GB818031A - Improvements in and relating to membranes of selective permeability - Google Patents

Improvements in and relating to membranes of selective permeability

Info

Publication number
GB818031A
GB818031A GB3228554A GB3228554A GB818031A GB 818031 A GB818031 A GB 818031A GB 3228554 A GB3228554 A GB 3228554A GB 3228554 A GB3228554 A GB 3228554A GB 818031 A GB818031 A GB 818031A
Authority
GB
United Kingdom
Prior art keywords
ion
exchange resin
group
emulsion
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3228554A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB818031A publication Critical patent/GB818031A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Ion-permeable membranes are made by dispersing an ion-exchange resin in an aqueous emulsion of a beinding agent having an electric charge opposite to that carried by the ion-exchange resin, a surface active agent being incorporated in the dispersion to prevent the ion-exchange resin causing the premature coagulation of the emulsion, and then coagulating the emulsion. The binding agent may be natural or synthetic rubber, polyvinyl chloride or a polyvinyl ester and the ion-exchange resin may be a sulphonated cross-linked polystyrene, or cross-linked polystyrene into which quaternary ammonium groups have been introduced. The surface active agent may be the disodium, salt of methylene dinaphthalenesulphonic acid, a condensation product of a fatty alcohol and ethylene oxide, or cetyltrimethylammonium bromide. Coagulation may be effected and a membrane prepared by coating the mixture on a glass plate and drying at 90 DEG C. for 30 minutes, the membrane being thereafter removed from the glass plate by soaking in water. Specifications 450,309, 489,437, 498,251, [both in Group IV], 556,622, 577,707, [Group IV], 654,706, [Group IV (a)], 662,314, [670,348, 679,850, 679,851, 679,852, 679,853, 683,399, 683,400, 694,778, [all in Group IV (a)], 719,315 and 721,161 are referred to.ALSO:Ion-permeable membranes are made by dispersing an ion-exchange resin in an aqueous emulsion of a binding-agent having an electric charge opposite to that carried by the ion-exchange resin, a surface-active agent being incorporated in the dispersion to prevent the ion-exchange resin causing the premature coagulation of the emulsion, and then coagulating the emulsion. The binding agent may be natural or synthetic rubber, polyvinyl chloride or a polyvinyl ester and the ion-exchange resin may be a sulphonated cross-linked polystyrene, or cross-linked polystyrene into which quaternary ammonium groups have been introduced. The surface-active agent may be the disodium salt of methylene dinaphthalenesulphonic acid, a condensation product of a fatty alcohol and ethylene oxide, or cetyltrimethylammonium bromide. Coagulation may be effected and a membrane prepared by coating the mixture on a glass plate and drying at 90 DEG C. for 30 minutes, the membrane being thereafter removed from the glass plate by soaking in water. Specifications 450,309, 489,437, 498,251, 556,622, 577,707, [all in Group IV], 654,706, 662,314, [Group III], 670,348, 679,850, 679,851, 679,852, 679,853, 683,399, 683,400, 694,778, 719,315 and 721,161 are referred to.
GB3228554A 1954-11-08 Improvements in and relating to membranes of selective permeability Expired GB818031A (en)

Publications (1)

Publication Number Publication Date
GB818031A true GB818031A (en) 1959-08-12

Family

ID=1742939

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3228554A Expired GB818031A (en) 1954-11-08 Improvements in and relating to membranes of selective permeability

Country Status (1)

Country Link
GB (1) GB818031A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2509738A1 (en) * 1981-07-20 1983-01-21 Dorr Oliver Inc SOLID POLYMER ELECTROLYTE MEMBER AND PROCESS FOR PRODUCING THE SAME
FR2554824A1 (en) * 1983-11-11 1985-05-17 Nippon Light Metal Co PREPARATIONS FOR FORMATION OF A HYDROPHILIC FILM, PROCESS FOR THEIR IMPLEMENTATION AND ARTICLES THUS COATED
CN115850756A (en) * 2022-12-14 2023-03-28 西安交通大学 Preparation method of hydrogen bond-based acidic ion gel film, gas sensor and preparation method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2509738A1 (en) * 1981-07-20 1983-01-21 Dorr Oliver Inc SOLID POLYMER ELECTROLYTE MEMBER AND PROCESS FOR PRODUCING THE SAME
FR2554824A1 (en) * 1983-11-11 1985-05-17 Nippon Light Metal Co PREPARATIONS FOR FORMATION OF A HYDROPHILIC FILM, PROCESS FOR THEIR IMPLEMENTATION AND ARTICLES THUS COATED
GB2151641A (en) * 1983-11-11 1985-07-24 Nippon Light Metal Co Hydrophilic film-forming coating compositions
CN115850756A (en) * 2022-12-14 2023-03-28 西安交通大学 Preparation method of hydrogen bond-based acidic ion gel film, gas sensor and preparation method

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