GB695461A - Improvements in and relating to 2-thienyl-substituted silanes - Google Patents
Improvements in and relating to 2-thienyl-substituted silanesInfo
- Publication number
- GB695461A GB695461A GB14870/50A GB1487050A GB695461A GB 695461 A GB695461 A GB 695461A GB 14870/50 A GB14870/50 A GB 14870/50A GB 1487050 A GB1487050 A GB 1487050A GB 695461 A GB695461 A GB 695461A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thienyl
- phenyl
- formula
- methyl
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 2-thienyl-substituted silanes Chemical class 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- SUSFECFQWWLONT-UHFFFAOYSA-N C(C)[Si](OCC)(OCC)C=1SC=CC1 Chemical compound C(C)[Si](OCC)(OCC)C=1SC=CC1 SUSFECFQWWLONT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 239000007818 Grignard reagent Substances 0.000 abstract 1
- BGFPLLXDVFDKJC-UHFFFAOYSA-N benzyl-dichloro-thiophen-2-ylsilane Chemical compound C(C1=CC=CC=C1)[Si](Cl)(Cl)C=1SC=CC1 BGFPLLXDVFDKJC-UHFFFAOYSA-N 0.000 abstract 1
- UVUOYYJYKOPHBD-UHFFFAOYSA-N benzyl-diethoxy-thiophen-2-ylsilane Chemical compound C(C1=CC=CC=C1)[Si](OCC)(OCC)C=1SC=CC1 UVUOYYJYKOPHBD-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- URVDFKFLQPWXNK-UHFFFAOYSA-N bromo-cyclohexyl-dithiophen-2-ylsilane Chemical compound C1(CCCCC1)[Si](Br)(C=1SC=CC1)C=1SC=CC1 URVDFKFLQPWXNK-UHFFFAOYSA-N 0.000 abstract 1
- GWWDYTGWZSRIKA-UHFFFAOYSA-N bromo-didecyl-thiophen-2-ylsilane Chemical compound C(CCCCCCCCC)[Si](Br)(C=1SC=CC1)CCCCCCCCCC GWWDYTGWZSRIKA-UHFFFAOYSA-N 0.000 abstract 1
- AIDXLGSDURDKBW-UHFFFAOYSA-N butoxy-cyclohexyl-dithiophen-2-ylsilane Chemical compound C1(CCCCC1)[Si](OCCCC)(C=1SC=CC1)C=1SC=CC1 AIDXLGSDURDKBW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- DEPVFYAOAUKMFL-UHFFFAOYSA-N chloro-dimethyl-thiophen-2-ylsilane Chemical compound C[Si](C)(Cl)C1=CC=CS1 DEPVFYAOAUKMFL-UHFFFAOYSA-N 0.000 abstract 1
- HKEGBWIZUJCGKD-UHFFFAOYSA-N chloro-dipentyl-thiophen-2-ylsilane Chemical compound C(CCCC)[Si](Cl)(C=1SC=CC1)CCCCC HKEGBWIZUJCGKD-UHFFFAOYSA-N 0.000 abstract 1
- LAQQNSYDSMXKFH-UHFFFAOYSA-N chloro-diphenyl-thiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](Cl)(C=1SC=CC1)C1=CC=CC=C1 LAQQNSYDSMXKFH-UHFFFAOYSA-N 0.000 abstract 1
- OOKZCIYIBWJXTR-UHFFFAOYSA-N chloro-methyl-dithiophen-2-ylsilane Chemical compound C[Si](Cl)(C=1SC=CC1)C=1SC=CC1 OOKZCIYIBWJXTR-UHFFFAOYSA-N 0.000 abstract 1
- PFFSRZQENGMIMY-UHFFFAOYSA-N chloro-phenyl-dithiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](Cl)(C=1SC=CC1)C=1SC=CC1 PFFSRZQENGMIMY-UHFFFAOYSA-N 0.000 abstract 1
