GB600917A - Emulsion polymerization - Google Patents

Emulsion polymerization

Info

Publication number
GB600917A
GB600917A GB16975/44A GB1697544A GB600917A GB 600917 A GB600917 A GB 600917A GB 16975/44 A GB16975/44 A GB 16975/44A GB 1697544 A GB1697544 A GB 1697544A GB 600917 A GB600917 A GB 600917A
Authority
GB
United Kingdom
Prior art keywords
glycol
maleate
vinyl
styrene
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16975/44A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB600917A publication Critical patent/GB600917A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
    • B25B—TOOLS OR BENCH DEVICES NOT OTHERWISE PROVIDED FOR, FOR FASTENING, CONNECTING, DISENGAGING OR HOLDING
    • B25B13/00—Spanners; Wrenches
    • B25B13/48—Spanners; Wrenches for special purposes
    • B25B13/50—Spanners; Wrenches for special purposes for operating on work of special profile, e.g. pipes
    • B25B13/5008—Spanners; Wrenches for special purposes for operating on work of special profile, e.g. pipes for operating on pipes or cylindrical objects
    • B25B13/5016—Spanners; Wrenches for special purposes for operating on work of special profile, e.g. pipes for operating on pipes or cylindrical objects by externally gripping the pipe
    • B25B13/5025—Spanners; Wrenches for special purposes for operating on work of special profile, e.g. pipes for operating on pipes or cylindrical objects by externally gripping the pipe using a pipe wrench type tool
    • B25B13/5041—Spanners; Wrenches for special purposes for operating on work of special profile, e.g. pipes for operating on pipes or cylindrical objects by externally gripping the pipe using a pipe wrench type tool with movable or adjustable jaws
    • B25B13/5058—Linearly moving or adjustable, e.g. with an additional small tilting or rocking movement
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D06M15/51—Unsaturated polymerisable polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

A process comprises polymerizing to substantially insoluble form a homogenous mixture including at least one material containing a single ethylenic linkage and an unsaturated alkyd resin, said mixture being emulsified in water before polymerization. The unsaturated alkyd resins are preferably produced by the esterification of an alpha-beta-unsaturated polycarboxylic acid with a polyhydric alcohol, particularly a glycol. An emulsifying agent may be present, although some of the alkyd resins may themselves be active as emulsifiers, e.g. hexa-, hepta- and octaethylene glycol maleates. Emulsifiers specified are diamyl, dihexyl, dioctyl sulphosuccinic esters and salts, salts of alkylated naphthalene sulphonic acids, long chain quaternary ammonium compounds, sulphonated or sulphated higher alcohols and their salts, sulphonated oils, glycol oleates and linoleates, mineral oil sulphonates, aromatic sulphonates, wax acid soaps, triethanolamine soaps, monoglycerol linoleates, amino sulphonates and sulphates, ammoniacal or other alkaline caseins, lecithin, cholesterol, saponin, gelatine and emulsifying gums such as gum arabic. Surface tension modifiers such as cyclohexanol, benzyl alcohol and pine oil may be present. Specified materials containing a single ethylenic linkage are styrene, o-, m- or p-methyl styrene, alpha-methyl styrene, 2,4-dimethyl styrene, 2,3-diethyl styrene, 2-5-dimethyl styrene, isopropenyltoluene, vinyl naphthalene, the methyl, ethyl, propyl, butyl, cyclohexyl and cetyl esters of acrylic and methacrylic acids, vinyl acetate, vinyl butyrate, vinyl laurate, vinyl stearate, acrolein, methacrolein, acrylonitrile, methacrylonitrile, vinyl ether, methacrylamide, acrylamide, diallyl phthalate, diallyl succinate, triallyl carballylate and triallyl phosphate. Specified alkyd resins are diethylene glycol maleate, alpha-propylene glycol maleate, hexaethylene glycol maleate, heptaethylene glycol maleate, octaethylene glycol maleate, dodecaethylene glycol maleate, decamethylene glycol maleate, octadecandiol maleate, the maleic esters of 2-2-dimethyl-propanediol-1-3, of 1-3-butanediol, of 1-2-propanediol and of 2-ethyl-2-butyl-butanediol-1-3, glycerol maleate undecylenate, triethyleneglycol chlormaleate, triethylene glycol terpene maleate, ethylene glycol fumarate and diethylene glycol fumarate. Polymerization catalysts include the organic superoxides, aldehydic and acidic peroxides, soluble cobalt salts and p-toluene sulphonic acid. Polymerization inhibitors which may be present include hydroquinone, benzaldehyde, ascorbic acid, isoascorbic acid, resorcinol, tannin, sym.-di-beta-naphthyl p-phenyldiamine and phenolic resins. Other resins, e.g. melamine-formaldehyde, urea-formaldehyde, cellulose esters and ethers, phenolic resins, alkyd resins and ester gum may be present. The alkyd resins may be prepared by the esterification of an alpha-beta-unsaturated organic acid with a polyhydric alcohol and may be modified with monohydric alcohols, monobasic acids and dibasic acids.
GB16975/44A 1944-09-05 Emulsion polymerization Expired GB600917A (en)

Publications (1)

Publication Number Publication Date
GB600917A true GB600917A (en) 1948-04-22

Family

ID=1732722

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16975/44A Expired GB600917A (en) 1944-09-05 Emulsion polymerization

Country Status (1)

Country Link
GB (1) GB600917A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1054620B (en) * 1956-10-17 1959-04-09 Bayer Ag Solvent-free, air-drying paints
DE1121732B (en) * 1953-05-11 1962-01-11 Telefunken Patent Electrolytic capacitor
DE1191569B (en) * 1962-08-10 1965-04-22 Kalk Chemische Fabrik Gmbh Process for the production of self-extinguishing, fine-pored polyester molded parts
DE1198551B (en) * 1962-03-31 1965-08-12 Herberts & Co Gmbh Dr Kurt Process for the production of glass fiber mats or fabrics which are pre-impregnated with unsaturated polyester
DE1199982B (en) * 1962-04-06 1965-09-02 Kalk Chemische Fabrik Gmbh Manufacture of fine-pored molded parts from polyester molding compounds
DE1220606B (en) * 1961-11-02 1966-07-07 Dr Guenther Will Process for producing porous molded parts

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1121732B (en) * 1953-05-11 1962-01-11 Telefunken Patent Electrolytic capacitor
DE1054620B (en) * 1956-10-17 1959-04-09 Bayer Ag Solvent-free, air-drying paints
DE1220606B (en) * 1961-11-02 1966-07-07 Dr Guenther Will Process for producing porous molded parts
DE1198551B (en) * 1962-03-31 1965-08-12 Herberts & Co Gmbh Dr Kurt Process for the production of glass fiber mats or fabrics which are pre-impregnated with unsaturated polyester
DE1199982B (en) * 1962-04-06 1965-09-02 Kalk Chemische Fabrik Gmbh Manufacture of fine-pored molded parts from polyester molding compounds
DE1191569B (en) * 1962-08-10 1965-04-22 Kalk Chemische Fabrik Gmbh Process for the production of self-extinguishing, fine-pored polyester molded parts

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