GB715099A - Improvements in the manufacture of polymer beads - Google Patents
Improvements in the manufacture of polymer beadsInfo
- Publication number
- GB715099A GB715099A GB9643/52A GB964352A GB715099A GB 715099 A GB715099 A GB 715099A GB 9643/52 A GB9643/52 A GB 9643/52A GB 964352 A GB964352 A GB 964352A GB 715099 A GB715099 A GB 715099A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymerization
- dispersing agent
- methyl
- ethyl
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Discrete, spherical beads are produced by vigorously agitating a monomer in a non-solvent liquid, particularly water, in the presence of a dispersing agent and a catalyst, stopping the agitation before any appreciable polymerization has taken place and permitting the polymerization to be completed while the mixture remains in a quiescent state. Monomers specified are styrene and/or methyl methacrylate, vinyl pyridine and mixtures of methyl methacrylate with divinyl benzene or diethylene glycol diallyl dicarbonate. The dispersing agent may be the sodium salts of N-oleyl-N-methyl taurine, 2-ethyl-2-methylundecanol-4-sulphate, N-lauroyl-N-N-methyl taurine and lauryl sulphate; the dioctyl ester of sodium sulphosuccinic acid, N-octadecyl tetrasodium (1 : 2-dicarboxyl ethyl sulphosuccinamate), diglycerol monolaurate, lauryl ether of polyethylene glycol, cetyl trimethyl ammonium chloride, mixtures of the above or starch. Catalysts specified are benzoyl, tetrahydronaphthalene, methyl ethyl ketone and hydrogen peroxides, cumene and t-butyl hydroperoxides and N-(a -azo-bis-isobutyronitrile). The polymerization may be carried out in an inert atmosphere and the temperature may be between 30 DEG and 75 DEG C. Beads of size 1 to 200 microns are obtained, the actual size being mainly controlled by the amount and nature of the dispersing agent used.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US715099XA | 1951-05-01 | 1951-05-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB715099A true GB715099A (en) | 1954-09-08 |
Family
ID=22101779
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9643/52A Expired GB715099A (en) | 1951-05-01 | 1952-04-17 | Improvements in the manufacture of polymer beads |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB715099A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2814833A (en) * | 1955-02-19 | 1957-12-03 | American Enka Corp | Method for preparing granular polyamides |
DE1110869B (en) * | 1959-04-25 | 1961-07-13 | Henkel & Cie Gmbh | Process for the production of solid, water-soluble polymers or copolymers |
US3468986A (en) * | 1966-11-15 | 1969-09-23 | David J Watanabe | Method for producing a solid particulate material |
-
1952
- 1952-04-17 GB GB9643/52A patent/GB715099A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2814833A (en) * | 1955-02-19 | 1957-12-03 | American Enka Corp | Method for preparing granular polyamides |
DE1110869B (en) * | 1959-04-25 | 1961-07-13 | Henkel & Cie Gmbh | Process for the production of solid, water-soluble polymers or copolymers |
US3468986A (en) * | 1966-11-15 | 1969-09-23 | David J Watanabe | Method for producing a solid particulate material |
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