GB810642A - A process for the preparation of esters of acylphosphorous acids - Google Patents
A process for the preparation of esters of acylphosphorous acidsInfo
- Publication number
- GB810642A GB810642A GB14121/57A GB1412157A GB810642A GB 810642 A GB810642 A GB 810642A GB 14121/57 A GB14121/57 A GB 14121/57A GB 1412157 A GB1412157 A GB 1412157A GB 810642 A GB810642 A GB 810642A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- acid
- give
- chloride
- phosphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 9
- 150000007513 acids Chemical class 0.000 title abstract 5
- 150000002148 esters Chemical class 0.000 title abstract 3
- -1 carboxylic acid halide Chemical class 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 abstract 3
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 abstract 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- NQGIJDNPUZEBRU-UHFFFAOYSA-N dodecanoyl chloride Chemical compound CCCCCCCCCCCC(Cl)=O NQGIJDNPUZEBRU-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- WFSGQBNCVASPMW-UHFFFAOYSA-N 2-ethylhexanoyl chloride Chemical compound CCCCC(CC)C(Cl)=O WFSGQBNCVASPMW-UHFFFAOYSA-N 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- WQCRMVOOMCEJJY-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)P(O)(O)O Chemical compound C(CCCCCCCCCCC)(=O)P(O)(O)O WQCRMVOOMCEJJY-UHFFFAOYSA-N 0.000 abstract 1
- GEQZNVRUHDONAP-UHFFFAOYSA-N CCCCC(CC)C(P(O)(O)OCC)=O Chemical compound CCCCC(CC)C(P(O)(O)OCC)=O GEQZNVRUHDONAP-UHFFFAOYSA-N 0.000 abstract 1
- UJAPIHXXMFVWEE-UHFFFAOYSA-N CCCCC(CC)COP(C(C(CC)CCCC)=O)(O)O Chemical compound CCCCC(CC)COP(C(C(CC)CCCC)=O)(O)O UJAPIHXXMFVWEE-UHFFFAOYSA-N 0.000 abstract 1
- TZROXHVFGCUOES-UHFFFAOYSA-N CCCCCCCCCCCC(P(O)(O)OCCCC)=O Chemical compound CCCCCCCCCCCC(P(O)(O)OCCCC)=O TZROXHVFGCUOES-UHFFFAOYSA-N 0.000 abstract 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- PWAXUOGZOSVGBO-UHFFFAOYSA-N adipoyl chloride Chemical compound ClC(=O)CCCCC(Cl)=O PWAXUOGZOSVGBO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 abstract 1
- GGCXLVWDCPTFMN-UHFFFAOYSA-N bis(2-chloroethyl) hydrogen phosphite Chemical compound ClCCOP(O)OCCCl GGCXLVWDCPTFMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical class OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 abstract 1
- IPIVAXLHTVNRBS-UHFFFAOYSA-N decanoyl chloride Chemical compound CCCCCCCCCC(Cl)=O IPIVAXLHTVNRBS-UHFFFAOYSA-N 0.000 abstract 1
- BVXOPEOQUQWRHQ-UHFFFAOYSA-N dibutyl phosphite Chemical compound CCCCOP([O-])OCCCC BVXOPEOQUQWRHQ-UHFFFAOYSA-N 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- FPIQZBQZKBKLEI-UHFFFAOYSA-N ethyl 1-[[2-chloroethyl(nitroso)carbamoyl]amino]cyclohexane-1-carboxylate Chemical compound ClCCN(N=O)C(=O)NC1(C(=O)OCC)CCCCC1 FPIQZBQZKBKLEI-UHFFFAOYSA-N 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000003977 halocarboxylic acids Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 238000009884 interesterification Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000005292 vacuum distillation Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4062—Esters of acids containing the structure -C(=X)-P(=X)(XR)2 or NC-P(=X)(XR)2, (X = O, S, Se)
- C07F9/4065—Esters of acids containing the structure -C(=X)-P(=X)(XR)2, (X = O, S, Se)
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH26995A DE1010965B (de) | 1956-05-08 | 1956-05-08 | Verfahren zur Herstellung von sauren Estern der Acylphosphonsaeuren bzw. ihrer Salze |