- CNTCEWHHXAYPGH-UHFFFAOYSA-N dibromo-ethyl-thiophen-2-ylsilane Chemical compound C(C)[Si](Br)(Br)C=1SC=CC1 CNTCEWHHXAYPGH-UHFFFAOYSA-N 0.000 abstract 1
- OMNMKYPGLQFGSI-UHFFFAOYSA-N dibromo-phenyl-thiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](Br)(Br)C=1SC=CC1 OMNMKYPGLQFGSI-UHFFFAOYSA-N 0.000 abstract 1
- SNJAALGWZAQAGC-UHFFFAOYSA-N dibutoxy-ethyl-thiophen-2-ylsilane Chemical compound C(C)[Si](OCCCC)(OCCCC)C=1SC=CC1 SNJAALGWZAQAGC-UHFFFAOYSA-N 0.000 abstract 1
- JCSHMBBSJGGQJE-UHFFFAOYSA-N dibutoxy-phenyl-thiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](OCCCC)(OCCCC)C=1SC=CC1 JCSHMBBSJGGQJE-UHFFFAOYSA-N 0.000 abstract 1
- UGFDJIXLQUMXLQ-UHFFFAOYSA-N dichloro-ethenyl-thiophen-2-ylsilane Chemical compound C=C[Si](Cl)(Cl)C1=CC=CS1 UGFDJIXLQUMXLQ-UHFFFAOYSA-N 0.000 abstract 1
- KQXGAPJWAMOGFO-UHFFFAOYSA-N dichloro-methyl-thiophen-2-ylsilane Chemical compound C[Si](Cl)(Cl)C=1SC=CC1 KQXGAPJWAMOGFO-UHFFFAOYSA-N 0.000 abstract 1
- FJXFGHSXGKECTD-UHFFFAOYSA-N dichloro-phenyl-thiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](C=1SC=CC1)(Cl)Cl FJXFGHSXGKECTD-UHFFFAOYSA-N 0.000 abstract 1
- OOLVMQQBGMOBMT-UHFFFAOYSA-N didecyl(4-thiophen-2-ylbutoxy)silane Chemical compound C(CCCCCCCCC)[SiH](OCCCCC=1SC=CC1)CCCCCCCCCC OOLVMQQBGMOBMT-UHFFFAOYSA-N 0.000 abstract 1
- XNGICWNYKDTYEV-UHFFFAOYSA-N diethoxy-methyl-thiophen-2-ylsilane Chemical compound C[Si](OCC)(OCC)C=1SC=CC1 XNGICWNYKDTYEV-UHFFFAOYSA-N 0.000 abstract 1
- ASRJNHXRAXDLSA-UHFFFAOYSA-N diethoxy-phenyl-thiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](OCC)(OCC)C=1SC=CC1 ASRJNHXRAXDLSA-UHFFFAOYSA-N 0.000 abstract 1
- YCXRFRNUIUSUJO-UHFFFAOYSA-N dimethyl(2-thiophen-2-ylethoxy)silane Chemical compound C[SiH](OCCC=1SC=CC1)C YCXRFRNUIUSUJO-UHFFFAOYSA-N 0.000 abstract 1
- ZWRLWSPTDOAMDB-UHFFFAOYSA-N dipentyl(2-thiophen-2-ylethoxy)silane Chemical compound C(CCCC)[SiH](OCCC=1SC=CC1)CCCCC ZWRLWSPTDOAMDB-UHFFFAOYSA-N 0.000 abstract 1
- UXYRBIXIJRZZIG-UHFFFAOYSA-N diphenyl(6-thiophen-2-ylhexoxy)silane Chemical compound C1(=CC=CC=C1)[SiH](OCCCCCCC=1SC=CC1)C1=CC=CC=C1 UXYRBIXIJRZZIG-UHFFFAOYSA-N 0.000 abstract 1
- LQFLFCSIYZFVND-UHFFFAOYSA-N dipropyl(3-thiophen-2-ylpropoxy)silane Chemical compound C(CC)[SiH](OCCCC=1SC=CC1)CCC LQFLFCSIYZFVND-UHFFFAOYSA-N 0.000 abstract 1
- UBAASZJFIVZCTA-UHFFFAOYSA-N ethenyl-bis(2-methylpropoxy)-thiophen-2-ylsilane Chemical compound C(=C)[Si](OCC(C)C)(OCC(C)C)C=1SC=CC1 UBAASZJFIVZCTA-UHFFFAOYSA-N 0.000 abstract 1
- LTNYBOWKBGKWCN-UHFFFAOYSA-N ethoxy-methyl-dithiophen-2-ylsilane Chemical compound C[Si](OCC)(C=1SC=CC1)C=1SC=CC1 LTNYBOWKBGKWCN-UHFFFAOYSA-N 0.000 abstract 1
