GB657599A - Method of improving the fire-and heat-resistance of materials and compositions for use therein - Google Patents
Method of improving the fire-and heat-resistance of materials and compositions for use thereinInfo
- Publication number
- GB657599A GB657599A GB13630/47A GB1363047A GB657599A GB 657599 A GB657599 A GB 657599A GB 13630/47 A GB13630/47 A GB 13630/47A GB 1363047 A GB1363047 A GB 1363047A GB 657599 A GB657599 A GB 657599A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- resin
- formaldehyde
- aldehydes
- phosphoric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A composition for imparting fire-resistance to combustible materials comprises a thermosetting resin salt of a basic nitrogen-containing anion exchange resin with at least 2 milli-equivalents per gram of said resin of a strong non-oxidizing inorganic acid. The inorganic acid, preferably having a dissociation constant of 10-3 or higher, may be hydrochloric acid or other hydrogen halide or a polyvalent acid such as sulphuric or phosphoric. The anion exchange (or acid-absorbent) resins are such basic resins as are capable of forming resin salts from which the acid is no longer completely removable by alkali or acid treatment and include those obtained when basic nitrogen-containing organic compounds such as amines or guanidine are condensed with aldehydes, hydroxy-aldehydes (e.g. sugars or starches) or with mixtures of aldehydes and ketones so that not all the basic groups are linked to aldehyde, e.g. by condensing (1) m-substituted aromatic amines or aromatic polyamines with aldehydes and/or carbohydrates, with or without ketones; (2) aliphatic polyalkylene polyamines with aldehydes or carbohydrates and ketones or phenols; (3) a strongly basic derivative of cyanamide such as guanidine or guanylurea with a weakly-basic derivative of cyanamide such as urea, thiourea, dicyandiamide, or melamine with an aldehyde and, optionally, a carbohydrate. The resins are combined with as much acid as possible which, in general, is about 15 milli-equivalents of acid per gram up to 25 milli-equivalents by forming the resin in the presence of the acid or treating it with aqueous acid. Combustible materials such as wallboard, fibreboard, cardboard, wood, plywood, fabrics and paper may be coated or impregnated with the resin salt. The latter may be in a low state of polymerization and be employed, for example, in an aqueous dispersion containing wheat paste, as an adhesive for laminar material or veneers, or for coating metal surfaces or may be dispersed in a heat-cured insoluble state, in a liquid medium containing a film-forming agent such as a drying oil, an alkyd, oil-modified alkyd, or other film-forming resin or a cellulose derivative and be employed as a coating composition. Pigments, plasticizers such as p-toluene sulphonamide and fillers may be added. In examples: (1) (a) guanidine carbonate and melamine were reacted with aqueous formaldehyde and concentrated phosphoric acid added until CO2 evolution stopped. The gel formed on heating the viscous dispersion was washed free of excess phosphoric acid; (b) the viscous dispersion may be used as a coating composition; (d) the gel may be ground with alkyd resin, titanium dioxide, thinner and cobalt and lead driers to give a coating composition; (e) guanidine carbonate and melamine were reacted with aqueous formaldehyde, concentrated phosphoric acid added and the mixture heated to form a gel which was washed and dispersed in an alcoholic solution of ethyl cellulose; (f) fabric was dipped into a liquid composition-similar to that of (e) and containing a plasticizer, e.g. p-toluene sulphonamide or urea; (g), (h) a dispersion similar to that of (b) was used as an adhesive both with, and without, wheat paste; (2) a urea, guanidine carbonate and formaldehyde product was treated with concentrated sulphuric acid; (3) a melamine, guanidine carbonate and formaldehyde product was treated with sulphuric acid; (4) m-phenylenediamine dihydrochloride was reacted with formaldehyde in the presence of concentrated hydrochloric acid to give a resin hydrochloride; (5) as in (4) with the addition of dicyandiamide; (6) a phenol, triethylene tetramine and formaldehyde resin was treated with phosphoric acid; (7) triethylene tetramine, phosphoric acid, aqueous formaldehyde and acetone were refluxed; (8) deAcidite ionexchanger resin was treated with phosphoric acid, and washed, the washed product being mixed into a varnish. U.S.A. Specifications 2,198,874, 2,246,527, 2,251,234, 2,259,169, 2,290,345, 2,341,907, 2,354,671, 2,356,151 and 2,362,086 are referred to. The Specification as open to inspection under Sect. 91 comprises also the use of the solid resin salt in moulding or as a dust to protect combustible material against fire. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US657599XA | 1946-05-22 | 1946-05-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB657599A true GB657599A (en) | 1951-09-19 |
Family
ID=22064903
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13630/47A Expired GB657599A (en) | 1946-05-22 | 1947-05-21 | Method of improving the fire-and heat-resistance of materials and compositions for use therein |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB657599A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4219456A (en) * | 1977-12-21 | 1980-08-26 | Deutsche Gold- Und Silber Scheideanstalt Vormals Roessler | Flame retardant agent solution of phosphoric acid containing condensate of guanidine and formaldehyde compatible with formaldehyde resin solutions |
DE102007005527A1 (en) * | 2007-02-03 | 2008-08-07 | Alzchem Trostberg Gmbh | Process for treating wood parts |
-
1947
- 1947-05-21 GB GB13630/47A patent/GB657599A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4219456A (en) * | 1977-12-21 | 1980-08-26 | Deutsche Gold- Und Silber Scheideanstalt Vormals Roessler | Flame retardant agent solution of phosphoric acid containing condensate of guanidine and formaldehyde compatible with formaldehyde resin solutions |
DE102007005527A1 (en) * | 2007-02-03 | 2008-08-07 | Alzchem Trostberg Gmbh | Process for treating wood parts |
US8445072B2 (en) | 2007-02-03 | 2013-05-21 | Alzchem Trostberg Gmbh | Method for treating wooden parts |
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