GB453422A - Process for the manufacture of condensation products of olefines - Google Patents
Process for the manufacture of condensation products of olefinesInfo
- Publication number
- GB453422A GB453422A GB361635A GB361635A GB453422A GB 453422 A GB453422 A GB 453422A GB 361635 A GB361635 A GB 361635A GB 361635 A GB361635 A GB 361635A GB 453422 A GB453422 A GB 453422A
- Authority
- GB
- United Kingdom
- Prior art keywords
- boron fluoride
- compounds
- naphthalene
- treated
- olefines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/68—Catalytic processes with halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1213—Boron fluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Mono-olefines are condensed with aromatic compounds in the presence of addition compounds obtained from boron fluoride containing at least one hydrogen atom capable of dissociation, e.g. compounds of boron fluoride with water such as the dihydrate, with alcohols such as the diethylalcoholate, or with acids such as the diacetate or the compounds with phosphoric acid described in Specification 451,359, [Group III]. Olefines specified are ethylene, propylene, isohexylene, and nonylene; aromatic compounds specified are benzene and its homologues, polynuclear hydrocarbons such as naphthalene and hydroxy compounds such as phenols. Elevated temperatures and pressures are preferable. In examples: (1) naphthalene is treated with ethylene or propylene in presence of boron fluoride dihydrate; (2) naphthalene is treated with isononylene in presence of a compound obtained from boron fluoride and phosphoric acid; (3) phenol is treated with propylene in presence of boron fluoride dihydrate; (5) naphthalene is treated with isohexylene in presence of the dialcoholate of boron fluoride with ethyl alcohol. Specification 307,802, [Class 2 (iii)], also is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB361635A GB453422A (en) | 1935-02-04 | 1935-02-04 | Process for the manufacture of condensation products of olefines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB361635A GB453422A (en) | 1935-02-04 | 1935-02-04 | Process for the manufacture of condensation products of olefines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB453422A true GB453422A (en) | 1936-09-04 |
Family
ID=9761678
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB361635A Expired GB453422A (en) | 1935-02-04 | 1935-02-04 | Process for the manufacture of condensation products of olefines |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB453422A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2425839A (en) * | 1942-02-05 | 1947-08-19 | Phillips Petroleum Co | Catalytic alkylation of aromatic hydrocarbons |
US2469823A (en) * | 1944-11-29 | 1949-05-10 | Socony Vacuum Oil Co Inc | Alkylation of thiophene |
US2471922A (en) * | 1944-06-22 | 1949-05-31 | Phillips Petroleum Co | Production of aromatic derivatives |
US2544818A (en) * | 1945-11-16 | 1951-03-13 | Phillips Petroleum Co | Alkylation of phenols |
US2563073A (en) * | 1946-09-13 | 1951-08-07 | Universal Oil Prod Co | Haloalkylation of thiophene |
-
1935
- 1935-02-04 GB GB361635A patent/GB453422A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2425839A (en) * | 1942-02-05 | 1947-08-19 | Phillips Petroleum Co | Catalytic alkylation of aromatic hydrocarbons |
US2471922A (en) * | 1944-06-22 | 1949-05-31 | Phillips Petroleum Co | Production of aromatic derivatives |
US2469823A (en) * | 1944-11-29 | 1949-05-10 | Socony Vacuum Oil Co Inc | Alkylation of thiophene |
US2544818A (en) * | 1945-11-16 | 1951-03-13 | Phillips Petroleum Co | Alkylation of phenols |
US2563073A (en) * | 1946-09-13 | 1951-08-07 | Universal Oil Prod Co | Haloalkylation of thiophene |
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