerization process |
NL227164A (en) * | 1957-04-27 | |||
US2976252A (en) * | 1957-05-10 | 1961-03-21 | Exxon Research Engineering Co | Temperature-staged catalyst pretreatment |
NL124337C (en) * | 1957-05-28 | |||
NL283121A (en) * | 1957-07-16 | |||
US2918457A (en) * | 1957-09-26 | 1959-12-22 | Sun Oil Co | Copolymer of propylene and butene-1 |
BE572163A (en) * | 1957-10-19 | |||
BE571954A (en) * | 1957-10-21 | |||
BE572307A (en) * | 1957-10-23 | |||
NL104123B (en) * | 1957-10-25 | |||
DE1128662B (en) * | 1957-11-09 | 1962-04-26 | Ruhrchemie Ag | Process for the production of polyolefins |
BE573749A (en) * | 1957-12-11 | |||
NL113090C (en) * | 1958-02-03 | |||
DE1240285B (en) * | 1958-02-06 | 1967-05-11 | Hibernia Ag | Process for the production of high molecular weight and highly crystalline polymers from olefins with 3 or more carbon atoms |
BE576919A (en) * | 1958-03-21 | |||
DE1117308B (en) * | 1958-03-31 | 1961-11-16 | Eastman Kodak Co | Process for the preparation of polyolefins containing aryl or alicyclic radicals |
BE578139A (en) * | 1958-05-05 | |||
NL134019C (en) * | 1958-06-27 | |||
DE1135661B (en) * | 1958-08-02 | 1962-08-30 | Huels Chemische Werke Ag | Process for processing low-pressure polypropylene |
US3082197A (en) * | 1958-12-01 | 1963-03-19 | Phillips Petroleum Co | Polymerization of conjugated diolefins in the presence of transition metal borohydrides |
BE585154A (en) * | 1958-12-06 | |||
IT599950A (en) * | 1958-12-12 | |||
DE1105618B (en) * | 1959-01-26 | 1961-04-27 | Huels Chemische Werke Ag | Process for the production of isotactic polystyrenes |
US3244678A (en) * | 1959-01-27 | 1966-04-05 | Du Pont | Process for copolymerizing a straight chain alpha olefin with a conjugated diene |
US2965692A (en) * | 1959-04-06 | 1960-12-20 | Sun Oil Co | Preparation of viscous polymers |
IT609922A (en) * | 1959-06-06 | |||
BE591405A (en) * | 1959-06-12 | |||
DE1183245B (en) * | 1959-06-24 | 1964-12-10 | Huels Chemische Werke Ag | Process for the production of polyolefins with a uniform degree of polymerization |
DE1164666B (en) * | 1959-06-29 | 1964-03-05 | Grace W R & Co | Process for the production of high molecular weight polypropylene |
US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
US3067189A (en) * | 1959-12-24 | 1962-12-04 | Shell Oil Co | Diene polymerization catalyst |
DE1201996B (en) * | 1960-05-18 | 1965-09-30 | Grace W R & Co | Process for the polymerization or copolymerization of monoolefins, diolefins or styrene |
US3100218A (en) * | 1961-07-20 | 1963-08-06 | Monsanto Chemicals | Purification of diethylaluminum chloride with crystalline titanium trichloride |
US3324094A (en) * | 1962-11-08 | 1967-06-06 | Mitsubishi Petrochemical Co | Process for the manufacture of polymers and copolymers of isobutylene |
US3226336A (en) * | 1963-05-08 | 1965-12-28 | Rexall Drug Chemical | Composition and process for preparing a three-component polymerization system |
-
0
- NL NL202552D patent/NL202552A/xx unknown
- LU LU33991D patent/LU33991A1/xx unknown
- NL NL111136D patent/NL111136C/xx active
- BE BE543259D patent/BE543259A/xx unknown
- IT IT526101D patent/IT526101A/it unknown
- BE BE549638D patent/BE549638A/xx unknown
-
1955
- 1955-11-19 CH CH536961A patent/CH365879A/en unknown
- 1955-11-19 CH CH2680655A patent/CH365222A/en unknown
- 1955-11-29 GB GB34154/55A patent/GB828791A/en not_active Expired
- 1955-11-30 FR FR1139806D patent/FR1139806A/en not_active Expired
-
1956
- 1956-07-10 GB GB21373/56A patent/GB836814A/en not_active Expired
- 1956-07-13 FR FR70731D patent/FR70731E/en not_active Expired
-
1960
- 1960-09-21 DE DE19601520237 patent/DE1520237A1/en active Pending
-
1961
- 1961-04-13 CY CY21961A patent/CY219A/en unknown
- 1961-12-31 MY MY196161A patent/MY6100061A/en unknown
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4309522A (en) | 1979-07-25 | 1982-01-05 | Chemische Werke Huels, Aktiengesellschaft | Process for the production of extensively amorphous butene-1-propene-ethene terpolymers having a high softening point |
EP0032734A1 (en) * | 1980-01-18 | 1981-07-29 | Montedison S.p.A. | Components of catalysts for polymerizing alpha-olefins and catalysts prepared therefrom |
US6743869B2 (en) | 1997-07-15 | 2004-06-01 | Phillips Petroleum Company | High polymer solids slurry polymerization employing 1-olefin comonomer |
US6806324B2 (en) | 1997-07-15 | 2004-10-19 | Phillips Petroleum Company | High solids slurry polymerization using heat exchange to condense the flashed diluent |
US7482303B2 (en) | 2001-10-10 | 2009-01-27 | Dominique Bosteels | Catalytic burning reaction |
US7723257B2 (en) | 2001-10-10 | 2010-05-25 | Dominique Bosteels | Process for the catalytic control of radial reaction |
WO2008077204A2 (en) * | 2006-12-22 | 2008-07-03 | Dominique Bosteels | Catalytic combustion process with rejuvenation step |
WO2008077204A3 (en) * | 2006-12-22 | 2008-10-30 | Dominique Bosteels | Catalytic combustion process with rejuvenation step |
US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
Also Published As
Publication number | Publication date |
---|---|
MY6100061A (en) | 1961-12-31 |
LU33991A1 (en) | |
FR70731E (en) | 1959-07-10 |
FR1139806A (en) | 1957-07-05 |
CH365879A (en) | 1962-11-30 |
NL202552A (en) | |
BE549638A (en) | |
DE1520237A1 (en) | 1969-03-27 |
CH365222A (en) | 1962-10-31 |
BE543259A (en) | |
NL111136C (en) | |
IT526101A (en) | |
CY219A (en) | 1961-04-13 |
GB836814A (en) | 1960-06-09 |
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