Publications (1)
Publication Number | Publication Date |
---|---|
GB810642A true GB810642A (en) | 1959-03-18 |
Family
ID=7150451
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14121/57A Expired GB810642A (en) | 1956-05-08 | 1957-05-03 | A process for the preparation of esters of acylphosphorous acids |
Country Status (3)
Country | Link |
---|---|
US (1) | US2900408A (de) |
DE (1) | DE1010965B (de) |
GB (1) | GB810642A (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4774262A (en) * | 1980-04-21 | 1988-09-27 | Minemet Recherche | Application of diphosphonic derivatives to cation exchange, new diphosphonic derivatives, and production process therefor |
US5407969A (en) * | 1990-10-19 | 1995-04-18 | Kleiner; Hans-Jerg | Acyl-(2'-hydroxybiphenyl-2-yl)-phosphinic acid salts, their preparation and use |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3118876A (en) * | 1958-07-26 | 1964-01-21 | Takeda Pharmaceutical | Process for preparing glycoside phosphates |
NL121615C (de) * | 1958-09-06 | 1900-01-01 | ||
US3012054A (en) * | 1960-03-18 | 1961-12-05 | Dow Chemical Co | Tetraalkyl esters of diphosphonates |
NL132418C (de) * | 1962-04-13 | |||
US3324202A (en) * | 1963-07-09 | 1967-06-06 | Fmc Corp | Phosphorus-containing polyols |
US3382060A (en) * | 1964-11-18 | 1968-05-07 | Chemagro Corp | Dialkyl and diphenyl esters of aryloxyacetyl-phosphonic acid as herbicides |
US3400148A (en) * | 1965-09-23 | 1968-09-03 | Procter & Gamble | Phosphonate compounds |
US3676532A (en) * | 1969-11-21 | 1972-07-11 | Olin Corp | Alpha-(dialkoxyphosphinyl)aryl methyl dialkyl phosphates |
US3944599A (en) * | 1970-04-13 | 1976-03-16 | Monsanto Company | Substituted ethane diphosphonic acids and salts |
US3957858A (en) * | 1970-04-13 | 1976-05-18 | Monsanto Company | Substituted ethane diphosphonic acids and salts and esters thereof |
US3940436A (en) * | 1970-04-13 | 1976-02-24 | Monsanto Company | Substituted ethane diphosphonic acids and salts and esters thereof |
US3899496A (en) * | 1970-10-06 | 1975-08-12 | Henkel & Cie Gmbh | Production of 1-aminoalkane-1,1-diphosphonic acids |
DE2965566D1 (en) * | 1978-07-14 | 1983-07-07 | Basf Ag | Acylphosphinoxide compounds, their preparation and their use |
US4339443A (en) * | 1978-09-22 | 1982-07-13 | Fbc Limited | Compounds and compositions |
DE3039998A1 (de) * | 1980-10-23 | 1982-06-03 | Bayer Ag, 5090 Leverkusen | Phosphonoformaldehyd, ein verfahren zu seiner herstellung und seine verwendung als zwischenprodukt fuer die herstellung von arzneimittel |
US5017306A (en) * | 1988-11-09 | 1991-05-21 | W. R. Grace & Co.-Conn. | Corrosion inhibitor |
US5266722A (en) * | 1988-11-09 | 1993-11-30 | W. R. Grace & Co.-Conn. | Polyether bis-phosphonic acid compounds |
US4981648A (en) * | 1988-11-09 | 1991-01-01 | W. R. Grace & Co.-Conn. | Inhibiting corrosion in aqueous systems |
US4911887A (en) * | 1988-11-09 | 1990-03-27 | W. R. Grace & Co.-Conn. | Phosphonic acid compounds and the preparation and use thereof |
IL91362A0 (en) * | 1989-08-20 | 1990-03-19 | Yissum Res Dev Co | Bisphosphonates,process for preparing them and pharmaceutical compositions containing them |
US5196409A (en) * | 1989-08-20 | 1993-03-23 | Yissum, Research Development Company Of The Hebrew University Of Jerusalem | Bisphosphonates, pharmaceutical compositions, and process for the treatment of irregularities in calcium metabolism |
