GB763636A - Improvements in or relating to vinyl ethers - Google Patents

Improvements in or relating to vinyl ethers

Info

Publication number
GB763636A
GB763636A GB9694/54A GB969454A GB763636A GB 763636 A GB763636 A GB 763636A GB 9694/54 A GB9694/54 A GB 9694/54A GB 969454 A GB969454 A GB 969454A GB 763636 A GB763636 A GB 763636A
Authority
GB
United Kingdom
Prior art keywords
vinyloxyethyl
methyl
vinyl
butyl
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9694/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB763636A publication Critical patent/GB763636A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14—Monomers containing only one unsaturated aliphatic radical
    • C08F16/28—Monomers containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

763,636. Polymers of vinyloxyalkylcarbamates. ROHM & HAAS CO. March 29, 1954 [April 10, 1953], No. 9094/54. Class 2 (6). [Also in Groups III, IV (b), IV (c), VI and VIII] One or more vinyloxyalkylcarbamates of formula wherein Z is a methylene or polymethylene group optionally containing hydrocarbon substituents and containing not more than seven carbon atoms; R is hydrogen or an alkyl, alkenyl, cyclohexyl or benzyl group; R‹ is a monovalent or divalent residue of an esterforming hydroxy compound (e.g. a hydrocarbon group optionally containing one or more ether or thioether linkages and/or chlorine or nitro substituents); n is 1 or 2; and R<SP>1</SP> and R<SP>11</SP> are alkyl groups and either or both may also be hydrogen when both R is other than hydrogen and Z is such that O and N are separated by a chain of 4C or more, alone or admixed with one or more other monomers are polymerized in bulk, aqueous emulsion or organic solution. in the presence of a polymerization catalyst. The other monomers may be acrylates (e.g. methyl and butyl acrylates), methacrylates (e.g. methyl, ethyl and butyl methacrylates), acrylonitrile, methacrylonitrile, acrylamides, methacrylamides, styrene, ureidoethyl vinyl ether, ureidopropyl vinyl ether, vinyl hydroxyethyl ether, vinyl esters (e.g. vinyl acetate, vinyl butyrate and vinyl laurate) or mixtures thereof. In aqueous emulsion the emulsifier may be an octylphenoxypolyethoxyethanol. Specified solvents are dimethylformamide and xylene. Exemplified vinyloxyalkyl carbamates are methyl and ethyl N - (vinyloxy - tert. - butyl) carbamates; ethylene, propylene, diethylene glycol and thiodiethylene bis - [N - (vinyloxy - tert. - butyl) carbamates]; methyl, allyl, benzyl, cyclohexyl, dodecyl and octadecyl N-vinyloxyethyl-N- methylcarbamates; methyl N-vinyloxyethyl- N-cyclohexylcarbamate; ethyl N-vinyloxyethyl - N - 2 - ethylhexylcarbamate; methyl N - vinyloxyethyl - N - α - methylbenzylcarbamate; methallyl N-vinyloxyethyl-N- ethylcarbamate; butyl N-vinyloxyethyl-N- butylcarbamate; ethyl 5-N-vinyloxypentylcarbamate; ethyl N-2-vinyloxyisobutylcarbamate; allyl N-vinyloxyethyl-N-butylcarbamate; methyl N-vinyloxyethylcarbamate and diethylene glycol bis - (N - vinyloxyethyl N- methylcarbamate). The catalyst may be azodiisobutyronitrile; azodiisobutyramide; dimethyl, diethyl or dibutyl azodiisobutyrate; azobis - (α : γ - dimethylvaleronitrile); azobis- (α - methylbutyronitrile); azobis - (α - methylvaleronitrile); dimethyl or diethyl azobismethylvalerate; a mercaptan; acetyl, caproyl, lauroyl or benzoyl peroxide; tert.-butyl hydroperoxide ; butyl perbenzoate; or ammonium, potassium or sodium persulfate (e.g. in conjunction with diethylenetriamine). Homopolymers containing an allyl group may be converted to cross-linked products by heating or by air drying in presence of cobalt compounds. The polymers may be deposited from solvents as hard films, if desired, after previous treatment with diethylenetriamine. Vinyloxyalkylcarbamate monomers having large substituents (e.g. ethyl N-vinyloxyethyl-N-2-ethylhexylcarbamate) may be employed as plasticizers for vinyl chloride polymers (e.g. vinyl chloride/vinyl acetate copolymer). Vinyloxyalkylcarbamate monomers and in particular diethylene glycol bis-(N-methyl-N-vinyloxyethylcarbamate) may be mixed with an adipic acid/maleic anhydride/propylene glycol condensate and benzoyl peroxide and the mixture used to impregnate fibre-glass sheets which are subsequently heated to 140‹ C.
GB9694/54A 1953-04-10 1954-03-29 Improvements in or relating to vinyl ethers Expired GB763636A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US763636TA 1953-04-10 1953-04-10

Publications (1)

Publication Number Publication Date
GB763636A true GB763636A (en) 1956-12-12

Family

ID=31975684

Family Applications (2)

Application Number Title Priority Date Filing Date
GB9694/54A Expired GB763636A (en) 1953-04-10 1954-03-29 Improvements in or relating to vinyl ethers
GB21063/56A Expired GB834575A (en) 1953-04-10 1956-07-06 Vinyl compounds

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB21063/56A Expired GB834575A (en) 1953-04-10 1956-07-06 Vinyl compounds

Country Status (3)

Country Link
DE (1) DE1028343B (en)
FR (2) FR1097938A (en)
GB (2) GB763636A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3144468A (en) * 1961-11-10 1964-08-11 Du Pont Alpha-cyanatomethoxy ethers

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1055525B (en) * 1955-07-15 1959-04-23 Rohm & Haas Process for the preparation of vinylthioalkyl carbamates

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3144468A (en) * 1961-11-10 1964-08-11 Du Pont Alpha-cyanatomethoxy ethers

Also Published As

Publication number Publication date
DE1028343B (en) 1958-04-17
FR75114E (en) 1961-03-13
GB834575A (en) 1960-05-11
FR1097938A (en) 1955-07-12

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