GB604746A - Composite selenium electrode - Google Patents
Composite selenium electrodeInfo
- Publication number
- GB604746A GB604746A GB2273/44A GB227344A GB604746A GB 604746 A GB604746 A GB 604746A GB 2273/44 A GB2273/44 A GB 2273/44A GB 227344 A GB227344 A GB 227344A GB 604746 A GB604746 A GB 604746A
- Authority
- GB
- United Kingdom
- Prior art keywords
- selenium
- carbon
- electrode
- mixture
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052711 selenium Inorganic materials 0.000 title abstract 6
- 239000011669 selenium Substances 0.000 title abstract 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title abstract 5
- 239000002131 composite material Substances 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- 229910052799 carbon Inorganic materials 0.000 abstract 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 238000004070 electrodeposition Methods 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052737 gold Inorganic materials 0.000 abstract 2
- 239000010931 gold Substances 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 125000003748 selenium group Chemical group *[Se]* 0.000 abstract 2
- 229910003599 H2SeO4 Inorganic materials 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 229910018162 SeO2 Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 238000000137 annealing Methods 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 239000011152 fibreglass Substances 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 238000007747 plating Methods 0.000 abstract 1
- SPVXKVOXSXTJOY-UHFFFAOYSA-N selane Chemical compound [SeH2] SPVXKVOXSXTJOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000058 selane Inorganic materials 0.000 abstract 1
- QYHFIVBSNOWOCQ-UHFFFAOYSA-N selenic acid Chemical compound O[Se](O)(=O)=O QYHFIVBSNOWOCQ-UHFFFAOYSA-N 0.000 abstract 1
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B19/00—Selenium; Tellurium; Compounds thereof
- C01B19/02—Elemental selenium or tellurium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/06—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising selenium or tellurium in uncombined form other than as impurities in semiconductor bodies of other materials
- H01L21/10—Preliminary treatment of the selenium or tellurium, its application to the foundation plate, or the subsequent treatment of the combination
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/06—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising selenium or tellurium in uncombined form other than as impurities in semiconductor bodies of other materials
- H01L21/10—Preliminary treatment of the selenium or tellurium, its application to the foundation plate, or the subsequent treatment of the combination
- H01L21/101—Application of the selenium or tellurium to the foundation plate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/06—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising selenium or tellurium in uncombined form other than as impurities in semiconductor bodies of other materials
- H01L21/10—Preliminary treatment of the selenium or tellurium, its application to the foundation plate, or the subsequent treatment of the combination
- H01L21/105—Treatment of the surface of the selenium or tellurium layer after having been made conductive
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
604,746. Electrodeposition of selenium. STANDARD TELEPHONES & CABLES, Ltd. Feb. 7, 1944, No. 2273. Convention date, Jan. 5, 1943. [Class 41] [Also in Group V] A low-resistivity electrode suitable for the electro-deposition of selenium, comprises a mixture of selenium and one or more materials from the group carbon, gold, platinum, and palladium. The electrode may be used as an anode with a plating solution comprising SeO2 dissolved in dilute H2SO, H2SeO4, HNO3, or HCl, as described in Specification 592,165, or as a cathode in the anodic deposition from H2Se derived from dilute H2SO4 as described in Specification 579,851. A mixture of 10- 75 per cent by weight of carbon powder and the balance selenium powder is heated in a mould to a temperature causing sintering or preferably above the melting-point of selenium, and then allowed to cool. The selenium is then preferably reduced to metallic form by annealing below the melting-point. Alternatively, the mixture may be compressed with or without heating, in which case the carbon can be as low as 2.5 per cent. Other mixtures referred to are 20 per cent and 28.5 per cent of carbon. The finished electrode 16, Fig. 2, is fitted with a conducting 'core 17 of gold, platinum, or graphite, or'the core may enter the electrode so little as not to be immersed in the electrolyte, Fig. 4 (not shown). In Fig. 5, a porous, ceramic cup 20 is placed round a cast or compressed mixture 21 for use as an anode. Other porous containers comprise a bag of fibre glass, and a glass tube having a porous end-piece made of sintered glass, the porous container in each case serving to retain deposited carbon, (Figs. 6, 7, not shown).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US471346A US2428055A (en) | 1943-01-05 | 1943-01-05 | Composite selenium electrode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB604746A true GB604746A (en) | 1948-07-09 |
Family
ID=23871272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2273/44A Expired GB604746A (en) | 1943-01-05 | 1944-02-07 | Composite selenium electrode |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2428055A (en) |
| GB (1) | GB604746A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3239444A (en) * | 1962-02-08 | 1966-03-08 | Honeywell Inc | Oxygen sensing polarographic cell |
| US4640744A (en) * | 1984-01-23 | 1987-02-03 | Standard Oil Company (Indiana) | Amorphous carbon electrodes and their use in electrochemical cells |
| CN105070892B (en) | 2015-09-22 | 2018-03-06 | 中国科学院化学研究所 | A kind of preparation method and application of selenium carbon complex |
| US11588149B2 (en) | 2015-09-22 | 2023-02-21 | Ii-Vi Delaware, Inc. | Immobilized selenium in a porous carbon with the presence of oxygen, a method of making, and uses of immobilized selenium in a rechargeable battery |
| US11784303B2 (en) | 2015-09-22 | 2023-10-10 | Ii-Vi Delaware, Inc. | Immobilized chalcogen and use thereof in a rechargeable battery |
| US10734638B2 (en) | 2015-09-22 | 2020-08-04 | Ii-Vi Delaware, Inc. | Immobilized selenium, a method of making, and uses of immobilized selenium in a rechargeable battery |
| WO2017143021A1 (en) * | 2016-02-17 | 2017-08-24 | Ii-Vi Incorporated | Immobilized selenium, a method of making, and uses of immobilized selenium in a rechargeable battery |
| US11870059B2 (en) | 2017-02-16 | 2024-01-09 | Consejo Superior De Investigaciones Cientificas (Csic) | Immobilized selenium in a porous carbon with the presence of oxygen, a method of making, and uses of immobilized selenium in a rechargeable battery |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US312948A (en) * | 1885-02-24 | Thomas bmoey atkinson | ||
| US504703A (en) * | 1893-09-12 | August breuee | ||
| US636142A (en) * | 1899-07-31 | 1899-10-31 | Albert Edward Hodgson | Secondary battery. |
| US893565A (en) * | 1903-04-18 | 1908-07-14 | Henry Spencer Blackmore | Electrode. |
| US877408A (en) * | 1904-03-17 | 1908-01-21 | Francis M F Cazin | Manufacture of electric incandescent lamps. |
| US779733A (en) * | 1904-06-28 | 1905-01-10 | Union Carbide Corp | Electrode. |
| US1999573A (en) * | 1930-08-29 | 1935-04-30 | William W Odell | Special carbon black |
| US2301756A (en) * | 1941-03-05 | 1942-11-10 | Battelle Memorial Institute | Powder metal bearing and method of making the same |
-
1943
- 1943-01-05 US US471346A patent/US2428055A/en not_active Expired - Lifetime
-
1944
- 1944-02-07 GB GB2273/44A patent/GB604746A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2428055A (en) | 1947-09-30 |
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