DE4240964A1 (de) * | 1992-12-05 | 1994-06-09 | Basf Ag | Arenbisphosphinoxide |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2491920A (en) * | 1946-05-16 | 1949-12-20 | Du Pont | Diesters of 1-ketophosphonic acids |
US2629731A (en) * | 1951-03-07 | 1953-02-24 | Shell Dev | Esters of phosphonoformic acids and polyhydric alcohols |
US2719167A (en) * | 1953-04-13 | 1955-09-27 | Ciba Ltd | Compounds containing phosphorus and process therefor |
-
1956
- 1956-05-08 DE DEH26995A patent/DE1010965B/de active Pending
-
1957
- 1957-05-03 GB GB14121/57A patent/GB810642A/en not_active Expired
- 1957-05-07 US US657496A patent/US2900408A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4774262A (en) * | 1980-04-21 | 1988-09-27 | Minemet Recherche | Application of diphosphonic derivatives to cation exchange, new diphosphonic derivatives, and production process therefor |
US5156824A (en) * | 1980-04-21 | 1992-10-20 | Compagnie Francaise De Mokta | Application of diphosphonic derivatives to cation exchange, new diphosphonic derivatives and production process therefor |
US5407969A (en) * | 1990-10-19 | 1995-04-18 | Kleiner; Hans-Jerg | Acyl-(2'-hydroxybiphenyl-2-yl)-phosphinic acid salts, their preparation and use |
Also Published As
Publication number | Publication date |
---|---|
US2900408A (en) | 1959-08-18 |
DE1010965B (de) | 1957-06-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB810642A (en) | A process for the preparation of esters of acylphosphorous acids | |
US2426224A (en) | Processes for producing dibasic acids and derivatives of dibasic acids | |
JPS6234787B2 (de) | ||
US3787486A (en) | Preparation of haloethane phosphonic acids | |
GB917952A (en) | Production of ester type anionic surface active agents | |
GB772206A (en) | Improvements in and relating to cellular compositions | |
US2934556A (en) | Boron compounds and methods of preparation | |
US2535173A (en) | 3-phosphonopropane-1, 1-dicarboxylic acid esters and method of preparation | |
US2376067A (en) | Unsaturated carboxylic acids | |
US4007229A (en) | Preparation of hydroxyalkyl phosphine oxides and sulfides | |
US2718524A (en) | Production of tetraesters of pyrophosphoric acid | |
US2959609A (en) | Process for preparing vinyl-phosphonic-acid-bis-(beta-chlorethyl)-ester | |
US3373231A (en) | Monoesters of phosphonic acids | |
US3875196A (en) | Process for preparing phosphoric acid esters of fatty acid mono- or di-glycerides | |
GB728997A (en) | Process for the esterification of dicarboxylic acids of high boiling and decomposition point with mono- or polyhydric alcohols | |
GB827718A (en) | Improvements in or relating to the manufacture of vinyl esters | |
US3350481A (en) | Monoesters of phosphonic acids | |
GB963882A (en) | Process for the manufacture of unsaturated phosphonic acid dichlorides | |
US2754322A (en) | Catalytic dehydrochlorination of alpha, beta-dichloropropionic acid acompounds | |
US2716668A (en) | Polyhalogenomethanes | |
GB1069078A (en) | Phosphorus compounds containing an arylsulphonic acid ester group and process for preparing them | |
US3391227A (en) | Monoesters of phosphonic acids | |
GB740444A (en) | Manufacture of sulphur derivatives of organic phosphorus compounds | |
US3361853A (en) | Monoesters of phosphonic acids | |
US3626038A (en) | Process far preparing diesters of cis-propenyl-phosphonic acid |