- LGQCHXXWQUWDRB-UHFFFAOYSA-N ethoxy-phenyl-dithiophen-2-ylsilane Chemical compound C1(=CC=CC=C1)[Si](OCC)(C=1SC=CC1)C=1SC=CC1 LGQCHXXWQUWDRB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Thienylsilanes of the formula <FORM:0695461/IV (b)/1> wherein R1 is a monovalent hydrocarbon radical, Z is a halogen or an alkoxy radical of the formula OR in which R is a monovalent saturated hydrocarbon radical, and m and n are each equal to 1 or 2, the sum of m+n being not more than 3, are prepared by reacting a 2-thienyl Grignard reagent with a compound of the formula (R1)qSi(X)4-q, where R1 has th above significance, X is a halogen and q is 1 or 2, or a compound of the formula (R1)rSi(OR)4-r, where R1 and R have the above significance and r is 1 or 2, or by reacting a thienylsilane of the above formula in which Z is a halogen atom with an alcohol ROH where R is a monovalent saturated aliphatic radical. The radical X may be chlorine, bromine or fluorine or the ethoxy, propoxy, butoxy or hexoxy radicals. In the examples, the following compounds are prepared, methyl 2-thienyl dichlorosilane, methyl di-(2-thienyl) chlorosilane, dimethyl 2-thienyl-chlorosilane, phenyl 2-thienyl dichlorosilane, methyl 2-thienyl diethoxysilane, phenyl 2-thienyl diethoxysilane, methyl di-(2-thienyl) ethoxysilane and dimethyl 2-thienylethoxysilane. The following compounds are also mentioned:-2-thienyldichlorosilane, ethyl 2-thienyl dibromosilane, dipropyl and diamyl 2 - thienylchlorosilane, didecyl 2 - thienyl-bromosilane, phenyl 2 - thienyldibromosilane, diphenyl 2-thienylchlorosilane, phenyl di-(2-thienyl) chlorosilane, benzyl 2-thienyldichloro silane, cyclohexyl di(2-thienyl) bromosilane, vinyl 2-thienyldichlorosilane, allyl 2-thienyl-dichlorosilane, ethyl 2-thienyldiethoxysilane, ethyl 2-thienyldibutoxysilane, dipropyl 2-thienylpropoxysilane, diamyl 2 - thienylethoxysilane, didecyl 2 - thienylbutoxysilane, phenyl 2 - thienyldibutoxysilane, diphenyl 2 - thienylhexoxysilane, phenyl di-(2-thienyl) ethoxysilane, benzyl 2-thienyldiethoxysilane, cyclohexyl di-(2-thienyl) butoxysilane, vinyl 2-thienyldiisobutoxysilane and allyl 2-thienyldiethoxysilane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US695461XA | 1949-06-25 | 1949-06-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB695461A true GB695461A (en) | 1953-08-12 |
Family
ID=22089698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14870/50A Expired GB695461A (en) | 1949-06-25 | 1950-06-14 | Improvements in and relating to 2-thienyl-substituted silanes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB695461A (en) |
-
1950
- 1950-06-14 GB GB14870/50A patent/GB695461A/en not_active Expired
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